In order to describe quantum heat engines, here we systematically study isothermal and isochoric processes for quantum thermodynamic cycles. Based on these results the quantum versions of both the Carnot heat engine and the Otto heat engine are defined without ambiguities. We also study the properties of quantum Carnot and Otto heat engines in comparison with their classical counterparts. Relations and mappings between these two quantum heat engines are also investigated by considering their respective quantum thermodynamic processes. In addition, we discuss the role of Maxwell's demon in quantum thermodynamic cycles. We find that there is no violation of the second law, even in the existence of such a demon, when the demon is included correctly as part of the working substance of the heat engine.
We analyze the new redefinitions of heat Q and work W recently presented in [arXiv: 1912.01939; arXiv:1912.01983v5] in the quantum thermodynamics domain. According to these redefinitions, heat must be associated with the variation of entropy, while work must be associated with variation of state vectors. Analyzing the behavior of two specific examples, we show some peculiarities of these new redefinitions which, based on the counterexample presented, seems to point to a possible inadequacy of these redefinitions.
For heat engines working between two heat baths, functionality is often conditioned on a set of fixed constraints such as given internal structure of the engine and given temperatures for the baths. It is, however, important to devise heat engines which can function adaptively, in particular when the engine is a quantum system and the baths are subject to fluctuations. Here we study a model for an adaptive quantum heat engine whose heat baths can have variable temperatures. We obtain conditions under which such an engine can still operate. Moreover, we propose an enhancement of the heat engine…
The free energy of a quantum oscillator in an arbitrary heat bath at a temperature T is given by a "remarkable formula" which involves only a single integral. This leads to a corresponding simple result for the entropy. The low temperature limit is examined in detail and we obtain explicit results both for the case of an Ohmic heat bath and a radiation heat bath. More general heat bath models are also examined. This enables us to determine the entropy at zero temperature in order to check the third law of thermodynamics in the quantum regime
We provide a characterization of energy in the form of exchanged heat and work between two interacting constituents of a closed, bipartite, correlated quantum system. By defining a binding energy we derive a consistent quantum formulation of the first law of thermodynamics, in which the role of correlations becomes evident, and this formulation reduces to the standard classical picture in relevant systems. We next discuss the emergence of the second law of thermodynamics under certain---but fairly general---conditions such as the Markovian assumption. We illustrate the role of correlations and…
We introduce a new quantum heat engine, in which the working medium is a quantum system with a discrete level and a continuum. Net work done by this engine is calculated and discussed. The results show that this quantum heat engine behaves like the two-level quantum heat engine in both the high-temperature and the low-temperature limits, but it operates differently in temperatures between them. The efficiency of this quantum heat engine is also presented and discussed.
We analyze an autonomous thermoelectric engine composed of two superconducting qubits coupled to separate heat baths and connected by a Josephson junction. Work and heat are process quantities and not observables of the engine quantum system, but their rates can be derived from the steady state expectation value of appropriate system observables and their fluctuations are given by correlation functions determined with the GKLS master equation and quantum regression theorem. The correlation functions also reveal a cyclical, dynamical transfer of energy - the strokes of the engine - hiding under…
Incorporating time into thermodynamics allows addressing the tradeoff between efficiency and power. A qubit engine serves as a toy model to study this tradeoff from first principles, based on the quantum theory of open systems. We study the quantum origin of irreversibility, originating from heat transport, quantum friction and thermalization in the presence of external driving. We construct various finite-time engine cycles based on the Otto and Carnot templates. Our analysis highlights the role of coherence and the quantum origin of entropy production.
The role of the third law of thermodynamics in the Szilard engine has been addressed. If the ground state is non-degenerate, the entropy production defined as the work extractable from the engine divided by temperature vanishes as temperature approaches zero due to the third law. The degenerate ground state induced by the symmetry or by accidence gives rise to non-zero entropy production at zero temperature associated with the residual entropy. Various physical situations such as the SZE consisting of bosons or fermions either with or without interaction have been investigated.
