What is the Temperature Dependence of the Casimir Force between Real Metals?
G. L. Klimchitskaya
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10 pages, 1 figure, Contribution to the 5th Workshop on Quantum Field Theory under the Influence of External Conditions, Leipzig, Germany, 10-14 Sep 2001
The situation with the temperature corrections to the Casimir force between real metals of finite conductivity is reported. It is shown that the plasma dielectric function is well adapted to the Lifshitz formula and leads to reasonable results for real conductors. The Drude dielectric function which describes media with dissipation is found not to belong to the application range of the Lifshitz formula at nonzero temperature. For Drude metals the special modification of the zero-frequency term of this formula is suggested. The contradictory results on the subject in recent literature are analysed and explained.
We establish strict upper limits for the Casimir interaction between multilayered structures of arbitrary dielectric or diamagnetic materials. We discuss the appearance of different power laws due to frequency-dependent material constants. Simple analytical expressions are in good agreement with numerical calculations based on Lifshitz theory. We discuss the improvements required for current (meta) materials to achieve a repulsive Casimir force.
We reply to the "Comment on 'The Lifshitz-Matsubara sum formula for the Casimir pressure between magnetic metallic mirrors'" [arXiv:1604.06432]. We believe the comment misrepresents our papers, and fails to provide a plausible resolution to the conflict between theory and experiment.
We have performed comparative measurements of the Casimir force between a metallic plate and a transparent sphere coated with metallic films of different thicknesses. We have observed that, if the thickness of the coating is less than the skin-depth of the electromagnetic modes that mostly contribute to the interaction, the force is significantly smaller than that measured with a thick bulk-like film. Our results provide the first direct evidence of the skin-depth effect on the Casimir force between metallic surfaces.
We derive an analytic behavior of the Casimir free energy, entropy and pressure of metallic films in vacuum at low temperature. It is shown that this behavior differs significantly depending on whether the plasma or the Drude model is used to describe the dielectric properties of film metal. For metallic films described by the lossless plasma model the thermal corrections to the Casimir energy and pressure drop to zero exponentially fast with increasing film thickness. There is no classical limit in this case. The Casimir entropy satisfies the Nernst heat theorem. For metallic films with perfe…
We study the influence of finite conductivity of metals on the Casimir effect. We put the emphasis on explicit theoretical evaluations which can help comparing experimental results with theory. The reduction of the Casimir force is evaluated for plane metallic plates. The reduction of the Casimir energy in the same configuration is also calculated. It can be used to infer the reduction of the force in the plane-sphere geometry through the `proximity theorem'. Frequency dependent dielectric response functions of the metals are represented either by the simple plasma model or, more accurately, b…
The thermal Casimir effect in ideal metal rectangular boxes is considered using the method of zeta functional regularization. The renormalization procedure is suggested which provides the finite expression for the Casimir free energy in any restricted quantization volume. This expression satisfies the classical limit at high temperature and leads to zero thermal Casimir force for systems with infinite characteristic dimensions. In the case of two parallel ideal metal planes the results, as derived previously using thermal quantum field theory in Matsubara formulation and other methods, are rep…
We consider two parallel corrugated plates and show that a Casimir torque arises when the corrugation directions are not aligned. We follow the scattering approach and calculate the Casimir energy up to second order in the corrugation amplitudes, taking into account nonspecular reflections, polarization mixing and the finite conductivity of the metals. We compare our results with the proximity force approximation, which overestimates the torque by a factor 2 when taking the conditions that optimize the effect. We argue that the Casimir torque could be measured for separation distances as large…
Emphasizing first the utility of the generalized Fresnel coefficients in the theory of the Casimir effect in planar cavities, we complement our previous discussion of the ordinary Casimir force on and the Casimir stress in a metal (plasma) slab in a planar cavity. We demonstrate strong dependence of the Casimir stress in a thin slab on properties of the bounding medium in the symmetric Lifshitz configuration. Contrary to this, the stress in a thick slab gradually becomes insensitive on external boundary conditions. We also consider the position dependence of the Casimir force on and stress in …
The Casimir force between two metallic plates is affected by their roughness state. This effect is usually calculated through the so-called `proximity force approximation' which is only valid for small enough wavevectors in the spectrum of the roughness profile. We introduce here a more general description with a wavevector-dependent roughness sensitivity of the Casimir effect. Since the proximity force approximation underestimates the effect, a measurement of the roughness spectrum is needed to achieve the desired level of accuracy in the theory-experiment comparison.
