We demonstrate that decoherence of many-spin systems can drastically differ from decoherence of single-spin systems. The difference originates at the most basic level, being determined by parity of the central system, i.e. by whether the system comprises even or odd number of spin-1/2 entities. Therefore, it is very likely that similar distinction between the central spin systems of even and odd parity is important in many other situations. Our consideration clarifies the physical origin of the unusual two-step decoherence found previously in the two-spin systems.
The transmon superconducting qubit is being intensely investigated as a promising approach for the physical implementation of quantum information processing, and high quality factors of order $10^6$ have been achieved both in two- and three-dimensional architectures. These high quality factors enable detailed investigations of decoherence mechanisms. An intrinsic decoherence process originates from the coupling between the qubit degree of freedom and the quasiparticles that tunnel across Josephson junctions. In a transmon, tunneling of a single quasiparticle is associated with a change in pari…
We show how it is possible to suppress decoherence using tailored external forcing acting as pulses. In the limit of infinitely frequent pulses decoherence and dissipation are completely frozen; however, a significant decoherence suppression is already obtained when the frequency of the pulses is of the order of the reservoir typical frequency scale. This method could be useful in particular to suppress the decoherence of the center-of-mass motion in ion traps.
A parity measurement on two qubits, each consisting of a single atom in a cavity, can be realized by measuring the phase shift of a probe beam, which interacts sequentially with the two qubits, but imperfections lead to decoherence within the subspaces of a given parity. We demonstrate that a different setup, where the probe light interacts repeatedly with the qubits, can reduce the rate of decoherence within the odd or the even parity subspace significantly. We consider both the case of a resonant and the case of a nonresonant light-atom interaction and find that the performance is comparable…
We study the entanglement between the 2D vibrational motion and two ground state hyperfine levels of a trapped ion, Under particular conditions this entanglement depends on the parity of the total initial vibrational quanta. We study the robustness of this quantum coherence effect with respect to the presence of non-dissipative sources of decoherence, and of an imperfect initial state preparation.
Notwithstanding radical conceptual differences between classical and quantum mechanics, it is usually assumed that physical measurements concern observables common to both theories . Not so with the eigenvalues ($\pm 1$) of the parity operator. The effect of such a measurement on a mixture of even and odd states of the harmonic oscillator is akin to separating at a single stroke a pair of shuffled card decks: the result is a set of definite parity, though otherwise mixed. The Wigner function should be a sensitive probe for this phenomenon, for it can be interpreted as the expectation value of …
We present a scheme able to protect the quantum states of a cavity mode against the decohering effects of photon loss. The scheme preserves quantum states with a definite parity, and improves previous proposals for decoherence control in cavities. It is implemented by sending single atoms, one by one, through the cavity. The atomic state gets first correlated to the photon number parity. The wrong parity results in an atom in the upper state. The atom in this state is then used to inject a photon in the mode via adiabatic transfer, correcting the field parity. By solving numerically the exact …
Quasiparticle excitations adversely affect the performance of superconducting devices in a wide range of applications. They limit the sensitivity of photon detectors in astronomy, the accuracy of current sources in metrology, the cooling power of micro-refrigerators, and could break the topological protection of Majorana qubits. In superconducting circuits for quantum information processing, tunneling of quasiparticles across Josephson junctions constitutes a decoherence mechanism. As relaxation and pure dephasing times of transmon-type charge qubits now reach 100 microseconds, understanding w…
The decoherence of two initially entangled qubits in anisotropic band gap photonic crystal has been studied analytically without Born or Markovian approximation. It is shown that the decoherence dynamics of two qubits in photonic crystal is greatly different from that of two qubits in vacuum or subjected to usual non-Markovian reservoir. The results also show that the finite time decoherence invoked by spontaneous emission could be suppressed efficiently and the entanglement of the Bell state possesses odd parity is more easily preserved in photonic crystal than that of the Bell state possesse…
We study the application of decoupling techniques to the case of a damped vibrational mode of a chain of trapped ions, which can be used as a quantum bus in linear ion trap quantum computers. We show that vibrational heating could be efficiently suppressed using appropriate ``parity kicks''. We also show that vibrational decoherence can be suppressed by this decoupling procedure, even though this is generally more difficult because the rate at which the parity kicks have to applied increases with the effective bath temperature.
