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arXiv 1604.01460cond-mat.str-el
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分子三角晶格$κ$ -(ET)$_2$ Ag $_2$(CN)$_3$中量子自旋液体的压力调谐交换耦合

Pressure-Tuned Exchange Coupling of a Quantum Spin Liquid in the Molecular Triangular Lattice $κ$-(ET)$_2$Ag$_2$(CN)$_3$

Yasuhiro Shimizu, Takaaki Hiramatsu, Mitsuhiko Maesato, Akihiro Otsuka, Hideki Yamochi, Akihiro Ono, Masayuki Itoh, Makoto Yoshida, Masashi Takigawa, Yukihiro Yoshida, Gunzi Saito

摘要:

研究了自旋为1/2三角晶格的有机Mott绝缘体$κ$ -(ET)$_2$ Ag $_2$(CN)$_3$中的量子自旋液体的压力效应.负化学压力的应用$κ$ -(ET)$_2$ Cu $_2$(CN)$_3$,这是一个众所周知的姐妹莫特绝缘体,允许广泛的调整反铁磁交换耦合,与$J/k_{\rm B} = 175 - 310$ K,在静水压力。基于压力下的$^{13}$ C核磁共振测量,我们揭示了静态和动态自旋磁化率的普遍标度下降到低温$\sim 0.1k_{\rm B}T/J$。持续的涨落和剩余比热系数与无隙低激发的存在是一致的。因此,我们的结果表明,基本的有限温度特性的量子自旋液体在一个广泛的参数范围。

英文摘要:

The effects of pressure on a quantum spin liquid are investigated in an organic Mott insulator $κ$-(ET)$_2$Ag$_2$(CN)$_3$ with a spin-1/2 triangular lattice. The application of negative chemical pressure to $κ$-(ET)$_2$Cu$_2$(CN)$_3$, which is a well-known sister Mott insulator, allows for extensive tuning of antiferromagnetic exchange coupling, with $J/k_{\rm B} = 175 - 310$ K, under hydrostatic pressure. Based on $^{13}$C nuclear magnetic resonance measurements under pressure, we uncover universal scaling in the static and dynamic spin susceptibilities down to low temperatures $\sim 0.1k_{\rm B}T/J$. The persistent fluctuations and residual specific heat coefficient are consistent with the presence of gapless low-lying excitations. Our results thus demonstrate fundamental finite-temperature properties of quantum spin liquid in a wide parameter range.

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