The quantum analog of Carnot cycles in few-particle systems consists of two quantum adiabatic steps and two isothermal steps. This construction is formally justified by use of a minimum work principle. It is then shown, without relying on any microscopic interpretations of work or heat, that the heat-to-work efficiency of the quantum Carnot cycle thus constructed may be further optimized, provided that two conditions regarding the expectation value of some generalized force operators evaluated at equilibrium states are satisfied. In general the optimized efficiency is system-specific, lower than the Carnot efficiency, and dependent upon both temperatures of the cold and hot reservoirs. Simple computational examples are used to illustrate our theory. The results should be an important guide towards the design of favorable working conditions of a realistic quantum heat engine.
In order to build a quantum analog of traditional Carnot engine, a common choice is replacing the two thermodynamic adiabatic processes with two quantum mechanical adiabatic processes. In general, such quantum Carnot engine has six strokes. We analyze the efficiency of such six-stroke quantum Carnot engine in a perturbative way.
We study the possibility of achieving the Carnot efficiency in a finite-power underdamped Brownian Carnot cycle. Recently, it was reported that the Carnot efficiency is achievable in a general class of finite-power Carnot cycles in the vanishing limit of the relaxation times. Thus, it may be interesting to clarify how the efficiency and power depend on the relaxation times by using a specific model. By evaluating the heat-leakage effect intrinsic in the underdamped dynamics with the instantaneous adiabatic processes, we demonstrate that the compatibility of the Carnot efficiency and finite pow…
We want to understand whether and to which extent the maximal (Carnot) efficiency for heat engines can be reached at a finite power. To this end we generalize the Carnot cycle so that it is not restricted to slow processes. We show that for realistic (i.e. not purposefully-designed) engine-bath interactions, the work-optimal engine performing the generalized cycle close to the maximal efficiency has a long cycle time and hence vanishing power. This aspect is shown to relate to the theory of computational complexity. A physical manifestation of the same effect is the Levinthal's paradox in the …
Similarity between quantum mechanics and thermodynamics is discussed. It is found that if the Clausius equality is imposed on the Shannon entropy and the analogue of the heat quantity, then the value of the Shannon entropy comes to formally coincide with that of the von Neumann entropy of the canonical density matrix, and pure-state quantum mechanics apparently transmutes into quantum thermodynamics. The corresponding quantum Carnot cycle of a simple two-state model of a particle confined in a one-dimensional infinite potential well is studied, and its efficiency is shown to be identical to th…
Achieving the Carnot efficiency at finite power is a challenging problem in heat engines due to the trade-off relation between efficiency and power that holds for general heat engines. It is pointed out that the Carnot efficiency at finite power may be achievable in the vanishing limit of the relaxation times of a system without breaking the trade-off relation. However, any explicit model of heat engines that realizes this scenario for arbitrary temperature difference has not been proposed. Here, we investigate an underdamped Brownian Carnot cycle where the finite-time adiabatic processes conn…
We study the maximum efficiency of a Carnot cycle heat engine based on a small system. It is revealed that due to the finiteness of the system, irreversibility may arise when the working substance contacts with a heat bath. As a result, there is a working-substance-dependent correction to the usual Carnot efficiency, which is valid only when the working substance is in the thermodynamic limit. We derives a general and simple expression for the maximum efficiency of a Carnot cycle heat engine in terms of the relative entropy. This maximum efficiency approaches the usual Carnot efficiency asympt…