We theoretically study the decoherence and the dynamical decoupling control of nitrogen-vacancy center electron spins in high-purity diamond, where the hyperfine interaction with $^{13}$C nuclear spins is the dominating decoherence mechanism. The decoherence is formulated as the entanglement between the electron spin and the nuclear spins, which is induced by nuclear spin bath evolution conditioned on the electron spin state. The nuclear spin bath evolution is driven by elementary processes such as single spin precession and pairwise flip-flops. The importance of different elementary processes…
We theoretically investigate spin decoherence of a single nitrogen-vacancy (NV) center in diamond. Using the spin coherent state P-representation method, coherence evolution of the NV center surrounded by nitrogen electron spins (N) is simulated. We find that spin decoherence time as well as free-induction decay of the NV center depend on the spatial configuration of N spins. Both the spin decoherence rate (1/T2) and dephasing rate (1/T2*) of the NV center increase linearly with the concentration of the N spins. Using the P-representation method, we also demonstrate extracting noise spectrum o…
Dressed spin states, a spin coupling to continuous radiation fields, can fundamentally change how a spin responds to magnetic fluctuations. Using dressed spin states, we were able to protect an electron spin in diamond from decoherence. Dressing a spin with resonant microwaves at a coupling rate near 1 MHz leads to a 50 times reduction in the linewidth of the spin transition, limited by transit-time broadening. The spin decoherence and the energy level structure of the dressed states were probed with optical coherent-population-trapping processes. Compared with dynamical decoupling, where effe…
The decoherence of mixed electron-nuclear spin qubits is a topic of great current importance, but understanding is still lacking: while important decoherence mechanisms for spin qubits arise from quantum spin bath environments with slow decay of correlations, the only analytical framework for explaining observed sharp variations of decoherence times with magnetic field is based on the suppression of classical noise. Here we obtain a general expression for decoherence times of the central spin system which exposes significant differences between quantum-bath decoherence and decoherence by class…
We study the decoherence of a central spin-1/2 due to a closed environment composed of spin-1/2 particles. It is known that a frustrated spin environment, such as a spin glass, is much more efficient for decoherence of the central spin than a similar size environment without frustration. We construct a Hamiltonian where the degree of frustration is parametrized by a single parameter $κ$. By use of this model we find that the environment can be classified by two distinct regimes with respect to the strength of level repulsion. These regimes behave qualitatively different with respect to decoher…
We discuss the operational definition of decoherence in various solid state systems. In particular, we review, in the context of spin-based solid state quantum computation, the introduction of $T_1$ and $T_2$ to describe decoherence in a two level system. We provide a perspective on recent experiments involving the manipulation of spin coherence in semiconductors, and discuss specific decoherence and dephasing issues in electron spin-based quantum dot quantum computer architectures.
We introduce an exactly solvable model to study decoherence of a central spin interacting with a spin bath where the coupling is mediated by phonons which we assume to be in a coherent state or thermal distribution. For the coherent state case, we find that the decoherence factor decays in a Gaussian fashion and it becomes independent of the phonon frequencies at short times. If the phonon energies are much larger than spin-phonon coupling or bath spins are fully polarized, decoherence time becomes independent of the initial phonon state. For the thermal state case, phonons play more important…
The decoherence of two initially entangled qubits in a squeezed vacuum cavity has been investigated exactly. The results show that, first, in principle, the disentanglement time decreases with the increasing of squeeze parameter r, due to the augmenting of average photon number of every mode in squeezed vacuum cavity. Second, there are entanglement revivals after complete disentanglement for the case of even parity initial Bell state, while there are entanglement decrease and revival before complete disentanglement for the case of odd parity initial Bell state. The results are quite different …
We investigate hyperfine-induced decoherence in a triangular spin-cluster for different qubit encodings. Electrically controllable eigenstates of spin chirality (C_z) show decoherence times that approach milliseconds, two orders of magnitude longer than those estimated for the eigenstates of the total spin projection (S_z) and of the partial spin sum (S_{12}). The robustness of chirality is due to its decoupling from both the total- and individual-spin components in the cluster. This results in a suppression of the effective interaction between C_z and the nuclear spin bath.
