A closed expression for the harmonic oscillator wave function after the passage of a linear signal with arbitrary time dependence is derived. Transition probabilities are simple to express in terms of Laguerre polynomials. Spontaneous transitions are neglected. The exact result is of some interest for the physics of short laser pulses, since it may serve as an accuracy test for numerical methods.
We outline a general method of obtaining exact solutions of Schroedinger equations with a position dependent effective mass. Exact solutions of several potentials including shape invariant potentials have also been obtained.
The intertwining operator technique is applied to difference Schroedinger equations with operator-valued coefficients. It is shown that these equations appear naturally when a discrete basis is used for solving a multichannel Schroedinger equation. New families of exactly solvable multichannel Hamiltonians are found.
We construct a general algorithm generating the analytic eigenfunctions as well as eigenvalues of one-dimensional stationary Schroedinger Hamiltonians. Both exact and quasi-exact Hamiltonians enter our formalism but we focus on quasi-exact interactions for which no such general approach has been considered before. In particular we concentrate on a generalized sextic oscillator but also on the Lame and the screened Coulomb potentials.
A supersymmetric technique for the solution of the effective mass Schrö% dinger equation is proposed. Exact solutions of the Schroedinger equation corresponding to a number of potentials are obtained. The potentials are fully isospectral with the original potentials. The conditions for the shape invariance of the potentials are discussed.
We propose a general method for constructing quasi-exactly solvable potentials with three analytic eigenstates. These potentials can be real or complex functions but the spectrum is real. A comparison with other methods is also performed.
An algebraic method of constructing potentials for which the Schroedinger equation with position dependent mass can be solved exactly is presented. A general form of the generators of su(1,1) algebra has been employed with a unified approach to the problem. Our systematic approach reproduces a number of earlier results and also leads to some novelties. We show that the solutions of the Schroedinger equation with position dependent mass are free from the choice of parameters for position dependent mass. Two classes of potentials are constructed that include almost all exactly solvable potential…
It is shown that the eigenvalue problem for the Hamiltonians of the standard form, $H=p^2/(2m)+V(x)$, is equivalent to the classical dynamical equation for certain harmonic oscillators with time-dependent frequency. This is another indication of the central role played by time-dependent harmonic oscillators in quantum mechanics. The utility of the known results for eigenvalue problem in the solution of the dynamical equations of a class of time-dependent harmonic oscillators is also pointed out.
It is shown how using the classical Hamilton-Jacobi equation one can arrive at the time-dependent wave equation. Although the former equation was originally used by E.Schroedinger to get the wave equation, we propose a different approach. In the first place, we do not use the principle of least action and, in addition, we arrive at the time-dependent equation, while Schroedinger (in his first seminal paper) used the least action principle and obtained the stationary wave equation. The proposed approach works for any classical Hamilton-Jacobi equation. In addition, by introducing information lo…
We construct arbitrary-order Darboux transformations for Schroedinger equations with energy-dependent potential and position-dependent mass within the Dunkl formalism. Our construction is based on a point transformation that interrelates our equations with the standard Schroedinger case. We apply our method to generate several solvable Dunkl-Schroedinger equations.
We solve the parametric generalized effective Schrödinger equation with a specific choice of posi-tion-dependent mass function and Morse oscillator potential by means of the Nikiforov-Uvarov (NU) method combined with the Pekeris approximation scheme. All bound-state energies are found explicitly and all corresponding radial wave functions are built analytically. We choose the Weyl or Li and Kuhn ordering for the ambiguity parameters in our numerical work to calculate the energy spectrum for a few and diatomic molecules with arbitrary vibration and rotation quantum numbers and different positio…
Two families of quasi exactly solvable 2*2 matrix Schroedinger operators are constructed. The first one is based on a polynomial matrix potential and depends on three parameters. The second is a one-parameter generalisation of the scalar Lame equation. The relationship between these operators and QES Hamiltonians already considered in the literature is pointed out.
It is shown that for a class of position dependent mass Schroedinger equation the shape invariance condition is equivalent to a potential symmetry algebra. Explicit realization of such algebras have been obtained for some shape invariant potentials.
We present a highly accurate method for solving single-active-electron (SAE) atomic eigenset in momentum space. The trouble of Coulomb kernel singularity is bypassed with numerical quadrature, which is simple but effective. The complicated Lande regularization method is no longer necessary. The data of accuracy for some low-lying states of the hydrogen and SAE helium atom were tabulated. Two examples of using the generated eigenset to solve the hydrogen atom under strong-field laser pulses were shown. The momentum and the coordinate representation are complementary to each other in quantum mec…
We derive an exact propagation scheme for nonlinear Schroedinger equations. This scheme is entirely analogous to the propagation of linear Schroedinger equations. We accomplish this by defining a special operator whose algebraic properties ensure the correct propagation. As applications, we provide a simple proof of a recent conjecture regarding higher-order integrators for the Gross-Pitaevskii equation, extend it to multi-component equations, and to a new class of integrators.
