We investigate the thermodynamical aspects of the Casimir effect in the case of plane parallel plates made of real metals. The thermal corrections to the Casimir force between real metals were recently computed by several authors using different approaches based on the Lifshitz formula with diverse results. Both the Drude and plasma models were used to describe a real metal. We calculate the entropy density of photons between metallic plates as a function of the surface separation and temperature. Some of these approaches are demonstrated to lead to negative values of entropy and to nonzero entropy at zero temperature depending on the parameters of the system. The conclusion is that these approaches are in contradiction with the third law of thermodynamics and must be rejected. It is shown that the plasma dielectric function in combination with the unmodified Lifshitz formula is in perfect agreement with the general principles of thermodynamics. As to the Drude dielectric function, the modification of the zero-frequency term of the Lifshitz formula is outlined that not to violate the laws of thermodynamics.
We study the finite temperature Casimir interaction between two concentric cylinders. When the separation between the cylinders is much smaller than the radii of the cylinders, the asymptotic expansions of the Casimir interaction are derived. Both the low temperature and the high temperature regions are considered. The leading terms are found to agree with the proximity force approximations. The low temperature leading term of the temperature correction is also computed and it is found to be independent of the boundary conditions imposed on the larger cylinder.
We show how to compute Casimir forces at nonzero temperatures with time-domain electromagnetic simulations, for example using a finite-difference time-domain (FDTD) method. Compared to our previous zero-temperature time-domain method, only a small modification is required, but we explain that some care is required to properly capture the zero-frequency contribution. We validate the method against analytical and numerical frequency-domain calculations, and show a surprising high-temperature disappearance of a non-monotonic behavior previously demonstrated in a piston-like geometry.
Recently D. A. R. Dalvit and S. K. Lamoreaux arXiv:0805.1676 [Phys. Rev. Lett. v.101, 163203 (2008)] suggested the modification of the reflection coefficients in the Lifshitz theory taking into account the screening effects and diffusion currents. We demonstrate that the suggested modification is thermodynamically and experimentally inconsistent.
We consider the Casimir-Helmholtz free energy at nonzero temperature $T$ for a circular cylinder and perfectly conducting wedge closed by a cylindrical arc, either perfectly conducting or isorefractive. The energy expression at nonzero temperature may be regularized to obtain a finite value, except for a singular corner term in the case of the wedge which is present also at zero temperature. Assuming the medium in the interior of the cylinder or wedge be nondispersive with refractive index $n$, the temperature dependence enters only through the non-dimensional parameter $2πnaT$, $a$ being the …
In this paper, dedicated to the career of Tom Erber, we consider the Casimir interaction between weakly coupled bodies at nonzero temperature. For the case of semitransparent bodies, that is, ones described by delta-function potentials, we first examine the interaction between an infinite plane and an arbitrary curved surface. In weak coupling, such an interaction energy coincides with the exact form of the proximity force approximation obtained by summing the interaction between opposite surface elements at arbitrary temperature. This result generalizes a theorem proved recently by Decca et a…
We show that macroscopic thermodynamical properties - such as functions of internal energy and magnetization - can detect quantum entanglement in solids at nonzero temperatures in the thermodynamical limit. We identify the parameter regions (critical values of magnetic field and temperature) within which entanglement is witnessed by these thermodynamical quantities.
The rigorous finite-temperature QED formalism of the polarization tensor is used to study the combined effect of nonzero mass gap $m$ and chemical potential $μ$ on the Casimir force and its thermal correction in the experimentally relevant configuration of a Au sphere interacting with a real graphene sheet or with graphene-coated dielectric substrates made of different materials. It is shown that for both a free-standing graphene sheet and for graphene-coated substrates the magnitude of the Casimir force decreases as $m$ is increased, while it increases as $μ$ is increased, indicating that the…
The application of the Lifshitz theory to describe the thermal Casimir force between dielectrics and semiconductors is considered. It is shown that for all true dielectrics (i.e., for all materials having zero conductivity at zero temperature) the inclusion of a nonzero conductivity arising at nonzero temperature into the model of dielectric response leads to the violation of the Nernst heat theorem. This result refers equally to simple insulators, intrinsic semiconductors, Mott-Hubbard dielectrics and doped semiconductors with doping concentration below a critical value. We demonstrate that i…
We investigate the Casimir pressure between two parallel plates made of magnetic materials at nonzero temperature. It is shown that for real magnetodielectric materials only the magnetic properties of ferromagnets can influence the Casimir pressure. This influence is accomplished through the contribution of the zero-frequency term of the Lifshitz formula. The possibility of the Casimir repulsion through the vacuum gap is analyzed depending on the model used for the description of the dielectric properties of the metal plates.
