Examples of geometric phases abound in many areas of physics. They offer both fundamental insights into many physical phenomena and lead to interesting practical implementations. One of them, as indicated recently, might be an inherently fault-tolerant quantum computation. This, however, requires to deal with geometric phases in the presence of noise and interactions between different physical subsystems. Despite the wealth of literature on the subject of geometric phases very little is known about this very important case. Here we report the first experimental study of geometric phases for mixed quantum states. We show how different they are from the well understood, noiseless, pure-state case.
Geometric phase (GP) independent of energy and time rely only on the geometry of state space. It has been argued to have potential fault tolerance and plays an important role in quantum information and quantum computation. We present the first experiment for producing and measuring an Abelian geometric phase shift in a three-level system by using NMR interferometry. In contrast to existing experiments, based on the geometry of $S^2$, our experiment concerns the geometric phase with the geometry of $SU(3)/U(2)$. Two interacting qubits have been used to provide such a three-dimensional Hilbert s…
Geometric phase has been proposed as one of the promising methodologies to perform fault tolerant quantum computations. However, since decoherence plays a crucial role in such studies, understanding of mixed state geometric phase has become important. While mixed state geometric phase was first introduced mathematically by Uhlmann, recently Sjoqvist et al. [Phys. Rev. Lett. 85(14), 2845 (2000)] have described the mixed state geometric phase in the context of quantum interference and shown theoretically that the visibility as well as the shift of the interference pattern are functions of geomet…
We give a constructive proof that all mixed states of N qubits in a sufficiently small neighborhood of the maximally mixed state are separable. The construction provides an explicit representation of any such state as a mixture of product states. We give upper and lower bounds on the size of the neighborhood, which show that its extent decreases exponentially with the number of qubits. We also discuss the implications of the bounds for NMR quantum computing.
The Yang-Baxter equation is an important tool in theoretical physics, with many applications in different domains that span from condensed matter to string theory. Recently, the interest on the equation has increased due to its connection to quantum information processing. It has been shown that the Yang-Baxter equation is closely related to quantum entanglement and quantum computation. Therefore, owing to the broad relevance of this equation, besides theoretical studies, it also became significant to pursue its experimental implementation. Here, we show an experimental realization of the Yang…
It is exponentially hard to simulate quantum systems by classical algorithms, while quantum computer could in principle solve this problem polynomially. We demonstrate such an quantum-simulation algorithm on our NMR system to simulate an hydrogen molecule and calculate its ground-state energy. We utilize the NMR interferometry method to measure the phase shift and iterate the process to get a high precision. Finally we get 17 precise bits of the energy value, and we also analyze the source of the error in the simulation.
The universal quantum homogeniser can transform a qubit from any state to any other state with arbitrary accuracy, using only unitary transformations to perform this task. Here we present an implementation of a finite quantum homogeniser using nuclear magnetic resonance (NMR), with a four-qubit system. We compare the homogenisation of a mixed state to a pure state, and the reverse process. After accounting for the effects of decoherence in the system, we find the experimental results to be consistent with the theoretical symmetry in how the qubit states evolve in the two cases. We analyse the …
We provide a physical prescription based on interferometry for introducing the total phase of a mixed state undergoing unitary evolution, which has been an elusive concept in the past. We define the parallel transport condition that provides a connection-form for obtaining the geometric phase for mixed states. The expression for the geometric phase for mixed state reduces to well known formulas in the pure state case when a system undergoes noncyclic and unitary quantum evolution.
Geometric phase may enable inherently fault-tolerant quantum computation. However, due to potential decoherence effects, it is important to understand how such phases arise for {\it mixed} input states. We report the first experiment to measure mixed-state geometric phases in optics, using a Mach-Zehnder interferometer, and polarization mixed states that are produced in two different ways: decohering pure states with birefringent elements; and producing a nonmaximally entangled state of two photons and tracing over one of them, a form of remote state preparation.