The first law of thermodynamics restates the law of conservation of energy. It partitions the change in energy of a system into two pieces, heat and work. While there is no ambiguity to define heat and work in classical thermodynamics, their classification in the quantum regime is not that obvious. Thus, the first law of thermodynamics becomes problematic in the quantum regime. However, recent studies have shown if contribution of quantum coherence is considered to the change of internal energy of the system, the first law of thermodynamics can be extended to the quantum domain. Here we invest…
Energy is often partitioned into heat and work by two independent paths corresponding to the change in the eigenenergies or the probability distributions of a quantum system. The discrepancies of the heat and work for various quantum thermodynamic processes have not been well characterized in literature. Here we show how the work in quantum machines is differentially related to isochoric, isothermal, and adiabatic processes. We prove that the energy exchanges during the quantum isochoric and isothermal processes are simply depending on the change in the eigenenergies or the probability distrib…
Considering an entropy-based division of energy transferred into heat and work, we develop an alternative theoretical framework for the thermodynamic analysis of two-level systems. When comparing these results with those obtained under the standard definitions of these quantities, we observe the appearance of a new term of work, which represents the energy cost of rotating the Bloch vector in presence of the external field that defines the local Hamiltonian. Additionally, we obtain explicit expressions for the temperature, the heat capacity and the internal entropy production of the system in …
We study the quantum mechanical generalization of force or pressure, and then we extend the classical thermodynamic isobaric process to quantum mechanical systems. Based on these efforts, we are able to study the quantum version of thermodynamic cycles that consist of quantum isobaric process, such as quantum Brayton cycle and quantum Diesel cycle. We also consider the implementation of quantum Brayton cycle and quantum Diesel cycle with some model systems, such as single particle in 1D box and single-mode radiation field in a cavity. These studies lay the microscopic (quantum mechanical) foun…
A heat engine is a machine which uses the temperature difference between a hot and a cold reservoir to extract work. Here both reservoirs are quantum systems and a heat engine is described by a unitary transformation which decreases the average energy of the bipartite system. On the molecular scale, the ability of implementing such a unitary heat engine is closely connected to the ability of performing logical operations and classical computing. This is shown by several examples: (1) The most elementary heat engine is a SWAP-gate acting on 1 hot and 1 cold two-level systems with different ener…
With a class of quantum heat engines which consists of two-energy-eigenstate systems undergoing, respectively, quantum adiabatic processes and energy exchanges with heat baths at different stages of a cycle, we are able to clarify some important aspects of the second law of thermodynamics. The quantum heat engines also offer a practical way, as an alternative to Szilard's engine, to physically realise Maxwell's daemon. While respecting the second law on the average, they are also capable of extracting more work from the heat baths than is otherwise possible in thermal equilibrium.
We introduce a class of quantum heat engines which consists of two-energy-eigenstate systems, the simplest of quantum mechanical systems, undergoing quantum adiabatic processes and energy exchanges with heat baths, respectively, at different stages of a cycle. Armed with this class of heat engines and some interpretation of heat transferred and work performed at the quantum level, we are able to clarify some important aspects of the second law of thermodynamics. In particular, it is not sufficient to have the heat source hotter than the sink, but there must be a minimum temperature difference …
A quantum model of a heat engine resembling the Otto cycle is employed to explore strategies to suppress frictional losses. These losses are caused by the inability of the engine's working medium to follow adiabatically the change in the Hamiltonian during the expansion and compression stages. By adding external noise to the engine, frictional losses can be suppressed.
By using a laser and maser in tandem, it is possible to obtain laser action in the hot exhaust gases involved in heat engine operation. Such a "quantum afterburner" involves the internal quantum states of working gas atoms or molecules as well as the techniques of cavity quantum electrodynamics and is therefore in the domain of quantum thermodynamics. As an example, it is shown that Otto cycle engine performance can be improved beyond that of the "ideal" Otto heat engine.
We construct the smallest possible self contained heat engines; one composed of only two qubits, the other of only a single qutrit. The engines are self-contained as they do not require external sources of work and/or control. They are able to produce work which is used to continuously lift a weight. Despite the dimension of the engine being small, it is still able to operate at the Carnot efficiency.
Thermodynamic Roles of Quantum Environments: From Heat Baths to Work Reservoirs
Institute of Physics, University of Freiburg（弗赖堡大学物理研究所）；Dipartimento di Fisica “Aldo Pontremoli”, Università degli Studi di Milano（米兰大学阿尔多·蓬特莫利物理系）；EUCOR Centre for Quantum Science and Quantum Computing, University of Freiburg（弗赖堡大学EUCOR量子科学与工程中心）
Landauer's erasure principle is a cornerstone of thermodynamics and information theory. According to this principle, erasing information incurs a minimum energy cost. Recently, Vaccaro and Barnett [Proc. R. Soc {\bf 467}, 1770 (2011)] explored information erasure in the context of multiple conserved quantities and showed that the erasure cost can be solely in terms of spin angular momentum. As Landauer's erasure principle plays a fundamental role in heat engines, their result considerably widens the possible configurations that heat engines can have. Motivated by this, we propose here a novel …
We describe how electromagnetically induced transparency may be used to construct a non-traditional near-ideal quantum heat engine as constrained by the Second Law. The engine is pumped by a thermal reservoir that may be either hotter or colder than that of an exhaust reservoir, and also by a monochromatic laser. As output, it produces a bright narrow emission at line center of an otherwise absorbing transition.