We calculate the Casimir force between two parallel ideal metal plates when there is an intervening chiral medium present. Making use of methods of quantum statistical mechanics we show how the force can be found in a simple and compact way. The expression for the force is in agreement with that obtained recently by Q.-D. Jiang and F. Wilczek [Phys. Rev. B {\bf 99}, 125403 (2019)], in their case with the use of Green function methods.
The Casimir force acting between two test bodies made of different metals is considered. The finiteness of the conductivity of the metals is taken into account perturbatively up to the fourth order of the relative penetration depths of electromagnetic zero-point oscillations into the metals. The influence of nonzero temperature is computed explicitly for separate orders of perturbation and found to be important in the zeroth and first orders only. The configurations of two parallel plates and a sphere (spherical lens) above a plate are considered made of $Au$ and $Cr$. The obtained results can…
We compute the Casimir interaction between a plane and a sphere, the configuration employed in the most precise experiments. The scattering formula is developed by taking a suitably chosen plane-wave and multipole basis and is valid for arbitrary values of the sphere radius, inter-plate distance, temperature and arbitrary dielectric functions for both sphere and plate. Our analytical and numerical results for metallic surfaces show a non-trivial interplay between the effects of curvature, temperature, finite conductivity and dissipation.
We calculate the Casimir force and free energy for plane metallic mirrors at non-zero temperature. Numerical evaluations are given with temperature and conductivity effects treated simultaneously. The results are compared with the approximation where both effects are treated independently and the corrections simply multiplied. The deviation between the exact and approximated results takes the form of a temperature dependent function for which an analytical expression is given. The knowledge of this function allows simple and accurate estimations at the % level.
We examine the conditions of validity for the Lifshitz-Matsubara sum formula for the Casimir pressure between magnetic metallic plane mirrors. As in the previously studied case of non-magnetic materials (Guerout et al, Phys. Rev. E 90 042125), we recover the usual expression for the lossy model of optical response, but not for the lossless plasma model. We also show that the modes associated with the Foucault currents play a crucial role in the limit of vanishing losses, in contrast to expectations.
We carefully re-examine the conditions of validity for the consistent derivation of the Lifshitz-Matsubara sum formula for the Casimir pressure between metallic plane mirrors. We recover the usual expression for the lossy Drude model, but not for the lossless plasma model. We give an interpretation of this new result in terms of the modes associated with the Foucault currents which play a role in the limit of vanishing losses, in contrast to common expectations.
We propose a new theory of thermal Casimir effect, holding for the experimentally important case of metallic surfaces with a roughness having a spatial scale smaller than the skin depth. The theory is based on a simple phenomenological model for a rough conductor, that explicitly takes account of the fact that ohmic conduction in the immediate vicinity of the surface of a conductor is much impeded by surface roughness, if the amplitude of roughness is smaller than the skin depth. As a result of the new model, we find that surface roughness strongly influences the magnitude of the thermal corre…
The frequency spectrum of the finite temperature correction to the Casimir force can be determined by the use of the Lifshitz formalism for metallic plates of finite conductivity. We show that the correction for the TE electromagnetic modes is dominated by frequencies so low that the plates cannot be modelled as ideal dielectrics. We also address the issues relating to the behavior of electromagnetic fields at the surfaces an within metallic conductors, and claculate the surface modes using appropriate low-frequency metallic boundary conditions. Our result brings the tehrmal correction into ag…
The frequency spectrum of the finite temperature correction to the Casimir force can be determined by use of the Lifshitz formalism for metallic plates of finite conductivity. We show that the correction for the $TE$ electromagnetic modes is dominated by frequencies so low that the plates cannot be modelled as ideal dielectrics. We also address issues relating to the behavior of electromagnetic fields at the surfaces and within metallic conductors, and calculate the surface modes using appropriate low-frequency metallic boundary conditions. Our result brings the thermal correction into agreeme…