We provide a review of both new experimental and theoretical developments in the Casimir effect. The Casimir effect results from the alteration by the boundaries of the zero-point electromagnetic energy. Unique to the Casimir force is its strong dependence on shape, switching from attractive to repulsive as function of the size, geometry and topology of the boundary. Thus the Casimir force is a direct manifestation of the boundary dependence of quantum vacuum. We discuss in depth the general structure of the infinities in the field theory which are removed by a combination of zeta-functional r…
We study the quantum and thermal fluctuations of eddy (Foucault) currents in thick metallic plates. A Casimir interaction between two plates arises from the coupling via quasi-static magnetic fields. As a function of distance, the relevant eddy current modes cross over from a quantum to a thermal regime. These modes alone reproduce previously discussed thermal anomalies of the electromagnetic Casimir interaction between good conductors. In particular, they provide a physical picture for the Casimir entropy whose nonzero value at zero temperature arises from a correlated, glassy state.
We review recent results on the low-temperature behaviors of the Casimir-Polder and Casimir free energy an entropy for a polarizable atom interacting with a graphene sheet and for two graphene sheets, respectively. These results are discussed in the wide context of problems arising in the Lifshitz theory of van der Waals and Casimir forces when it is applied to metallic and dielectric bodies. After a brief treatment of different approaches to theoretical description of the electromagnetic response of graphene, we concentrate on the derivation of response function in the framework of thermal qu…
The low-temperature behavior of the Casimir-Polder free energy and entropy for an atom near a dielectric plate are found on the basis of the Lifshitz theory. The obtained results are shown to be thermodynamically consistent if the dc conductivity of the plate material is disregarded. With inclusion of dc conductivity, both the standard Lifshitz theory (for all dielectrics) and its generalization taking into account screening effects (for a wide range of dielectrics) violate the Nernst heat theorem. The inclusion of the screening effects is also shown to be inconsistent with experimental data o…
It is well known since a long time that all lossy conductors at finite temperature display an electronic noise, the Johnson-Nyquist noise, arising from the thermal agitation of electric charges inside the conductor. The existence of this noise implies that two nearby discharged conductors at finite temperature should repel each other, as a result of the electrodynamic interaction between the Johnson-Nyquist currents in either conductor and the eddy currents they induce in the other. It is suggested that this force is at the origin of the recently discovered large repulsive correction to the th…
The impedance boundary condition is used to calculate the Casimir force in configurations of two parallel plates and a shpere (spherical lens) above a plate at both zero and nonzero temperature. The impedance approach allows one to find the Casimir force between the realistic test bodies regardless of the electromagnetic fluctuations inside the media. Although this approach is an approximate one, it has wider areas of application than the Lifshitz theory of the Casimir force. The general formulas of the impedance approach to the theory of the Casimir force are given and the formal substitution…
We give a rigorous analytical derivation of low-temperature behavior of the Casimir entropy in the framework of the Lifshitz formula combined with the Drude dielectric function. An earlier result that the Casimir entropy at zero temperature is not equal to zero and depends on the parameters of the system is confirmed, i.e. the third law of thermodynamics (the Nernst heat theorem) is violated. We illustrate the resolution of this thermodynamical puzzle in the context of the surface impedance approach by several calculations of the thermal Casimir force and entropy for both real metals and diele…
We find the Casimir-like energies for strings and membranes. We show that the related Casimir forces can be interpreted as quantum corrections to the classical tensions of the strings and membranes. We see that these corrections always increase the tensions of the circular string as well as spherical membrane, while for the straight string, rectangular and cylindrical membranes, these Casimir forces may increase or decrease the tensions. So we find that the quantum vacuum can break the (tensional) isotropy of the rectangular and cylindrical membranes. Also obtaining the nonzero-temperature Cas…
