The efficiency at the maximum power (EMP) for finite-time Carnot engines established with the low-dissipation model, relies significantly on the assumption of the inverse proportion scaling of the irreversible entropy generation $ΔS^{(\mathrm{ir})}$ on the operation time $τ$, i.e., $ΔS^{(\mathrm{ir})}\propto1/τ$. The optimal operation time of the finite-time isothermal process for EMP has to be within the valid regime of the inverse proportion scaling. Yet, such consistency was not tested due to the unknown coefficient of the $1/τ$-scaling. In this paper, using a two-level atomic heat engine as an illustration, we reveal that the optimization of the finite-time Carnot engines with the low-dissipation model is self-consistent only in the regime of $η_{\mathrm{C}}\ll1$, where $η_{\mathrm{C}}$ is the Carnot efficiency. In the large-$η_{\mathrm{C}}$ regime, the operation time for EMP obtained with the low-dissipation model is not within the valid regime of the $1/τ$-scaling, and the exact EMP is found to surpass the well-known bound $η_{+}=η_{\mathrm{C}}/(2-η_{\mathrm{C}})$
In order to build a quantum analog of traditional Carnot engine, a common choice is replacing the two thermodynamic adiabatic processes with two quantum mechanical adiabatic processes. In general, such quantum Carnot engine has six strokes. We analyze the efficiency of such six-stroke quantum Carnot engine in a perturbative way.
A quantum-mechanical analog of the Carnot engine reversibly working at vanishing temperature, shortly termed the quantum-mechanical Carnot engine, is discussed. A general formula for the efficiency of such an engine with an arbitrary confining potential is presented. Its expression is purely given in terms of the structure of the energy spectrum. Dependency of the efficiency on the form of a potential as an analog of the working material in thermodynamics implies nonuniversality of the engine. This may be due to the absence of the second-law-like principle in pure-state quantum mechanics.
A role of the superposition principle is discussed for the quantum-mechanical Carnot engine introduced by Bender, Brody, and Meister [J. Phys. A 33, 4427 (2000)]. It is shown that the efficiency of the engine can be enhanced by superposition of quantum states. A finite-time process is also discussed, and the condition of the maximum power output is presented. Interestingly, the efficiency at the maximum power is lower than that without superposition.
Stability is an important property of small thermal machines with fluctuating power output. We here consider a finite-time quantum Carnot engine based on a degenerate multilevel system and study the influence of its finite Hilbert space structure on its stability. We optimize in particular its relative work fluctuations with respect to level degeneracy and level number. We find that its optimal performance may surpass those of nondegenerate two-level engines or harmonic oscillator motors. Our results show how to realize high-performance, high-stability cyclic quantum heat engines.
We investigate the efficiency at maximum power (EMP) of irreversible quantum Carnot engines that perform finite-time cycles between two temperature tunable baths. The temperature form we adopt can be experimentally realized in squeezed baths in the high temperature limit, which makes our proposal of practical relevance. Focusing on low dissipation engines, we first generalize the pervious upper as well as lower bounds for the EMP to temperature tunable cases in which they are solely determined by a generalized Carnot limit. As an illustrative example, we then consider a minimal heat engine mod…
The Carnot statement of the second law of thermodynamics poses an upper limit on the efficiency of all heat engines. Recently, it has been studied whether generic quantum features such as coherence and quantum entanglement could allow for quantum devices with efficiencies larger than the Carnot efficiency. The present study shows that this is not permitted by the laws of thermodynamics. In particular, we will show that rather the definition of heat has to be modified to account for the thermodynamic cost for maintaining coherence and entanglement. Our theoretical findings are numerically illus…
In this work an example of a cyclic engine based on a quantum-mechanical properties of the strongly non linear quantum oscillator described by the Poschl-Teller [PT] model is examined. Using the [PT] model as shown in our earlier works [1-4], a quantum-mechanical analog of Carnot cycle (i.e quantum heat engine) has been constructed through the changes of both, the width L of the well and its quantum state. This quantum heat engine has a cycle consisting of adiabatic and isothermal quantum processes. The efficiency of the quantum engine based on the Poschl-Teller-like potential is derived and i…