We study the lateral Casimir force between corrugated dielectric plates. We use the dielectric contrast perturbation theory [R. Golestanian, {\it Phys. Rev. Lett.} {\bf 95}, 230601, (2005)], which allows us to consider arbitrary deformations with large amplitudes. We consider sinusoidal, rectangular, and sawtooth corrugations, for samples made of silicon and gold. We use the plasma and Drude-Lorentz models for the permittivity of gold and silicon, respectively. For these geometries and materials, the lateral Casimir force is {\it not} a sinusoidal function of the relative lateral displacement …
We give a rigorous analytical derivation of low-temperature behavior of the Casimir entropy in the framework of the Lifshitz formula combined with the Drude dielectric function. An earlier result that the Casimir entropy at zero temperature is not equal to zero and depends on the parameters of the system is confirmed, i.e. the third law of thermodynamics (the Nernst heat theorem) is violated. We illustrate the resolution of this thermodynamical puzzle in the context of the surface impedance approach by several calculations of the thermal Casimir force and entropy for both real metals and diele…
Recently Guerout et al. [Phys. Rev. E, v.93, 022108 (2016)] advocated that the lossless plasma model has to be redefined as the limit of the Drude model when the relaxation parameter goes to zero. It was claimed that the previously used plasma model cannot correctly describe the Casimir pressure between two plates made of both nonmagnetic and magnetic metals and has to be replaced with the redefined one. We show that the suggested redefinition does not satisfy necessary physical requirements imposed on the dielectric permittivity. We also present a plausible explanation to the fact that the lo…
The physical origin of the negative thermal correction to the Casimir force between metals is clarified. For this purpose the asymptotic behavior of the thermal Casimir force is analyzed at large and small distances in the real frequency representation. Contributions from propagating and evanescent waves are considered separately. At large distances they cancel each other in substantial degree so that only the attractive Lifshitz limit survives. At smaller separations the repulsive evanescent contribution of s-polarization dominates in the case of two metals or a metal and a high-permittivity …
The first precise measurement of the Casimir force between dissimilar metals is reported. The attractive force, between a Cu layer evaporated on a microelectromechanical torsional oscillator, and an Au layer deposited on an Al$_2$O$_3$ sphere, was measured dynamically with a noise level of 6 fN/$\sqrt{\rm{Hz}}$. Measurements were performed for separations in the 0.2-2 $μ$m range. The results agree to better than 1% in the 0.2-0.5 $μ$m range with a theoretical model that takes into account the finite conductivity and roughness of the two metals. The observed discrepancies, which are much larger…
We investigate the thermodynamical aspects of the Casimir effect in the case of plane parallel plates made of real metals. The thermal corrections to the Casimir force between real metals were recently computed by several authors using different approaches based on the Lifshitz formula with diverse results. Both the Drude and plasma models were used to describe a real metal. We calculate the entropy density of photons between metallic plates as a function of the surface separation and temperature. Some of these approaches are demonstrated to lead to negative values of entropy and to nonzero en…
We investigate the electromagnetic Casimir interactions of an object contained within an otherwise empty, perfectly conducting spherical shell. For a small object we present analytical calculations of the force, which is directed away from the center of the cavity, and the torque, which tends to align the object opposite to the preferred alignment outside the cavity. For a perfectly conducting sphere as the interior object, we compute the corrections to the proximity force approximation (PFA) numerically. In both cases the results for the interior configuration match smoothly onto those for th…
We find the joint effect of non-zero temperature and finite conductivity onto the Casimir force between real metals. Configurations of two parallel plates and a sphere (lens) above a plate are considered. Perturbation theory in two parameters (the relative temperature and the relative penetration depth of zero point oscillations into the metal) is developed. Perturbative results are compared with computations. Recent evidence concerning possible existence of large temperature corrections at small separations between the real metals is not supported.
