Thermodynamic instability and first-order phase transition in an ideal Bose gas
Jeong-Hyuck Park, Sang-Woo Kim
备注：
1+21 pages; 3 figures (2 color and 1 B/W); Final version to appear in Physical Review A. Title changed from the previous one, "7616: Critical number of ideal Bose gas confined in a cubic box"
We conduct a rigorous investigation into the thermodynamic instability of ideal Bose gas confined in a cubic box, without assuming thermodynamic limit nor continuous approximation. Based on the exact expression of canonical partition function, we perform numerical computations up to the number of particles one million. We report that if the number of particles is equal to or greater than a certain critical value, which turns out to be 7616, the ideal Bose gas subject to Dirichlet boundary condition reveals a thermodynamic instability. Accordingly we demonstrate - for the first time - that, a system consisting of finite number of particles can exhibit a discontinuous phase transition featuring a genuine mathematical singularity, provided we keep not volume but pressure constant. The specific number, 7616 can be regarded as a characteristic number of 'cube' that is the geometric shape of the box.
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A Bose gas in an external potential is studied by means of the local density approximation. Analytical results are derived for the thermodynamic properties of an ideal Bose gas in a generic power-law trapping potential, and their dependence on the mutual interaction of atoms in the case of a non-ideal Bose gas.
How many $\mathrm{H_{2}O}$ molecules are needed to form water? While the precise answer is not known, it is clear that the answer should be a finite number rather than infinity. We revisit with care the ideal Bose gas confined in a cubic box which is discussed in most statistical physics textbooks. We show that the isobar of the ideal gas zigzags on the temperature-volume plane featuring a `boiling-like' discrete phase transition, provided the number of particles is equal to or greater than a particular value: 7616. This demonstrates for the first time how a finite system can feature a mathema…
We study the behaviour of an ideal non-relativistic Bose gas in a three-dimensional space where one of the dimensions is compactified to form a circle. In this case there is no phase transition like that for the case of an infinite volume, nevertheless Bose-Einstein condensation signified by a sudden buildup of particles in the ground state can occur. We use the grand canonical ensemble to study this problem. In particular, the specific heat is evaluated numerically, as well as analytically in certain limits. We show analytically how the familiar result for the specific heat is recovered as we…
We show that the recently discovered thermodynamic equivalence between noninteracting Bose and Fermi gases in two dimensions, and between one-dimensional Bose and Fermi systems with linear dispersion, both in the grand-canonical ensemble, are special cases of a larger class of equivalences of noninteracting systems having an energy-independent single-particle density of states. We also conjecture that the same equivalence will hold in the grand-canonical ensemble for any noninteracting quantum gas with a discrete ladder-type spectrum whenever $σΔ/ N k_{\rm B} T$ is small, where $N$ is the aver…
We analyze the Casimir forces for an ideal Bose gas enclosed between two infinite parallel walls separated by the distance D. The walls are characterized by the Dirichlet boundary conditions. We show that if the thermodynamic state with Bose-Einstein condensate present is correctly approached along the path pertinent to the Dirichlet b.c. then the leading term describing the large-distance decay of thermal Casimir force between the walls is 1/D^2 with a non-universal amplitude. The next order correction is lnD/D^3. These observations remain in contrast with the decay law for both the periodic …
We study the charged non-relativistic Bose gas interacting with a constant magnetic field but which is otherwise free. The notion of Bose-Einstein condensation for the three dimensional case is clarified, and we show that although there is no condensation in the sense of a phase transition, there is still a maximum in the specific heat which can be used to define a critical temperature. Although the absence of a phase transition persists for all values of the magnetic field, we show how as the magnetic field is reduced the curves for the specific heat approach the free field curve. For large v…
Using semiclassical approximation method, Bose-Einstein condensation (BEC) of a relativistic ideal boson gas (RIBG) with and without antibosons in three-dimensional (3-D) harmonic traps is investigated. The BEC transition temperature T_{c} and the Helmholtz free energy at T_{c} are calculated. The effect of the rest mass of the boson on the properties of the system is also studied. We find that T_{c} of RIBG is higher than that of the nonrelativistic approximation. The RIBG with antibosons is also investigated and it is found that the Helmholtz free energy of the system with antibosons at T_{c…
A relativistic complex scalar boson field at finite temperature $T$ is examined below its critical Bose-Einstein condensation temperature. It is shown that at the same $T$ the state with antibosons has higher entropy, lower Helmholtz free energy and higher pressure than the state without antibosons, but the same Gibbs free energy as it should. This implies that the configuration without antibosons is metastable. Results are generalized for arbitrary $d$ spatial dimensions.
The mean ground state occupation number and condensate fluctuations of interacting and non-interacting Bose gases confined in a harmonic trap are considered by using a canonical ensemble approach. To obtain the mean ground state occupation number and the condensate fluctuations, an analytical description for the probability distribution function of the condensate is provided directly starting from the analysis of the partition function of the system. For the ideal Bose gas, the probability distribution function is found to be a Gaussian one for the case of the harmonic trap. For the interactin…
We show that an Ideal Bose gas that is contained within a very thin ring exhibits phenomena analogous to the Bloch and Josephson oscillations of a charged Ideal Fermi gas in a thin ring. If the walls of the ring are constrained to have an angular velocity $ω$, the angular momentum has an anomalous component that is periodic in $ω$, with a period equal to the quantum of angular velocity $ω_{0}\equiv \hbar /mR^{2}$. If a constant applied torque is applied to the walls, there will be component of the angular momentum of the gas that is periodic in time, with a 'Josephson frequency' given by $f_{J…