The quantum nature of bulk ensemble NMR quantum computing --the center of recent heated debate, is addressed. Concepts of the mixed state and entanglement are examined, and the data in a 2 qubit liquid NMR quantum computation are analyzed. It is pointed out that the key problem in the current debate is the understanding of entanglement in a mixed state system. The following points are concluded in this Letter: 1)Density matrix describes the "state" of an average particle in an ensemble. It can not describe the state of an individual particle in an ensemble in detail; 2) Entanglement is a prope…
NMR is emerging as a valuable testbed for the investigation of foundational questions in quantum mechanics. The present paper outlines the preparation of a class of mixed states, called pseudo-pure states, that emulate pure quantum states in the highly mixed environment typically used to describe solution-state NMR samples. It also describes the NMR observation of spinor behavior in spin 1/2 nuclei, the simulation of wave function collapse using a magnetic field gradient, the creation of entangled (or Bell) pseudo-pure states, and a brief discussion of quantum computing logic gates, including …
We theoretically investigate the phase sensitivity with parity detection on a Mach-Zehnder interferometer with a coherent state combined with a photon-added squeezed vacuum state. When the phase shift approaches zero, the squeezed vacuum state is indeed the optimal state within a constraint on the average number of photons. However, when the phase shift to be estimated slightly deviates from zero, the optimal state is neither the squeezed vacuum state nor the photon-subtracted squeezed vacuum state, but the photon-added squeezed vacuum state when they carry many photons. Finally, we show that …
We revise the problem first addressed by Braunstein and co-workers (Phys. Rev. Lett. {\bf 83} (5) (1999) 1054) concerning the separability of very noisy mixed states represented by general density matrices with the form $ρ_ε= (1-ε)M_d+ερ_1$. From a detailed numerical analysis, it is shown that: (1) there exist infinite values in the interval taken for the density matrix expansion coefficients, $-1\le c_{α_1,...,α_N}\le 1$, which give rise to {\em non-physical density matrices}, with trace equal to 1, but at least one {\em negative} eigenvalue; (2) there exist entangled matrices outside the pre…
In presence of dissipation, quantal states may acquire complex-valued phase effects. We suggest a notion of dissipative interferometry that accommodates this complex-valued structure and that may serve as a tool for analyzing the effect of certain kinds of external influences on quantal interference. The concept of mixed-state phase and concomitant gauge invariance is extended to dissipative internal motion. The resulting complex-valued mixed-state interference effects lead to well-known results in the unitary limit and in the case of dissipative motion of pure quantal states. Dissipative inte…
Experimental NMR implementations of the Deutsch-Josza quantum algorithm based on pesudo-pure spin states exhibit an exponential sensitivity scaling with the number of qubits. By employing truly mixed spin states in spin Liouville space, where molecules with different nuclear spin configurations represent different input states, the Deutsch-Josza problem can be solved by single function evaluation without sensitivity loss concomitant with increase of the number of bits.
Dymanics of spin dimers in multiple quantum NMR experiment is studied on the 5-qubit superconducting quantum processor of IBM {Quantum Experience} for the both {pure} ground and thermodynamic equilibrium (mixed) initial states. The work can be considered as a first step towards an application of quantum computers to solving problems of magnetic resonance. This article is dedicated to Prof. Klaus Möbius and Prof. Kev Salikhov on the occasion of their 85th birthdays.
We give a general method of construting quantum circuit for random \QTR{it}{satisfiability} (SAT) problems with the basic logic gates such as multi-qubit controlled-NOT and NOT gates. The sizes of these circuits are almost the same as the sizes of the SAT formulas. Further, a parallelization scheme is described to solve random SAT problems efficiently through these quantum circuits in \QTR{it}{nuclear magnetic resonance} (NMR) ensemble quantum computing. This scheme exploits truly mixed states as input states rather than pseudo-pure states, and combines with the topological nanture of the NMR …
We find for the unitary evolution of spin-1/2 systems that the "purely mathematical mixed state holonomy of Uhlmann limitedly agrees, in the case of evolution over geodesic spherical triangles, with the holonomy "in the experimental context of quantum interferometry" recently proposed by Sjoqvist, Pati, Ekert, Anandan, Ericsson, Oi and Vedral (Phys. Rev. Lett. 85 [2000], 2845-2848).