The surface impedance approach to the description of the thermal Casimir effect in the case of real metals is elaborated starting from the free energy of oscillators. The Lifshitz formula expressed in terms of the dielectric permittivity depending only on frequency is shown to be inapplicable in the frequency region where a real current may arise leading to Joule heating of the metal. The standard concept of a fluctuating electromagnetic field on such frequencies meets difficulties when used as a model for the zero-point oscillations or thermal photons in the thermal equilibrium inside metals.…
We investigate the Casimir force acting between real metals at nonzero temperature. It is shown that the zero-frequency term of Lifshitz formula has interpretation problem in the case of real metal described by Drude model. It happens because the scattering theory underlying Lifshitz formula is not well formulated when the dielectric permittivity takes account of dissipation. To give the zeroth term of Lifshitz formula the definite meaning different prescriptions were used recently by different authors with diversed results. These results are shown to be improper and in disagreement with exper…
Recently J.S. Hoye, I.Brevik, J.B. Aarseth, and K.A. Milton [Phys. Rev. E v.67, 056116 (2003); quant-ph/0212125] proposed that if the Lifshitz formula is combined with the Drude model, the transverse electric zero mode does not contribute to the result for real metals and there arises a linear temperature correction to the Casimir force at small temperatures. The authors claim that in spite of the fact that the Casimir entropy in their approach is negative, the Nernst heat theorem is satisfied. In the present Comment we show that the authors' conclusion regarding the Nernst heat theorem is in …
In a recent paper, Geyer, Klimchitskaya, and Mostepanenko [Phys. Rev. A 67, 062102 (2003); quant-ph/0306038] proposed the final solution of the problem of temperature correction to the Casimir force between real metals. The basic idea was that one cannot use the dielectric permittivity in the frequency region where a real current may arise leading to Joule heating of the metal. Instead, the surface impedance approach is proposed as a solution of all contradictions. The purpose of this comment is to show that (i) the main idea contradicts to the fluctuation dissipation theorem, (ii) the propose…
The analytic asymptotic expressions for the Casimir free energy, pressure and entropy at low temperature in the configuration of one metal and one dielectric plate are obtained. For this purpose we develop the perturbation theory in a small parameter proportional to the product of the separation between the plates and the temperature. This is done using both the simplified model of an ideal metal and of a dielectric with constant dielectric permittivity and for the realistic case of the metal and dielectric with frequency-dependent dielectric permittivities. The analytic expressions for all re…
We present systematic measurements of the Casimir force between a gold-coated plate and a sphere coated with a Hydrogen Switchable Mirror (HSM). HSMs are shiny metals that can become transparent by hydrogenation. In spite of such a dramatic change of the optical properties of the sphere, we did not observe any significant decrease of the Casimir force after filling the experimental apparatus with hydrogen. This counterintuitive result can be explained by the Lifshitz theory that describes the Casimir attraction between metallic and dielectric materials.
The frequencies of transitions between hyperfine levels of ground-state atoms can be measured with exquisite precision using magnetic-resonance techniques. This makes hyperfine transitions ideal probes of QED effects originating from the interaction of atoms with the quantized electromagnetic field. One of the most remarkable effects predicted by QED is the Casimir-Polder shift experienced by the energy levels of atoms placed near one or more dielectric objects. Here we compute the Casimir-Polder shift and the width of hyperfine transitions between ground-state Zeeman sub-levels of an hydrogen…
The Casimir and van der Waals forces acting between two metallic plates or a sphere (lens) above a plate are calculated accounting for the finite conductivity of the metals. The simple formalism of surface modes is briefly presented which allows the possibility to obtain the generalization of Lifshitz results for the case of two semi-spaces covered by the thin layers. Additional clarifications of the regularization procedure provides the means to obtain reliable results not only for the force but also for the energy density. This, in turn, leads to the value of the force for the configuration …
The regularized total Casimir energy in spacetimes with boundaries is not in general equal to the integral of the regularized energy density. This paradoxical phenomenon is most transparently analyzed in the simple example of a massless scalar field in 1+1 dimensions confined to a line element of length $L$ and obeying Dirichlet boundary conditions.
We comment on progress in measurements of the Casimir force and discuss what is the actual reliability of different experiments. In this connection a more rigorous approach to the usage of such concepts as accuracy, precision, and measure of agreement between experiment and theory, is presented. We demonstrate that all measurements of the Casimir force employing spherical lenses with centimeter-size curvature radii are fundamentally flawed due to the presence of bubbles and pits on their surfaces. The commonly used formulation of the proximity force approximation is shown to be inapplicable fo…
he Casimir force is calculated between plates with thin metallic coating. Thin films are described with spatially dispersive (nonlocal) dielectric functions. For thin films the nonlocal effects are more relevant than for half-spaces. However, it is shown that even for film thickness smaller than the mean free path for electrons, the difference between local and nonlocal calculations of the Casimir force is of the order of a few tenths of a percent. Thus the local description of thin metallic films is adequate within the current experimental precision and range of separations.
