Introduction to NMR Quantum Information Processing
R. Laflamme, E. Knill, D. G. Cory, E. M. Fortunato, T. Havel, C. Miquel, R. Martinez, C. Negrevergne, G. Ortiz, M. A. Pravia, Y. Sharf, S. Sinha, R. Somma, L. Viola
After a general introduction to nuclear magnetic resonance (NMR), we give the basics of implementing quantum algorithms. We describe how qubits are realized and controlled with RF pulses, their internal interactions, and gradient fields. A peculiarity of NMR is that the internal interactions (given by the internal Hamiltonian) are always on. We discuss how they can be effectively turned off with the help of a standard NMR method called ``refocusing''. Liquid state NMR experiments are done at room temperature, leading to an extremely mixed (that is, nearly random) initial state. Despite this high degree of randomness, it is possible to investigate QIP because the relaxation time (the time scale over which useful signal from a computation is lost) is sufficiently long. We explain how this feature leads to the crucial ability of simulating a pure (non-random) state by using ``pseudopure'' states. We discuss how the ``answer'' provided by a computation is obtained by measurement and how this measurement differs from the ideal, projective measurement of QIP. We then give implementations of some simple quantum algorithms with a typical experimental result. We conclude with a discussion of what we have learned from NMR QIP so far and what the prospects for future NMR QIP experiments are.
Quantum computing exploits fundamentally new models of computation based on quantum mechanical properties instead of classical physics, and it is believed that quantum computers are able to dramatically improve computational power for particular tasks. At present, nuclear magnetic resonance (NMR) has been one of the most successful platforms amongst all current implementations. It has demonstrated universal controls on the largest number of qubits, and many advanced techniques developed in NMR have been adopted to other quantum systems successfully. In this review, we show how NMR quantum proc…
Quantum ensembles form easily accessible architectures for studying various phenomena in quantum physics, quantum information science, and spectroscopy. Here we review some recent protocols for measurements in quantum ensembles by utilizing ancillary systems. We also illustrate these protocols experimentally via nuclear magnetic resonance techniques. In particular, we shall review noninvasive measurements, extracting expectation values of various operators, characterizations of quantum states, and quantum processes, and finally quantum noise engineering.
NMR quantum information processing studies rely on the reconstruction of the density matrix representing the so-called pseudo-pure states (PPS). An initially pure part of a PPS state undergoes unitary and non-unitary (relaxation) transformations during a computation process, causing a "loss of purity" until the equilibrium is reached. Besides, upon relaxation, the nuclear polarization varies in time, a fact which must be taken into account when comparing density matrices at different instants. Attempting to use time-fixed normalization procedures when relaxation is present, leads to various an…
While a bit is the fundamental unit of binary classical information, a qubit is the fundamental unit of quantum information. In quantum information processing (QIP), it is customary to call the qubits under study as system qubits, and the additional qubits as ancillary qubits. In this thesis, I describe various schemes to exploit the ancillary qubits to efficiently perform many QIP tasks and their experimental demonstrations in nuclear magnetic resonance (NMR) systems. Particularly, we have showed that, in the presence of sufficient ancillary qubits, it is possible to completely characterize a…
A connection of the Wigner-Yanase skew information and multiple quantum (MQ) NMR coherences is considered at different temperatures and evolution times of nuclear spins with dipole-dipole interactions in MQ NMR experiments in solids. It is shown that the Wigner-Yanase skew information at temperature $T$ is equal to the double second moment of the MQ NMR spectrum at the double temperature for any evolution times. A comparison of the many-spin entanglement obtained with the Wigner-Yanase information and the Fisher information is conducted.
High performance quantum information processing requires efficient control of undesired decohering effects, which are present in realistic quantum dynamics. To deal with this issue, a powerful strategy is to employ transitionless quantum driving (TQD), where additional fields are added to speed up the evolution of the quantum system, achieving a desired state in a short time in comparison with the natural decoherence time scales. In this paper, we provide an experimental investigation of the performance of a generalized approach for TQD to implement shortcuts to adiabaticity in nuclear magneti…
An ensemble of nuclear spin-pairs under certain conditions is known to exhibit singlet state life-times much longer than other non-equilibrium states. This property of singlet state can be exploited in quantum information processing for efficient initialization of quantum registers. Here we describe a general method of initialization and experimentally demonstrate it with two-, three-, and four-qubit nuclear spin registers.