We identify a velocity distribution function of ideal gas particles that is compatible with the local equilibrium assumption and the fundamental thermodynamic relation satisfying the endoreversibility. We find that this distribution is a Maxwell--Boltzmann distribution with a spatially uniform temperature and a spatially varying local center-of-mass velocity. We construct the local equilibrium Carnot cycle of an ideal gas, based on this distribution, and show that the efficiency of the present cycle is given by the endoreversible Carnot efficiency using the molecular kinetic temperatures of th…
We study a Brownian Carnot cycle introduced by T. Schmiedl and U. Seifert [Europhys. Lett. \textbf{81}, 20003 (2008)] from a viewpoint of the linear irreversible thermodynamics. By considering the entropy production rate of this cycle, we can determine thermodynamic forces and fluxes of the cycle and calculate the Onsager coefficients for general protocols, that is, arbitrary schedules to change the potential confining the Brownian particle. We show that these Onsager coefficients contain the information of the protocol shape and they satisfy the tight-coupling condition irrespective of whatev…
We study a finite-time Carnot cycle of a weakly interacting gas which we can regard as a nearly ideal gas in the limit of $T_\mathrm{h}-T_\mathrm{c}\to 0$ where $T_\mathrm{h}$ and $T_\mathrm{c}$ are the temperatures of the hot and cold heat reservoirs, respectively. In this limit, we can assume that the cycle is working in the linear-response regime and can calculate the Onsager coefficients of this cycle analytically using the elementary molecular kinetic theory. We reveal that these Onsager coefficients satisfy the so-called tight-coupling condition and this fact explains why the efficiency …
Carnot established in 1824 that the efficiency of cyclic engines operating between a hot bath at absolute temperature $T_{hot}$ and a bath at a lower temperature $T_{cold}$ cannot exceed $1-T_{cold}/T_{hot}$. We show that linear oscillators alternately in contact with hot and cold baths obey this principle in the quantum as well as in the classical regime. The expression of the work performed is derived from a simple prescription. Reversible and non-reversible cycles are illustrated. The paper begins with historical considerations and is essentially self-contained.
Carnot's four-part ideal-gas cycle includes both isothermal and adiabatic expansions and compressions. Analyzing this cycle provides the fundamental basis for statistical thermodynamics. We explore the cycle here from a pedagogical view in order to promote understanding of the macroscopic thermodynamic entropy, the state function associated with thermal energy changes. From the alternative microscopic viewpoint the Hamiltonian ${\cal H}(q,p)$ is the energy and entropy is the (logarithm of the) phase-space volume $Ω$ associated with a macroscopic state. We apply two novel forms of Hamiltonian m…
We employ the recently developed framework of the energetics of stochastic processes (called `stochastic energetics'), to re-analyze the Carnot cycle in detail, taking account of fluctuations, without taking the thermodynamic limit. We find that both processes of connection to and disconnection from heat baths and adiabatic processes that cause distortion of the energy distribution are sources of inevitable irreversibility within the cycle. Also, the so-called null-recurrence property of the cumulative efficiency of energy conversion over many cycles and the irreversible property of isolated, …
The Carnot cycle is a prototype of ideal heat engine to draw mechanical energy from the heat flux between two thermal baths with the maximum efficiency, dubbed as the Carnot efficiency $η_{\mathrm{C}}$. Such efficiency can only be reached by thermodynamical equilibrium processes with infinite time, accompanied unavoidably with vanishing power - energy output per unit time. In real-world applications, the quest to acquire high power leads to an open question whether a fundamental maximum efficiency exists for finite-time heat engines with given power. We experimentally implement a finite-time C…
