Carnot's theorem poses a fundamental limit on the maximum efficiency achievable from an engine that works between two reservoirs at thermal equilibrium. We extend this result to the case of arbitrary nonthermal stationary reservoirs, even with quantum coherence. In order to do this we prove that a single nonthermal reservoir is formally equivalent to multiple equilibrium ones. Finally, we discuss the possibility of realizing an engine that works at unit efficiency by exploiting quantum coherence present in the reservoir.
We present the exact theory of quantum engines whose working medium is a network of driven oscillators performing an arbitrary cyclic process while coupled to thermal and nonthermal reservoirs. We show that when coupled to a single reservoir work cannot be extracted unless there is population inversion, and prove that the ratio between the heat flowing out and into the working medium cannot be arbitrarily small, satisfying a form of Clausius inequality. We use such identity to prove that the efficiency of linear quantum engines satisfies a generalized bound, which coincides with the Carnot lim…
We present a (random) mechanical model consisting of two lottery-like reservoirs at altitude $E_h$ and $E_l<E_h$, respectively, in the earth's gravitational field. Both reservoirs consist of $N$ possible ball locations. The upper reservoir contains initially $n_h\le N$ weight-1 balls and the lower reservoir contains initially $n_l\le N$ weight-1 balls. Empty locations are treated as weight-0 balls. These reservoirs are being shaken up so that all possible ball configurations are equally likely to occur. A cycle consists of exchanging a ball randomly picked from the higher reservoir and a ball …
Heat engines extract work by running cyclically between two heat reservoirs. When the two reservoirs are thermal and at different temperatures, the maximum efficiency of the engine is given by the Carnot limit. Here we consider a quantum Otto cycle for a time-dependent harmonic oscillator coupled to an engineered squeezed thermal reservoir. We show that the efficiency at maximum power increases with the degree of squeezing, exponentially approaching unity for large squeezing parameters $r$. Furthermore, we propose an experimental scheme to implement such a system by using a single trapped ion …
We investigate the heat transport between two nonthermal reservoirs based on a microscopic collision model. We consider a bipartite system consisting of two identical subsystems, and each subsystem interacts with its own local reservoir, which consists of a large collection of initially uncorrelated ancillas. Then a heat transport is formed between two reservoirs by a sequence of pairwise collisions (inter-subsystem and subsystem-local reservoir). In this paper we consider two kinds of reservoir's initial states, the thermal state, and the state with coherence whose diagonal elements are the s…
The quantum analog of Carnot cycles in few-particle systems consists of two quantum adiabatic steps and two isothermal steps. This construction is formally justified by use of a minimum work principle. It is then shown, without relying on any microscopic interpretations of work or heat, that the heat-to-work efficiency of the quantum Carnot cycle thus constructed may be further optimized, provided that two conditions regarding the expectation value of some generalized force operators evaluated at equilibrium states are satisfied. In general the optimized efficiency is system-specific, lower th…
Based on a quantum thermodynamic protocol for shortcut to isothermality that smoothly modify the system-reservoir interaction can significantly speed up an isothermal process while keeping the overall dissipation constant [Phys. Rev. X. 10, 031015 (2020)], we extend the study of optimization performance of Carnot-like heat engines and refrigerators in a straightforward and unified way. We derive the universal optimization efficiency of heat engines and the optimization coefficient of performance of refrigerators under two unified optimization criterions, i.e., chi criterion and omega criterion…
We analyze the efficiency of thermal engines (either quantum or classical) working with a single heat reservoir like atmosphere. The engine first gets an energy intake, which can be done in arbitrary non-equilibrium way e.g. combustion of fuel. Then the engine performs the work and returns to the initial state. We distinguish two general classes of engines where the working body first equilibrates within itself and then performs the work (ergodic engine) or when it performs the work before equilibrating (non-ergodic engine). We show that in both cases the second law of thermodynamics limits th…