Heat engines are fundamental physical objects to develop nonequilibrium thermodynamics. The thermodynamic performance of the heat engine is determined by the choice of cycle and time-dependence of parameters. Here, we propose a systematic numerical method to find a heat engine cycle to optimize some target functions. We apply the method to heat engines with slowly varying parameters and show that the method works well. Our numerical method is based on the genetic algorithm which is widely applied to various optimization problems.
The aim of this paper is to determine lost works in a molecular engine and compare results with macro (classical) heat engines. Firstly, irreversible thermodynamics are reviewed for macro and molecular cycles. Secondly, irreversible thermodynamics approaches are applied for a quantum heat engine with -1/2 spin system. Finally, lost works are determined for considered system and results show that macro and molecular heat engines obey same limitations. Moreover, a quantum thermodynamic approach is suggested in order to explain the results previously obtained from an atomic viewpoint.
In this work, we introduce the concept of the fractional quantum heat engine. We examine the space-fractional quantum Szilard heat engine as an example to show that the space-fractional quantum heat engines can produce higher efficiency than the conventional quantum heat engines.
Explaining the influence of strong coupling in the dynamics of open quantum systems is one of the most challenging issues in the rapidly growing field of quantum thermodynamics. By using a particular definition of heat, we develop a new approach to study thermodynamics in the strong coupling regime, which takes into account quantum resources as coherence and entanglement. We apply the method to calculate the time-dependent thermodynamic properties of a system and an environment interacting via the generalized amplitude-damping channel (GADC). The results indicate that the transient imbalance b…
All existing heat machines are dissipative open systems. Hence, they cannot operate fully coherently. We propose to replace this conventional thermodynamic paradigm by a completely different one, whereby heat machines are nonlinear coherent closed systems comprised of few field modes. Their thermal-state input is transformed by nonlinear interactions into non-thermal output with controlled quantum fluctuations and the capacity to deliver work in a chosen mode. This new paradigm allows the bridging of quantum coherent and thermodynamic descriptions.
Thermodynamics has recently been extended to small scales with resource theories that model heat exchanges. Real physical systems exchange diverse quantities: heat, particles, angular momentum, etc. We generalize thermodynamic resource theories to exchanges of observables other than heat, to baths other than heat baths, and to free energies other than the Helmholtz free energy. These generalizations are illustrated with "grand-potential" theories that model movements of heat and particles. Free operations include unitaries that conserve energy and particle number. From this conservation law an…
Fluctuations of thermodynamic observables, such as heat and work, contain relevant information on the underlying physical process. These fluctuations are however not taken into account in the traditional laws of thermodynamics. While the second law is extended to fluctuating systems by the celebrated fluctuation theorems, the first law is generally believed to hold even in the presence of fluctuations. Here we show that in the presence of quantum fluctuations, also the first law of thermodynamics may break down. This happens because quantum mechanics imposes constraints on the knowledge of hea…
We present a detailed thermodynamic analysis of a three-level quantum heat engine coupled continuously to hot and cold reservoirs. The system is driven by an oscillating external field and is described by the Markovian quantum master equation. We use the general form of the dissipator which is consistent with thermodynamics. We calculate the heat, power, and efficiency of the system for the heat-engine operating regime and also examine the thermodynamic uncertainty relation. The efficiency of the system is strongly dependent on the structure of the dissipator, and the correlations between diff…
We study the heat statistics of a quantum Brownian motion described by the Caldeira-Leggett model. By using the path integral approach, we introduce a novel concept of the quantum heat functional along every pair of Feynman paths. This approach has an advantage of improving our understanding about heat in quantum systems. First, we demonstrate the microscopic reversibility of the system by connecting the heat functional to the forward and its time-reversed probabilities. Second, we analytically prove the quantum-classical correspondence of the heat functional and their statistics, which allows…
Small systems (of interest in the areas of nanophysics, quantum information, etc.) are particularly vulnerable to environmental effects. Thus, we determine various thermodynamic functions for an oscillator in an arbitrary heat bath at arbitrary temperatures. Explicit results are presented for the most commonly discussed heat bath models: Ohmic, single relaxation time and blackbody radiation.
