Triangular Heisenberg antiferromagnets are prototypes of geometric frustration, even if for nearest-neighbor interactions quantum fluctuations are not usually strong enough to destroy magnetic ordering: stronger frustration is required to stabilize a spin-liquid phase. On the basis of static magnetization and electron spin resonance measurements, we demonstrate the emergence of ${\tilde{j}_{\text{eff}}=\frac12}$ moments in the triangular-lattice magnet Na$_2$BaCo(PO$_4$)$_2$. These moments are subject to an extra source of frustration that causes magnetic correlations to set in far above both the magnetic ordering and Weiss temperatures. Corroborating the $\tilde{j}_{\text{eff}}=\frac12$ ground state, theory identifies ferromagnetic Kitaev exchange anisotropy as additional frustrating agent, altogether putting forward Na$_2$BaCo(PO$_4$)$_2$ as a promising Kitaev spin-liquid material.
Ground State Properties of the Doped Kitaev-Heisenberg Chain: Topological Superconducting and Mott Insulating Phases Driven by Magnetic Frustration
University of Warsaw(华沙大学);TU Wien(维也纳工业大学);Technical University Dresden(德累斯顿工业大学);Institute for Theoretical Solid State Physics, IFW Dresden(德累斯顿联邦材料研究所理论固态物理研究所)
We study the orbitally frustrated singlet-triplet models that emerge in the context of spin-orbit coupled Mott insulators with $t_{2g}^4$ electronic configuration. In these compounds, low-energy magnetic degrees of freedom can be cast in terms of three-flavor "triplon" operators describing the transitions between spin-orbit entangled $J=0$ ionic ground state and excited $J=1$ levels. In contrast to a conventional, flavor-isotropic O(3) singlet-triplet models, spin-orbit entangled triplon interactions are flavor-and-bond selective and thus highly frustrated. In a honeycomb lattice, we find clos…
Recently, Co-based honeycomb magnets have been proposed as promising candidate materials to host the Kitaev spin liquid state. One of the front-runners is BaCo$_2$(AsO$_4$)$_2$ (BCAO), where it was suggested that the exchange processes between Co$^{2+}$ ions via the surrounding edge-sharing oxygen octahedra could give rise to bond-dependent Kitaev interactions. In this work, we present and analyze comprehensive inelastic neutron scattering studies of BCAO with fields in the honeycomb plane. Combining the constraints from the magnon excitations in the high-field polarized state and the inelasti…
In the pseudospin-$\frac{1}{2}$ honeycomb Mott insulators with strong spin-orbit coupling, there are two types of bond-dependent exchange interactions, named Kitaev ($K$) and $Γ$, leading to strong frustration. While the ground state of the Kitaev model is a quantum spin liquid with fractionalized excitations, the ground state of the $Γ$ model remains controversial. In particular, the phase diagram of the $KΓ$ model with ferromagnetic $K$ and antiferromagnetic $Γ$ interactions has been intensively studied because of its relevance to candidate materials such as $α$-RuCl$_{3}$. Numerical studies…
The quest for Kitaev quantum spin liquids has led to great interest in honeycomb quantum magnets with strong spin-orbit coupling. It has been recently proposed that even Mott insulators with $3d$ transition metal ions, having nominally weak spin-orbit coupling, can realize such exotic physics. Motivated by this, we study the rhombohedral honeycomb cobaltates CoTiO$_3$, BaCo$_2$(PO$_4$)$_2$, and BaCo$_2$(AsO$_4$)$_2$, using $\textit{ab initio}$ density functional theory, which takes into account realistic crystal field distortions and chemical information, in conjunction with exact diagonalizat…
The layered honeycomb lattice iridate Cu$_2$IrO$_3$ is the closest realization of the Kitaev quantum spin liquid, primarily due to the enhanced interlayer separation and nearly ideal honeycomb lattice. We report pressure-induced structural evolution of Cu$_2$IrO$_3$ by powder x-ray diffraction (PXRD) up to $\sim$17 GPa and Raman scattering measurements up to $\sim$25 GPa. A structural phase transition (monoclinic $C2/c \: \rightarrow$ triclinic $P\bar{1}$) is observed with a broad mixed phase pressure range ($\sim$4 to 15 GPa). The triclinic phase consists of heavily distorted honeycomb lattic…