Approaching Carnot Efficiency at Finite Power in an Experimentally Feasible Quantum Heat Engine
The University of Tokyo（东京大学）；RIKEN Center for Quantum Computing (RQC)（理化学研究所量子计算中心）；Inamori Research Institute for Science (InaRIS)（稻盛科学研究所）；Kyushu University（九州大学）
We want to understand whether and to which extent the maximal (Carnot) efficiency for heat engines can be reached at a finite power. To this end we generalize the Carnot cycle so that it is not restricted to slow processes. We show that for realistic (i.e. not purposefully-designed) engine-bath interactions, the work-optimal engine performing the generalized cycle close to the maximal efficiency has a long cycle time and hence vanishing power. This aspect is shown to relate to the theory of computational complexity. A physical manifestation of the same effect is the Levinthal's paradox in the …
There exists a consistent thermodynamical formalism with canonical definition of local temperatures which allows to extend the Carnot bound also to non-equilibrium baths, like those discussed in the Letter
Based on a quantum thermodynamic protocol for shortcut to isothermality that smoothly modify the system-reservoir interaction can significantly speed up an isothermal process while keeping the overall dissipation constant [Phys. Rev. X. 10, 031015 (2020)], we extend the study of optimization performance of Carnot-like heat engines and refrigerators in a straightforward and unified way. We derive the universal optimization efficiency of heat engines and the optimization coefficient of performance of refrigerators under two unified optimization criterions, i.e., chi criterion and omega criterion…
A cyclic thermodynamic heat engine runs most efficiently if it is reversible. Carnot constructed such a reversible heat engine by combining adiabatic and isothermal processes for a system containing an ideal gas. Here, we present an example of a cyclic engine based on a single quantum-mechanical particle confined to a potential well. The efficiency of this engine is shown to equal the Carnot efficiency because quantum dynamics is reversible. The quantum heat engine has a cycle consisting of adiabatic and isothermal quantum processes that are close analogues of the corresponding classical proce…
Carnot's theorem poses a fundamental limit on the maximum efficiency achievable from an engine that works between two reservoirs at thermal equilibrium. We extend this result to the case of arbitrary nonthermal stationary reservoirs, even with quantum coherence. In order to do this we prove that a single nonthermal reservoir is formally equivalent to multiple equilibrium ones. Finally, we discuss the possibility of realizing an engine that works at unit efficiency by exploiting quantum coherence present in the reservoir.
In their work [J. Phys. A: Math. Gen. 33, 4427 (2000)], Bender, Brody, and Meister have shown by employing a two-state model of a particle confined in the one-dimensional infinite potential well that it is possible to construct a quantum-mechanical analog of the Carnot engine through the changes of both the width of the well and the quantum state in a specific manner. Here, a discussion is developed about realizing the maximum power of such an engine, where the width of the well moves at low but finite speed. The efficiency of the engine at the maximum power output is found to be universal ind…
We consider the optimization of a finite-time Carnot engine characterized by small dissipations. We bound the power with a simple inequality and show that the optimal strategy is to perform small cycles around a given working point, which can be thus chosen optimally. Remarkably, this optimal point is independent of the figure of merit combining power and efficiency that is being maximized. Furthermore, for a general class of dynamics the power output becomes proportional to the heat capacity of the working substance. Since the heat capacity can scale supra-extensively with the number of const…
We study the physical implementation of the Photon Carnot engine (PCE) based on the cavity QED system [M. Scully et al, Science, \textbf{299}, 862 (2003)]. Here, we analyze two decoherence mechanisms for the more practical systems of PCE, the dissipation of photon field and the pure dephasing of the input atoms. As a result we find that (I) the PCE can work well to some extent even in the existence of the cavity loss (photon dissipation); and (II) the short-time atomic dephasing, which can destroy the PCE, is a fatal problem to be overcome.
