Starting from our idea of combining the Feynman path integral spirit and the Dyson series kernel, we find an explicit and general form of time evolution operator that is a $c$-number function and a power series of perturbation including all order approximations in the unperturbed Hamiltonian representation. Based on it, we obtain an exact solution of the Schrödinger equation in general quantum systems independent of time. Comparison of our exact solution with the existed perturbation theory makes some features and significance of our exact solution clear. The conclusions expressly indicate that our exact solution is obviously consistent with the usual time-independent perturbation theory at any order approximation, it explicitly calculates out the expanding coefficients of the unperturbed state in the non-perturbation method, and it fully solves the recurrence equation of the expansion coefficients of final state in the unperturbed Hamiltonian representation from a view of time-dependent perturbation theory. At the same time, the exact solution of the von Neumann equation is also given. Our results can be thought of as theoretical developments of quantum dynamics, and are helpful for understanding the dynamical behavior and related subjects of general quantum systems in both theory and application. Our exact solution, together with its sequence studies on perturbation theory [An Min Wang, quant-ph/0611217] and open system dynamics [An Min Wang, quant-ph/0601051] can be used to establish the foundation of theoretical formulism of quantum mechanics in general quantum systems. Further applications of our exact solution to quantum theory can be expected.
We comment that the conditionally exactly solvable potential of Dutt et al. and the exactly solvable potential from which it is derived form a dual system.
Orthogonal Polynomials in Quantum Mechanics. Exact solutions of the Schrodinger equation with the hyperbolic Scarf potential (Scarf II) in terms of Romanovski polynomials. Among the applications included is the solution of the problem of an electron within a particular potential leading to the definition of new non-spherical angular functions.
With the use of the general covariant matrix 10-dimensional Petiau-Duffin-Kemmer formalism in cylindrical coordinates exact solutions of the quantum-mechanical equation for a particle with spin 1 in the presence of an external homogeneous magnetic field are constructed. Three linearly independent types of solutions are separated; in each case the formula for the energy levels has been found.Within similar technique for the quantum-mechanical equation for a particle with spin 1 and additional intrinsic electromagnetic characteristics - polarizability, exact solutions are found in the presence o…
A new type of supersymmetric transformations of the coupled-channel radial Schroedinger equation is introduced, which do not conserve the vanishing behavior of solutions at the origin. Contrary to usual transformations, these ``non-conservative'' transformations allow, in the presence of thresholds, the construction of potentials with coupled scattering matrices from uncoupled potentials. As an example, an exactly-solvable potential matrix is obtained which provides a very simple model of Feshbach-resonance phenomenon.
In recent years, one of the most interesting developments in quantum mechanics has been the construction of new exactly solvable potentials connected with the appearance of families of exceptional orthogonal polynomials (EOP) in mathematical physics. In contrast with families of (Jacobi, Laguerre and Hermite) classical orthogonal polynomials, which start with a constant, the EOP families begin with some polynomial of degree greater than or equal to one, but still form complete, orthogonal sets with respect to some positive-definite measure. We show how they may appear in the bound-state wavefu…
Brief introduction to the discrete quantum mechanics is given together with the main results on various exactly solvable systems. Namely, the intertwining relations, shape invariance, Heisenberg operator solutions, annihilation/creation operators, dynamical symmetry algebras including the $q$-oscillator algebra and the Askey-Wilson algebra. A simple recipe to construct exactly and quasi-exactly solvable Hamiltonians in one-dimensional `discrete' quantum mechanics is presented. It reproduces all the known ones whose eigenfunctions consist of the Askey scheme of hypergeometric orthogonal polynom…
We derive an exact solution of an explicitly time-dependent multichannel model of quantum mechanical nonadiabatic transitions. In the limit N >>1, where N is the number of states, we find that the survival probability of the initially populated state remains finite despite an almost arbitrary choice of a large number of parameters. This observation proves that quantum mechanical nonadiabatic transitions among a large number of states can effectively keep memory about the initial state of the system. This property can lead to a strongly non-ergodic behavior even in the thermodynamic limit of so…
We present a simple recipe to construct exactly and quasi-exactly solvable Hamiltonians in one-dimensional `discrete' quantum mechanics, in which the Schrödinger equation is a difference equation. It reproduces all the known ones whose eigenfunctions consist of the Askey scheme of hypergeometric orthogonal polynomials of a continuous or a discrete variable. The recipe also predicts several new ones. An essential role is played by the sinusoidal coordinate, which generates the closure relation and the Askey-Wilson algebra together with the Hamiltonian. The relationship between the closure relat…
The author discusses a different kind of Hermitian quantum mechanics, called $J$-Hermitian quantum mechanics. He shows that $PT$-symmetric quantum mechanics is indeed $J$-Hermitian quantum mechanics, and that time evolution (in the Krein space of states) is unitary if and only if Hamiltonian is $J$-Hermitian (or equivalently $PT$-symmetric). An issue with unitarity comes up when time evolution is considered in the Hilbert space of states rather than in the Krein space of states. The author offers possible scenarios with this issue.
