The ideal Bose-gas with finite number $N$ of particles is investigated. The exact expressions for the partition functions and occupation numbers in the grand canonical, canonical and microcanonical ensembles are found. The asymp\-totic expressions (in the case $N\gg1$) for the partition functions and occupation numbers in the canonical and microcanonical ensembles are evaluated. It is shown that the chemical potential $μ$ of the ideal Bose-gas can lie in the range $-\infty<μ<\infty$ oppositely to the widely adopted opinion that the value of this potential is negative.
We study the Bose-Einstein condensation for a 3-d system of ideal Bose gas which is harmonically trapped along two perpendicular directions and is confined in between two slabs along the other perpendicular direction. We calculate the Casimir force between the two slabs for this system of trapped Bose gas. At finite temperatures this force for thermalized photons in between two plates has a classical expression which is independent of $\hbar$. At finite temperatures the Casimir force for our system depends on $\hbar$. For the calculation of Casimir force we consider only the Dirichlet boundary…
We study the Casimir effect for a 3-d system of ideal Bose gas in a slab geometry with Dirichlet boundary condition. We calculate the temperature($T$) dependence of the Casimir force below and above the Bose-Einstein condensation temperature($T_c$). At $T\le T_c$ the Casimir force vanishes as $[\frac{T}{T_c}]^{3/2}$. For $T\gtrsim T_c$ it weakly depends on temperature. For $T\gg T_c$ it vanishes exponentially. At finite temperatures this force for thermalized photons in between two plates has a classical expression which is independent of $\hbar$. At finite temperatures the Casimir force for o…
The ideal uniform two-dimensional (2D) Fermi and Bose gases are considered both in the thermodynamic limit and the finite case. We derive May's Theorem, viz. the correspondence between the internal energies of the Fermi and Bose gases in the thermodynamic limit. This results in both gases having the same heat capacity. However, as we shall show, the thermodynamic limit is never truly reached in two dimensions and so it is essential to consider finite-size effects. We show in an elementary manner that for the finite 2D Bose gas, a pseudo-Bose-Einstein condensate forms at low temperatures, incom…
The Casimir effect of an ideal Bose gas trapped in a generic power-law potential and confined between two slabs with Dirichlet, Neumann, and periodic boundary conditions is investigated systematically, based on the grand potential of the ideal Bose gas, the Casimir potential and force are calculated. The scaling function is obtained and discussed. The special cases of free and harmonic potentials are also discussed. It is found that when T<Tc (where Tc is the critical temperature of Bose-Einstein condensation), the Casimir force is a power-law decay function; when T>Tc, the Casimir force is an…
We consider an ideal Bose gas contained in a cylinder in three spatial dimensions, subjected to a uniform gravitational field. It has been claimed by some authors that there is discrepancy between the semi-classical and quantum calculations in the thermal properties of such a system. To check this claim, we calculate the heat capacity and isothermal compressibility of this system semi-classically as well as from the quantum spectrum of the density of states. The quantum calculation is done for a finite number of particles. We find good agreement between the two calculations when the number of …
We discuss the relationship between the cycle probabilities in the path-integral representation of the ideal Bose gas, off-diagonal long-range order, and Bose--Einstein condensation. Starting from the Landsberg recursion relation for the canonic partition function, we use elementary considerations to show that in a box of size L^3 the sum of the cycle probabilities of length k >> L^2 equals the off-diagonal long-range order parameter in the thermodynamic limit. For arbitrary systems of ideal bosons, the integer derivative of the cycle probabilities is related to the probability of condensing k…
Using a field-theoretic approach, we systematically generalize the usual semiclassical approximation for a harmonically trapped ideal Bose gas in such a way that its range of applicability is essentially extended. With this we can analytically calculate thermodynamic properties even for small particle numbers. In particular, it now becomes possible to determine the critical temperature as well as the temperature dependence of both heat capacity and condensate fraction in low-dimensional traps, where the standard semiclassical approximation is not even applicable.