The role of mixed state entanglement in liquid-state nuclear magnetic resonance (NMR) quantum computation is not yet well-understood. In particular, despite the success of quantum information processing with NMR, recent work has shown that quantum states used in most of those experiments were not entangled. This is because these states, derived by unitary transforms from the thermal equilibrium state, were too close to the maximally mixed state. We are thus motivated to determine whether a given NMR state is entanglable - that is, does there exist a unitary transform that entangles the state? …
The Greenberger-Horne-Zeilinger (GHZ) effect provides an example of quantum correlations that cannot be explained by classical local hidden variables. This paper reports on the experimental realization of GHZ correlations using nuclear magnetic resonance (NMR). The NMR experiment differs from the originally proposed GHZ experiment in several ways: it is performed on mixed states rather than pure states; and instead of being widely separated, the spins on which it is performed are all located in the same molecule. As a result, the NMR version of the GHZ experiment cannot entirely rule out class…
We study two different decoherence modes for entangled qubits by considering a Liouville - von Neumann master equation. Mode A is determined by projection operators onto the eigenstates of the Hamiltonian and mode B by projectors onto rotated states. We present solutions for general and for Bell diagonal states and calculate for the later the mixedness and the amount of entanglement given by the concurrence. We propose a realization of the decoherence modes within neutron interferometry by applying fluctuating magnetic fields. An experimental test of the Kraus operator decomposition describing…
We investigate evolution of quantum correlations in ensembles of two-qubit nuclear spin systems via nuclear magnetic resonance techniques. We use discord as a measure of quantum correlations and the Werner state as an explicit example. We first introduce different ways of measuring discord and geometric discord in two-qubit systems and then describe the following experimental studies: (a) We quantitatively measure discord for Werner-like states prepared using an entangling pulse sequence. An initial thermal state with zero discord is gradually and periodically transformed into a mixed state wi…
A bipartite quantum system in a mixed state can exhibit nonclassical correlations, which can go beyond quantum entanglement. While quantum discord is the standard measure of quantifying such general quantum correlations, the nonclassicality can be determined by simpler means via the measurement of witness operators. We experimentally construct a positive map to witness nonclassicality of two qubits in an NMR system. The map can be decomposed so that a single run of an experiment on an ensemble of spins suffices to detect the nonclassicality in the state, if present. We let the state evolve in …
A kinematic approach to the geometric phase for mixed quantal states in nonunitary evolution is proposed. This phase is manifestly gauge invariant and can be experimentally tested in interferometry. It leads to well-known results when the evolution is unitary.
After a general introduction to nuclear magnetic resonance (NMR), we give the basics of implementing quantum algorithms. We describe how qubits are realized and controlled with RF pulses, their internal interactions, and gradient fields. A peculiarity of NMR is that the internal interactions (given by the internal Hamiltonian) are always on. We discuss how they can be effectively turned off with the help of a standard NMR method called ``refocusing''. Liquid state NMR experiments are done at room temperature, leading to an extremely mixed (that is, nearly random) initial state. Despite this hi…
This paper surveys our recent research on quantum information processing by nuclear magnetic resonance (NMR) spectroscopy. We begin with a geometric introduction to the NMR of an ensemble of indistinguishable spins, and then show how this geometric interpretation is contained within an algebra of multispin product operators. This algebra is used throughout the rest of the paper to demonstrate that it provides a facile framework within which to study quantum information processing more generally. The implementation of quantum algorithms by NMR depends upon the availability of special kinds of m…
It is often assumed that the ancilla qubits required for encoding a qubit in quantum error correction (QEC) have to be in pure states, $|00...0>$ for example. In this letter, we seek an encoding scheme, in which the ancillae may be in a uniformly mixed state. We demonstrate our scheme experimentally by making use of a three-qubit NMR quantum computer. Moreover, the encoded state has an interesting nature in terms of Quantum Discord, or purely quantum correlations between the data-qubit and ancillae.