We propose a spin-star network, where a central spin-$1/2$ is coupled with XXZ interaction to $N$ outer spin-$1/2$ particles, as a quantum fuel. If the network is in thermal equilibrium with a cold bath, the central spin can have an effective temperature larger than the bath one and scaling nonlinearly with $N$. The nonlinearity can be tuned to $N^2, N^3$ or $N^4$ with the anisotropy parameter of the coupling. Using a stream of central-spin particles to pump a micromaser cavity, we calculate the dynamics of the cavity field using a coarse-grained master equation. Our study reveals that the cen…
Heat engines extract work by running cyclically between two heat reservoirs. When the two reservoirs are thermal and at different temperatures, the maximum efficiency of the engine is given by the Carnot limit. Here we consider a quantum Otto cycle for a time-dependent harmonic oscillator coupled to an engineered squeezed thermal reservoir. We show that the efficiency at maximum power increases with the degree of squeezing, exponentially approaching unity for large squeezing parameters $r$. Furthermore, we propose an experimental scheme to implement such a system by using a single trapped ion …
A heat engine operating in the one-shot finite-size regime, where systems composed of a small number of quantum particles interact with hot and cold baths and are restricted to one-shot measurements, delivers fluctuating work. Further, engines with lesser fluctuation produce a lesser amount of deterministic work. Hence, the heat-to-work conversion efficiency stays well below the Carnot efficiency. Here we overcome this limitation and attain Carnot efficiency in the one-shot finite-size regime, where the engines allow the working systems to simultaneously interact with two baths via the semi-lo…
We investigate scaling of work and efficiency of a photonic Carnot engine with the number of quantum coherent resources. Specifically, we consider a generalization of the "phaseonium fuel" for the photonic Carnot engine, which was first introduced as a three-level atom with two lower states in a quantum coherent superposition by [M. O. Scully, M. Suhail Zubairy, G. S. Agarwal, and H. Walther, Science {\bf 299}, 862 (2003)], to the case of $N+1$ level atoms with $N$ coherent lower levels. We take into account atomic relaxation and dephasing as well as the cavity loss and derive a coarse grained…
It is possible to extract work from a quantum-mechanical system whose dynamics is governed by a time-dependent cyclic Hamiltonian. An energy bath is required to operate such a quantum engine in place of the heat bath used to run a conventional classical thermodynamic heat engine. The effect of the energy bath is to maintain the expectation value of the system Hamiltonian during an isoenergetic expansion. It is shown that the existence of such a bath leads to equilibrium quantum states that maximise the von Neumann entropy. Quantum analogues of certain thermodynamic relations are obtained that …
Heat engines constitute the major building blocks of modern technologies. However, conventional heat engines with higher power yield lesser efficiency and vice versa and respect various power-efficiency trade-off relations. This is also assumed to be true for the engines operating in the quantum regime. Here we show that these relations are not fundamental. We introduce quantum heat engines that deliver maximum power with Carnot efficiency in the one-shot finite-size regime. These engines are composed of working systems with a finite number of quantum particles and are restricted to one-shot m…
Unbounded Work Extraction and Zero Work Fluctuations in a Super-Carnot Otto Information Engine
College of Physics, Jilin University（吉林大学物理学院）；Department of Chemistry and Department of Physics and Astronomy, State University of New York at Stony Brook（纽约州立大学石溪分校化学系和物理与天文学系）
The quantum engine cycle serves as an analogous representation of classical heat engines for microscopic systems and the quantum regime of thermal devices is composed of a single element. In this work, the Quantum-Mechanical properties of a non-linear quantum oscillator described by the Woods-Saxon [WS] model are examined. The Quantum-Mechanical analogue of the Carnot cycle was constructed using changes in both the width L of the well and the quantum state of the potential well. The efficiency of the quantum engine, consisting of adiabatic and isothermal processes based on the Woods-Saxon [WS]…
Entropy is one of the most basic concepts in thermodynamics and statistical mechanics. The most widely used definition of statistical mechanical entropy for a quantum system is introduced by von Neumann. While in classical systems, the statistical mechanical entropy is defined by Gibbs. The relation between these two definitions of entropy is still not fully explored. In this work, we study this problem by employing the phase-space formulation of quantum mechanics. For those quantum states having well-defined classical counterparts, we study the quantum-classical correspondence and quantum cor…
Sadi Carnot's theorem regarding the maximum efficiency of heat engines is considered to be of fundamental importance in thermodynamics. This theorem famously states that the maximum efficiency depends only on the temperature of the heat baths used by the engine, but not on the specific structure of baths. Here, we show that when the heat baths are finite in size, and when the engine operates in the quantum nanoregime, a revision to this statement is required. We show that one may still achieve the Carnot efficiency, when certain conditions on the bath structure are satisfied; however if that i…
We present a (random) mechanical model consisting of two lottery-like reservoirs at altitude $E_h$ and $E_l<E_h$, respectively, in the earth's gravitational field. Both reservoirs consist of $N$ possible ball locations. The upper reservoir contains initially $n_h\le N$ weight-1 balls and the lower reservoir contains initially $n_l\le N$ weight-1 balls. Empty locations are treated as weight-0 balls. These reservoirs are being shaken up so that all possible ball configurations are equally likely to occur. A cycle consists of exchanging a ball randomly picked from the higher reservoir and a ball …