We study the modification of the second law of thermodynamics for a quantum system interacting with a reservoir regarding quantum coherence. The whole system is isolated so that neither energy nor information is lost. It is discovered that the coherence of the reservoir can serves as a useful resource allowing the system extract more energy from the reservoir; among the coherence measures, only is the relative entropy of coherence feasible to quantitatively characterize energy exchange. We demonstrate that a thermodynamic cycle between two coherent reservoirs can output more work than its clas…
We propose a spin-star network, where a central spin-$1/2$ is coupled with XXZ interaction to $N$ outer spin-$1/2$ particles, as a quantum fuel. If the network is in thermal equilibrium with a cold bath, the central spin can have an effective temperature larger than the bath one and scaling nonlinearly with $N$. The nonlinearity can be tuned to $N^2, N^3$ or $N^4$ with the anisotropy parameter of the coupling. Using a stream of central-spin particles to pump a micromaser cavity, we calculate the dynamics of the cavity field using a coarse-grained master equation. Our study reveals that the cen…
Quantum absorption refrigerator (QAR) autonomously extracts heat from a cold bath and dumps into a hot bath by exploiting the input heat from a higher temperature reservoir. QARs typically require three-body interactions. We propose and examine a two-body QAR model based upon optomechanical-like coupling in the working medium composed of either two two-level systems or two harmonic oscillators or one two-level atom and a harmonic oscillator. In the ideal case without internal dissipation, within the experimentally realizable parameters, our model can attain the coefficient of performance that …
We derive an efficiency bound for continuous quantum heat engines absorbing heat from squeezed thermal reservoirs. Our approach relies on a full-counting statistics description of nonequilibrium transport and it is not limited to the framework of irreversible thermodynamics. Our result, a generalized Carnot efficiency bound, is valid beyond the small squeezing and high temperature limit. Our findings are embodied in a prototype three-terminal quantum photoelectric engine where a qubit converts heat absorbed from a squeezed thermal reservoir into electrical power. We demonstrate that in the qua…
Recent theoretical and experimental studies in quantum heat engines show that, in the quasi-static regime, it is possible to have higher efficiency than the limit imposed by Carnot, provided that engineered reservoirs are used. The quasi-static regime, however, is a strong limitation to the operation of heat engines, since infinitely long time is required to complete a cycle. In this paper we propose a two-level model as the working substance to perform a quantum Otto heat engine surrounded by a cold thermal reservoir and a squeezed hot thermal reservoir. Taking advantage of this model we show…
We study a limit cycle of a quantum Otto engine whose each cycle consists of two finite-time quantum isochoric (heating or cooling) processes and two quantum adiabatic work-extracting processes. Considering a two-level system as a working substance that weakly interacts with two reservoirs comprising an infinite number of bosons, we investigate the non-Markovian effect (short-time behavior of the reduced dynamics in the quantum isochoric processes (QIPs)) on work extraction after infinite repetition of the cycles. We focus on the parameter region where energy transferred to the reservoir can c…
Unbounded Work Extraction and Zero Work Fluctuations in a Super-Carnot Otto Information Engine
College of Physics, Jilin University（吉林大学物理学院）；Department of Chemistry and Department of Physics and Astronomy, State University of New York at Stony Brook（纽约州立大学石溪分校化学系和物理与天文学系）
Landauer's erasure principle is a cornerstone of thermodynamics and information theory. According to this principle, erasing information incurs a minimum energy cost. Recently, Vaccaro and Barnett [Proc. R. Soc {\bf 467}, 1770 (2011)] explored information erasure in the context of multiple conserved quantities and showed that the erasure cost can be solely in terms of spin angular momentum. As Landauer's erasure principle plays a fundamental role in heat engines, their result considerably widens the possible configurations that heat engines can have. Motivated by this, we propose here a novel …
We consider a photo--Carnot engine that consists of a single--mode radiation field in an optical cavity. One the heat reservoirs is made of a beam of thermally entangled pairs of two--level atoms that interact resonantly with the cavity. We express the thermodynamic efficiency of the engine in terms of the quantum discord of the atomic pair and find that it can exceed its classical value. Our results show that useful work can be extracted from quantum correlations, indicating that the latter are a valuable resource in quantum thermodynamics.