The problem with the temperature dependence of the Casimir force is investigated. Specifically, the entropy behavior in the low temperature limit, which caused debates in the literature, is analyzed. It is stressed that the behavior of the relaxation frequency in the $T\to0$ limit does not play a physical role since the anomalous skin effect dominates in this range. In contrast with the previous works, where the approximate Leontovich impedance was used for analysis of nonlocal effects, we give description of the problem in terms of exact nonlocal impedances. It is found that the Casimir entro…
We investigate the Casimir force acting between real metals at nonzero temperature. It is shown that the zero-frequency term of Lifshitz formula has interpretation problem in the case of real metal described by Drude model. It happens because the scattering theory underlying Lifshitz formula is not well formulated when the dielectric permittivity takes account of dissipation. To give the zeroth term of Lifshitz formula the definite meaning different prescriptions were used recently by different authors with diversed results. These results are shown to be improper and in disagreement with exper…
Recently J.S. Hoye, I.Brevik, J.B. Aarseth, and K.A. Milton [Phys. Rev. E v.67, 056116 (2003); quant-ph/0212125] proposed that if the Lifshitz formula is combined with the Drude model, the transverse electric zero mode does not contribute to the result for real metals and there arises a linear temperature correction to the Casimir force at small temperatures. The authors claim that in spite of the fact that the Casimir entropy in their approach is negative, the Nernst heat theorem is satisfied. In the present Comment we show that the authors' conclusion regarding the Nernst heat theorem is in …
We evaluate the Casimir-Polder potential between two atoms in the presence of an infinite perfectly conducting plate and at nonzero temperature. In order to calculate the potential, we use a method based on equal-time spatial correlations of the electric field, already used to evaluate the effect of boundary conditions on interatomic potentials. This method gives also a transparent physical picture of the role of a finite temperature and boundary conditions on the Casimir-Polder potential. We obtain an analytical expression of the potential both in the near and far zones, and consider several …
We find analytic asymptotic expressions at low temperature for the Casimir free energy, entropy and pressure of two parallel graphene sheets in the framework of the Lifshitz theory. The reflection coefficients of electromagnetic waves on graphene are described on the basis of first principles of quantum electrodynamics at nonzero temperature using the polarization tensor in (2+1)-dimensional space-time. The leading contributions to the Casimir entropy and to the thermal corrections to the Casimir energy and pressure are given by the thermal correction to the polarization tensor at nonzero Mats…
The situation with the temperature corrections to the Casimir force between real metals of finite conductivity is reported. It is shown that the plasma dielectric function is well adapted to the Lifshitz formula and leads to reasonable results for real conductors. The Drude dielectric function which describes media with dissipation is found not to belong to the application range of the Lifshitz formula at nonzero temperature. For Drude metals the special modification of the zero-frequency term of this formula is suggested. The contradictory results on the subject in recent literature are analy…
The analytic expressions for the free energy and entropy of the Casimir-Polder interaction between a polarizable and magnetizable atom and a graphene sheet are found in the limiting case of low temperature. In so doing, the response of graphene to electromagnetic fluctuations is described in the framework of the Dirac model by means of the polarization tensor in (2+1)-dimensional space-time. It is shown that the dominant contribution to the low-temperature behavior is given by an explicit dependence of the polarization tensor on temperature as a parameter. We demonstrate that the Lifshitz theo…
We derive the low-temperature behavior of the Casimir-Polder free energy for a polarizable atom interacting with graphene sheet which possesses the nonzero energy gap $Δ$ and chemical potential $μ$. The response of graphene to the electromagnetic field is described by means of the polarization tensor in the framework of Dirac model on the basis of first principles of thermal quantum field theory in the Matsubara formulation. It is shown that the thermal correction to the Casimir-Polder energy consists of three contributions. The first of them is determined by the Matsubara summation using the …
We consider polarizable sheets modeled by a lattice of delta function potentials. The Casimir interaction of two such lattices is calculated at nonzero temperature. The heat kernel expansion for periodic singular background is discussed in relation with the high temperature asymptote of the free energy.