Various examples of exactly solvable `discrete' quantum mechanics are explored explicitly with emphasis on shape invariance, Heisenberg operator solutions, annihilation-creation operators, the dynamical symmetry algebras and coherent states. The eigenfunctions are the (q-)Askey-scheme of hypergeometric orthogonal polynomials satisfying difference equation versions of the Schrödinger equation. Various reductions (restrictions) of the symmetry algebra of the Askey-Wilson system are explored in detail.
An exact solution of the energy shift in each quantum mechanical energy levels in a one dimensional symmetrical linear harmonic oscillator has been investigated. The solution we have used here is firstly derived by manipulating Schrodinger differential equation to be confluent hypergeometric differential equation. The final exact numerical results of the energy shifts are then found by calculating the final analytical solution of the confluent hypergeometric equation with the use of a software (Mathcad Plus 6.0) or a program programmed by using Turbo Pascal 7.0. We find that the results of the…
The exact quantum-mechanical equations for beams of free particles including photons and for beams of Dirac and spin-1 particles in a uniform magnetic field have been derived. These equations present the exact generalizations of the well-known paraxial equations in optics (exact Helmholtz equation for light beams) and particle physics and of the previously obtained paraxial equation for a Dirac particle in a uniform magnetic field. Some basic properties of exact wave eigenfunctions of particle beams have been determined.
A comprehensive review of exactly solvable quantum mechanics is presented with the emphasis of the recently discovered multi-indexed orthogonal polynomials. The main subjects to be discussed are the factorised Hamiltonians, the general structure of the solution spaces of the Schroedinger equation (Crum's theorem and its modifications), the shape invariance, the exact solvability in the Schroedinger picture as well as in the Heisenberg picture, the creation/annihilation operators and the dynamical symmetry algebras, coherent states, various deformation schemes (multiple Darboux transformations)…
A review of fundamentals and physical applications of fractional quantum mechanics has been presented. Fundamentals cover fractional Schrödinger equation, quantum Riesz fractional derivative, path integral approach to fractional quantum mechanics, hermiticity of the Hamilton operator, parity conservation law and the current density. Applications of fractional quantum mechanics cover dynamics of a free particle, new representation for a free particle quantum mechanical kernel, infinite potential well, bound state in δ-potential well, linear potential, fractional Bohr atom and fractional oscilla…
Exact Heisenberg operator solutions for independent `sinusoidal coordinates' as many as the degree of freedom are derived for typical exactly solvable multi-particle quantum mechanical systems, the Calogero systems based on any root system. These Heisenberg operator solutions also present the explicit forms of the annihilation-creation operators for various quanta in the interacting multi-particle systems. At the same time they can be interpreted as multi-variable generalisation of the three term recursion relations for multi-variable orthogonal polynomials constituting the eigenfunctions.
In this article, we discussed certain properties of non-Hermitian $\CP$-symmetry Hamiltonian, and it is shown that a consistent physical theory of quantum mechanics can be built on a ${\cal C} \CP$-symmetry Hamiltonian. In particular, we show that these theories have unitary time evolution, and conservation probability. Furthermore, transition from quantum mechanics to classical mechanics is investigate and it is found that the Ehrenfest theorem is satisfied.
We present a unified approach for solving and classifying exactly solvable potentials. Our unified approach encompasses many well-known exactly solvable potentials. Moreover, the new approach can be used to search systematically for a new class of solvable potentials.
The analytic solutions of the one-dimensional Schroedinger equation for the trigonometric Rosen-Morse potential reported in the literature rely upon the Jacobi polynomials with complex indices and complex arguments. We first draw attention to the fact that the complex Jacobi polynomials have non-trivial orthogonality properties which make them uncomfortable for physics applications. Instead we here solve above equation in terms of real orthogonal polynomials. The new solutions are used in the construction of the quantum-mechanic superpotential.
A supersymmetric technique for the solution of the effective mass Schrö% dinger equation is proposed. Exact solutions of the Schroedinger equation corresponding to a number of potentials are obtained. The potentials are fully isospectral with the original potentials. The conditions for the shape invariance of the potentials are discussed.
The question of whether sunlight induces coherent dynamics in biological systems is under debate. Here we show, on the basis of an exact fully quantum mechanical treatment, that thermal light induces excited-state coherences in matter similar to those induced by a coherent state. We demonstrate the phenomenon on a V-type model system and a two-state Born-Oppenheimer molecular system. Remarkably, wavepacket-like dynamics is induced in the excited molecular potential-energy surface.