Experimental implementation of a quantum algorithm requires unitary operator decomposition. Here we treat the unitary operator decomposition as an optimization problem and use Genetic Algorithm, a global optimization method inspired by nature's evolutionary process for operator decomposition. As an application, we apply this to NMR Quantum Information Processing and find a probabilistic way of doing universal quantum computation using global hard pulses. We also demonstrate efficient creation of singlet state (as a special case of Bell state) directly from thermal equilibrium using an optimum …
Nuclear magnetic resonance (NMR) has been widely used in the context of quantum information processing (QIP). However, despite the great similarities between NMR and nuclear quadrupole resonance (NQR), no experimental implementation for QIP using NQR has been reported. We describe the implementation of basic quantum gates and their applications on the creation of pseudopure states using linearly polarized radiofrequency pulses under static magnetic field perturbation. The NQR quantum operations were implemented using a single crystal sample of KClO3 and observing 35Cl nuclei, which posses spin…
On Statistical Query Sampling and NMR Quantum Computing
我们引入了一个“统计查询采样”模型，其中算法的目标是以合理的概率产生隐藏集合$Ssubseteqbit^n$中的元素。该算法通过oracle调用（统计查询）获得关于$S$的信息，其中该算法提交查询函数$g(cdot)$并接收对$Pr_{x in S}[g(x)=1]$的近似。我们展示了这个模型是如何与NMR量子计算，其中只有统计特性的量子系统的合奏可以测量，特别是一个问题，是否可以将标准的量子算法的NMR设置，而不把所有的经典后处理到量子系统。使用傅立叶分析技术在相关的背景下{em统计查询学习}，我们证明了一些下界（信息理论和密码）的算法产生一个$xin S$的能力，即使当集$S$是相当简单的。这些下限指出了将NMR量子计算有效地应用于诸如Shor和Simon算法之类的涉及显著经典后处理的算法的困难。我们还明确地将统计查询采样的概念与统计查询学习的概念联系起来。一个扩展的摘要出现在2003年第18届IEEE计算复杂性年会（CCC 2003）上。关键词：统计查询，核磁共振量子计算，下界
The existence of contextuality in quantum mechanics is a fundamental departure from the classical description of the world. Currently, the quest to identify scenarios which cannot be more contextual than quantum theory is at the forefront of research in quantum contextuality. In this work, we experimentally test two inequalities, which are capable of revealing fully contextual quantum correlations, on a Hilbert space of dimension 8 and 4 respectively, on an NMR quantum information processor. The projectors associated with the contextuality inequalities are first reformulated in terms of Pauli …
We present the first NMR implementation of a scheme for selective and efficient quantum process tomography without ancilla. We generalize this scheme such that it can be implemented efficiently using only a set of measurements involving product operators. The method allows us to estimate any element of the quantum process matrix to a desired precision, provided a set of quantum states can be prepared efficiently. Our modified technique requires fewer experimental resources as compared to the standard implementation of selective and efficient quantum process tomography, as it exploits the speci…
Estimation of quantum states is one of the most important steps in any quantum information processing experiment. A naive reconstruction of the density matrix from experimental measurements can often give density matrices which are not positive, and hence not physically acceptable. How do we ensure that at all stages of reconstruction, we keep the density matrix positive and normalized? Recently a method has been suggested based on maximum likelihood estimation, wherein the density matrix is guaranteed to be positive definite. We experimentally implement this protocol and demonstrate its utili…
In this chapter we review the contributions of Nuclear Magnetic Resonance to the study of quantum correlations, including its capabilities to prepare initial states, generate unitary transformations, and characterize the final state. These are the three main demands to implement quantum information processing in a physical system, which NMR offers, nearly to perfection, though for a small number of qubits. Our main discussion will concern liquid samples at room temperature.