Honeycomb iridates are thought to have strongly spin-anisotropic exchange interactions that could lead to an extraordinary state of matter known as the Kitaev quantum spin liquid. The realization of this state requires almost perfectly frustrated interactions between the magnetic Ir$^{4+}$ ions, but small imbalances in energy make other ordered states more favorable. Indeed, the closeness in energy of these ordered states is itself a signature of the intrinsic frustration in the system. In this work, we illustrate that small magnetic fields can be employed to drive the frustrated quantum magne…
The Kitaev-Heisenberg (KH) model has been proposed to capture magnetic interactions in iridate Mott insulators on the honeycomb lattice. We show that analogous interactions arise in many other geometries built from edge-sharing IrO_6 octahedra, including the pyrochlore and hyperkagome lattices relevant to Ir2O4 and Na4Ir3O8 respectively. The Kitaev spin liquid exact solution does not generalize to these lattices. However, a different exactly soluble point of the honeycomb lattice KH model, obtained by a four-sublattice transformation to a ferromagnet, generalizes to all these lattices. A Klein…
Materials that realize Kitaev spin models with bond-dependent anisotropic interactions have long been searched for, as the resulting frustration effects are predicted to stabilize novel forms of magnetic order or quantum spin liquids. Here we explore the magnetism of $γ$-Li$_2$IrO$_3$, which has the topology of a 3D Kitaev lattice of inter-connected Ir honeycombs. Using resonant magnetic x-ray diffraction we find a complex, yet highly-symmetric incommensurate magnetic structure with non-coplanar and counter-rotating Ir moments. We propose a minimal Kitaev-Heisenberg Hamiltonian that naturally …
Cubic crystal structure and regular octahedral environment of Ir$^{4+}$ render antifluorite-type K$_2$IrCl$_6$ a model fcc antiferromagnet with a combination of Heisenberg and Kitaev exchange interactions. High-resolution synchrotron powder diffraction confirms cubic symmetry down to at least 20 K, with a low-energy rotary mode gradually suppressed upon cooling. Using thermodynamic and transport measurements, we estimate the activation energy of $Δ\simeq 0.7$ eV for charge transport, the antiferromagnetic Curie-Weiss temperature of $θ_{\rm CW}\simeq -43$ K, and the extrapolated saturation fiel…
We review the consequences of intrinsic frustration of the orbital superexchange and of spin-orbital entanglement. While Heisenberg perturbing interactions remove frustration in the compass model, the lowest columnar excitations are robust in the nanoscopic compass clusters and might be used for quantum computations. Entangled spin-orbital states determine the ground states in some cases, while in others concern excited states and lead to measurable consequences, as in the $R$VO$_3$ perovskites. On-site entanglement for strong spin-orbit coupling generates the frustrated Kitaev-Heisenberg mode…
We report the existence of a phase transition at high temperature in the 3D Kitaev candidate material, $β$-Li$_2$IrO$_3$. We show that the transition is bulk, intrinsic and orders a tiny magnetic moment with a spatially anisotropic saturation moment. We show that even though this transition is global, it does not freeze the local Ir moments, which order at much lower temperatures into an incommensurate state. Rather, the ordered moment has an orbital origin that is coupled to spin correlations, likely of a Kitaev origin. The separate ordering of spin-correlated orbital moments and of local Ir …
Kitaev quantum spin liquid, massively quantum entangled states, is so scarce in nature that searching for new candidate systems remains a great challenge. Honeycomb heterostructure could be a promising route to realize and utilize such an exotic quantum phase by providing additional controllability of Hamiltonian and device compatibility, respectively. Here, we provide epitaxial honeycomb oxide thin film Na3Co2SbO6, a candidate of Kitaev quantum spin liquid proposed recently. We found a spin glass and antiferromagnetic ground states depending on Na stoichiometry, signifying not only the import…
Layered honeycomb magnets are of interest as potential realizations of the Kitaev quantum spin liquid (KQSL), a quantum state with long-range spin entanglement and an exactly solvable Hamiltonian. Conventional magnetically ordered states are present for all currently known candidate materials, however, because non-Kitaev terms in the Hamiltonians obscure the Kitaev physics. Current experimental studies of the KQSL are focused on 4d- or 5d-transition-metal-based honeycombs, in which strong spin-orbit coupling can be expected, yielding Kitaev interaction that dominate in an applied magnetic fiel…