We study an ideal Bose gas of N atoms contained in a box formed by two identical planar and parallel surfaces S, enclosed by a mantle of height a perpendicular to them. Calling r0 the mean atomic distance, we assume S >> r0^2 while a may be comparable to r0. In the bidimensional limit (a/r0 << 1) we find a macroscopic number of atoms in the condensate at temperatures T ~1/log(N); therefore, condensation cannot be described in terms of intensive quantities; in addition, it occurs at temperatures not too low in comparison to the tridimensional case. When condensation is present we also find a ma…
In a recent experiment, a Bose-Einstein condensate was trapped in an anharmonic potential which is well approximated by a harmonic and a quartic part. The condensate was set into such a fast rotation that the centrifugal force in the corotating frame overcompensates the harmonic part in the plane perpendicular to the rotation axis. Thus, the resulting trap potential became Mexican-hat shaped. We present an analysis for an ideal Bose gas which is confined in such an anharmonic rotating trap within a semiclassical approximation where we calculate the critical temperature, the condensate fraction…
A Bose gas in an external potential is studied by means of the local density approximation. Analytical results are derived for the thermodynamic properties of an ideal Bose gas in a generic power-law trapping potential, and their dependence on the mutual interaction of atoms in the case of a non-ideal Bose gas.
We study the behaviour of an ideal non-relativistic Bose gas in a three-dimensional space where one of the dimensions is compactified to form a circle. In this case there is no phase transition like that for the case of an infinite volume, nevertheless Bose-Einstein condensation signified by a sudden buildup of particles in the ground state can occur. We use the grand canonical ensemble to study this problem. In particular, the specific heat is evaluated numerically, as well as analytically in certain limits. We show analytically how the familiar result for the specific heat is recovered as we…
We show that the recently discovered thermodynamic equivalence between noninteracting Bose and Fermi gases in two dimensions, and between one-dimensional Bose and Fermi systems with linear dispersion, both in the grand-canonical ensemble, are special cases of a larger class of equivalences of noninteracting systems having an energy-independent single-particle density of states. We also conjecture that the same equivalence will hold in the grand-canonical ensemble for any noninteracting quantum gas with a discrete ladder-type spectrum whenever $σΔ/ N k_{\rm B} T$ is small, where $N$ is the aver…
We analyze the Casimir forces for an ideal Bose gas enclosed between two infinite parallel walls separated by the distance D. The walls are characterized by the Dirichlet boundary conditions. We show that if the thermodynamic state with Bose-Einstein condensate present is correctly approached along the path pertinent to the Dirichlet b.c. then the leading term describing the large-distance decay of thermal Casimir force between the walls is 1/D^2 with a non-universal amplitude. The next order correction is lnD/D^3. These observations remain in contrast with the decay law for both the periodic …
A Bose gas in an external potential is studied by means of the semi-classical approximation. Analytical results are derived for the energy of an interacting Bose gas in a generic power-law trapping potential. An expression for the chemical potential below the critical temperature is also obtained. The theoretical results are in qualitative agreement with a recent energy measurement.
The wave function of a dilute hard sphere Bose gas at low temperatures is discussed, emphasizing the formation of pairs. The pair distribution function is calculated for two values of $\sqrt{ρa^3}$.
We investigate the exact solution of the q-deformed one-dimensional Bose gas to derive all integrals of motion and their corresponding eigenvalues. As an application, the thermodynamics is given and compared to an effective field theory at low temperatures.
We produce the discontinuity in the specific heat of a homogeneous, dilute, and weakly interacting Bose gas in a short-wavelength range with a simple statistical method. The magnitude of the discontinuity at the phase transition temperature is obtained as a function of the density and scattering length of the Bose particles.
In this paper, we calculate the explicit expression for the fugacity for two- and three-dimensional weakly interacting Bose and Fermi gases from their equations of state in isochoric and isobaric processes, respectively, based on the mathematical result of the boundary problem of analytic functions --- the homogeneous Riemann-Hilbert problem. We also discuss the Bose-Einstein condensation phase transition of three-dimensional hard-sphere Bose gases.