The Casimir force acting between two test bodies made of different metals is considered. The finiteness of the conductivity of the metals is taken into account perturbatively up to the fourth order of the relative penetration depths of electromagnetic zero-point oscillations into the metals. The influence of nonzero temperature is computed explicitly for separate orders of perturbation and found to be important in the zeroth and first orders only. The configurations of two parallel plates and a sphere (spherical lens) above a plate are considered made of $Au$ and $Cr$. The obtained results can…
The thermal free energy and pressure of dispersion interaction between two graphene sheets described by the Dirac model are calculated using the Lifshitz formula with reflection coefficients expressed via the polarization tensor. The obtained results for a pristine graphene are found to be in agreement with computations using Coulomb coupling between density fluctuations. For a graphene with nonzero mass gap parameter a qualitatively different behavior for the free energy and pressure is obtained. The Lifshitz formula with reflection coefficients expressed via the polarization tensor is used a…
We derive an analytic behavior of the Casimir free energy, entropy and pressure of metallic films in vacuum at low temperature. It is shown that this behavior differs significantly depending on whether the plasma or the Drude model is used to describe the dielectric properties of film metal. For metallic films described by the lossless plasma model the thermal corrections to the Casimir energy and pressure drop to zero exponentially fast with increasing film thickness. There is no classical limit in this case. The Casimir entropy satisfies the Nernst heat theorem. For metallic films with perfe…
We give a comprehensive presentation of methods for calculating the Casimir force to arbitrary accuracy, for any number of objects, arbitrary shapes, susceptibility functions, and separations. The technique is applicable to objects immersed in media other than vacuum, nonzero temperatures, and spatial arrangements in which one object is enclosed in another. Our method combines each object's classical electromagnetic scattering amplitude with universal translation matrices, which convert between the bases used to calculate scattering for each object, but are otherwise independent of the details…
Several problems at the interface between the field-theoretical description of the Casimir effect and experiments on measuring the Casimir force are discussed. One of these problems is connected with the definition of the Casimir free energy in ideal metal rectangular boxes satisfying the general physical requirements. It is shown that the consideration of rectangular boxes with a partition (piston) does not negate the previously known results obtained for boxes without a piston. Both sets of results are found to be in mutual agreement. Another problem is related to the use of the proximity fo…
The physical reasons why the Drude dielectric function is not compatible with the Lifshitz formula, as opposed to the generalized plasma-like permittivity, are presented. Essentially, the problem is connected with the finite size of metal plates. It is shown that the Lifshitz theory combined with the generalized plasma-like permittivity is thermodynamically consistent.
The Casimir force is calculated analytically for configurations of two parallel plates and a spherical lens (sphere) above a plate with account of nonzero temperature, finite conductivity of the boundary metal and surface roughness. The permittivity of the metal is described by the plasma model. It is proved that in case of the plasma model the scattering formalism of quantum field theory in Matsubara formulation underlying Lifshitz formula is well defined and no modifications are needed concerning the zero-frequency contribution. The temperature correction to the Casimir force is found comple…
We analyze the high temperature (or classical) limit of the Casimir effect. A useful quantity which arises naturally in our discussion is the ``relative Casimir energy", which we define for a configuration of disjoint conducting boundaries of arbitrary shapes, as the difference of Casimir energies between the given configuration and a configuration with the same boundaries infinitely far apart. Using path integration techniques, we show that the relative Casimir energy vanishes exponentially fast in temperature. This is consistent with a simple physical argument based on Kirchhoff's law. As a …
We study the spatial fluctuations of the Casimir-Polder force experienced by an atom or a small sphere moved above a metallic plate at fixed separation distance. We demonstrate that unlike the mean force, the magnitude of these fluctuations crucially relies on the relaxation of conduction electron in the metallic bulk, and even achieves values that differ by orders of magnitude depending on the amount of dissipation. We also discover that fluctuations suffer a spectacular decrease at large distances in the case of nonzero temperature.