Infinite families of multi-indexed orthogonal polynomials are discovered as the solutions of exactly solvable one-dimensional quantum mechanical systems. The simplest examples, the one-indexed orthogonal polynomials, are the infinite families of the exceptional Laguerre and Jacobi polynomials of type I and II constructed by the present authors. The totality of the integer indices of the new polynomials are finite and they correspond to the degrees of the `virtual state wavefunctions' which are `deleted' by the generalisation of Crum-Adler theorem. Each polynomial has another integer n which co…
We obtain a complete series solution of stationary Schrödinger's equation in the general quantum systems. It is exact in the sense that any approximation means is not used, or that the whole corrections or contributions from all order perturbations are involved if the perturbation concept is introduced. Furthermore, the useful forms of our exact solution and a new expression the complete Green operator are given out. As a universal and analytical solution, it is helpful for the theoretical derivations and practical calculations in quantum theory.
The recently proposed PT-symmetric quantum mechanics works with complex potentials which possess, roughly speaking, a symmetric real part and an anti-symmetric imaginary part. We propose and describe a new exactly solvable model of this type. It is defined as a specific analytic continuation of the shape-invariant potential of Morse. In contrast to the latter well-known example, all the new spectrum proves real, discrete and bounded below. All its three separate subsequences are quadratic in n.
In this work we present the simplest generic form of the propagator for the time-dependent quadratic Hamiltonian. We manifest the simplicity of our method by giving explicitly the propagators for a free particle in time-dependent electric field, forced harmonic oscillator and the Paul trap. Exact transition amplitudes and uncertainties are calculated analytically for the Paul trap and harmonic oscillator. The results show that near the instability regions very large quantum mechanical uncertainties are obtained as demonstrated in a special figure. The method is also applied to calculating the …
The problem of quantum harmonic oscillator with "regular+random" square frequency, subjected to "regular+random external force, is considered in framework of representation of the wave function by complex-valued random process. Average transition probabilities are calculated. Stochastic density matrix method is developed, which is used for investigation of thermodinamical characteristics of the system, such as entropy and average energy.
We present the general ideas on SuperSymmetric Quantum Mechanics (SUSY-QM) using different representations for the operators in question, which are defined by the corresponding bosonic Hamiltonian as part of SUSY Hamiltonian and its supercharges, which are defined as matrix or differential operators. We show that, although most of the SUSY partners of one-dimensional Schrödinger problems have already been found,there are still some unveiled aspects of the factorization procedure which may lead to richer insights of the problem involved.
Exact solutions of several nonstationary problems of quantum mechanics are obtained. It is shown that if the initial conditions of the problem correspond to the localized-in-space particle, then it moves exactly along the classical trajectory, and the wave packet is not spread in time.
We derive the analytical eigenvalues and eigenstates of a family of potentials wells with exponential form (FPWEF). We provide a brief summary of the supersymmetry formalism applied to quantum mechanics and illustrate it by producing from the FPWEF another class of exact solutions made of their isospectral partners. Interestingly, a subset of the supersymmetric partners provides a class of exactly solvable double well potentials. We use the exact solutions of the FPWEF to test the robustness and accuracy of different approximation schemes. We determine (i) the ground state through variational …
Analytic expressions for the energy eigenvalues and eigenfunctions of a one-dimensional harmonic crystal are obtained. The average energy and density profiles are obtained numerically as a function of temperature. A surprisingly large number of energy levels (eg.\ 5,000 for 4 particles) are required for reliable results at even moderate temperatures.
A comprehensive review of the discrete quantum mechanics with the pure imaginary shifts and the real shifts is presented in parallel with the corresponding results in the ordinary quantum mechanics. The main subjects to be covered are the factorised Hamiltonians, the general structure of the solution spaces of the Schroedinger equation (Crum's theorem and its modification), the shape invariance, the exact solvability in the Schroedinger picture as well as in the Heisenberg picture, the creation/annihilation operators and the dynamical symmetry algebras, the unified theory of exact and quasi-ex…
Contrary to a wide-spread commonplace, an exact, ray-based treatment holding for any kind of monochromatic wave-like features (such as diffraction and interference) is provided by the structure itself of the Helmholtz equation. This observation allows to dispel - in apparent violation of the Uncertainty Principle - another commonplace, forbidding an exact, trajectory-based approach to Wave Mechanics.
We apply the Frobenius (power-series) method to some simple exactly-solvable and conditionally-solvable quantum-mechanical models with supposed physical interest. We show that the supposedly exact solutions to radial eigenvalue equations derived in recent papers are not correct because they do not satisfy some well-known theorems. We also discuss the origin of the mistake by means of the approach indicated above.