We study the charged non-relativistic Bose gas interacting with a constant magnetic field but which is otherwise free. The notion of Bose-Einstein condensation for the three dimensional case is clarified, and we show that although there is no condensation in the sense of a phase transition, there is still a maximum in the specific heat which can be used to define a critical temperature. Although the absence of a phase transition persists for all values of the magnetic field, we show how as the magnetic field is reduced the curves for the specific heat approach the free field curve. For large v…
We reconcile a long-standing controversy regarding the transition temperature of the Bose-Einstein condensation in a dilute interacting Bose gas, by showing that there is a crossover between ideal gas and interacting gas. The former corresponds to a Knudsen (or collisionless) regime, in which the mean-free-path is much larger than the system dimension, while the latter corresponds to the opposite hydrodynamic regime. The deviation of the transition temperature from that of the non-interacting gas is proportional to the square root of a in the Knudsen regime, and to a in the hydrodynamic regime…
We consider an ideal Bose gas enclosed in a $d$-dimensional slab of thickness $D$. Using the grand canonical ensemble we calculate the variance of the thermal Casimir force acting on the slab's walls. The variance evaluated per unit wall area is shown to decay like $ Δ_{var}/D$ for large $D$. The amplitude $ Δ_{var}$ is a non-universal function of two scaling variables $λ/ ξ$ and $D/ ξ$, where $λ$ is the thermal de Broglie wavelength and $ξ$ is the bulk correlation length. It can be expressed via the bulk pressure, the Casimir force per unit wall area, and its derivative with respect to chemic…
In this paper we show that for a non-ideal Bose gas there exists an upper limit on the transition temperature above which Bose-Einstein condensation cannot occur regardless of the pressure applied. Such upper limits for some realistic Bose gases are estimated. This result implies that there may also exist an upper limit on the transition temperature of superconductors.
We investigate the interaction effect between atoms and the finite size effect of a Bose-Einstein gas at finite temperature. Using a mean field approach, we derive the thermodynamic potential on finite systems and obtain the condensate fraction, the chemical potential and the internal energy with the interaction and the finite size effects taken into account. In this approach, we can treat thermodynamic quantities as those of the ideal Bose gas. It is found that the interaction effect shifts the transition temperature by a few percent toward the lower temperature. Above the transition temperat…
Physical properties of ideal Bose gas with the fractal dimensionality between D=2 and D=3 are theoretically investigated. Calculation shows that the characteristic features of the specific heat and the superfluid density of ideal Bose gas in fractal dimensions are strikingly similar to those of superfluid Helium-4 in porous media. This result indicates that the geometrical factor is dominant over mutual interactions in determining physical properties of Helium-4 in porous media.
We investigate the fluctuations of the condensate in the ideal and weakly interacting Bose gases confined in a box of volume V within canonical ensemble. Canonical ensemble is developed to describe the behavior of the fluctuations when different methods of approximation to the weakly interacting Bose gases are used. Research shows that the fluctuations of the condensate exhibit anomalous behavior for the interacting Bose gas confined in a box.
We present a scheme of analytical calculations determining the critical temperature and the number of condensed atoms of ideal gas Bose-Einstein condensation in external potentials with 1D, 2D or 3D periodicity. In particular we show that the width of the lowest energy band appears as the main parameter determining the critical temperature of condensation. Is obtained a very simple, proportional to 1/3 degree, regularity for this dependence. The fundamental role of tunneling in physics of condensate establishment is underscored.