Recent advances in experimental control of colloidal systems have spurred a revolution in the production of mesoscale thermodynamic devices. Functional "textbook" engines, such as the Stirling and Carnot cycles, have been produced in colloidal systems where they operate far from equilibrium. Simultaneously, significant theoretical advances have been made in the design and analysis of such devices. Here, we use methods from thermodynamic geometry to characterize the optimal finite-time, nonequilibrium cyclic operation of the parametric harmonic oscillator contact with a time-varying heat bath, …
We investigate the efficiency of a quantum Carnot engine based on open quantum dynamics theory. The model includes time-dependent external fields for the subsystems controlling the isothermal and isentropic processes and for the system--bath (SB) interactions controlling the transition between these processes. Numerical simulations are conducted in a nonperturbative and non-Markovian SB coupling regime using the hierarchical equations of motion under these fields at different cycle frequencies. The work applied to the total system and the heat exchanged with the baths are rigorously evaluated.…
We investigate the efficiency at maximum power of an irreversible Carnot engine performing finite-time cycles between two reservoirs at temperatures $T_h$ and $T_c$ $(T_c<T_h)$, taking into account of internally dissipative friction in two "adiabatic" processes. In the frictionless case, the efficiencies at maximum power output are retrieved to be situated between $η_{_C}/$ and $η_{_C}/(2-η_{_C})$, with $η_{_C}=1-T_c/{T_h}$ being the Carnot efficiency. The strong limits of the dissipations in the hot and cold isothermal processes lead to the result that the efficiency at maximum power output a…
In this work an example of a cyclic engine based on a quantum-mechanical properties of the strongly non linear quantum oscillator described by the Poschl-Teller [PT] model is examined. Using the [PT] model as shown in our earlier works [1-4], a quantum-mechanical analog of Carnot cycle (i.e quantum heat engine) has been constructed through the changes of both, the width L of the well and its quantum state. This quantum heat engine has a cycle consisting of adiabatic and isothermal quantum processes. The efficiency of the quantum engine based on the Poschl-Teller-like potential is derived and i…
A quantum-mechanical analog of the Carnot engine reversibly working at vanishing temperature, shortly termed the quantum-mechanical Carnot engine, is discussed. A general formula for the efficiency of such an engine with an arbitrary confining potential is presented. Its expression is purely given in terms of the structure of the energy spectrum. Dependency of the efficiency on the form of a potential as an analog of the working material in thermodynamics implies nonuniversality of the engine. This may be due to the absence of the second-law-like principle in pure-state quantum mechanics.
We study the efficiency at the maximal power $η_\mathrm{max}$ of a finite-time Carnot cycle of a weakly interacting gas which we can reagard as a nearly ideal gas. In several systems interacting with the hot and cold reservoirs of the temperatures $T_\mathrm{h}$ and $T_\mathrm{c}$, respectively, it is known that $η_\mathrm{max}=1-\sqrt{T_\mathrm{c}/T_\mathrm{h}}$ which is often called the Curzon-Ahlborn (CA) efficiency $η_\mathrm{CA}$. For the first time numerical experiments to verify the validity of $η_\mathrm{CA}$ are performed by means of molecular dynamics simulations and reveal that our …
We construct an example of heat engine whose efficiency at maximum power breaks down the previously derived bounds in the linear response regime. Such example takes a classical harmonic oscillator as the working substance undergoing a finite-time Otto cycle. Using a specific kind of shortcut to adiabaticity, valid only in the linear response regime, quasistatic work is performed at arbitrarily short times. The cycle duration is then reduced to the sum of relaxation times during the thermalization strokes exclusively. Thus, power is maximum since the work is maximum (quasistatic work) and the c…
Considering ideal paramagnetic medium, in this paper we deduced an expression for the thermal efficiency of Carnot heat engine with a paramagnetic gas as working substance. We found that the efficiency depends on the limits of maximum and minimal temperature imposed on the Carnot cycle, as in the ideal gas, photon gas and variable Chaplygin gas.