The double well potential is arguably one of the most important potentials in quantum mechanics, because the solution contains the notion of a state as a linear superposition of `classical' states, a concept which has become very important in quantum information theory. It is therefore desirable to have solutions to simple double well potentials that are accessible to the undergraduate student. We describe a method for obtaining the numerically exact eigenenergies and eigenstates for such a model, along with the energies obtained through the Wentzel-Kramers-Brillouin (WKB) approximation. The e…
We consider supersymmetric quantum mechanical models with both local and nonlocal potentials. We present a nonlocal deformation of exactly solvable local models. Its energy eigenfunctions and eigenvalues are determined exactly. We observe that both our model Hamiltonian and its supersymmetric partner may have normalizable zero-energy ground states, in contrast to local models with nonperiodic or periodic potentials.
We present a simple recipe to construct the Green's function associated with a Hamiltonian of the form H=H_0+V, where H_0 is a Hamiltonian for which the associated Green's function is known and V is a delta-function potential. We apply this result to the case in which H_0 is the Hamiltonian of a free particle in D dimensions. Field theoretic concepts such as regularization, renormalization, dimensional transmutation and triviality are introduced naturally in order to deal with an infinity which shows up in the formal expression of the Green's function for D>1.
We put forward and prove a simple theorem stating that the eigenvalues of a tridiagonal matrix change their sign (as a set), once the signs of the diagonal elements of the matrix are changed. We also provide an example of application of this theorem in quantum physics. Specifically, we introduce the notion of duality and self-duality for a sextic-polynomial quasi-exactly-solvable potential, and demonstrate that the algebraic parts of the spectrum of the dual potentials have signs opposite to one another (as sets). Our Theorem furnishes an elegant one-line proof of this statement. In addition, …
Standard Quantum Mechanics (QM) predicts an anti-intuitive fenomenon here referred to as "quantum autoscattering", which is excluded by Bhomian Mechanics. The scheme of a gedanken experiment testing the QM prediction is briefly discussed.
In his recent paper arXiv:1312.7738, the author discussed $J$-Hermitian quantum mechanics and showed that $PT$-symmetric quantum mechanics is essentially $J$-Hermitian quantum mechanics. In this paper, the author discusses finite $J$-Hermitian quantum mechanics which is derived naturally from its continuum one and its relationship with finite $PT$-symmetric quantum mechanics.
In this paper we develop a discussion about PT Symmetric Quantum Mechanics, working with basics elements of this theory. In a simple case of two body system, we developed the Quantum Brachistochrone problem. Comparing the results obtained through the PT Symmetric Quantum Mechanics with that ones obtained using the standard formalism, we conclude that this new approach is not able to reveal any new effect.
This is an introductory chapter of the book in progress on quantum foundations and incompleteness of quantum mechanics. Quantum mechanics is represented as statistical mechanics of classical fields.
The exact factorization of an electron-nuclear wavefunction [A. Abedi, N. T. Maitra, and E. K. U. Gross, Phys. Rev. Lett. 105, 123002 (2010)] allows us to define the rigorous nuclear time-dependent Schrödinger equation (TDSE) with a time-dependent potential-energy surface (TDPES) that fully accounts for the coupling to the electronic motion and drives the nuclear wavepacket dynamics. Here, we study whether the propagation of multiple classical trajectories can reproduce the quantum nuclear motion in strong-field processes when their motions are governed by the quantum Hamilton-Jacobi equation …
In spite of its popularity, it has not been possible to vindicate the conventional wisdom that classical mechanics is a limiting case of quantum mechanics. The purpose of the present paper is to offer an alternative point of view in which quantum mechanics emerges as a limiting case of classical mechanics in which the classical system is decoupled from its environment.
Quantum computation teaches us that quantum mechanics exhibits exponential complexity. We argue that the standard scientific paradigm of "predict and verify" cannot be applied to testing quantum mechanics in this limit of high complexity. We describe how QM can be tested in this regime by extending the usual scientific paradigm to include {\it interactive experiments}.
Bohm Mechanics and Nelson Stochastic Mechanics are confronted with Quantum Mechanics in presence of non-interacting subsystems. In both cases, it is shown that correlations at different times of compatible position observables on stationary states agree with Quantum Mechanics only in the case of product wave functions. By appropriate Bell-like inequalities it is shown that no classical theory, in particular no stochastic process, can reproduce the quantum mechanical correlations of position variables of non interacting systems at different times.
We discuss foundation of quantum mechanics (interpretations, superposition, principle of complementarity, locality, hidden variables) and quantum information theory.
The correspondence of a new form of quantum mechanics based on a quantum version of the action principle, which was proposed earlier [arXiv:0807.3508], with the ordinary quantum mechanics is established. New potentialities of the quantum action principle in the interpretation of quantum mechanics are considered.