We study Si:P donor electron spin decoherence due to anisotropic hyperfine (AHF) interaction with the surrounding nuclear spin bath. In particular, we clarify the electron spin echo envelope modulation (ESEEM) in the Si:P system and the resonancelike contributions from nuclear spins in various shells away from the P atoms. We suggest an approach to minimize AHF-induced decoherence by avoiding the resonances and orienting an applied magnetic field along directions that can periodically eliminate contributions from the dominant nearest neighbor atoms. Our remarkable agreement with experiment dem…
Silicon is promising for spin-based quantum computation because nuclear spins, a source of magnetic noise, may be eliminated through isotopic enrichment. Long spin decoherence times, $T_2$, have been measured in isotope-enriched silicon but come far short of the $T_2 = 2 T_1$ limit. The effect of nuclear spins on $T_2$ is well established. However, the effect of background electron spins from ever present residual phosphorus impurities in silicon can also produce significant decoherence. We study spin decoherence decay as a function of donor concentration, $^{29}$Si concentration, and temperat…
We consider the decoherence of a single localized electron spin due to its coupling to the lattice nuclear spin bath in a semiconductor quantum computer architecture. In the presence of an external magnetic field and at low temperatures, the dominant decoherence mechanism is the spectral diffusion of the electron spin resonance frequency due to the temporally fluctuating random magnetic field associated with the dipolar interaction induced flip-flops of nuclear spin pairs. The electron spin dephasing due to this random magnetic field depends intricately on the quantum dynamics of the nuclear s…
Many-body correlations can yield key insights into the nature of interacting systems; however, detecting them is often very challenging in many-particle physics, especially in nanoscale systems. Here, taking a phosphorus donor electron spin in a natural-abundance 29Si nuclear spin bath as our model system, we discover both theoretically and experimentally that many-body correlations in nanoscale nuclear spin baths produce identifiable signatures in the decoherence of the central spin under multiple-pulse dynamical decoupling control. We find that when the number of decoupling -pulses is odd, c…
We uncover two microscopic physical settings with significant pure spin decoherence. First, for quantum dots (QD) electrostatically confined in two-dimensional hole gas, decoherence comes from qubit spin-orbit (SO) coupling to phonons, whose decay due to free charge carriers in contacts is described by Ohmic weighted phonon spectral function. We derive significant SO interactions affecting holes with origin and symmetry distinct from that of conventionally considered Dresselhaus and Rashba terms. In the second setting of electron or hole QDs coupled to a linear chain of atoms, decoherence is d…
We theoretically study the nuclear spin induced decoherence of a quantum dot in Si that is confined at a SiGe interface. We calculate decoherence time dependence on $^{73}$Ge in the barrier layer to evaluate the importance of Ge as well as Si enrichment for long decoherence times. We use atomistic tight-binding modeling for an accurate account of the electron wavefunction which is particularly important for determining the contact hyperfine interactions with the Ge nuclear spins. We find decoherence times due to Ge spins at natural concentrations to be milliseconds. This suggests SiGe/Si quant…
The dynamics of a spin-1/2 particle coupled to a nuclear spin bath through an isotropic Heisenberg interaction is studied, as a model for the spin decoherence in quantum dots. The time-dependent polarization of the central spin is calculated as a function of the bath-spin distribution and the polarizations of the initial bath state. For short times, the polarization of the central spin shows a gaussian decay, and at later times it revives displaying nonmonotonic time dependence. The decoherence time scale dep ends on moments of the bath-spin distribuition, and also on the polarization strength…
A quantum cluster expansion method is developed for the problem of localized electron spin decoherence due to dipolar fluctuations of lattice nuclear spins. At the lowest order it provides a microscopic explanation for the Lorentzian diffusion of Hahn echoes without resorting to any phenomenological Markovian assumption. Our numerical results show remarkable agreement with recent electron spin echo experiments in phosphorus doped silicon.