We explore the response of Ir $5d$ orbitals to pressure in $β$-$\mathrm{Li_2IrO_3}$, a hyperhoneycomb iridate in proximity to a Kitaev quantum spin liquid (QSL) ground state. X-ray absorption spectroscopy reveals a reconstruction of the electronic ground state below 2 GPa, the same pressure range where x-ray magnetic circular dichroism shows an apparent collapse of magnetic order. The electronic reconstruction, which manifests a reduction in the effective spin-orbit (SO) interaction in $5d$ orbitals, pushes $β$-$\mathrm{Li_2IrO_3}$ further away from the pure $J_{\rm eff}=1/2$ limit. Although l…
We study the Kitaev spin-$1/2$ ladder, a model which exhibits self-localization due to fractionalization caused by exchange frustration. When a weak magnetic field is applied, the model is described by an effective fermionic Hamiltonian, with an additional time reversal symmetry breaking term. We show that this term alone is not capable of delocalizing the system but flux mobility is a prerequisite. For magnetic fields larger but comparable to the flux gap, fluxes become mobile and drive the system into a delocalized regime, featuring finite dc transport coefficients. Our findings are based on…
The unconventional magnetic orderings found in Kitaev spin liquid candidates suggest frustration of spin interactions, and raise a possibility of nearby spin liquid phases. In particular, counter-rotating spiral ordering in three-dimensional (3D) iridates is striking, and understanding the microscopic mechanism of such ordering may provide routes to 3D Kitaev spin liquids. We study a minimal 3D model including Kitaev $K$ and a symmetric off-diagonal bond-dependent $Γ$ interaction on the hyperhoneycomb lattice using exact diagonalization. We first show that a 12-site unitary transformation unve…
Magnetic moments arranged at the corners of a honeycomb lattice are predicted to form a novel state of matter, Kitaev quantum spin liquid, under the influence of frustration effects between bond-dependent Ising interactions. Some layered honeycomb iridates and related materials, such as Na$_{2}$IrO$_{3}$ and $α$-RuCl$_{3}$, are proximate to Kitaev quantum spin liquid, but bosonic spin-wave excitations associated with undesirable antiferromagnetic long-range order mask the inherent properties of Kitaev Hamiltonian. Here, we use $^{63}$Cu nuclear quadrupole resonance to uncover the low energy sp…
We discuss the finite-temperature phase diagram of the Heisenberg-Kitaev model on the hexagonal lattice, which has been suggested to describe the spin-orbital exchange of the effective spin-1/2 momenta in the Mott insulating Iridate Na2IrO3. At zero-temperature this model exhibits magnetically ordered states well beyond the isotropic Heisenberg limit as well as an extended gapless spin liquid phase around the highly anisotropic Kitaev limit. Using a pseudofermion functional renormalization group (RG) approach, we extract both the Curie-Weiss scale and the critical ordering scale (for the magne…
We investigate the non-Abelian topological chiral spin liquid phase in the two-dimensional (2D) Kitaev honeycomb model subject to a magnetic field. By combining density matrix renormalization group (DMRG) and exact diagonalization (ED) we study the energy spectra, entanglement, topological degeneracy, and expectation values of Wilson loop operators, allowing for robust characterization. While the ferromagnetic (FM) Kitaev spin liquid is already destroyed by a weak magnetic field with Zeeman energy $H_*^\text{FM} \approx 0.02$, the antiferromagnetic (AFM) spin liquid remains robust up to a magn…
We report a $^{35}$Cl nuclear magnetic resonance (NMR) study of the diluted Kitaev material $α$-Ru$_{1-x}$Ir$_x$Cl$_3$ ($x=0.1$ and $0.2$) where non-magnetic Ir$^{3+}$ dopants substitute Ru$^{3+}$ ions. Upon dilution, the $^{35}$Cl spectra exhibit unusual large magnetic inhomogeneity, which sets in at temperatures below the Kitaev exchange energy scale. At the same time, the $^{35}$Cl spin-lattice relaxation rate $T_1^{-1}$ as a function of dilution and magnetic field unravels a critical doping of $x_c\approx 0.22$, towards which both the field-induced spin gap and the zero-field magnetic orde…
Relevance of on-site and intersite Coulomb interactions in the Kitaev-Heisenberg magnet Na$_3$Co$_2$SbO$_6$