Based on the canonical ensemble, we suggested the simple scheme for taking into account Gaussian fluctuations in a finite system of ideal boson gas. Within framework of scheme we investigated the influence of fluctuations on the particle distribution in Bose -gas for two cases - with taking into account the number of particles in the ground state and without this assumption. The temperature and fluctuation parameter dependences of the modified Bose- Einstein distribution have been determined. Also the dependence of the condensation temperature on the fluctuation distribution parameter has been…
We investigate perturbative thermodynamic geometry of nonextensive ideal Classical, Bose and Fermi gases.We show that the intrinsic statistical interaction of nonextensive Bose (Fermi) gas is attractive (repulsive) similar to the extensive case but the value of thermodynamic curvature is changed by nonextensive parameter. In contrary to the extensive ideal classical gas, the nonextensive one may be divided to two different regimes. According to deviation parameter of the system to the nonextensive case, one can find a special value of fugacity, $z^{*}$, where the sign of thermodynamic curvatur…
In this study, we have derived close form of the Casimir force for the non-interacting ideal Bose gas between two slabs in harmonic-optical lattice potential by using Ketterle and van Druten approximation. We find that Bose-Einstein condensation temperature $T_{c}$ is a critical point for different physical behavior of the Casimir force. We have shown that Casimir force of confined Bose gas in the presence of the harmonic-optical potential decays with inversely proportional to $d^{5}$ when $T\leq T_{c}$. However, in the case of $T>T_{c}$, it decays exponentially depends on separation $d$ of th…
In an ideal Bose gas that is driven into a steady state far from thermal equilibrium, a generalized form of Bose condensation can occur. Namely, the single-particle states unambiguously separate into two groups: the group of Bose-selected states, whose occupations increase linearly with the total particle number, and the group of all other states whose occupations saturate [Phys. Rev. Lett. 111, 240405 (2013)]. However, so far very little is known about how the number of Bose-selected states depends on the properties of the system and its coupling to the environment. The answer to this questio…
We show that the thermodynamic behavior of relativistic ideal Bose gas, recently studied numerically by Grether et al., can be obtained analytically. Using the analytical results, we obtain the critical behavior of the relativistic Bose gas exactly for all the regimes. We show that these analytical results reduce to those of Grether et al. in different regimes of the Bose gas. Furthermore, we also obtain an analytically closed form expression for the energy density for the Bose gas which is valid in all regimes.
Using semiclassical approximation method, Bose-Einstein condensation (BEC) of a relativistic ideal boson gas (RIBG) with and without antibosons in three-dimensional (3-D) harmonic traps is investigated. The BEC transition temperature T_{c} and the Helmholtz free energy at T_{c} are calculated. The effect of the rest mass of the boson on the properties of the system is also studied. We find that T_{c} of RIBG is higher than that of the nonrelativistic approximation. The RIBG with antibosons is also investigated and it is found that the Helmholtz free energy of the system with antibosons at T_{c…
The mean ground state occupation number and condensate fluctuations of interacting and non-interacting Bose gases confined in a harmonic trap are considered by using a canonical ensemble approach. To obtain the mean ground state occupation number and the condensate fluctuations, an analytical description for the probability distribution function of the condensate is provided directly starting from the analysis of the partition function of the system. For the ideal Bose gas, the probability distribution function is found to be a Gaussian one for the case of the harmonic trap. For the interactin…
Some thermodynamic properties of weakly interacting Bose systems are derived from dimensional and heuristic arguments and thermodynamic relations, without resorting to statistical mechanics.
Gas-liquid condensation (GLC) in an attractive Bose gas is studied on the basis of statistical mechanics. Using some results in combinatorial mathematics, the following are derived: (1) With decreasing temperature, the Bose-statistical coherence grows in the many-body wave function, which gives rise to the divergence of the grand partition function prior to Bose-Einstein condensation. It is a quantum-mechanical analogue to the GLC in a classical gas (quantum GLC). (2) This GLC is triggered by the bosons with zero momentum. Compared with the classical GLC, an incomparably weaker attractive forc…
We develop a theory to describe the damping of elementary excitations of a Bose-condensed gas in the hydrodynamic regime for the thermal cloud. We discuss second sound in a spatially homogeneous gas and the lowest excitations of a trapped condensate.