We report on room-temperature coherent manipulation of the spin of a single nitrogen-vacancy center in diamond and a study of its coherence as a function of magnetic field. We use magnetic resonance to induce Rabi nutations, and apply a Hahn spin echo to remove the effect of low-frequency dephasing. A sharp rise in the decoherence rate is observed at magnetic fields where the nitrogen-vacancy center spin couples resonantly to substitutional nitrogen spins via the magnetic dipolar coupling. Finally, we find evidence that away from these energy resonances spin flips of nitrogen electrons are the…
We describe a model for the interaction of the internal (spin) degree of freedom of a quantum lattice-gas particle with an environmental bath. We impose the constraints that the particle-bath interaction be fixed, while the state of the bath is random, and that the effect of the particle-bath interaction be parity invariant. The condition of parity invariance defines a subgroup of the unitary group of actions on the spin degree of freedom and the bath. We derive a general constraint on the Lie algebra of the unitary group which defines this subgroup, and hence guarantees parity invariance of t…
Coherent single electron spin oscillation in a double quantum dot system driven by a magnetic electron spin resonance field is studied theoretically using a Bloch-type rate equation approach. The oscillation frequency and relaxation time obtained using typical model parameters are consistent with experiment findings. The dominant decoherence mechanism is identified to be a leakage current through a Coulomb blockade barrier at a quantum dot during the spin manipulation. Nuclear field fluctuations which induce a long relaxation time are found to contribute only negligibly to the decoherence desp…
The dynamics of a spin in the presence of a deterministic and a fluctuating magnetic field is solved for analytically to obtain the averaged value of the spin as a function of time for various kinds of fluctuations (noise). Specifically, analytic results are obtained for the time dependence of the expectation value of the spin, averaged over fluctuations, for Gaussian white noise and Guassian colored noise, as well as non-Gaussian telegraph noise. Fluctuations cause the decay of the average spin vector (decoherence). For noise with finite temporal correlation time, a deterministic component of…
We study a pair of capacitively coupled singlet-triplet spin qubits. We characterize the two-qubit decoherence through two complementary measures, the decay time of coupled-qubit oscillations and the fidelity of entangled state preparation. We provide a quantitative map of their dependence on charge noise and field noise, and we highlight the magnetic field gradient across each singlet-triplet qubit as an effective tool to suppress decoherence due to charge noise.
We propose a method based on optically detected magnetic resonance (ODMR) to measure the decoherence time $T_{2}$ of a single electron spin in a semiconductor quantum dot. The electron spin resonance (ESR) of a single excess electron on a quantum dot is probed by circularly polarized laser excitation. Due to Pauli blocking, optical excitation is only possible for one of the electron-spin states. The photoluminescence is modulated due to the ESR which enables the measurement of electron spin decoherence. We study different possible schemes for such an ODMR setup.
Decoherence of electron spins in nanoscale systems is important to quantum technologies such as quantum information processing and magnetometry. It is also an ideal model problem for studying the crossover between quantum and classical phenomena. At low temperatures or in light-element materials where the spin-orbit coupling is weak, the phonon scattering in nanostructures is less important and the fluctuations of nuclear spins become the dominant decoherence mechanism for electron spins. Since 1950s, semiclassical noise theories have been developed for understanding electron spin decoherence.…
We experimentally demonstrate that the decoherence of a spin by a spin bath can be completely eliminated by fully polarizing the spin bath. We use electron paramagnetic resonance at 240 gigahertz and 8 Tesla to study the spin coherence time $T_2$ of nitrogen-vacancy centers and nitrogen impurities in diamond from room temperature down to 1.3 K. A sharp increase of $T_2$ is observed below the Zeeman energy (11.5 K). The data are well described by a suppression of the flip-flop induced spin bath fluctuations due to thermal spin polarization. $T_2$ saturates at $\sim 250 μs$ below 2 K, where the …
Recently it has been proposed to use parity as a measure of the mechanism behind decoherence or the transformation from quantum to classical. Here, we show that the proposed experiment is more feasible than previously thought, as even an initial thermal state would exhibit the hypothesized symmetry breaking.
The clock transitions (CTs) of central spins have long coherence times because their frequency fluctuations vanish in the linear order of external field noise (such as Overhauser fields from nuclear spin baths). Therefore, CTs are useful for quantum technologies. Also, the quadratic dependence of frequencies on noises makes the CT decoherence an interesting physics problem. Thus we are motivated to study the decoherence of CTs. We consider noise from spin baths, which is one of the most relevant mechanisms of qubit decoherence. Various quantum many-body methods have been developed to study the…
Interaction of solid state qubits with environmental degrees of freedom strongly affects the qubit dynamics, and leads to decoherence. In quantum information processing with solid state qubits, decoherence significantly limits the performances of such devices. Therefore, it is necessary to fully understand the mechanisms that lead to decoherence. In this review we discuss how decoherence affects two of the most successful realizations of solid state qubits, namely, spin-qubits and superconducting qubits. In the former, the qubit is encoded in the spin 1/2 of the electron, and it is implemented…
Control of electron spin decoherence in contact with a mesoscopic bath of many interacting nuclear spins in an InAs quantum dot is studied by solving the coupled quantum dynamics. The nuclear spin bath, because of its bifurcated evolution predicated on the electron spin up or down state, measures the which-state information of the electron spin and hence diminishes its coherence. The many-body dynamics of nuclear spin bath is solved with a pair-correlation approximation. In the relevant timescale, nuclear pair-wise flip-flops, as elementary excitations in the mesoscopic bath, can be mapped int…
We demonstrate that an optically driven spin of a carrier in a quantum dot undergoes indirect dephasing via conditional optically induced charge evolution even in the absence of any direct interaction between the spin and its environment. A generic model for the indirect dephasing with a three-component system with spin, charge, and reservoir is proposed. This indirect decoherence channel is studied for the optical spin manipulation in a quantum dot with a microscopic description of the charge-phonon interaction taking into account its non-Markovian nature.