Institute for Theoretical Solid State Physics, Leibniz IFW Dresden(德累斯顿亥姆霍兹中心莱布尼茨研究所理论固态物理研究所);Department of Physics, Karpagam Academy of Higher Education(卡尔帕甘高等教育学院物理系);Centre for Computational Physics, Karpagam Academy of Higher Education(卡尔帕甘高等教育学院计算物理中心);School of Physics, University of Melbourne(墨尔本大学物理学院);Department of Physics, Technical University Dresden(德累斯顿工业大学物理系)
The recently-synthesized iridate $β$-Li$_2$IrO$_3$ has been proposed as a candidate to display novel magnetic behavior stabilized by frustration effects from bond-dependent, anisotropic interactions (Kitaev model) on a three-dimensional "hyperhoneycomb" lattice. Here we report a combined study using neutron powder diffraction and magnetic resonant x-ray diffraction to solve the complete magnetic structure. We find a complex, incommensurate magnetic order with non-coplanar and counter-rotating Ir moments, which surprisingly shares many of its features with the related structural polytype "strip…
The triangular-lattice Heisenberg antiferromagnet (HAF) is known to carry topological Z_2 vortex excitations which form a gas at finite temperatures. Here we show that the spin-orbit interaction, introduced via a Kitaev term in the exchange Hamiltonian, condenses these vortices into a triangular $Z_2$ vortex crystal at zero temperature. The cores of the Z_2 vortices show abrupt, soliton-like magnetization modulations and arise by a special intertwining of three honeycomb superstructures of ferromagnetic domains, one for each of the three sublattices of the 120-degree state of the pure HAF. Thi…
Two- and three-dimensional Kitaev magnets are prototypical frustrated quantum spin systems, in which the original spin degrees of freedom fractionalize into Majorana fermions and a $\mathbb{Z}_2$ gauge field -- a purely local phenomenon that reveals itself as a thermodynamic crossover at a temperature scale set by the strength of the bond-directional interactions. For conventional Kitaev magnets, the low-temperature thermodynamics reveals a second transition at which the $\mathbb{Z}_2$ gauge field orders and the system enters a spin liquid ground state. Here we discuss an explicit example that…
We study the interplay between the Kitaev and Ising interactions on both ladder and two dimensional lattices. We show that the ground state of the Kitaev ladder is a symmetry-protected topological (SPT) phase, which is protected by a $\mathbb{Z}_2 \times \mathbb{Z}_2$ symmetry. It is confirmed by the degeneracy of the entanglement spectrum and non-trivial phase factors (inequivalent projective representations of the symmetries), which are obtained within infinite matrix-product representation of numerical density matrix renormalization group. We derive the effective theory to describe the topo…
The topologically nontrivial magnetic phase with a $Z_2$-vortex (Z$_2$V) lattice is investigated by simulation in the Kitaev-Heisenberg honeycomb model expanded by considering the second- and third-nearest-neighbor Heisenberg interactions ($J_{H2}$ and $J_{H3}$). On the parameter region of the Z$_2$V phase, a gradual modulation of vortex density is observed, together with a transition from single-Z$_2$V to triple-Z$_2$V state driven by the variation of frustration. Additionally, $Z_2$ vortices are arranged in different manners on the whole honeycomb structure for these two types of Z$_2$V stat…
With large spin-orbit coupling, the $t_{2g}^5$ electron configuration in $d$-metal oxides is prone to highly anisotropic exchange interactions and exotic magnetic properties. In $5d^5$ iridates, given the existing variety of crystal structures, the magnetic anisotropy can be tuned from antisymmetric to symmetric Kitaev-type, with interaction strengths that outsize the isotropic terms. By many-body electronic-structure calculations we here address the nature of the magnetic exchange and the intriguing spin-glass behavior of Li$_2$RhO$_3$, a $4d^5$ honeycomb oxide. For pristine crystals without …
We introduce a frustration-free, one-dimensional model of spinless fermions with hopping, p-wave superconducting pairing and alternating chemical potentials. The model possesses two exactly degenerate ground states even for finite system sizes. We present analytical results for the strong Majorana zero modes, the phase diagram and the topological order. Furthermore, we generalise our results to include interactions.