We briefly review the theory of Bose-Einstein condensation in the two-dimensional trapped Bose gas and, in particular the relationship to the theory of the homogeneous two-dimensional gas and the Berezinskii-Kosterlitz-Thouless phase. We obtain a phase diagram for the trapped two-dimensional gas, finding a critical temperature above which the free energy of a state with a pair of vortices of opposite circulation is lower than that for a vortex-free Bose-Einstein condensed ground state. We identify three distinct phases which are, in order of increasing temperature, a phase coherent Bose-Einste…
We propose a microscopic approach describing the interaction of an ideal gas of hydrogenlike atoms with a weak electromagnetic field. This approach is based on the Green-function formalism and an approximate formulation of the method of second quantization for quantum many-particle systems in the presence of bound states of particles. The dependencies of the propagation velocity and damping rate of electromagnetic pulses on the microscopic characteristics of the system are studied for a gas of hydrogenlike atoms. For a Bose-Einstein condensate of alkali-metal atoms we find the conditions when …
Properties of the ground state and the spectrum of elementary excitations are investigated for the low density ultracold spinor 3D Bose gas of particles with arbitrary nonzero spin. Gross-Pitaevskii equations are derived. Within the framework of the considering interaction Hamiltonian it is shown that the ground state spin structure and spin part of the chemical potential is determined by the renormalized interaction, being defined by the contribution of the virtual large momenta. The ferromagnetic structure of the ground state, and the equation of the phase, density, and spin dynamics are obt…
We study the lengths of the cycles formed by trajectories in the Feynman-Kac representation of the Bose gas. We discuss the occurrence of infinite cycles and their relation to Bose-Einstein condensation.
The question of whether the BEC is a necessary condition of the Meissner effect is examined. The electromagnetic susceptibility of a charged Bose gas with short-range repulsion is studied using the perturbation theory with respect to the repulsive force. With decreasing temperature, the Bose-statistical coherence grows, and prior to the BEC phase the susceptibility shows a singularity implying the Meissner effect. This means that the BEC is a sufficient, but not a necessary condition of the Meissner effect in the charged Bose gas with short-range repulsion.
We consider two-dimensional imperfect attractive Fermi and repulsive Bose gases consisting of spinless point particles whose total interparticle interaction energy is represented by $a N^2/2 V$ with $a=-a_{F}\leq 0$ for fermions, and $a=a_{B}\geq 0$ for bosons. We show that in spite of the attraction the thermodynamics of $d=2$ imperfect Fermi gas remains well defined for $0 \leq a_{F}\leq a_{0}=h^2/2πm$, and is exactly the same as the one of the repulsive imperfect Bose gas with $a_{B}=a_{0}-a_{F}$. In particular, for $a_{F}=a_{0}$ one observes the thermodynamic equivalence of the attractive …
We explore the phase transitions of the ideal relativistic neutral Bose gas confined in a cubic box, without assuming the thermodynamic limit nor continuous approximation. While the corresponding non-relativistic canonical partition function is essentially a one-variable function depending on a particular combination of temperature and volume, the relativistic canonical partition function is genuinely a two-variable function of them. Based on an exact expression of the canonical partition function, we performed numerical computations for up to hundred thousand particles. We report that if the …
We show that an Ideal Bose gas that is contained within a very thin ring exhibits phenomena analogous to the Bloch and Josephson oscillations of a charged Ideal Fermi gas in a thin ring. If the walls of the ring are constrained to have an angular velocity $ω$, the angular momentum has an anomalous component that is periodic in $ω$, with a period equal to the quantum of angular velocity $ω_{0}\equiv \hbar /mR^{2}$. If a constant applied torque is applied to the walls, there will be component of the angular momentum of the gas that is periodic in time, with a 'Josephson frequency' given by $f_{J…
A relativistic complex scalar boson field at finite temperature $T$ is examined below its critical Bose-Einstein condensation temperature. It is shown that at the same $T$ the state with antibosons has higher entropy, lower Helmholtz free energy and higher pressure than the state without antibosons, but the same Gibbs free energy as it should. This implies that the configuration without antibosons is metastable. Results are generalized for arbitrary $d$ spatial dimensions.