In their work [J. Phys. A: Math. Gen. 33, 4427 (2000)], Bender, Brody, and Meister have shown by employing a two-state model of a particle confined in the one-dimensional infinite potential well that it is possible to construct a quantum-mechanical analog of the Carnot engine through the changes of both the width of the well and the quantum state in a specific manner. Here, a discussion is developed about realizing the maximum power of such an engine, where the width of the well moves at low but finite speed. The efficiency of the engine at the maximum power output is found to be universal ind…
We study the efficiency at maximum power, $η^*$, of engines performing finite-time Carnot cycles between a hot and a cold reservoir at temperatures $T_h$ and $T_c$, respectively. For engines reaching Carnot efficiency $η_C=1-T_c/T_h$ in the reversible limit (long cycle time, zero dissipation), we find in the limit of low dissipation that $η^*$ is bounded from above by $η_C/(2-η_C)$ and from below by $η_C/2$. These bounds are reached when the ratio of the dissipation during the cold and hot isothermal phases tend respectively to zero or infinity. For symmetric dissipation (ratio one) the Curzon…
We study two-dimensional quantum Carnot engines of spherical symmetry by considering the case of a particle on the surface of a sphere of changing radius. The Carnot cycle is built allowing the state of the system to change with the specific constrains discussed in Bender's work for Carnot cycles. After studying the Carnot cycle, we maximize the output power and efficiency of the system to show that as it happens in one dimension systems:(i) the efficiency can be optimized; being its optimal value independent of the parameters describing the system and that the optimal output power at the opti…
Aiming to explore physical limits of wind turbines, we develop a model for determining the work extractable from a compressible fluid flow. The model employs conservation of mass, energy and entropy and leads to a universal bound for the efficiency of the work extractable from kinetic energy. The bound is reached for a sufficiently slow, weakly-forced quasi-one-dimensional, dissipationless flow. In several respects the bound is similar to the Carnot limit for the efficiency of heat-engines. More generally, we show that the maximum work-extraction demands a contribution from the enthalpy, and i…
We determine the statistics of work in isothermal volume changes of a classical ideal gas consisting of a single particle. Combining our results with the findings of Lua and Grosberg [J. Chem. Phys. B 109, 6805 (2005)] on adiabatic expansions and compressions we then analyze the joint probability distribution of heat and work for a microscopic, non-equilibrium Carnot cycle and determine its efficiency at maximum power.
The Carnot cycle imposes a fundamental upper limit to the efficiency of a macroscopic motor operating between two thermal baths. However, this bound needs to be reinterpreted at microscopic scales, where molecular bio-motors and some artificial micro-engines operate. As described by stochastic thermodynamics, energy transfers in microscopic systems are random and thermal fluctuations induce transient decreases of entropy, allowing for possible violations of the Carnot limit. Despite its potential relevance for the development of a thermodynamics of small systems, an experimental study of micro…
Carnot established in 1824 that the efficiency $η_{C}$ of reversible engines operating between a hot bath at absolute temperature $T_{hot}$ and a cold bath at temperature $T_{cold}$ is equal to $1-T_{cold}/T_{hot}$. Carnot particularly considered air as a working fluid and small bath-temperature differences. Plugging into Carnot's expression modern experimental values, exact agreement with modern Thermodynamics is found. However, in a recently published paper ["Sadi Carnot on Carnot's theorem", \textit{Am. J. Phys.} \textbf{70}(1), 42-47, 2002], Guemez and others consider a "modified cycle" in…
We consider the optimization of a finite-time Carnot engine characterized by small dissipations. We bound the power with a simple inequality and show that the optimal strategy is to perform small cycles around a given working point, which can be thus chosen optimally. Remarkably, this optimal point is independent of the figure of merit combining power and efficiency that is being maximized. Furthermore, for a general class of dynamics the power output becomes proportional to the heat capacity of the working substance. Since the heat capacity can scale supra-extensively with the number of const…