The nuclear spin of a phosphorus atom in silicon has been used as a quantum bit in various quantum-information experiments. It has been proposed that this nuclear-spin qubit can be efficiently controlled by an ac electric field, when embedded in a two electron dot-donor setup subject to intrinsic or artificial spin-orbit interaction. Exposing the qubit to control electric fields in that setup exposes it to electric noise as well. In this work, we describe the effect of electric noise mechanisms, such as phonons and $1/f$ charge noise, and estimate the corresponding decoherence time scales of t…
Decoherence of a center spin or qubit in a spin bath is essentially determined by the many-body bath evolution. We develop a cluster-correlation expansion (CCE) theory for the spin bath dynamics relevant to the qubit decoherence problem. A cluster correlation term is recursively defined as the evolution of a group of bath spins divided by the cluster correlations of all the subgroups. The so-defined correlation accounts for the authentic collective excitations within a given group. The bath propagator is the product of all possible cluster correlation terms. For a finite-time evolution as in t…
The time evolution of spin states of two electrons interacting with a nuclear spin bath in a quantum dot system is studied. The hyperfine interaction between the electrons and the nuclear spins is modeled by an isotropic Heisenberg interaction, and the interaction between the electron spins by Heisenberg exchange. Depending on the extent of the overlap between the spatial wave functions of the electrons, there are two physically different cases, namely the two qubits either interact with the same set of nuclear spins or they see different nuclear spin environment. In the two cases, the decoher…
We theoretically investigate the spin dynamics of a heavy hole confined to an unstrained III-V semiconductor quantum dot and interacting with a narrowed nuclear-spin bath. We show that band hybridization leads to an exponential decay of hole-spin superpositions due to hyperfine-mediated nuclear pair flips, and that the accordant single-hole-spin decoherence time T2 can be tuned over many orders of magnitude by changing external parameters. In particular, we show that, under experimentally accessible conditions, it is possible to suppress hyperfine-mediated nuclear-pair-flip processes so strong…
In this paper, we study the electron spin decoherence of single defects in silicon carbide (SiC) nuclear spin bath. We find that, although the natural abundance of $^{29}\rm{Si}$ ($p_{\rm{Si}}=4.7\%$) is about 4 times larger than that of $^{13}{\rm C}$ ($p_{\rm{C}}=1.1\%$), the electron spin coherence time of defect centers in SiC nuclear spin bath in strong magnetic field ($B>300~\rm{Gauss}$) is longer than that of nitrogen-vacancy (NV) centers in $^{13}{\rm C}$ nuclear spin bath in diamond. The reason for this counter-intuitive result is the suppression of heteronuclear-spin flip-flop proces…
An entangled state prepared in the decoherence free sub-space together with a Ramsey type measurement can probe parity violation in heavy alkali ions like Ba+ or Ra+. Here we propose an experiment with Ba+ ions as an example to measure the small parity violating effect in this system.
In this report, we examine the decoherence of a spin qubits system coupled to counted spin chain with a $1/r^2$ interaction by using influence functional. We also examine the time evolution of density matrix numerically when environment is Gaussian noise.
We study the decoherence of two coupled spins that interact with a spin-bath environment. It is shown that the connectivity and the coupling strength between the spins in the environment are of crucial importance for the decoherence of the central system. Changing the connectivity or coupling strenghts changes the decoherence of the central system from Gaussian to exponential decay law.
