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arXiv 1208.5307cond-mat.supr-concond-mat.mtrl-sci
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Ag掺杂对层状Bi4O4S3超导电性的抑制

Suppression of superconductivity in layered Bi4O4S3 by Ag doping

S. G. Tan, P. Tong, Y. Liu, W. J. Lu, L. J. Li, B. C. Zhao, Y. P. Sun

摘要:

本文报道了新型层状超导体Bi_(4-x)Ag_xO_(4-S)_3(0<x<0.2)多晶样品的X射线衍射、磁化强度和输运测量结果。当x>0.10时,超导转变温度(TC)逐渐降低,最后被抑制.因此,电阻率从x 0.1的金属行为改变<0.1 to a semiconductor-like behavior for x>。Seebeck系数的分析表明,有两种类型的类电子载流子占主导地位,在不同的温度范围内,表示负责的输运性质的多带效应。超导性的抑制和电阻率的增加可以归因于掺杂后费米能级向低能侧的偏移,这降低了EF处的态密度。此外,我们的结果表明,在母Bi 4 O 4S 3的超导电性是本征和掺杂剂Ag更喜欢进入BiS 2层,这可能会从根本上改变电子结构。

英文摘要:

We report X-ray diffraction, magnetization and transport measurements for polycrystalline samples of the new layered superconductor Bi4-xAgxO4S3 (0<x<0.2). The superconducting transition temperature (TC) decreases gradually and finally suppressed for x>0.10. Accordingly, the resistivity changes from a metallic behavior for x<0.1 to a semiconductor-like behavior for x>0.1. The analysis of Seebeck coefficient shows there are two types of electron-like carriers dominate at different temperature regions, indicative of a multiband effect responsible for the transport properties. The suppression of superconductivity and the increased resistivity can be attributed to a shift of the Fermi level to the lower-energy side upon doping, which reduces the density of states at EF. Further, our result indicates the superconductivity in the parent Bi4O4S3 is intrinsic and the dopant Ag prefers to enter the BiS2 layers, which may essentially modify the electronic structure.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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