We investigate the efficiency at maximum power (EMP) of irreversible quantum Carnot engines that perform finite-time cycles between two temperature tunable baths. The temperature form we adopt can be experimentally realized in squeezed baths in the high temperature limit, which makes our proposal of practical relevance. Focusing on low dissipation engines, we first generalize the pervious upper as well as lower bounds for the EMP to temperature tunable cases in which they are solely determined by a generalized Carnot limit. As an illustrative example, we then consider a minimal heat engine mod…
We analyse non-equilibrium Carnot-like cycles built with a colloidal particle in a harmonic trap, which is immersed in a fluid that acts as a heat bath. Our analysis is carried out in the overdamped regime. The cycle comprises four branches: two isothermal processes and two \textit{locally} adiabatic ones. In the latter, both the temperature of the bath and the stiffness of the harmonic trap vary in time, but in such a way that the average heat vanishes for all times. All branches are swept at a finite rate and, therefore, the corresponding processes are irreversible, not quasi-static. Specifi…
Stochastic thermodynamics has revolutionized our understanding of heat engines operating in finite time. Recently, numerous studies have considered the optimal operation of thermodynamic cycles acting as heat engines with a given profile in thermodynamic space (e.g. $P-V$ space in classical thermodynamics), with a particular focus on the Carnot engine. In this work, we use the lens of thermodynamic geometry to explore the full space of thermodynamic cycles with continuously-varying bath temperature in search of optimally shaped cycles acting in the slow-driving regime. We apply classical isope…
With the Lipkin-Meshkov-Glick (LMG) model as an illustration, we construct a thermodynamic cycle composed of two isothermal processes and two isomagnetic field processes and study the thermodynamic performance of this cycle accompanied by the quantum phase transition (QPT). We find that for a finite particle system working below the critical temperature, the efficiency of the cycle is capable of approaching the Carnot limit when the external magnetic field λ_{1} corresponding to one of the isomagnetic processes reaches the crosspoint of the ground states' energy level, which can become critica…
From thermodynamics point of view, in this era of aiming at energy conservation and sustainability, we need to develop more accurate ways to design thermal power, cooling and heat pump cycles. It has been the general practice in thermodynamic analysis of cycles to use the Carnot efficiency and Carnot coefficient of performance which are the highest upper bound to efficiency and COP of cycles. In the present report through the application of the second law of thermodynamics for irreversible processes, which results in the general inequality relation for the entropy production, we have introduce…
A heat engine operating in the one-shot finite-size regime, where systems composed of a small number of quantum particles interact with hot and cold baths and are restricted to one-shot measurements, delivers fluctuating work. Further, engines with lesser fluctuation produce a lesser amount of deterministic work. Hence, the heat-to-work conversion efficiency stays well below the Carnot efficiency. Here we overcome this limitation and attain Carnot efficiency in the one-shot finite-size regime, where the engines allow the working systems to simultaneously interact with two baths via the semi-lo…
We analyze the effect of impurity on the work output and efficiency of quantum Otto and quantum Carnot heat cycles, modeled as a single quantum particle in an infinite square well (ISW) potential, which is the working substance. We solve this quantum mechanical system perturbatively up to first and second order in strength of the impurity for strong and weak coupling regimes, respectively. We derive the analytical expressions of work and efficiency for the strong coupling regime to the first order in the strength parameter. The threshold value of the strength parameter in weak coupling is obta…
In the present work, a power law dissipative Carnot like heat engine cycle of two irreversible isothermal and two irreversible adiabatic processes with finite time non-adiabatic dissipation is considered and the efficiency under two optimization criteria $\dotΩ$ figure of merit and efficient power, $χ_{ep}$ is studied. The generalized extreme bounds of the optimized efficiency under the above said optimization criteria are obtained. The lower and upper bounds of the efficiency for the low dissipation Carnot-like heat engine under these optimization criteria are obtained with dissipation level …