Within the framework of self-adjoint operator of time in non-relativistic quantum mechanics some properties of solutions of Schroedinger equation, related to Hilbert space formalism, are investigated for two types of time dependent Hamiltonian.
A new class of quasi exactly solvable potentials with a variable mass in the Schroedinger equation is presented. We have derived a general expression for the potentials also including Natanzon confluent potentials. The general solution of the Schroedinger equation is determined and the eigenstates are expressed in terms of the orthogonal polynomials.
We investigate wavepacket solutions for time-dependent Schoedinger equation in the presence of an exponentially decaying potential. Assuming for travelling wave solutions the phase to be a linear combination of the space and time coordinates, we obtain two distinct wavepacket solutions for the Schroedinger equation. The wavepackets counterpropagate in space at a constant velocity without any distortion or spreading thus retain their initial form at arbitrarily large distances.
Systems governed by the Non-linear Schroedinger Equation (NLSE) with various external PT-symmetric potentials are considered. Exact solutions have been obtained for the same through the method of ansatz, some of them being solitonic in nature. It is found that only the unbroken PT-symmetric phase is realized in these systems, characterized by real energies.
Some exactly solvable potentials in the position dependent mass background are generated whose bound states are given in terms of Laguerre- or Jacobi-type $X_1$ exceptional orthogonal polynomials. These potentials are shown to be shape invariant and isospectral to the potentials whose bound state solutions involve classical Laguerre or Jacobi polynomials.
By assuming that a particle of energy hbar.omega is actually a dissipative system maintained in a nonequilibrium steady state by a constant throughput of energy (heat flow), the exact Schroedinger equation is derived, both for conservative and nonconservative systems. Thereby, only universal properties of oscillators and nonequilibrium thermostatting are used, such that a maximal model independence of the hypothesised sub-quantum physics is guaranteed. It is claimed that this represents the shortest derivation of the Schroedinger equation from (modern) classical physics in the literature, and …
We outline a method based on successive canonical transformations which yields a product expansion for the evolution operator of a general (possibly non-Hermitian) Hamiltonian. For a class of such Hamiltonians this expansion involves a finite number of terms, and our method gives the exact solution of the corresponding time-dependent Schroedinger equation. We apply this method to study the dynamics of a general nondegenerate two-level quantum system, a time-dependent classical harmonic oscillator, and a degenerate system consisting of a spin 1 particle interacting with a time-dependent electri…
A revised iterative method based on Green function defined by quadratures along a single trajectory is proposed to solve the low-lying quantum wave function for Schroedinger equation. Specially a new expression of the perturbed energy is obtained, which is much simpler than the traditional one. The method is applied to solve the unharmonic oscillator potential. The revised iteration procedure gives exactly the same result as those based on the single trajectory quadrature method. A comparison of the revised iteration method to the old one is made using the example of Stark effect. The obtained…
A useful semiclassical method to calculate eigenfunctions of the Schroedinger equation is the mapping to a well-known ordinary differential equation, as for example Airy's equation. In this paper we generalize the mapping procedure to the nonlinear Schroedinger equation or Gross-Pitaevskii equation describing the macroscopic wave function of a Bose-Einstein condensate. The nonlinear Schroedinger equation is mapped to the second Painleve equation, which is one of the best-known differential equations with a cubic nonlinearity. A quantization condition is derived from the connection formulae of …
The following comparison rules for the discrete spectrum of the position-dependent mass (PDM) Schroedinger equation are established. (i) If a constant mass $m_0$ and a PDM $m(x)$ are ordered everywhere, that is either $m_0\leq m(x)$ or $m_0\geq m(x)$, then the corresponding eigenvalues of the constant-mass Hamiltonian and of the PDM Hamiltonian with the same potential and the BenDaniel-Duke ambiguity parameters are ordered. (ii) The corresponding eigenvalues of PDM Hamiltonians with the different sets of ambiguity parameters are ordered if $\nabla^2 (1/m(x))$ has a definite sign. We prove thes…
The stationary Schroedinger equation of the harmonic oscillator is deformed by a Darboux transformation to construct time-dependent potentials with the oscillator profile. The Darboux (supersymmetric or factorization) method is usually developed in the spatial variables of the Schroedinger equation. Here we follow a variation introduced by Bagrov, Samsonov and Shekoyan to include the time-variable as a parameter of the transformation.