We extend the off-diagonal geometric phase [Phys. Rev. Lett. {\bf 85}, 3067 (2000)] to mixed quantal states. The nodal structure of this phase in the qubit (two-level) case is compared with that of the diagonal mixed state geometric phase [Phys. Rev. Lett. {\bf 85}, 2845 (2000)]. Extension to higher dimensional Hilbert spaces is delineated. A physical scenario for the off-diagonal mixed state geometric phase in polarization-entangled two-photon interferometry is proposed.
Continuum-electron interferometry for enhancement of photoelectron circular dichroism and measurement of bound, free, and mixed contributions to chiral response
Off-diagonal mixed state phases based upon a concept of orthogonality adapted to unitary evolution and a proper normalisation condition are introduced. Some particular instances are analysed and parallel transport leading to the off-diagonal mixed state geometric phase is delineated. A complete experimental realisation of the off-diagonal mixed state geometric phases in the qubit case using polarisation-entangled two-photon interferometry is proposed.
We analyze the effects of quantum correlations, such as entanglement and discord, on the efficiency of phase estimation by studying four quantum circuits that can be readily implemented using NMR techniques. These circuits define a standard strategy of repeated single-qubit measurements, a classical strategy where only classical correlations are allowed, and two quantum strategies where nonclassical correlations are allowed. In addition to counting space (number of qubits) and time (number of gates) requirements, we introduce mixedness as a key constraint of the experiment. We compare the effi…
Twirl operations, which convert impure singlet states into Werner states, play an important role in many schemes for entanglement purification. In this paper we describe strategies for implementing twirl operations, with an emphasis on methods suitable for ensemble quantum information processors such as nuclear magnetic resonance (NMR) quantum computers. We implement our twirl operation on a general two-spin mixed state using liquid state NMR techniques, demonstrating that we can obtain the singlet Werner state with high fidelity.
Most quantum error correcting codes are predicated on the assumption that there exists a reservoir of qubits in the state $\ket{0}$, which can be used as ancilla qubits to prepare multi-qubit logical states. In this report, we examine the consequences of relaxing this assumption, and propose a method to increase the fidelity produced by a given code when the ancilla qubits are initialized in mixed states, using the same number of qubits, at most doubling the number of gates. The procedure implemented consists of altering the encoding operator to include the inverse of the unitary operation use…
We show that for an m-partite quantum system, there is a ball of radius 2^{-(m/2-1)} in Frobenius norm, centered at the identity matrix, of separable (unentangled) positive semidefinite matrices. This can be used to derive an epsilon below which mixtures of epsilon of any density matrix with 1 - epsilon of the maximally mixed state will be separable. The epsilon thus obtained is exponentially better (in the number of systems) than existing results. This gives a number of qubits below which NMR with standard pseudopure-state preparation techniques can access only unentangled states; with parame…
The metric underlying the mixed state geometric phase in unitary and nonunitary evolution [Phys. Rev. Lett. {\bf 85}, 2845 (2000); Phys. Rev. Lett. {\bf 93}, 080405 (2004)] is delineated. An explicit form for the line element is derived and shown to be related to an averaged energy dispersion in the case of unitary evolution. The line element is measurable in interferometry involving nearby internal states. Explicit geodesics are found in the single qubit case. It is shown how the Bures line element can be obtained by extending our approach to arbitrary decompositions of density operators. The…
Single-photon sources are a fundamental resource in quantum optics. The indistinguishability and purity of photons emitted from different sources are crucial (necessary, essential) properties for many quantum applications to ensure high-visibility interference between different sources. The state of a single-photon source is described by the modes occupied by the single light quanta. Thus the ability to determine the mode structure of a single-photon source provides a means to assess its quality, compare different sources, and provide feedback for source engineering. Here, we propose and demon…
