NMR Contributions to the study of Quantum Correlations
Isabela A. Silva, Jefferson G. Filgueiras, Ruben Auccaise, Alexandre M. Souza, Raimund Marx, Steffen J. Glaser, Tito J. Bonagamba, Roberto S. Sarthour, Ivan S. … 展开作者
Isabela A. Silva, Jefferson G. Filgueiras, Ruben Auccaise, Alexandre M. Souza, Raimund Marx, Steffen J. Glaser, Tito J. Bonagamba, Roberto S. Sarthour, Ivan S. Oliveira, Eduardo R. deAzevedo
备注：
24 pages, 14 figures. Contribution to "Lectures on general quantum correlations and their applications", edited by Felipe Fanchini, Diogo Soares-Pinto, and Gerardo Adesso. Sorry for being late!
In this chapter we review the contributions of Nuclear Magnetic Resonance to the study of quantum correlations, including its capabilities to prepare initial states, generate unitary transformations, and characterize the final state. These are the three main demands to implement quantum information processing in a physical system, which NMR offers, nearly to perfection, though for a small number of qubits. Our main discussion will concern liquid samples at room temperature.
Nuclear magnetic resonance (NMR) has enormous applications. Two-dimensional NMR is an essential technique to characterize correlations between nuclei and, hence, molecule structures. Towards the ultimate goal of single-molecule NMR, dynamical-decoupling- (DD) enhanced diamond quantum sensing enables the detection of single nuclear spins and nanoscale NMR. However, there is still the lack of a standard method in DD-based quantum sensing to characterize correlations between nuclear spins in single molecules. Here we present a scheme of two-dimensional DD-based quantum sensing, as a universal met…
In conventional NMR experiments, the Zeeman energy gaps of the nuclear spin ensembles are much lower than their thermal energies, and accordingly exhibit tiny polarizations. Generally such low-purity quantum states are devoid of quantum entanglement. However, there exist certain nonclassical correlations which can be observed even in such systems. In this chapter, we discuss three such quantum correlations, namely, quantum contextuality, Leggett-Garg temporal correlations, and quantum discord. In each case, we provide a brief theoretical background and then describe some results from NMR exper…
The existence of quantum correlation (as revealed by quantum discord), other than entanglement and its role in quantum-information processing (QIP), is a current subject for discussion. In particular, it has been suggested that this nonclassical correlation may provide computational speedup for some quantum algorithms. In this regard, bulk nuclear magnetic resonance (NMR) has been successfully used as a test bench for many QIP implementations, although it has also been continuously criticized for not presenting entanglement in most of the systems used so far. In this paper, we report a theoret…
The existence of contextuality in quantum mechanics is a fundamental departure from the classical description of the world. Currently, the quest to identify scenarios which cannot be more contextual than quantum theory is at the forefront of research in quantum contextuality. In this work, we experimentally test two inequalities, which are capable of revealing fully contextual quantum correlations, on a Hilbert space of dimension 8 and 4 respectively, on an NMR quantum information processor. The projectors associated with the contextuality inequalities are first reformulated in terms of Pauli …
The Greenberger-Horne-Zeilinger (GHZ) effect provides an example of quantum correlations that cannot be explained by classical local hidden variables. This paper reports on the experimental realization of GHZ correlations using nuclear magnetic resonance (NMR). The NMR experiment differs from the originally proposed GHZ experiment in several ways: it is performed on mixed states rather than pure states; and instead of being widely separated, the spins on which it is performed are all located in the same molecule. As a result, the NMR version of the GHZ experiment cannot entirely rule out class…
We propose two dimensional x-ray coherent correlation spectroscopy (2DXCS) for the study of interactions between core-electron and valence transitions. This technique might find experimental applications in the future when very high intensity x-ray sources become available. Spectra obtained by varying two delay periods between pulses show off-diagonal cross-peaks induced by coupling of core transitions of two different types. Calculations of the N1s and O1s signals of aminophenol isomers illustrate how novel information about many-body effects in electronic structure and excitations of molecul…