We solve the Schroedinger equation for an interacting spin-chain locally coupled to a quantum environment with a specific degeneracy structure. The reduced dynamics of the whole spin-chain as well as of single spins is analyzed. We show, that the total spin-chain relaxes to a thermal equilibrium state independently of the internal interaction strength. In contrast, the asymptotic states of each individual spin are thermal for weak but non-thermal for stronger spin-spin coupling. The transition between both scenarios is found for couplings of the order of $0.1 \times ΔE$, with $ΔE$ denoting the…
A new convenient method to diagonalize the non-relativistic many-body Schroedinger equation with two-body central potentials is derived. It combines kinematic rotations (democracy transformations) and exact calculation of overlap integrals between bases with different sets of mass-scaled Jacobi coordinates, thereby allowing for a great simplification of this formidable problem. We validate our method by obtaining a perfect correspondence with the exactly solvable three-body ($N=3$) Calogero model in 1D.
We present the quantum mechanics problem of the one-dimensional Schroedinger equation with the trigonometric Rosen-Morse potential. This potential is of possible interest to quark physics in so far as it captures the essentials of the QCD quark-gluon dynamics and (i) interpolates between a Coulomb-like potential (associated with one-gluon exchange) and the infinite wall potential (associated with asymptotic freedom), (ii) reproduces in the intermediary region the linear confinement potential (associated with multi-gluon self-interactions) as established by lattice QCD calculations of hadron pr…
Time-dependent Schroedinger equation represents the basis of any quantum-theoretical approach. The question concerning its proper content in comparison to the classical physics has not been, however, fully answered until now. It will be shown that there is one-to-one physical correspondence between basic solutions (represented always by one Hamiltonian eigenfunction only) and classical ones, as the non-zero quantum potential has not any physical sense, representing only the "numerical" difference between Hamilton principal function and the phase of corresponding wave function in the case of no…
This is the third part of a paper about non-relativistic Schroedinger theory on q-deformed quantum spaces like the braided line or the three-dimensional q-deformed Euclidean space. Propagators for the free q-deformed particle are derived and their basic properties are discussed. A time-dependent formulation of scattering is proposed. In this respect, q-analogs of the Lippmann-Schwinger equation are given. Expressions for their iterative solutions are written down. It is shown how to calculate S-matrices and transition probabilities. Furthermore, attention is focused on the question what become…
A transformation is found between the one dimensional Schroedinger equation and a pendulum problem. It is demonstrated how to construct exact solutions with the resulted pendulum equation. The relation of this transformation to the Zakharov-Shabat equations is pointed out.
An exactly solvable position-dependent mass Schrödinger equation in two dimensions, depicting a particle moving in a semi-infinite layer, is re-examined in the light of recent theories describing superintegrable two-dimensional systems with integrals of motion that are quadratic functions of the momenta. To get the energy spectrum a quadratic algebra approach is used together with a realization in terms of deformed parafermionic oscillator operators. In this process, the importance of supplementing algebraic considerations with a proper treatment of boundary conditions for selecting physical w…
An alternative method is proposed for deriving the time dependent Schroedinger equation from the pictures of wave and matrix mechanics. The derivation is of a mixed classical quantum character, since time is treated as a classical variable, thus avoiding any controversy over its meaning in quantum mechanics. The derivation method proposed in this paper requires no ad hoc assumption and avoids going through a second-order differential equation that can be reduced to the well known time-dependent Schroedinger equation only postulating a complex wavefunction with an exponential time dependence, a…
We constructed the representation of contextual probabilistic dynamics in the complex Hilbert space. Thus dynamics of the wave function can be considered as Hilbert space projections of realistic dynamics in a ``prespace''. The basic condition for representing of the prespace-dynamics is the law of statistical conservation of energy -- conservation of probabilities. Construction of the dynamical representation is an important step in the development of contextual statistical viewpoint to quantum processes. But the contextual statistical model is essentially more general than the quantum one. T…
The "main road" open by de Broglie's and Schroedinger's discovery of matter waves and of their eigen-functions branched off, as is well known, into different "sub-routes". The most widely accepted one is Standard Quantum Mechanics (SQM), interpreting the time-dependent Schroedinger equation as the basic evolution law of a wave-packet which represents the simultaneous probabilistic permanence of a particle in its full set of eigenstates. Another "sub-route" is offered by Bohm's Mechanics, able to reproduce the same results of SQM, while interpreting the stream-lines of the probability current d…