Na$_2$IrO$_3$, a honeycomb 5$d^5$ oxide, has been recently identified as a potential realization of the Kitaev spin lattice. The basic feature of this spin model is that for each of the three metal-metal links emerging out of a metal site, the Kitaev interaction connects only spin components perpendicular to the plaquette defined by the magnetic ions and two bridging ligands. The fact that reciprocally orthogonal spin components are coupled along the three different links leads to strong frustration effects and nontrivial physics. While the experiments indicate zigzag antiferromagnetic order i…
In the field of frustrated magnetism, Kitaev models provide a unique framework to study the phenomena of spin fractionalization and emergent lattice gauge theories in two and three spatial dimensions. Their ground states are quantum spin liquids, which can typically be described in terms of a Majorana band structure and an ordering of the underlying $\mathbb{Z}_2$ gauge structure. Here we provide a comprehensive classification of the "gauge physics" of a family of elementary three-dimensional Kitaev models, discussing how their thermodynamics and ground state order depends on the underlying la…
The combination of geometric frustration, extended hopping, spin-orbit coupling, and a disordered magnetic ground state make NaRuO$_{2}$ an attractive Heisenberg-Kitaev candidate material. Historically, NaRuO$_2$ has been a challenging material to produce, even in polycrystalline form. Here we present synthetic efforts that identify a propensity for Na$_\text{Ru}$ defects to form in NaRuO$_2$, revealing a full solid-solution between NaRuO$_{2}$ and disordered Na$_2$RuO$_3$. We report the synthesis of alloys along the Na$_{3+x}$Ru$_{3-x}$O$_6$ solid solution and characterize changes in the bulk…
Quantum spin systems such as magnetic insulators usually show classical magnetic order, but such classical states can give way to quantum liquids with exotic entanglement through two known mechanisms of frustration: geometric frustration in lattices with triangle motifs, and spin-orbit-coupling frustration in the exactly solvable quantum liquid of Kitaev's honeycomb lattice. Here we present the experimental observation of a new kind of frustrated quantum liquid arising in an unlikely place: the magnetic insulator Ba4Ir3O10 where Ir3O12 trimers form an unfrustrated square lattice. Experimentall…
The Heisenberg-Kitaev (HK) model on the triangular lattice is conceptually interesting for its interplay of geometric and exchange frustration. HK models are also thought to capture the essential physics of the spin-orbital entanglement in effective $j=1/2$ Mott insulators studied in the context of various 5d transition metal oxides. Here we argue that the recently synthesized Ba$_3$IrTi$_2$O$_9$ is a prime candidate for a microscopic realization of the triangular HK model. We establish that an infinitesimal Kitaev exchange destabilizes the 120$^\circ$ order of the quantum Heisenberg model and…
Anisotropic Kitaev Spin Glass in Li$_{2}$Ru$_{x}$Ir$_{1-x}$O$_{3}$
University of California, San Diego(加州大学圣迭戈分校);Institute of Science and Technology Austria(奥地利科学技术研究所);TRIUMF(特利昂夫实验室);Argonne National Laboratory(阿贡国家实验室);Brookhaven National Laboratory(布鲁克海文国家实验室);Lawrence Berkeley National Laboratory(劳伦斯伯克利国家实验室);Brigham Young University(杨百翰大学);University of California, Berkeley(加州大学伯克利分校)
We develop a microscopic theory of multipole interactions and orderings in 5$d^2$ transition metal ion compounds. In a cubic environment, the ground state of 5$d^2$ ions is a non-Kramers $E_g$ doublet, which is nonmagnetic but hosts quadrupole and octupole moments. We derive pseudospin one-half Hamiltonians describing various spin-orbital exchange processes between these ions. Direct overlap of the $t_{2g}$ orbitals results in bond-dependent pseudospin interactions similar to those for $e_g$ orbitals in manganites. The superexchange process via oxygen ions generates new types of pairwise inter…
On a ring, a single Jordan-Wigner transformation between the Kitaev model and the spin model suffers redundant degrees of freedom. However, we can establish an exact quaternary Jordan-Wigner mapping involving two Kitaev rings and two spin rings with periodic or antiperiodic boundary conditions. This mapping facilitates us to demonstrate exactly how a topological extended-kink (TEK) phase develops in the interacting Kitaev ring with odd number of lattice sites. The emergence of this new phase is attributed to the effect of geometrical ring frustration. Unlike the usual topological phases protec…