An implementation of quantum absorption chillers with three qubits has been recently proposed, that is ideally able to reach the Carnot performance regime. Here we study the working efficiency of such self-contained refrigerators, adopting a consistent treatment of dissipation effects. We demonstrate that the coefficient of performance at maximum cooling power is upper bounded by 3/4 of the Carnot performance. The result is independent of the details of the system and the equilibrium temperatures of the external baths. We provide design prescriptions that saturate the bound in the limit of a l…
The constraint relation for efficiency and power is crucial to design optimal heat engines operating within finite time. We find a universal constraint between efficiency and output power for heat engines operating in the low-dissipation regime. Such constraint is validated with an example of Carnot-like engine. Its microscopic dynamics is governed by the master equation. Based on the master equation, we connect the microscopic coupling strengths to the generic parameters in the phenomenological model. We find the usual assumption of low-dissipation is achieved when the coupling to thermal env…
A long standing open problem whether a heat engine with finite power achieves the Carnot efficiency is investigated. We rigorously prove a general trade-off inequality on thermodynamic efficiency and time interval of a cyclic process with quantum heat engines. In a first step, employing the Lieb-Robinson bound we establish an inequality on the change in a local observable caused by an operation far from support of the local observable. This inequality provides a rigorous characterization of the following intuitive picture that most of the energy released from the engine to the cold bath remain…
In order to describe quantum heat engines, here we systematically study isothermal and isochoric processes for quantum thermodynamic cycles. Based on these results the quantum versions of both the Carnot heat engine and the Otto heat engine are defined without ambiguities. We also study the properties of quantum Carnot and Otto heat engines in comparison with their classical counterparts. Relations and mappings between these two quantum heat engines are also investigated by considering their respective quantum thermodynamic processes. In addition, we discuss the role of Maxwell's demon in quan…
The efficiency of cyclic heat engines is limited by the Carnot bound. This bound follows from the second law of thermodynamics and is attained by engines that operate between two thermal baths under the reversibility condition whereby the total entropy does not increase. By contrast, the efficiency of engines powered by quantum non-thermal baths has been claimed to surpass the thermodynamic Carnot bound. The key to understanding the performance of such engines is a proper division of the energy supplied by the bath to the system into heat and work, depending on the associated change in the sys…
We investigate the efficiency of a quantum Carnot engine based on open quantum dynamics theory. The model includes time-dependent external fields for the subsystems controlling the isothermal and isentropic processes and for the system--bath (SB) interactions controlling the transition between these processes. Numerical simulations are conducted in a nonperturbative and non-Markovian SB coupling regime using the hierarchical equations of motion under these fields at different cycle frequencies. The work applied to the total system and the heat exchanged with the baths are rigorously evaluated.…
Mesoscopic thermoelectric heat engine is much anticipated as a device that allows us to utilize with high efficiency wasted heat inaccessible by conventional heat engines. However, the derivation of the heat current in this engine seems to be either not general or described too briefly, even inappropriate in some cases. In this paper, we give a clear-cut derivation of the heat current of the engine with suitable assumptions beyond the linear-response regime. It resolves the confusion in the definition of the heat current in the linear-response regime. After verifying that we can construct the …
The optimization of finite-time thermodynamic heat engines was intensively explored recently, yet limited to few cycles, e.g. finite-time Carnot-like cycle. In this paper, we supplement a new type of finite-time engine with quantum Otto cycle and show the better performance. The current model can be widely utilized benefited from the general \mathcal{C}/τ^{2} scaling of extra work for finite-time adiabatic process with long control time τ. Such scaling allows analytical optimization of the generic finite-time quantum Otto cycle to surpass the efficiency at maximum power for the Carnot-like eng…
We construct the smallest possible self contained heat engines; one composed of only two qubits, the other of only a single qutrit. The engines are self-contained as they do not require external sources of work and/or control. They are able to produce work which is used to continuously lift a weight. Despite the dimension of the engine being small, it is still able to operate at the Carnot efficiency.
Incorporating time into thermodynamics allows addressing the tradeoff between efficiency and power. A qubit engine serves as a toy model to study this tradeoff from first principles, based on the quantum theory of open systems. We study the quantum origin of irreversibility, originating from heat transport, quantum friction and thermalization in the presence of external driving. We construct various finite-time engine cycles based on the Otto and Carnot templates. Our analysis highlights the role of coherence and the quantum origin of entropy production.
In traditional thermodynamics the Carnot cycle yields the ideal performance bound of heat engines and refrigerators. We propose and analyze a minimal model of a heat machine that can play a similar role in quantum regimes. The minimal model consists of a single two-level system with periodically modulated energy splitting that is permanently, weakly, coupled to two spectrally-separated heat baths at different temperatures. The equation of motion allows to compute the stationary power and heat currents in the machine consistently with the second-law of thermodynamics. This dual-purpose machine …