Random local measurements have recently been proposed to construct entanglement witnesses and thereby detect the presence of bipartite entanglement. We experimentally demonstrate the efficacy of one such scheme on a two-qubit NMR quantum information processor. We show that a set of three random local measurements suffices to detect the entanglement of a general two-qubit state. We experimentally generate states with different amounts of entanglement, and show that the scheme is able to clearly witness entanglement. We perform complete quantum state tomography for each state and compute state f…
We undertake experimental detection of the entanglement present in arbitrary three-qubit pure quantum states on an NMR quantum information processor. Measurements of only four observables suffice to experimentally differentiate between the six classes of states which are inequivalent under stochastic local operation and classical communication (SLOCC). The experimental realization is achieved by mapping the desired observables onto Pauli $z$-operators of a single qubit, which is directly amenable to measurement. The detection scheme is applied to known entangled states as well as to states ran…
Multiple quantum (MQ) NMR methods \cite{Baum} are applied to the analysis of various problems of quantum information processing. It is shown that the two-spin/two-quantum Hamiltonian \cite{Baum} describing MQ NMR dynamics is related to the flip-flop Hamiltonian of a one-dimensional spin system in the approximation of the nearest neighbor interactions. As a result, it is possible to organize quantum state transfer along a linear chain. MQ NMR experiments are performed on quasi-one-dimensional chains of \BPChem{\^{19}F} nuclei in calcium fluorapatite \BPChem{Ca\_5(PO\_4)\_3F}. Relaxation of the …
Anyons have exotic statistical properties, fractional statistics, differing from Bosons and Fermions. They can be created as excitations of some Hamiltonian models. Here we present an experimental demonstration of anyonic fractional statistics by simulating a version of the Kitaev spin lattice model proposed by Han et al[Phys. Rev.Lett. 98, 150404 (2007)] using an NMR quantum information processor. We use a 7-qubit system to prepare a 6-qubit pseudopure state to implement the ground state preparation and realize anyonic manipulations, including creation, braiding and anyon fusion. A $π/2\times…
An algorithm based on quantum phase estimation, which discriminates quantum states nondestructively within a set of arbitrary orthogonal states, is described and experimentally verified by a NMR quantum information processor. The procedure is scalable and can be applied to any set of orthogonal states. Scalability is demonstrated through Matlab simulation.
The existence of quantum correlation (as revealed by quantum discord), other than entanglement and its role in quantum-information processing (QIP), is a current subject for discussion. In particular, it has been suggested that this nonclassical correlation may provide computational speedup for some quantum algorithms. In this regard, bulk nuclear magnetic resonance (NMR) has been successfully used as a test bench for many QIP implementations, although it has also been continuously criticized for not presenting entanglement in most of the systems used so far. In this paper, we report a theoret…
Physical potentials are routinely approximated to harmonic potentials so as to analytically solve the system dynamics. Often it is important to know when a quantum harmonic oscillator (QHO) behaves quantum mechanically and when classically. Recently Su et. al. [Phys. Rev. A {\bf 85}, 052126 (2012)] have theoretically shown that QHO exhibits quantum contextuality (QC) for a certain set of pseudospin observables. In this work, we encode the four eigenstates of a QHO onto four Zeeman product states of a pair of spin-1/2 nuclei. Using the techniques of NMR quantum information processing, we then d…
Methods to control errors will be essential for quantum information processing. It is widely believed that fault-tolerant quantum error correction is the leading contender to achieve this goal. Although the theory of fault-tolerant quantum error correction is very well understood, experimental implementation has been lagging. We study the feasibility of implementing repeated rounds of quantum error correction with refreshed ancillas in solid state nuclear magnetic resonance (NMR). In particular we study the procedure proposed for extracting entropy that consists of two stages; an error correct…
Multiple quantum (MQ) NMR with a dipolar ordered initial state opens new possibilities for the exploration of many-spin entanglement. In this paper, we investigate many-spin entanglement in a gas of spin-carrying molecules (atoms) in nanocavities in the conditions of MQ NMR with a dipolar ordered initial state. The second moment of the distribution of the intensities of MQ NMR coherences, which provides a lower bound on the quantum Fisher information, is used for an estimate of the number of the entangled spins. Many-spin entanglement is investigated at different temperatures and different num…
