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arXiv 1707.02891cond-mat.supr-con
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Bi2Sr2CaCu2O8 +d超导线材晶间临界电流密度与热处理制度的关系

Investigation of inter-grain critical current density in Bi2Sr2CaCu2O8+d superconducting wires and its relationship with the heat treatment protocol

I. Pallecchi, A. Leveratto, V. Braccini, V. Zunino, A. Malagoli

摘要:

在这项工作中,我们研究了Bi2Sr2CaCu2O8+d超导线材制备过程中的每个不同的热处理阶段对晶粒内和晶粒间超导性能的影响。我们测量了温度从4 K到40 K和磁场高达7 T的磁临界温度Tc值和输运临界电流密度Jc。从分析考虑弱连接行为和邻近效应的自场临界电流密度Jc(T)的温度依赖性,我们研究了晶界(GB)对超导电流的透明性,并且我们建立了在制造过程的不同步骤中的GB氧化与GB对超导电流的透明性之间的关系。我们发现晶界氧化开始于第一结晶阶段,但在836 °C的平台和缓慢冷却阶段变得完全,并在延长的后退火步骤中进一步增强。这样的氧化使得GB更导电,从而改善晶粒间Jc值和温度依赖性。另一方面,从检查的Tc值的框架中的相图圆顶,我们发现,晶粒氧化已经在结晶步骤中的最佳掺杂,而连续的缓慢冷却和后退火处理进一步提高过掺杂的程度,特别是如果在氧气气氛中进行,而不是在空气中。

英文摘要:

In this work we investigate the effect of each different heat treatment stage in the fabrication of Bi2Sr2CaCu2O8+d superconducting wires on intra-grain and inter-grain superconducting properties. We measure magnetic critical temperature Tc values and transport critical current density Jc at temperatures from 4 K to 40 K and in fields up to 7 T. From an analysis of the temperature dependence of the self-field critical current density Jc(T) that takes into account weak link behavior and proximity effect, we study the grain boundaries (GB) transparency to supercurrents and we establish a relationship between GB oxygenation in the different steps of the fabrication process and the GB transparency to supercurrents. We find that grain boundary oxygenation starts in the first crystallization stage, but it becomes complete in the plateau at 836 °C and in slow cooling stages, and is further enhanced in the prolonged post annealing step. Such oxygenation makes GBs more conducting, thus improving the inter-grain Jc value and temperature dependence. On the other hand, from the inspection of the Tc values in the framework of the phase diagram dome, we find that grains are oxygenated already in the crystallization step up to the optimal doping, while successive slow cooling and post annealing treatments further enhance the degree of overdoping, especially if carried out in oxygen atmosphere rather than in air.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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