Schroedinger equation with potentials of the Kratzer plus polynomial type (say, quartic V(r) = A r^4 +B r^3 + C r^2+D r + F/r + G/r^2 etc) is considered. A new method of exact construction of some of its bound states is then proposed. it is based on the Taylor series terminated rigorously after N+1 terms at specific couplings and energies. This enables us to find the exact, complete and compact unperturbed solution of the Magyari's N+2 coupled and nonlinear algebraic conditions of the termination in the strong-coupling regime with G \to \infty. Next, at G < \infty, we adapt the Rayleigh-Schroe…
The quantum jump approach, where pairs of state vectors follow Stochastic Schroedinger Equation (SSE) in order to treat the exact quantum dynamics of two interacting systems, is first described. In this work the non-uniqueness of such stochastic Schroedinger equations is investigated to propose strategies to optimize the stochastic paths and reduce statistical fluctuations. In the proposed method, called the 'adaptative noise method', a specific SSE is obtained for which the noise depends explicitly on both the initial state and on the properties of the interaction Hamiltonian. It is also show…
Here we have studied first and second-order intertwining approach to generate isospectral partner potentials of position-dependent (effective) mass Schroedinger equation. The second-order intertwiner is constructed directly by taking it as second order linear differential operator with position depndent coefficients and the system of equations arising from the intertwining relationship is solved for the coefficients by taking an ansatz. A complete scheme for obtaining general solution is obtained which is valid for any arbitrary potential and mass function. The proposed technique allows us to …
We consider a class of one-dimensional chains of weakly coupled many level systems. We present a theory which predicts energy diffusion within these chains for almost all initial states, if some concrete conditions on their Hamiltonians are met. By numerically solving the time dependent Schroedinger equation, we verify this prediction. Close to equilibrium we analyze this behavior in terms of heat conduction and compute the respective coefficient directly from the theory.
The Principle of Least Action is used with a simple Lagrangian density, involving second-order derivatives of the wave function, to obtain the Schroedinger equation. A Hamiltonian density obtained from this simple Lagrangian density shows that Hamilton's equations also give the Schroedinger equation. This simple Lagrangian density is equivalent to a standard Lagrangian density with first-order derivatives. For a time-independent system the Principle of Least Action reduces to the energy variational principle. For time-dependent systems the Principle of Least Action gives time-dependent approxi…
We analyze two-dimensional Schrödinger operators with the potential $|xy|^p - λ(x^2+y^2)^{p/(p+2)}$ where $p\ge 1$ and $λ\ge 0$, which exhibit an abrupt change of its spectral properties at a critical value of the coupling constant $λ$. We show that in the supercritical case the spectrum covers the whole real axis. In contrast, for $λ$ below the critical value the spectrum is purely discrete and we establish a Lieb-Thirring-type bound on its moments. In the critical case the essential spectrum covers the positive halfline while the negative spectrum can be only discrete, we demonstrate numeric…
The well known interpretational difficulties with nonlinear Schrödinger and von Neumann equations can be reduced to the problem of computing multiple-time correlation functions in the absence of Heisenberg picture. Having no Heisenberg picture one often resorts to Zeno-type reasoning which explicitly involves the projection postulate as a means of computing conditional and joint probabilities. Although the method works well in linear quantum mechanics, it completely fails for nonlinear evolutions. We propose an alternative way of performing the same task in linear quantum mechanics and show th…
In this paper we consider the nonlinear one-dimensional time-dependent Schroedinger equation with a periodic potential and a local perturbation. In the limit of large periodic potential the time behavior of the wavefunction can be approximated, with a precise estimate of the remainder term, by means of the solution to the discrete nonlinear Schroedinger equation of the tight-binding model.
We discuss the relationship between exact solvability of the Schroedinger equation, due to a spatially dependent mass, and the ordering ambiguity. Some examples show that, even in this case, one can find exact solutions. Furthermore, it is demonstrated that operators with linear dependence on the momentum are nonambiguous.
The multiconfigurational time-dependent Hartree-Fock equations are discussed and solved for a one-dimensional model of the Helium atom. Results for the ground state energy and two-particle density as well as the absorption spectrum are presented and compared to direct solutions of the time-dependent Schroedinger equation.
A procedure to obtain the eigenenergies and eigenfunctions of a quantum spiked oscillator is presented. The originality of the method lies in an adequate use of asymptotic expansions of Wronskians of algebraic solutions of the Schroedinger equation. The procedure is applied to three familiar examples of spiked oscillators.