We extend a previous result [Phys. Rev. Lett. 105, 090403 (2010)] on Casimir repulsion between a plate with a hole and a cylinder centered above it to geometries in which the central object can no longer be treated as a point dipole. We show through numerical calculations that as the distance between the plate and central object decreases, there is an intermediate regime in which the repulsive force increases dramatically. Beyond this, the force rapidly switches over to attraction as the separation decreases further to zero, in line with the proximity force approximation. We demonstrate that t…
The Casimir-Polder and van der Waals interactions between an atom and a flat cavity wall are investigated under the influence of real conditions including the dynamic polarizability of the atom, actual conductivity of the wall material and nonzero temperature of the wall. The cases of different atoms near metal and dielectric walls are considered. It is shown that to obtain accurate results for the atom-wall interaction at short separations, one should use the complete tabulated optical data for the complex refractive index of the wall material and the accurate dynamic polarizability of an ato…
We find the analytic expressions for the Casimir free energy, entropy and pressure at low temperature in the configuration of two parallel plates made of magnetodielectic material. The cases of constant and frequency-dependent dielectic permittivity and magnetic permeability of the plates are considered. Special attention is paid to the account of dc conductivity. It is shown that in the case of finite static dielectric permittivity and magnetic permeability the Nernst heat theorem for the Casimir entropy is satisfied. If the dc conductivity is taken into account, the Casimir entropy goes to a…
We find the low-temperature behavior of the Casimir-Polder free energy and entropy for an atom interacting with real graphene sheet possessing nonzero energy gap and chemical potential. Employing the formalism of the polarization tensor, it is shown that the Casimir-Polder entropy goes to zero by the power law with vanishing temperature, i.e., the Nernst heat theorem is satisfied. This result is discussed in connection with the problems connected with account of free charge carriers in the Lifshitz theory.
We present the results of an experiment on measuring the gradient of the Casimir force between an Au-coated hollow glass microsphere and graphene-coated fused silica plate by means of a modified atomic force microscope cantilever based technique operated in the dynamic regime. These measurements were performed in high vacuum at room temperature. The energy gap and the concentration of impurities in the graphene sample used have been measured utilizing scanning tunnelling spectroscopy and Raman spectroscopy, respectively. The measurement results for the gradients of the Casimir force are found …
The Casimir interaction between two thick parallel plates, one made of metal and the other of dielectric, is investigated at nonzero temperature. It is shown that in some temperature intervals the Casimir pressure and the free energy of a fluctuating field are the nonmonotonous functions of temperature and the respective Casimir entropy can be negative. The physical interpretation for these conclusions is given. At the same time we demonstrate that the entropy vanishes when the temperature goes to zero, i.e., in the Casimir interaction between metal and dielectric the Nernst heat theorem is sa…
In view of the current discussion on the subject, an effort is made to show very accurately both analytically and numerically how the Drude dispersive model, assuming the relaxation is nonzero at zero temperature (which is the case when impurities are present), gives consistent results for the Casimir free energy at low temperatures. Specifically, we find that the free energy consists essentially of two terms, one leading term proportional to T^2, and a next term proportional to T^{5/2}. Both these terms give rise to zero Casimir entropy as T -> 0, thus in accordance with Nernst's theorem.
The Casimir-Polder interaction between an atom and a metal wall is investigated under the influence of real conditions including the dynamic polarizability of the atom, finite conductivity of the wall metal and nonzero temperature of the system. Both analytical and numerical results for the free energy and force are obtained over a wide range of the atom-wall distances. Numerical computations are performed for an Au wall and metastable He${}^{\ast}$, Na and Cs atoms. For the He${}^{\ast}$ atom we demonstrate, as an illustration, that at short separations of about the Au plasma wavelength at ro…
We propose two novel experiments on the measurement of the Casimir force acting between a gold coated sphere and semiconductor plates with markedly different charge carrier densities. In the first of these experiments a patterned Si plate is used which consists of two sections of different dopant densities and oscillates in the horizontal direction below a sphere. The measurement scheme in this experiment is differential, i.e., allows the direct high-precision measurement of the difference of the Casimir forces between the sphere and sections of the patterned plate or the difference of the equ…
We derive perturbation analytic expressions for the Casimir free energy and entropy between two dissimilar ferromagnetic plates which are applicale at arbitrarily low temperature. The dielectric properties of metals are described using either the nondissipative plasma model or the Drude model taking into account the dissipation of free charge carriers. Both cases of constant and frequency-dependent magnetic permeability are considered. It is shown that for ferromagnetic metals described by the plasma model the Casimir entropy goes to zero when the temperature vanishes, i.e., the Nernst heat th…