We consider a situation where an $N$-level system (NLS) is coupled successively to two heat baths with different temperatures without being necessarily thermalized and approaches a steady state. For this situation we apply a general Jarzinski-type equation and conclude that heat and entropy is flowing from the hot bath to the cold one. The Clausius relation between increase of entropy and transfer of heat divided by a suitable temperature assumes the form of two inequalities. Our approach is illustrated by an analytical example. For the linear regime, i.~e., for small temperature differences b…
We consider a situation where an $N$-level system (NLS) is coupled to a heat bath without being necessarily thermalized. For this situation we derive general Jarzinski-type equations and conclude that heat and entropy is flowing from the hot bath to the cold NLS and, vice versa, from the hot NLS to the cold bath. The Clausius relation between increase of entropy and transfer of heat divided by a suitable temperature assumes the form of two inequalities which have already been considered in the literature. Our approach is illustrated by an analytical example.
Certain solutions of Einstein's equations in anti-de Sitter spacetime can be engineered, using extended gravitational thermodynamics, to yield `holographic heat engines', devices that turn heat into useful mechanical work. On the other hand, there are constructions (both experimental and theoretical) where a series of operations is performed on a small quantum system, defining what are known as `quantum heat engines'. We propose that certain holographic heat engines can be considered models of quantum heat engines, and the possible fruitfulness of this connection is discussed. Motivated by fea…
The thermodynamics of small quantum many-body systems strongly coupled to a heat bath at low temperatures with non-Markovian behavior are new challenges for quantum thermodynamics, as traditional thermodynamics is built on large systems vanishingly weakly coupled to a non-dynamical reservoir. Important also are the quantum attributes, as in quantum coherence, correlations, entanglement and fluctuations. All told, one needs to reexamine the meaning of the thermodynamic functions, the viability of the thermodynamic relations and the validity of the thermodynamic laws anew. In one popular approac…
A new thermodynamic inequality is derived which leads to the maximum work that can be extracted from multi-heat baths with the assistance of discrete quantum feedback control. The maximum work is determined by the free-energy difference and a generalized mutual information content between the thermodynamic system and the feedback controller. This maximum work can exceed that in conventional thermodynamics and, in the case of a heat cycle with two heat baths, the heat efficiency can be greater than that of the Carnot cycle. The consistency of our results with the second law of thermodynamics is…
The Carnot statement of the second law of thermodynamics poses an upper limit on the efficiency of all heat engines. Recently, it has been studied whether generic quantum features such as coherence and quantum entanglement could allow for quantum devices with efficiencies larger than the Carnot efficiency. The present study shows that this is not permitted by the laws of thermodynamics. In particular, we will show that rather the definition of heat has to be modified to account for the thermodynamic cost for maintaining coherence and entanglement. Our theoretical findings are numerically illus…
Toward the formulation of the operational approach to quantum thermodynamics, the heat-up operator is explicitly constructed. This quantum operation generates for a generic system an irreversible transformation from a pure ground state at zero temperature to a state at finite temperature. The fixed point analysis shows that repeated applications of the operation map from an arbitrary state to the completely random state realized in the high-temperature limit. The change of the von Neumann entropy is evaluated for a simple bipartite spin-1/2 system. It is shown that remarkably, the second law o…
We study energetic exchanges and fluctuations in two-stroke quantum thermodynamic engines where the working fluid is represented by two multilevel quantum systems, i.e. qudits, the heat flow is allowed by relaxation with two thermal reservoirs at different temperatures, and the work exchange is operated by a partial-swap unitary interaction. We identify three regimes of operation (heat engine, refrigerator, and thermal accelerator), present the thermodynamic uncertainty relations between the entropy production and the signal-to-noise ratio of work and heat, and derive the full joint probabilit…
In this paper, we investigate the strong coupling quantum thermodynamics of the hybrid quantum system far away from equilibrium. The strong coupling hybrid system consists of a cavity and a spin ensemble of the NV centers in diamond under external driving that has been realized experimentally. We apply the renormalization theory of quantum thermodynamics we developed recently to study the transient quantum heat and work in this hybrid system. We find that the dissipation and fluctuation dynamics of the system induce the transient quantum heat current which involve the significant non-Markovian…