Modern applications of quantum control in quantum information science and technology require the precise characterization of quantum states and quantum channels. In particular, high-performance quantum state engineering often demands that quantum states are transferred with optimal efficiency via realizable controlled evolution, the latter often modeled by quantum channels. When an appropriate quantum control model for an interested system is constructed, the exploration of optimal bounds on state transfer for the underlying quantum channel is then an important task. In this work, we analyze t…
The geometric phase for a pure quantal state undergoing an arbitrary evolution is a ``memory'' of the geometry of the path in the projective Hilbert space of the system. We find that Uhlmann's geometric phase for a mixed quantal state undergoing unitary evolution not only depends on the geometry of the path of the system alone but also on a constrained bi-local unitary evolution of the purified entangled state. We analyze this in general, illustrate it for the qubit case, and propose an experiment to test this effect. We also show that the mixed state geometric phase proposed recently in the c…
Geometric phases play a central role in a variety of quantum phenomena, especially in condensed matter physics. Recently, it was shown that this fundamental concept exhibits a connection to quantum phase transitions where the system undergoes a qualitative change in the ground state when a control parameter in its Hamiltonian is varied. Here we report the first experimental study using the geometric phase as a topological test of quantum transitions of the ground state in a Heisenberg XY spin model. Using NMR interferometry, we measure the geometric phase for different adiabatic circuits that …
We consider the situation when the signal propagating through each arm of an interferometer has a complicated multi-mode structure. We find the relation between the particle-entanglement and the possibility to surpass the shot-noise limit of the phase estimation. Our results are general---they apply to pure and mixed states of identical and distinguishable particles (or combinations of both), for a fixed and fluctuating number of particles. We also show that the method for detecting the entanglement often used in two-mode system can give misleading results when applied to the multi-mode case.
Geometrical phases have been applied in virtually every major branch of physics and they play an important role in topology and knot theory in mathematics and quantum computation. However, most of the early works focus on pure quantum states which are very unrealistic and almost never occur in practice. The two existed definitions -Uhlmann's and Sjöqvist's- would result in different values for the geometric phase in general. The definition of geometric phase in mixed state scenario is still an open question. Here we present a unified framework for both approaches within one and the same formal…
The minimal time required for a system to evolve between two different states is an important notion for developing ultra-speed quantum computer and communication channel. Here, we introduce a new metric for non-degenerate density operator evolving along unitary orbit and show that this is experimentally realizable operation dependent metric on quantum state space. Using this metric, we obtain the geometric uncertainty relation that leads to a new quantum speed limit. Furthermore, we argue that this gives a tighter bound for the evolution time compared to any other bound. We also obtain a Levi…
For finite-dimensional bipartite quantum systems, we find the exact size of the largest balls, in spectral $l_p$ norms for $1 \le p \le \infty$, of separable (unentangled) matrices around the identity matrix. This implies a simple and intutively meaningful geometrical sufficient condition for separability of bipartite density matrices: that their purity $\tr ρ^2$ not be too large. Theoretical and experimental applications of these results include algorithmic problems such as computing whether or not a state is entangled, and practical ones such as obtaining information about the existence or n…
In 1985, Leggett and Garg (1985 Phys. Rev. Lett. 54 857) proposed a Bell-like inequality to test (in)compatibility between two fundamental concepts of quantum mechanics. The first concept is 'macroscopic realism', which is the quality of a physical property of a quantum system being independent of observation at the macroscopic level. The second concept is 'noninvasive measurability', which is the possibility of performing a measurement without disturbing the subsequent evolution of a system. One of the key requirement for testing the violation of the Leggett-Garg inequality, or Bell's time in…
Everett's concept of relative state is used to introduce a geometric phase that depends nontrivially on entanglement in a pure quantum state. We show that this phase can be measured in multiparticle interferometry. A correlation-dependent generalization of the relative state geometric phase to mixed quantum states is outlined.