The Casimir effect in graphene systems is reviewed with emphasis made on the large thermal correction to the Casimir force predicted at short separations between the test bodies. The computational results for the Casimir pressure and for the thermal correction are presented for both pristine graphene and real graphene sheets, which possess nonzero energy gap and chemical potential, obtained by means of exact polarization tensor. Two experiments on measuring the gradient of the Casimir force between an Au-coated sphere and graphene- coated substrates performed by using a modified atomic force m…
In this paper we study the system of a scalar quantum field confined between two plane, isotropic, and homogeneous parallel plates at thermal equilibrium. We represent the plates by the most general lossless and frequency-independent boundary conditions that satisfy the conditions of isotropy and homogeneity and are compatible with the unitarity of the quantum field theory. Under these conditions we compute the thermal correction to the quantum vacuum energy as a function of the temperature and the parameters encoding the boundary condition. The latter enables us to obtain similar results for …
We report precision measurements of the gradient of the Casimir force between an Au-coated sphere and graphene sheet deposited on a silica plate. The measurement data are compared with exact theory using the polarization tensor found in the framework of the Dirac model including effects of the nonzero chemical potential and energy gap of the graphene sample with no fitting parameters. The very good agreement between experiment and theory demonstrates the unusually big thermal effect at separations below 1 mum which has never been observed for conventional 3D materials. Thus, it is confirmed ex…
The analytic asymptotic expressions for the Casimir free energy and entropy for two parallel graphene sheets possessing nonzero energy gap $Δ$ and chemical potential $μ$ are derived at arbitrarily low temperature. Graphene is described in the framework of thermal quantum field theory in the Matsubara formulation by means of the polarization tensor in (2+1)-dimensional space-time. Different asymptotic expressions are found under the conditions $Δ>2μ$, $Δ=2μ$, and $Δ<2μ$ taking into account both the implicit temperature dependence due to a summation over the Matsubara frequencies and the explici…
The energy of fluctuating electromagnetic field is investigated for the thermal Casimir force acting between parallel plates made of real metal. It is proved that for nondissipative media with temperature independent dielectric permittivity the energy at nonzero temperature comprises of the (renormalized) energies of the zero-point and thermal photons. In this manner photons can be considered as collective elementary excitations of the matter of plates and electromagnetic field. If the dielectric permittivity depends on temperature the energy contains additional terms proportional to the deriv…
We apply the scattering approach to the Casimir interaction between two dielectric half-spaces separated by an electrolyte solution. We take the nonlocal electromagnetic response of the intervening medium into account, which results from the presence of movable ions in solution. In addition to the usual transverse modes, we consider longitudinal channels and their coupling by reflection at the surface of the local dielectric. The Casimir interaction energy is calculated from the matrix describing a round-trip of coupled transverse and longitudinal waves between the interacting surfaces. The no…
Using the recently derived representation for the polarization tensor in (2+1)-dimensional space-time allowing an analytic continuation to the entire plane of complex frequencies, we obtain simple analytic expressions for the reflection coefficients of graphene at nonzero Matsubara frequencies. In the framework of the Lifshitz theory, these coefficients are shown to lead to nearly exact results for the Casimir free energy and pressure between two graphene sheets. The constituent parts of large thermal effect, arising in the Casimir interaction at short separations due to an explicit parametric…
New exact results are given for the interior Casimir energies of infinitely long waveguides of triangular cross section (equilateral, hemiequilateral, and isosceles right triangles). Results for cylinders of rectangular cross section are rederived. In particular, results are obtained for interior modes belonging to Dirichlet and Neumann boundary conditions (TM and TE modes). These results are expressed in rapidly convergent series using the Chowla-Selberg formula, and in fact may be given in closed form, except for general rectangles. The energies are finite because only the first three heat-k…
We analyze the magnetic dipole contribution to atom-surface dispersion forces. Unlike its electrical counterpart, it involves small transition frequencies that are comparable to thermal energy scales. A significant temperature dependence is found near surfaces with a nonzero DC conductivity, leading to a strong suppression of the dispersion force at T > 0. We use thermal response theory for the surface material and discuss both normal metals and superconductors. The asymptotes of the free energy of interaction and of the entropy are calculated analytically over a large range of distances. Near…