A bipartite quantum system in a mixed state can exhibit nonclassical correlations, which can go beyond quantum entanglement. While quantum discord is the standard measure of quantifying such general quantum correlations, the nonclassicality can be determined by simpler means via the measurement of witness operators. We experimentally construct a positive map to witness nonclassicality of two qubits in an NMR system. The map can be decomposed so that a single run of an experiment on an ensemble of spins suffices to detect the nonclassicality in the state, if present. We let the state evolve in …
Diffusion noise is a major source of spectral line broadening in liquid state nano-scale nuclear magnetic resonance with shallow nitrogen-vacancy centres, whose main consequence is a limited spectral resolution. This limitation arises by virtue of the widely accepted assumption that nuclear spin signal correlations decay exponentially in nano-NMR. However, a more accurate analysis of diffusion shows that correlations survive for a longer time due to a power-law scaling, yielding the possibility for improved resolution and altering our understanding of diffusion at the nano-scale. Nevertheless,…
Quantum correlations are investigated theoretically in a two-spin system with the dipole-dipole interactions in the NMR multiple-pulse spin-locking experiments. We consider two schemes of the multiple-pulse spin-locking. The first scheme consists of $π/2$-pulses only and the delays between the pulses can differ. The second scheme contains $φ$-pulses ($0<φ<π$) and has equal delays between them. We calculate entanglement for both schemes for an initial separable state. We show that entanglement is absent for the first scheme at equal delays between $π/2$-pulses at arbitraty temperatures. Entangl…
Memoryless time evolutions are ubiquitous in nature but often correspond to a resolution-induced approximation, i.e. there are correlations in time whose effects are undetectable. Recent advances in the dynamical control of small quantum systems provide the ideal scenario to probe some of these effects. Here we experimentally demonstrate the precise induction of memory effects on the evolution of a quantum coin (qubit) by correlations engineered in its environment. In particular, we design a collisional model in Nuclear Magnetic Resonance (NMR) and precisely control the strength of the effects…
The non-local nature of the correlations possessed by quantum systems may be revealed by experimental demonstrations of the violation of Bell-type inequalities. Recent work has placed bounds on the correlations that quantum systems can possess in an actual experiment. These bounds were limited to a composite quantum system comprising of a few lower-dimensional subsystems. In a more general approach, it has been shown that fewer body correlations can reveal the non-local nature of the correlations arising from a quantum mechanical description of nature. Such tests on the correlations can be tra…
Out-of-time-order correlator (OTOC), been suggested as a measure of quantum information scrambling in quantum many-body systems, has received enormous attention recently. The experimental measurement of OTOC is quite challenging. The existing theoretical protocols consist in implementing time-reversal operations or using ancillary quantum systems, therefore only a few experiments have been reported. Recently, a new protocol to detect OTOC using statistical correlations between randomized measurements was put forward. In this work, we detect the OTOCs of a kicked-Ising model using this new meas…
The free-induction decay (FID) of the transverse magnetization in a dipolar-coupled rigid lattice is a fundamental problem in magnetic resonance and in the theory of many-body systems. As it was shown earlier the FID shapes for the systems of classical magnetic moments and for quantum nuclear spins ones coincide if there are many quite equivalent nearest neighbors V in a solid lattice. In this paper, we reduce a multispin density matrix of above system to a two-spin matrix. Then we obtain analytic expressions for the mutual information and the quantum and classical parts of correlations at the…
The effect of Gaussian fluctuations of nanopores filled with a gas of spin-carrying molecules ($s=1/2$) on the multiple quantum (MQ) NMR dynamics is investigated at different variances and correlation times of the fluctuations. We show that the fluctuations smooth out the evolution of MQ NMR coherence intensities which rapidly oscillate as functions of time in the absence of fluctuations. The growth and decay of the MQ coherence clusters in the fluctuating nanopore are also investigated.