We consider the vacuum-field pressure on boundaries of a metal slab in the middle of a cavity with perfectly reflecting mirrors adopting the plasma model for the metal and paying special attention to the surface plasmon polariton contribution to the pressure. We demonstrate that, with increasing cavity length, the pressure on a thin (d<<λ_P) slab in this system decreases from the Casimir pressure F_C at zero slab-mirror distances to the non-retarded force per unit area F_nr=1.19 (d/λ_P)F_C in the case of an isolated slab. In the first case the pressure is entirely due to the photonic modes pro…
We consider the Casimir-Polder interaction energy between a metallic nanoparticle and a metallic plate, as well as the Casimir interaction energy between two macroscopic metal plates, in terms of the many-body dispersion interactions between their constituents. Expressions for two- and three-body dispersion interactions between the microscopic parts of a real metal are first obtained, both in the retarded and non-retarded limits. These expressions are then used to evaluate, a compare each other, the overall two- and three-body contributions to the macroscopic Casimir-Polder and Casimir force, …
We discuss the temperature correction to the Casimir force between nonideal metallic bodies which caused disagreement in the literature. A general method to find the troubling term is proposed that does not require a direct reference to the Lifshitz formula. The linear in temperature correction is shown to survive for nonideal metals. It is important for small separations between bodies tested in the recent experiments.
It is well known that the Casimir force calculated at large separations using the Lifshitz theory differs by a factor of 2 for metals described by the Drude or plasma models. We argue that this difference is entirely determined by the contribution of transverse electric (s) evanescent waves. Taking into account that there is a lack of experimental information on the electromagnetic response of metals to low-frequency evanescent waves, we propose an experiment on measuring the magnetic field of an oscillating magnetic dipole spaced in vacuum above a thick metallic plate. According to our result…
The possibility to modify the strength of the Casimir effect by tailoring the dielectric functions of the interacting surfaces is regarded as a unique opportunity in the development of Micro- and NanoElectroMechanical Systems. In air, however, one expects that, unless noble metals are used, the electrostatic force arising from trapped charges overcomes the Casimir attraction, leaving no room for exploitation of Casimir force engineering at ambient conditions. Here we show that, in the presence of a conductive oxide, the Casimir force can be the dominant interaction even in air, and that the us…
We consider the Casimir effect of a massive vector field between two semi-infinite dielectric slabs. We first derive the generalization of the Lifshitz formula that gives the Casimir interaction energy of two magnetodielectric slabs separated by a magnetodielectric medium due to the vacuum fluctuations of a massive vector field. We then discuss the asymptotic behaviors of the Casimir energy and the Casimir force in various limits, such as low temperature, high temperature, small mass, large mass, up to the first order in the finite conductivity correction, for two real metal semispaces whose d…
We report an improved precision measurement of the Casimir force. The force is measured between a large Al coated sphere and flat plate using an Atomic Force Microscope. The primary experimental improvements include the use of smoother metal coatings, reduced noise, lower systematic errors and independent measurement of surface separations. Also the complete dielectric spectrum of the metal is used in the theory. The average statistical precision remains at the same 1% of the forces measured at the closest separation.
We propose a test on the role of relaxation properties of conduction electrons in the Casimir pressure between two parallel metal-coated plates kept at different temperatures. It is shown that for sufficiently thick metallic coatings the Casimir pressure and pressure gradient are determined by the mean of the equilibrium contributions calculated at temperatures of the two plates and by the term independent on separation. Numerical computations of the nonequilibrium pressures are performed for two parallel Au plates of finite thickness as a function of separation and temperature of one of the p…
For the first time, we have studied the impact of magnetic polarizability of a neutral metallic particle on the dynamical Casimir-Polder force, when the particle is uniformly moving with relativistic velocity parallel to the surface of an ideally conducting plate. The material properties of particle are taken into account within the Drude model approach.