We analyze an engine whose working fluid consists of a single quantum particle, paralleling Szilard's construction of a classical single-particle engine. Following his resolution of Maxwell's Second Law paradox using the latter, which turned on physically instantiating the demon (control subsystem), the quantum engine's design mirrors the classically-chaotic Szilard Map that operates a thermodynamic cycle of measurement, thermal-energy extraction, and memory reset. Focusing on the thermodynamic costs to observe and control the particle and comparing these in the quantum and classical limits, w…
We analyze an autonomous micro-engine as a closed quantum mechanical system, including the work it performs and the fuel it consumes. Our model system shows by example that it is possible to transfer energy steadily and spontaneously between fast and slow degrees of freedom, in analogy to the way combustion engines convert chemical energy into work. Having shown this possibility, we observe close analogies between the closed-system quantum dynamics of our micro-engine and the First and Second Law of Thermodynamics. From these analogies we deduce a generalized formulation of thermodynamics that…
We propose a quantum-enhanced heat engine with entanglement. The key feature of our scheme is superabsorption, which facilitates enhanced energy absorption by entangled qubits. Whereas a conventional engine with $N$ separable qubits provides power with a scaling of $P = Θ(N)$, our engine uses superabsorption to provide power with a quantum scaling of $P = Θ(N^2)$. This quantum heat engine also exhibits a scaling advantage over classical ones composed of $N$-particle Langevin systems. Our work elucidates the quantum properties allowing for the enhancement of performance.
In this paper, we study the role and relevance of the cost for an invariant-based shortcut to adiabaticity enabled qubit heat engine operates in a quantum Otto cycle. We consider a qubit heat engine with Landau-Zener Hamiltonian and improve its performance using the Lewis-Riesenfeld invariant-based shortcut to adiabaticity method. Addressing the importance of cost for better performance, the paper explores its relationship with the work and efficiency of the heat engine. We analyze the cost variation with the time duration of non-adiabatic unitary processes involved in the heat engine cycle. T…
We investigate the thermodynamic uncertainty relation (TUR), \textit{i.e.} a trade-off between entropy production rate and relative power fluctuations, for nondegenerate three-level and degenerate four-level maser heat engines. In the nondegenerate case, we consider two slightly different configurations of three-level maser heat engine and contrast their degree of violation of standard TUR. In the high-temperature limit, standard TUR relation is always violated for both configurations. We also uncover an invariance of TUR under simultaneous rescaling of the matter-field coupling constant and s…
Situations where a spontaneous process of energy or matter transfer is enhanced by an external device are widespread in nature (human sweating system, enzyme catalysis, facilitated diffusion across bio-membranes, industrial heat exchangers). The thermodynamics of such processes remains however open. Here we study enhanced heat transfer by a model junction immersed between two thermal baths at different temperatures $T_h$ and $T_c$ ($T_h>T_c$). The transferred heat power is enhanced via controlling the junction by means of external time-dependent fields. Provided that the spontaneous heat flow …
We develop a geometric framework to describe the thermodynamics of microscopic heat engines driven by slow periodic temperature variations and modulations of a mechanical control parameter. Covering both the classical and the quantum regime, our approach reveals a universal trade-off relation between efficiency and power that follows solely from geometric arguments and holds for any thermodynamically consistent microdynamics. Focusing on Lindblad dynamics, we derive a second bound showing that coherence as a genuine quantum effect inevitably reduces the performance of slow engine cycles regard…
Quantum heat engines are expected to outperform the classical counterparts due to quantum coherences involved. Here we experimentally execute a single-ion quantum heat engine and demonstrate, for the first time, the dynamics and the enhanced performance of the heat engine originating from the Liouvillian exceptional points (LEPs). In addition to the topological effects related to LEPs, we focus on thermodynamic effects, which can be understood by the Landau-Zener-Stuckelberg process under decoherence. We witness a positive net work from the quantum heat engine if the heat engine cycle dynamica…
Two testable schemes for quantum heat engines are investigated under the quantization framework of noncommutative (NC) quantum mechanics (QM). By identifying the phenomenological connection between the phase-space NC driving parameters and an effective external magnetic field, the NC effects on the efficiency coefficient, \mathcal{N} , of quantum engines can be quantified for two different cycles: an isomagnetic one and an isoenergetic one. In addition, paying a special attention to the quantum Carnot cycle, one notices that the inclusion of NC effects does not affect the maximal (Carnot) effi…