We investigate the isobar of an ideal Bose gas confined in a cubic box within the grand canonical ensemble, for a large yet finite number of particles, N. After solving the equation of the spinodal curve, we derive precise formulae for the supercooling and the superheating temperatures which reveal an N^{-1/3} or N^{-1/4} power correction to the known Bose-Einstein condensation temperature in the thermodynamic limit. Numerical computations confirm the accuracy of our analytical approximation, and further show that the isobar zigzags on the temperature-volume plane if N is greater than or equal…
We conduct a rigorous investigation into the thermodynamic instability of ideal Bose gas confined in a cubic box, without assuming thermodynamic limit nor continuous approximation. Based on the exact expression of canonical partition function, we perform numerical computations up to the number of particles one million. We report that if the number of particles is equal to or greater than a certain critical value, which turns out to be 7616, the ideal Bose gas subject to Dirichlet boundary condition reveals a thermodynamic instability. Accordingly we demonstrate - for the first time - that, a s…
Using a specially tuned mean-field Bose gas as a reference system, we establish a positive lower bound on the condensate density for continuous Bose systems with superstable two-body interactions and a finite gap in the one-particle excitations spectrum, i.e. we prove for the first time standard homogeneous Bose-Einstein condensation for such interacting systems.
We compute the shift of the transition temperature for a homogenous weakly interacting Bose gas in leading order in the scattering length a for given particle density n. Using variational perturbation theory through six loops in a classical three-dimensional scalar field theory, we obtain Delta T_c/T_c = 1.25+/-0.13 a n^(1/3), in agreement with recent Monte-Carlo results.
We investigate the effects of dimensional reduction in Bose gases induced by a strong harmonic confinement in the transverse cylindric radial direction. By using a generalized Lieb-Liniger theory, based on a variational treatment of the transverse width of the Bose gas, we analyze the transition from a 3D Bose-Einstein condensate to the 1D Tonks-Girardeau gas. The sound velocity and the frequency of the lowest compressional mode give a clear signature of the regime involved. We study also the case of negative scattering length deriving the phase diagram of the Bose gas (uniform, single soliton…
The model of spatial permutations is related to the Feynman-Kac representation of the Bose gas. The transition to infinite cycles corresponds to Bose-Einstein condensation. We review the general setting and some results, and we derive a multi-body interaction between permutation jumps, that is due to the original interactions between quantum particles.
The problem of particle fluctuations in arbitrary nonuniform systems with Bose-Einstein condensate is considered. This includes the case of trapped Bose atoms. It is shown that the correct description of particle fluctuations for any nonuniform system of interacting atoms always results in thermodynamically normal fluctuations.
Universal critical behavior in ideal Bose-Einstein condensation
Instituto de Física, Universidad Nacional Autónoma de México（墨西哥国立自治大学物理研究所）；Institut für Angewandte Physik, Universität Bonn（波恩大学应用物理研究所）；Kirchhoff-Institut für Physik, Universität Heidelberg（海德堡大学基希霍夫物理研究所）
How many $\mathrm{H_{2}O}$ molecules are needed to form water? While the precise answer is not known, it is clear that the answer should be a finite number rather than infinity. We revisit with care the ideal Bose gas confined in a cubic box which is discussed in most statistical physics textbooks. We show that the isobar of the ideal gas zigzags on the temperature-volume plane featuring a `boiling-like' discrete phase transition, provided the number of particles is equal to or greater than a particular value: 7616. This demonstrates for the first time how a finite system can feature a mathema…
The N-particle partition function of a one-dimensional $δ$-function bose gas is calculated explicitly using only the periodic boundary condition (the Bethe ansatz equation). The N-particles cluster integrals are shown to be the same as those by the thermal Bethe ansatz method.
We consider several models of interacting bosons in a one dimensional lattice. Some of them are not integrable like the Bose-Hubbard others are integrable. At low density all of these models can be described by the Bose gas with delta interaction. The lattice corrections corresponding to the different models are contrasted.
By considering the one-particle and two-particle scattering data of the spin-1/2 Heisenberg chain at T=0 we derive a continuum limit relating the spin chain to the 1D Bose gas. Applying this limit to the quantum transfer matrix approach of the Heisenberg chain we obtain expressions for the correlation functions of the Bose gas at arbitrary temperatures.
We apply the theorems from the theory of Toeplitz determinants to calculate the asymptotics of various correlators including the exponential ones in the inpenetrable one-dimensional Bose gas system. The known correlators in the free-fermion system are also used to test the generalized Fisher-Hartwig conjecture.