A novel ultrabright parametric source of polarization entangled photon pairs with striking spatial characteristics is reported. The distribution of the output electromagnetic k-modes excited by Spontaneous Parametris Down Conversion and coupled to the output detectors can be very broad. It could coincide with the full set of phase-matched excited modes, at least in principle. In this case a relevant conditional quasi-pure output state should be realized. By these (approximate) states realized over a full Entanglement-Ring output distribution, the non local properties of the generated entanglem…
The Berry phase has found applications in building topological order parameters for certain condensed matter systems. The question whether some geometric phase for mixed states can serve the same purpose has been raised, and proposals are on the table. We analyze the intricate behaviour of Uhlmann's geometric phase in the Kitaev chain at finite temperature, and then argue that it captures quite different physics from that intended. We also analyze the behaviour of a geometric phase introduced in the context of interferometry. For the Kitaev chain, this phase closely mirrors that of the Berry p…
Uhlmann's mixed state geometric phase [Rep. Math. Phys. {\bf 24}, 229 (1986)] is analyzed in the case of a qubit affected by isotropic decoherence treated in the Markovian approximation. It is demonstrated that this phase decreases rapidly with increasing decoherence rate and that it is most fragile to weak decoherence for pure or nearly pure initial states. In the unitary case, we compare Uhlmann's geometric phase for mixed states with that occurring in standard Mach-Zehnder interferometry [Phys. Rev. Lett. {\bf 85}, 2845 (2000)] and show that the latter is more robust to reduction in the len…
We find a large class of pure and mixed input states with which the phase estimation precision saturates the Cramer-Rao bound under the compound measurements of parity and particle number. We further propose a quantum-phase-estimation protocol for arbitrary input states, through which the precision achieved is always higher than or equal to that obtained via the original input state. We also demonstrate the implementation of the proposed scheme using a nonlinear interferometry and the realization of the nondemolition parity measurement in atomic condensates.
Quantum coherence is a crucial resource for quantum information processing. By employing the language of coherence orders largely applied in NMR systems, quantum coherence has been currently addressed in terms of multiple quantum coherences (MQCs). Here we investigate the $α$-MQCs, a novel class of multiple quantum coherences which is based on $α$-relative purity, an information-theoretic quantifier analogous to quantum fidelity and closely related to Rényi relative entropy of order $α$. Our framework enables linking $α$-MQCs to Wigner-Yanase-Dyson skew information (WYDSI), an asymmetry monoto…
We define an operational notion of phases in interferometry for a quantum system undergoing a completely positive non-unitary evolution. This definition is based on the concepts of quantum measurement theory. The suitable generalization of the Pancharatnan connection allows us to determine the dynamical and geometrical parts of the total phase between two states linked by a completely positive map. These results reduce to the knonw expressions of total, dynamical and geometrical phases for pure and mixed states evolving unitarily.
The decoherence of mixed electron-nuclear spin qubits is a topic of great current importance, but understanding is still lacking: while important decoherence mechanisms for spin qubits arise from quantum spin bath environments with slow decay of correlations, the only analytical framework for explaining observed sharp variations of decoherence times with magnetic field is based on the suppression of classical noise. Here we obtain a general expression for decoherence times of the central spin system which exposes significant differences between quantum-bath decoherence and decoherence by class…
Geometric phase has found a broad spectrum of applications in both classical and quantum physics, such as condensed matter and quantum computation. In this paper we introduce an operational geometric phase for mixed quantum states, based on spectral weighted traces of holonomies, and we prove that it generalizes the standard definition of geometric phase for mixed states, which is based on quantum interferometry. We also introduce higher order geometric phases, and prove that under a fairly weak, generically satisfied, requirement, there is always a well-defined geometric phase of some order. …