The Casimir free energy and pressure of thin metal films deposited on metallic plates are considered using the Lifshitz theory and the Drude and plasma model approaches to the role of conduction electrons. The bound electrons are taken into account by using the complete optical data of film and plate metals. It is shown that for films of several tens of nanometers thickness the Casimir free energy and pressure calculated using these approaches differ by hundreds and thousands percent and can be easily discriminated experimentally. According to our results, the free energy of a metal film does …
The Casimir interaction between two thick parallel plates, one made of metal and the other of dielectric, is investigated at nonzero temperature. It is shown that in some temperature intervals the Casimir pressure and the free energy of a fluctuating field are the nonmonotonous functions of temperature and the respective Casimir entropy can be negative. The physical interpretation for these conclusions is given. At the same time we demonstrate that the entropy vanishes when the temperature goes to zero, i.e., in the Casimir interaction between metal and dielectric the Nernst heat theorem is sa…
There has been recent criticism of our approach to the Casimir force between real metallic surfaces at finite temperature, saying it is in conflict with the third law of thermodynamics and in contradiction with experiment. We show that these claims are unwarranted, and that our approach has strong theoretical support, while the experimental situation is still unclear.
The measurement of the Casimir force between a large gold coated sphere and single crystal silicon plate is performed with an atomic force microscope. A rigorous statistical comparison of data with theory is done, without use of the concept of root-mean-square deviation, and excellent agreement is obtained. The Casimir force between metal and semiconductor is demonstrated to be significantly different than between two similar or dissimilar metals.
We give an example of a geometry in which two metallic objects in vacuum experience a repulsive Casimir force. The geometry consists of an elongated metal particle centered above a metal plate with a hole. We prove that this geometry has a repulsive regime using a symmetry argument and confirm it with numerical calculations for both perfect and realistic metals. The system does not support stable levitation, as the particle is unstable to displacements away from the symmetry axis.
The new approach to the theoretical description of the thermal Casimir force between real metals is presented. It uses the plasma-like dielectric permittivity that takes into account the interband transitions of core electrons. This permittivity precisely satisfies the Kramers-Kronig relations. The respective Casimir entropy is positive and vanishes at zero temperature in accordance with the Nernst heat theorem. The physical reasons why the Drude dielectric function, when substituted in the Lifshitz formula, is inconsistent with electrodynamics are elucidated. The proposed approach is the sing…
The energy of fluctuating electromagnetic field is investigated for the thermal Casimir force acting between parallel plates made of real metal. It is proved that for nondissipative media with temperature independent dielectric permittivity the energy at nonzero temperature comprises of the (renormalized) energies of the zero-point and thermal photons. In this manner photons can be considered as collective elementary excitations of the matter of plates and electromagnetic field. If the dielectric permittivity depends on temperature the energy contains additional terms proportional to the deriv…
We study the electromagnetic Casimir interaction of a compact object contained inside a closed cavity of another compact object. We express the interaction energy in terms of the objects' scattering matrices and translation matrices that relate the coordinate systems appropriate to each object. When the enclosing object is an otherwise empty metallic spherical shell, much larger than the internal object, and the two are sufficiently separated, the Casimir force can be expressed in terms of the static electric and magnetic multipole polarizabilities of the internal object, which is analogous to…
We extend our previous work [Phys. Rev. Lett. {\bf 100}, 183602 (2008)] on the generalization of the Casimir-Lifshitz theory to treat anisotropic magnetodielectric media, focusing on the forces between metals and magnetodielectric metamaterials and on the possibility of inferring magnetic effects by measurements of these forces. We present results for metamaterials including structures with uniaxial and biaxial magnetodielectric anisotropies, as well as for structures with isolated metallic or dielectric properties that we describe in terms of filling factors and a Maxwell Garnett approximatio…
Optical properties of the deposited gold films are discussed in connection with the Casimir force prediction. Voids in the films and electron scattering on the grain boundaries reduce the force at small separations on the 2% level in comparison with the bulk material prediction. The contribution of the patch potential due to polycrystalline structure of the films is shown to be small for the existing Casimir force experiments.
We study the Casimir-Polder potential of a multilevel alkali-metal atom near an optical nanofiber. We calculate the mean potential of the atom in a fine-structure level. We perform numerical calculations for the Casimir-Polder potentials of the ground state and a few low-lying excited states of a rubidium atom. We show that, unlike the potential of the ground state, which is negative and attractive, the potential of a low-lying excited state may take positive values, oscillate around the zero value with a decaying amplitude, and become repulsive in some regions of atom-to-surface distances. We…
