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arXiv 1105.5697cond-mat.quant-gascond-mat.stat-mechhep-th
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巨正则系综中理想玻色气体的等压线

Isobar of an ideal Bose gas within the grand canonical ensemble

Imtak Jeon, Sang-Woo Kim, Jeong-Hyuck Park

摘要:

本文研究了在巨正则系综中,当粒子数N很大但有限时,被限制在立方盒子中的理想玻色气体的等压线。通过求解旋节线方程,得到了精确的过冷和过热温度公式,在热力学极限下,该公式对已知的玻色-爱因斯坦凝聚温度进行了N^{-1/3}或N^{-1/4}次幂修正。数值计算证实了解析近似的准确性,并进一步表明,当N大于或等于14393时,等压线在温度-体积平面上是一致的。特别地,对于阿伏伽德罗粒子数,体积离散地膨胀约10^5倍。我们的结果与以前的研究在0.1%的误差内的正则系综定量同意。

英文摘要:

We investigate the isobar of an ideal Bose gas confined in a cubic box within the grand canonical ensemble, for a large yet finite number of particles, N. After solving the equation of the spinodal curve, we derive precise formulae for the supercooling and the superheating temperatures which reveal an N^{-1/3} or N^{-1/4} power correction to the known Bose-Einstein condensation temperature in the thermodynamic limit. Numerical computations confirm the accuracy of our analytical approximation, and further show that the isobar zigzags on the temperature-volume plane if N is greater than or equal to 14393. In particular, for the Avogadro's number of particles, the volume expands discretely about 10^5 times. Our results quantitatively agree with a previous study on the canonical ensemble within 0.1% error.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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