Quantum correlations in multiple quantum (MQ) NMR experiments are investigated in two-spin systems (dimers). In the initial moment of time one spin is in a pure quantum polarized state and the other spin is in the thermodynamic equilibrium state defined by the temperature of the sample. MQ NMR dynamics of dimers is investigated. It is shown that MQ NMR coherences of only the zeroth and second orders emerge in such a system. The intensities of those coherences are calculated. Entangled states appear in the course of the system evolution in the MQ NMR experiment. The quantum discord is obtained …
Quantum error correcting codes enable the information contained in a quantum state to be protected from decoherence due to external perturbations. Applied to NMR, quantum coding does not alter normal relaxation, but rather converts the state of a ``data'' spin into multiple quantum coherences involving additional ancilla spins. These multiple quantum coherences relax at differing rates, thus permitting the original state of the data to be approximately reconstructed by mixing them together in an appropriate fashion. This paper describes the operation of a simple, three-bit quantum code in the …
In this work we experimentally study the efficiency of various dynamical decoupling sequences for suppressing decoherence of single as well as multiple quantum coherences on large spin-clusters. The system involves crystallites of a powdered sample containing a large number of molecular protons interacting via long-range dipole-dipole interaction. The multiple quantum coherences are prepared by progressively creating correlations in the spin lattice using standard pulse sequences implementing two-quantum average Hamiltonian. The spin system is then subjected to various dynamical decoupling seq…
We investigate evolution of quantum correlations in ensembles of two-qubit nuclear spin systems via nuclear magnetic resonance techniques. We use discord as a measure of quantum correlations and the Werner state as an explicit example. We first introduce different ways of measuring discord and geometric discord in two-qubit systems and then describe the following experimental studies: (a) We quantitatively measure discord for Werner-like states prepared using an entangling pulse sequence. An initial thermal state with zero discord is gradually and periodically transformed into a mixed state wi…
We experimentally emulate interaction induced blockade and local spin freezing in two and three qubit Nuclear Magnetic Resonance (NMR) architecture. These phenomena are identical to the Rydberg blockade and Rydberg biased freezing. In Rydberg blockade, the simultaneous excitation of two or more atoms is blocked due to the level shift induced by the strong Van der Waal's interaction. In such a strong interaction regime, one can also observe Rydberg biased freezing, wherein the dynamics is confined to a subspace, with the help of multiple drives with unequal amplitudes. Here we drive NMR qubits …
Quantum error correcting codes have been shown to have the ability of making quantum information resilient against noise. Here we show that we can use quantum error correcting codes as diagnostics to characterise noise. The experiment is based on a three-bit quantum error correcting code carried out on a three-qubit nuclear magnetic resonance (NMR) quantum information processor. Utilizing both engineered and natural noise, the degree of correlations present in the noise affecting a two-qubit subsystem was determined. We measured a correlation factor of c=0.5+/-0.2 using the error correction pr…
Theoretical explorations have revealed that quantum batteries can exploit quantum correlation to achieve faster charging, thus promising exciting applications in future technologies. Using NMR architecture, here we experimentally investigate various aspects of quantum battery with the help of nuclear spin systems in star-topology configuration. We first carry out numerical analysis to study how charging a quantum battery depends on the relative purity factors of charger and battery spins. By experimentally measuring the polarization of the battery spin undergoing charging, we estimate the batt…
Reported in this paper is the impact of the fluctuations of the geometry of the nano-meter gas containers in the medium on the NMR line shape of the gas inside of the nano-containers. We calculate exactly the NMR line shape of the gas of spin-1/2 carrying molecules for two typical dynamics of the nano-container volume and the orientation with respect to the external magnetic field: (i) for a Gaussian stochastic dynamics, and (ii) for the regular harmonic vibrations. For the Gaussian ensemble of static disordered containers having an infinite correlation time, $τ_{\sf c} \to \infty $, the overa…
Quantum unitary evolution typically leads to thermalization of generic interacting many-body systems. There are very few known general methods for reversing this process, and we focus on the magic echo, a radio-frequency pulse sequence known to approximately "rewind" the time evolution of dipolar coupled homonuclear spin systems in a large magnetic field. By combining analytic, numerical, and experimental results we systematically investigate factors leading to the degradation of magic echoes, as observed in reduced revival of mean transverse magnetization. Going beyond the conventional analys…
Nuclear Magnetic Resonance (NMR) forms a natural test-bed to perform quantum information processing (QIP) and has so far proven to be one of the most successful quantum information processors. The nuclear spins in a molecule treated as quantum bits or qubits which are the basic building blocks of a quantum computer. The development of NMR over half a century puts it in a platform where we can utilize its excellent control techniques over an ensemble of spin systems and perform quantum computation in a highly controlled way. Apart from a successful quantum information processor, NMR is also a h…
Nuclear magnetic resonance spectroscopy is one of the few remaining areas of physical chemistry for which polynomially scaling simulation methods have not so far been available. Here, we report such a method and illustrate its performance by simulating common 2D and 3D liquid state NMR experiments (including accurate description of spin relaxation processes) on isotopically enriched human ubiquitin - a protein containing over a thousand nuclear spins forming an irregular polycyclic three-dimensional coupling lattice. The algorithm uses careful tailoring of the density operator space to only in…