We represent low dimensional quantum mechanical Hamiltonians by moderately sized finite matrices that reproduce the lowest O(10) boundstate energies and wave functions to machine precision. The method extends also to Hamiltonians that are neither Hermitian nor PT symmetric and thus allows to investigate whether or not the spectra in such cases are still real. Furthermore, the approach is especially useful for problems in which a position-dependent mass is adopted, for example in effective-mass models in solid-state physics or in the approximate treatment of coupled nuclear motion in molecular …
The consistency of the concept of quantum (quasi)particles possessing effective mass which is both position- and excitation-dependent is analyzed via simplified models. It is shown that the system may be stable even when the effective mass m=m(x,E) itself acquires negative values in a limited range of coordinates x and energies E.
We derive an exact single-body decomposition of the time-dependent Schroedinger equation for N pairwise-interacting fermions. Each fermion obeys a stochastic time-dependent norm-preserving wave equation. As a first test of the method we calculate the low energy spectrum of Helium. An extension of the method to bosons is outlined.
We obtain time dependent $q$-Gaussian wave-packet solutions to a non linear Schrödinger equation recently advanced by Nobre, Rego-Montero and Tsallis (NRT) [Phys. Rev. Lett. 106 (2011) 10601]. The NRT non-linear equation admits plane wave-like solutions ($q$-plane waves) compatible with the celebrated de Broglie relations connecting wave number and frequency, respectively, with energy and momentum. The NRT equation, inspired in the $q$-generalized thermostatistical formalism, is characterized by a parameter $q$, and in the limit $q \to 1$ reduces to the standard, linear Schrödinger equation. T…
A one-dimensional Schrödinger equation with position-dependent effective mass in the kinetic energy operator is studied in the framework of an $so(2,1)$ algebra. New mass-deformed versions of Scarf II, Morse and generalized Pöschl-Teller potentials are obtained. Consistency with an intertwining condition is pointed out.
A surprising "duality" of the Newton equation with time-dependent forces and the stationary Schroedinger equation is discussed. Wide classes of exact solutions not known before for few-body Newton equations are generated directly from exactly solvable multichannel models discovered in quantum mechanics due to the inverse problem and the supersymmetry (SUSYQ) approach. The application of this duality to the control of the stability (bifurcations) of classical motions is suggested.
With an apparent delay of over one century with respect to the development of standard Analytical Mechanics, but still in fully classical terms, the behavior of classical monochromatic wave beams in stationary media is shown to be ruled by a dispersive "Wave Potential" function, encoded in the structure of the Helmholtz equation. An exact, ray-based Hamiltonian description, revealing a strong ray coupling due to the Wave Potential, and reducing to the geometrical optics approximation when this function is neglected, is shown to hold even for typically wave-like phenomena such as diffraction an…
Based on the well-known relation between Fokker-Planck equations and Schroedinger equations of quantum mechanics (QM), we propose new deformed Fokker-Planck (FP) equations associated with the Schroedinger equations of "discrete" QM. The latter is a natural discretization of QM and its Schroedinger equations are difference instead of differential equations. Exactly solvable FP equations are obtained corresponding to exactly solvable "discrete" QM, whose eigenfunctions include various deformations of the classical orthogonal polynomials.
A recently proposed algorithm to obtain global solutions of the double confluent Heun equation is applied to solve the quantum mechanical problem of finding the energies and wave functions of a particle bound in a potential sum of a repulsive supersingular term, Ar(-4), plus an attractive Coulombian one, -Zr(-1). The existence of exact algebraic solutions for certain values of A is discussed.
Quantum mechanics has been argued to be a coarse-graining of some underlying deterministic theory. Here we support this view by establishing a map between certain solutions of the Schroedinger equation, and the corresponding solutions of the irrotational Navier-Stokes equation for viscous fluid flow. As a physical model for the fluid itself we propose the quantum probability fluid. It turns out that the (state-dependent) viscosity of this fluid is proportional to Planck's constant, while the volume density of entropy is proportional to Boltzmann's constant. Stationary states have zero viscosit…
In this article, we consider a set of trial wave-functions denoted by $| Q \right>$ and an associated set of operators $A_α$ which generate transformations connecting those trial states. Using variational principles, we show that we can always obtain a quantum Monte-Carlo method where the quantum evolution of a system is replaced by jumps between density matrices of the form $D = |Q_a> <Q_b|$, and where the average evolutions of the moments of $A_α$ up to a given order $k$, i.e. $< A_{α_1} >$, $< A_{α_1} A_{α_2} >$,..., $< A_{α_1} ... A_{α_k} >$, are constrained to follow the exact Ehrenfest e…