Quantum heat cycles and quantum refrigerators are analyzed using various quantum systems as their working mediums. For example, to evaluate the efficiency and the work done of the Carnot cycle in the quantum regime, one can consider the harmonic oscillator as it's working medium. For all these well-defined working substances (which are analyzed in commutative space structure), the efficiency of the engine is not up to the mark of the Carnot efficiency. So, one inevitable question arise, can one observe a catalytic effect on the efficiency of the engines and refrigerators when the space structu…
ICTP – The Abdus Salam International Centre for Theoretical Physics（阿卜杜斯·萨拉姆国际理论物理中心）；Laboratoire de Physique de l’École Normale Supérieure, CNRS, PSL University, Sorbonne Université, and Université de Paris（巴黎高等师范学院物理实验室，法国国家科学研究中心，巴黎文理研究大学，索邦大学，巴黎大学）；University of Potsdam, Institute of Physics & Astronomy（波茨坦大学，物理与天文学研究所）；Institute for Cross-Disciplinary Physics and Complex Systems, (IFISC, UIB-CSIC)（交叉学科物理与复杂系统研究所）
Differences between the thermodynamic behavior of the three-level amplifier (a quantum heat engine based on a thermally pumped laser) and the classical Carnot cycle are usually attributed to the essentially quantum or discrete nature of the former. Here we provide examples of a number of classical and semiclassical heat engines, such as thermionic, thermoelectric and photovoltaic devices, which all utilize the same thermodynamic mechanism for achieving reversibility as the three-level amplifier, namely isentropic (but non-isothermal) particle transfer between hot and cold reservoirs. This mech…
The availability of controllable macroscopic devices, which maintain quantum coherence over relatively long time intervals, for the first time allows an experimental realization of many effects previously considered only as Gedankenexperiments, such as the operation of quantum heat engines. The theoretical efficiency ηof quantum heat engines is restricted by the same Carnot boundary η_C as for the classical ones: any deviations from quasistatic evolution suppressing ηbelow η_C. Here we investigate an implementation of an analog of the Otto cycle in a tunable quantum coherent circuit and show t…
We study the 1-d isotropic Heisenberg model of two spin-1/2 systems as a quantum heat engine. The engine undergoes a four-step Otto cycle where the two adiabatic branches involve changing the external magnetic field at a fixed value of the coupling constant. We find conditions for the engine efficiency to be higher than the uncoupled model; in particular, we find an upper bound which is tighter than the Carnot bound. A new domain of parameter values is pointed out which was not feasible in the interaction-free model. Locally, each spin seems to effect the flow of heat in a direction opposite t…
The Carnot heat engine sets an upper bound on the efficiency of a heat engine. As an ideal, reversible engine, a single cycle must be performed in infinite time, and so the Carnot engine has zero power. However, there is nothing in principle forbidding the existence of a heat engine whose efficiency approaches that of Carnot while maintaining finite power. Such an engine must have very special properties, some of which have been discussed in the literature, in various limits. While recent theorems rule out a large class of engines from maintaining finite power at exactly the Carnot efficiency,…
There are two paradigms to study nanoscale engines in stochastic and quantum thermodynamics. Autonomous models, which do not rely on any external time-dependence, and models that make use of time-dependent control fields, often combined with dividing the control protocol into idealized strokes of a thermodynamic cycle. While the latter paradigm offers theoretical simplifications, its utility in practice has been questioned due to the involved approximations. Here, we bridge the two paradigms by constructing an autonomous model, which implements a thermodynamic cycle in a certain parameter regi…
We show that a 3-qubit system as studied for quantum information purposes can alternatively be used as a thermodynamic machine when driven in finite time and interfaced between two split baths. The spins are arranged in a chain where the working spin in the middle exercises Carnot cycles the area of which defines the exchanged work. The cycle orientation (sign of the exchanged work) flips as the difference of bath temperatures goes through a critical value.
It was reported that, if and only if the specific heat, correlation length, and dynamical exponents $α, ν$ and $z$, fulfill the condition $α-zν>0$, the phase transitions can enable a quantum heat engine to approach Carnot efficiency at finite power. We start our analysis via a different approach in which the effects of interaction and fluctuations on the Hamiltonian of a trapped dilute Bose gas belonging to the same universality as $XY$ model. Based on models of quantum Otto heat engines, we find the general expression of the efficiency which includes the correction due to interaction and fluc…