The introduction of the quantum analogue of a Carnot engine based on a bath comprising of particles with a small amount of coherence initiated an active line of research on the harnessing of different quantum resources for the enhancement of thermal machines beyond the standard reversible limit, with an emphasis on non-thermal baths containing quantum coherence. In our work, we investigate the impact of coherence on the thermodynamic tasks of a collision model which is composed of a system interacting, in the continuous time limit, with a series of coherent ancillas of two baths at different t…
We discuss whether, and under which conditions, it is possible to realize a heat engine simply by dynamically modulating the couplings between the quantum working medium and thermal reservoirs. For that purpose, we consider the paradigmatic model of a quantum harmonic oscillator, exposed to a minimal modulation, that is, a monochromatic driving of the coupling to only one of the thermal baths. We demonstrate, at any order in the system/bath coupling strength, that in this setup non--Markovianity of the bath is a necessary condition to obtain a heat engine. In addition, we identify suitable str…
We propose a quantum Stirling heat engine with an ensemble of harmonic oscillators as the working medium. We show that the efficiency of the harmonic oscillator quantum Stirling heat engine (HO-QSHE) at a given frequency can be maximized at a specific ratio of the temperatures of the thermal reservoirs. In the low temperature or equivalently high frequency limit of the harmonic oscillators, the efficiency of the HO-QSHE approaches the Carnot efficiency. Further, we analyse quantum Stirling heat engine with an ensemble of particle in box quantum systems as the working medium. Here both work and…
In this work we study how the non-Markovian character of the dynamics can affect the thermodynamic performance of a quantum thermal engine, by analysing the maximum power output of Carnot and Otto cycles departing from the quasi-static and infinite-time-thermalization regime respectively, introducing techniques for their control optimization in general dynamical models. In our model, non-Markovianity is introduced by allowing some degrees of freedom of the reservoirs to be taken into account explicitly and share correlations with the engine by Hamiltonian coupling. It is found that the non-Mar…
We propose a quantum absorption refrigerator using the quantum physics of resonant tunneling through quantum dots. The cold and hot reservoirs are fermionic leads, tunnel coupled via quantum dots to a central fermionic cavity, and we propose configurations in which the heat absorbed from the (very hot) central cavity is used as a resource to selectively transfer heat from the cold reservoir on the left, to the hot reservoir on the right. The heat transport in the device is particle---hole symmetric; we find two regimes of cooling as a function of the energy of the dots---symmetric with respect…
Quantum heat engines employ as working agents multi-level systems instead of gas-filled cylinders. We consider particularly two-level agents such as electrons immersed in a magnetic field. Work is produced in that case when the electrons are being carried from a high-magnetic-field region into a low-magnetic-field region. In watermills, work is produced instead when some amount of fluid drops from a high-altitude reservoir to a low-altitude reservoir. We show that this purely mechanical engine may in fact be considered as a two-level quantum heat engine, provided the fluid is viewed as consist…
Various quantum systems are considered as the working substance for the analysis of quantum heat cycles and quantum refrigerators. The ongoing technological challenge is how efficiently can a heat engine convert thermal energy to mechanical work. The seminal work of Carnot has proposed a fundamental upper limit-the Carnot limit on the efficiency of the heat engine. However, the heat engines can be operated beyond the fundamental upper limit by exploiting non-equilibrium reservoirs. Here, the change in the space structure introduces the non-equilibrium effect. So, a question arises whether a ch…
We derive the efficiency at maximal power of a scale-invariant (critical) quantum junction in exact form. Both Fermi and Bose statistics are considered. We show that time-reversal invariance is spontaneously broken. For fermions we implement a new mechanism for efficiency enhancement above the Curzon-Ahlborn bound, based on a shift of the particle energy in each heat reservoir, proportional to its temperature. In this setting fermionic junctions can even reach at maximal power the Carnot efficiency. The bosonic junctions at maximal power turn out to be less efficient then the fermionic ones.