We study the decoherence of two coupled spins that interact with a spin-bath environment. It is shown that the connectivity and the coupling strength between the spins in the environment are of crucial importance for the decoherence of the central system. For the anisotropic spin-bath, changing the connectivity or coupling strenghts changes the decoherence of the central system from Gaussian to exponential decay law. The initial state of the environment is shown to affect the decoherence process in a qualitatively significant manner.
Experiments involving phase coherent dynamics of networks of spins, such as echo experiments, will only work if decoherence can be suppressed. We show here, by analyzing the particular example of a crystalline network of Fe8 molecules, that most decoherence typically comes from pairwise interactions (particularly dipolar interactions) between the spins, which cause `correlated errors'. However at very low T these are strongly suppressed. These results have important implications for the design of quantum information processing systems using electronic spins.
A low temperature model system consisting of a central spin coupled to a spin-bath is studied to determine whether interaction among bath spins has an effect on central spin dynamics. In the absence of intra-environmental coupling, decoherence of the central spin is fast and irreversible. Strong intra-environmental interaction results in an effective decoupling of the central spin from the bath and suppression of decoherence. Weaker intra-environmental coupling reduces but does not eliminate decoherence. We believe that similar behaviour will be observed in any system with a self-interacting e…
For an electron spin in coupling with an interacting spin chain via hyperfine-type interaction, we investigate the dynamical evolutions of the pairwise entanglement of the spin chain and a correlation function joined the electron spin with a pair of chain spins in correspondence to the electron spin coherence evolution. Both quantities manifest a periodic and a decaying evolution. The entanglement of the spin bath is significant in distinguishing the zero-coherence status exhibited in periodic and decoherence evolutions of the electron spin. The periodical concurrence evolution of the spin bat…
An initial local excitation in a confined quantum system evolves exploring the whole system, returning to the initial position as a mesoscopic echo at the Heisenberg time. We consider a two weakly coupled spin chains, a spin ladder, where one is a quantum channel while the other represents an environment. We quantify decoherence in the quantum channel through the attenuation of the mesoscopic echoes. We evaluate decoherence rates for different ratios between sources of amplitude fluctuation and dephasing in the inter-chain interaction Hamiltonian. The many-body dynamics is seen as a one-body e…
The works on decoherence due to spin baths usually agree in studying a one-spin system in interaction with a large spin bath. In this paper we generalize those models by analyzing a many-spin system and by studying decoherence or its suppression in function of the relation between the numbers of spins of the system and the bath. This model may help to identify clusters of particles unaffected by decoherence, which, as a consequence, can be used to store quantum information.
We compare disentanglement and decoherence rates within two-spin and three-spin entangled systems subjected to all possible combinations of local and collective pure dephasing noise combinations. In all cases, the bipartite entanglement decay rate is found to be greater than or equal to the dephasing-decoherence rates and often significantly greater. This sharpens previous results for two-spin systems [T. Yu and J. H. Eberly Phys. Rev. B 68, 165322 (2003)] and extends them to the three-spin context.
An open ended spin chain can serves as a quantum data bus for the coherent transfer of quantum state information. In this paper, we investigate the efficiency of such quantum spin channels which work in a decoherence environment. Our results show that, the decoherence will significantly reduce the fidelity of quantum communication through the spin channels. Generally speaking, as the distance increases, the decoherence effects become more serious, which will put some constraints on the spin chains for long distance quantum state transfer.
By analytically solving the master equation, we investigate quantum state transfer, creation and distribution of entanglement in the model of Milburn's intrinsic decoherence. Our results reveal that the ideal spin channels will be destroyed by the intrinsic decoherence environment, and the detrimental effects become severe as the decoherence rate $γ$ and the spin chain length $N$ increase. For infinite evolution time, both the state transfer fidelity and the concurrence of the created and distributed entanglement approach steady state values, which are independent of the decoherence rate $γ$ a…
We demonstrate that the spin decoherence of nitrogen vacancy (NV) centers in diamond can be suppressed by a transverse magnetic field if the electron spin bath is the primary decoherence source. The NV spin coherence, created in "a decoherence-free subspace" is protected by the transverse component of the zero-field splitting, increasing the spin-coherence time about twofold. The decoherence due to the electron spin bath is also suppressed at magnetic fields stronger than ~25 gauss when applied parallel to the NV symmetry axis. Our method can be used to extend the spin-coherence time of simila…