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arXiv 1708.08962cond-mat.mes-hall
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通过无偏压低电平电荷测量量化石墨烯-溶液界面的固有表面电荷密度和电荷转移电阻

Quantifying the intrinsic surface charge density and charge-transfer resistance of the graphene-solution interface through bias-free low-level charge measurement

Jinglei Ping, A. T. Charlie Johnson

摘要:

石墨烯的基于液体的生物应用需要对石墨烯-液体界面的定量理解,其中吸附离子的表面电荷密度、界面电荷转移电阻和界面电荷噪声特别重要。我们通过测量石墨烯电极和不同离子强度的水溶液之间的零偏压法拉第电荷转移,使用可重复的、低噪声的、最小微扰的电荷测量技术来量化这些性质。测量结果表明,吸附的离子具有约-32.8 mC m-2的负表面电荷密度和特定的电荷转移电阻为6.5 pm 0.3 M $Ω$ cm 2。所有测试离子浓度的标准化电流噪声功率谱密度塌陷到1/f特性,其中$α$ = 1.1 pm 0.2。所有的结果都与石墨烯-溶液界面的理论预测非常一致。这种用于在亚pC尺度下监测电荷转移的最小微扰方法具有低噪声和超低功耗(~ fW),使其非常适合用于液体环境中的低水平生物电子学。

英文摘要:

Liquid-based bio-applications of graphene require a quantitative understanding of the graphene-liquid interface, with the surface charge density of adsorbed ions, the interfacial charge transfer resistance, and the interfacial charge noise being of particular importance. We quantified these properties through measurements of the zero-bias Faradaic charge-transfer between graphene electrodes and aqueous solutions of varying ionic strength using a reproducible, low-noise, minimally perturbative charge measurement technique. The measurements indicated that adsorbed ions had a negative surface charge density of approximately -32.8 mC m-2 and that the specific charge transfer resistance was 6.5pm0.3 M$Ω$ cm2. The normalized current noise power spectral density for all ionic concentrations tested collapsed onto a 1/f characteristic with $α$=1.1pm0.2. All the results are in excellent agreement with predictions of the theory for the graphene-solution interface. This minimally-perturbative method for monitoring charge-transfer at the sub-pC scale exhibits low noise and ultra-low power consumption (~ fW), making it well-suited for use in low-level bioelectronics in liquid environments.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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