Standard heat machines (engine, heat pump, refrigerator) are composed of a system ("working fluid") coupled to at least two equilibrium baths at different temperatures and periodically driven by an external device (piston or rotor) called sometimes work reservoir. The aim of this paper is to go beyond this scheme by considering environments which are stationary but cannot be decomposed into few baths at thermal equilibrium. Such situations are important, for example in solar cells, chemical machines in biology, various realizations of laser cooling or nanoscopic machines driven by laser radiat…
We analyze the power output of a quantum dot machine coupled to two electronic reservoirs via thermoelectric contacts, and to two thermal reservoirs - one hot and one cold. This machine is a nanoscale analogue of a conventional thermocouple heat-engine, in which the active region being heated is unavoidably also exchanging heat with its cold environment. Heat exchange between the dot and the thermal reservoirs is treated as a capacitive coupling to electronic fluctuations in localized levels, modeled as two additional quantum dots. The resulting multiple-dot setup is described using a master e…
The quantum heat engines have drawn much attention due to miniaturization of devices recently. We study the dynamics of the quantum Otto heat engine using the driven-dissipative Schrödinger equation. Starting from different initial states, we simulate the time evolutions of the internal energy, power and heat-work conversion efficiency. The initial state impacts on these thermodynamic quantities before the Otto cycle reaches stable. In the transition period, the efficiency and power may be higher or lower than the corresponding values in the cyclostationary state. Remarkably, the efficiency co…
We investigate the performance of a microscopic quantum heat engine consisting of V- or Lambda-type emitters interacting collectively or independently when being in contact with environmental thermal reservoirs. Though the efficiency of a Carnot's cycle is always higher than those associated with these setups, we have found that the performance of the cooperative Lambda-type heat engine may be larger than that of the V-type under similar conditions. Cooperativity among the emitters plays an important role for the Lambda-type setup, significantly improving its performance, while is less relevan…
In this paper, the foundations of classical phenomenological thermodynamics are being thoroughly revisited. A new rigorous basis for thermodynamics is laid out in the main text and presented in full detail in the appendix. All relevant concepts, such as work, heat, internal energy, heat reservoirs, reversibility, absolute temperature and entropy, are introduced on an abstract level and connected through traditional results, such as Carnot's Theorem, Clausius' Theorem and the Entropy Theorem. The paper offers insights into the basic assumptions one has to make in order to formally introduce a p…
The thermodynamics of quantum systems coupled to periodically modulated heat baths and work reservoirs is developed. By identifying affinities and fluxes, the first and second law are formulated consistently. In the linear response regime, entropy production becomes a quadratic form in the affinities. Specializing to Lindblad-dynamics, we identify the corresponding kinetic coefficients in terms of correlation functions of the unperturbed dynamics. Reciprocity relations follow from symmetries with respect to time reversal. The kinetic coefficients can be split into a classical and a quantum con…
We propose the use of a quantum thermal machine for low-temperature thermometry. A hot thermal reservoir coupled to the machine allows for simultaneously cooling the sample while determining its temperature without knowing the model-dependent coupling constants. In its most simple form, the proposed scheme works for all thermal machines which perform at Otto efficiency and can reach Carnot efficiency. We consider a circuit QED implementation which allows for precise thermometry down to $\sim$15 mK with realistic parameters. Based on the quantum Fisher information, this is close to the optimal …
We study the thermodynamic performance of the finite-time non-regenerative Stirling cycle used as a quantum heat engine. We consider specifically the case in which the working substance (WS) is a two-level system. The Stirling cycle is made of two isochoric transformations separated by a compression and an expansion stroke during which the working substance is in contact with a thermal reservoir. To describe these two strokes we derive a non-Markovian master equation which allows to study the dynamics of a driven open quantum system with arbitrary fast driving. We found that the finite-time dy…
Experimental Demonstration of a Measurement-Feedback Quantum Information Engine
Quantum Information Institute, School of Physics and Laboratory of Zhongyuan Light, Zhengzhou University（郑州大学物理学院量子信息研究所中原光实验室）；Department of Physics, Nanchang University（南昌大学物理系）