Compass models are theories of matter in which the couplings between the internal spin (or other relevant field) components are inherently spatially (typically, direction) dependent. Compass-type interactions appear in diverse physical systems including Mott insulators with orbital degrees of freedom (where interactions sensitively depend on the spatial orientation of the orbitals involved), the low energy effective theories of frustrated quantum magnets, systems with strong spin-orbit couplings (such as the iridates), vacancy centers, and cold atomic gases. Kitaev's models, in particular the …
Beyond Kitaev exchange: $Γ'$-driven magnetism in Ag$_3$LiRh$_2$O$_6$
Felix Bloch Institute for Solid-State Physics, University of Leipzig(莱比锡大学菲利克斯·布洛赫固体物理研究所);Technical University of Munich, TUM School of Natural Sciences, Physics Department(慕尼黑工业大学自然科学学院物理系);Munich Center for Quantum Science and Technology (MCQST)(慕尼黑量子科学与技术中心);Department of Physics and Center for Functional Materials, Wake Forest University(维克森林大学物理与功能材料中心);Department of Physics, Loughborough University(拉夫堡大学物理系);Blackett Laboratory, Imperial College London(帝国理工学院布莱克特实验室)
Heisenberg interactions are ubiquitous in magnetic materials and have been prevailing in modeling and designing quantum magnets. Bond-directional interactions offer a novel alternative to Heisenberg exchange and provide the building blocks of the Kitaev model, which has a quantum spin liquid (QSL) as its exact ground state. Honeycomb iridates, A2IrO3 (A=Na,Li), offer potential realizations of the Kitaev model, and their reported magnetic behaviors may be interpreted within the Kitaev framework. However, the extent of their relevance to the Kitaev model remains unclear, as evidence for bond-dir…
We have successfully synthesized the novel antiferromagnets with Ir$^{4+}$ honeycomb lattice ZnIrO$_3$ and MgIrO$_3$ and investigated their magnetic and thermodynamic properties. The two iridates are isomorphic but exhibit qualitatively different magnetic properties. ZnIrO$_3$ shows antiferromagnetic ordering below 46.6 K, whereas MgIrO$_3$ displays weak ferromagnetic behavior below 31.8 K owing to formation of a canted antiferromagnetic ordering. The measurement of magnetic susceptibility with using an oriented powder sample revealed the presence of an XY-like magnetic anisotropy and a tiltin…
There have been tremendous experimental and theoretical efforts toward discovery of quantum spin liquid phase in honeycomb-based-lattice materials with strong spin-orbit coupling. Here the bond-dependent Kitaev interaction between local moments provides strong magnetic frustration and if it is the only interaction present in the system, it will lead to an exactly solvable quantum spin liquid ground state. In all of these materials, however, the ground state is in a magnetically ordered phase due to additional interactions between local moments. Recently, it has been reported that the magnetic …
We calculate the two-magnon Raman scattering spectra in antiferromagnetic phases of several frustrated spin models defined on the honeycomb lattice. These include the Néel antiferromagnetic phase of a $J_1$-$J_2$-$J_3$ model and the stripe phase of the Heisenberg-Kitaev model. We show that both the magnetic frustration and the anisotropy of interactions may significantly affect the Raman spectra. We further discuss the implications of our results to the magnetic excitations of the iron-based compound BaFe$_2$Se$_2$O and show how the magnetic interactions can be extracted from fit to the Raman …
Dynamical magnetotropic susceptibility as a new probe of Kitaev materials and beyond
Institut für Theoretische Physik und Astrophysik, Universität Würzburg(维尔茨堡大学理论与天体物理研究所);TU Dresden(德累斯顿工业大学);Institute of Science and Technology Austria(奥地利科学技术研究院);Max-Planck-Institute for Chemical Physics of Solids(马克斯·普朗克固体化学物理研究所);Institute of Solid State Physics, TU Wien(维也纳工业大学固体物理研究所);Würzburg-Dresden Cluster of Excellence ctd.qmat(维尔茨堡-德累斯顿卓越集群ctd.qmat);Institute for Theoretical Solid State Physics, IFW Dresden(德累斯顿IFW理论固体物理研究所)
Emergent Vortex Ordering in a Multiflavor Pyrochlore-Lattice Compound GeCo$_2$O$_4$
University of Science and Technology of China(中国科学技术大学);Comprehensive Research Organization for Science and Society (CROSS)(综合研究组织科学社会);Rutherford Appleton Laboratory(鲁瑟福阿普顿实验室);Peking University(北京大学);China Institute of Atomic Energy(中国原子能科学研究院)