We study the adiabatic limit in the density matrix approach for a quantum system coupled to a weakly dissipative medium. The energy spectrum of the quantum model is supposed to be non-degenerate. In the absence of dissipation, the geometric phases for periodic Hamiltonians obtained previously by M.V. Berry are recovered in the present approach. We determine the necessary condition satisfied by the coefficients of the linear expansion of the non-unitary part of the Liouvillian in order to the imaginary phases acquired by the elements of the density matrix, due to dissipative effects, be geometric. The results derived are model-independent. We apply them to spin 1/2 model coupled to reservoir at thermodynamic equilibrium.
We introduce an adiabatic perturbation theory for quantum systems with degenerate energy spectra. This perturbative series enables one to rigorously establish conditions for the validity of the adiabatic theorem of quantum mechanics for degenerate systems. The same formalism can be used to find non-adiabatic corrections to the non-Abelian Wilczek-Zee geometric phase. These corrections are relevant to assess the validity of the practical implementation of the concept of fractional exchange statistics. We illustrate the formalism by exactly solving a time-dependent problem and comparing its solu…
We examine the conditions needed to accomplish stimulated Raman adiabatic passage (STIRAP) when the three levels (g, e and f) are degenerate, with arbitrary couplings contributing to the pump-pulse interaction (g - e) and to the Stokes-pulse interaction (e-f). We show that in general a sufficient condition for complete population removal from the g set of degenerate states for arbitrary, pure or mixed, initial state is that the degeneracies should not decrease along the sequence g, e and f. We show that when this condition holds it is possible to achieve the degenerate counterpart of conventio…
We present details and expand on the framework leading to the recently introduced degenerate adiabatic perturbation theory [Phys. Rev. Lett. 104, 170406 (2010)], and on the formulation of the degenerate adiabatic theorem, along with its necessary and sufficient conditions given in [Phys. Rev. A 85, 062111 (2012)]. We start with the adiabatic approximation for degenerate Hamiltonians that paves the way to a clear and rigorous statement of the associated degenerate adiabatic theorem, where the non-abelian geometric phase (Wilczek-Zee phase) plays a central role to its quantitative formulation. W…
A classical-kind phase-space formalism is developed to address the tiny intrinsic dynamical deviation from what is predicted by Wilczek-Zee theorem during quantum adiabatic evolution on degeneracy levels. In this formalism, the Hilbert space and the aggregate of degenerate eigenstates become the classical-kind phase-space and a high-dimensional subspace in the phase-space, respectively. Compared with the previous same study by a different method, the current result is qualitatively different in that the first-order deviation derived here is always perpendicular to the degeneracy subspace. A tr…
In the system of several interacting spins, geometric phases have been researched intensively.However, the studies are mainly focused on the adiabatic case (Berry phase), so it is necessary for us to study the non-adiabatic counterpart (Aharonov and Anandan phase). In this paper, we analyze both the non-degenerate and degenerate geometric phase of Lipkin-Meskov-Glick type model, which has many application in Bose-Einstein condensates and entanglement theory. Furthermore, in order to calculate degenerate geometric phases, the Floquet theorem and decomposition of operator are generalized. And th…
We theoretically examine a zero-temperature system of Fermi degenerate atoms coupled to bosonic molecules via collisionless rapid adiabatic passage across a Feshbach resonance, focusing on saturation of the molecular conversion efficiency at the slowest magnetic-field sweep rates. Borrowing a novel MANY-FERMION Fock-state theory, we find that a proper model of the magnetic-field sweep can systematically remove saturation. We also debunk the common misconception that many-body effects are responsible for molecules existing above the two-body threshold.
We present an efficient quantum algorithm for some independent set problems in graph theory, based on non-abelian adiabatic mixing. We illustrate the performance of our algorithm with analysis and numerical calculations for two different types of graphs, with the number of edges proportional to the number of vertices or its square. The theoretical advantages of our quantum algorithm over classical algorithms are discussed. Non-abelian adiabatic mixing can be a general technique to aid exploration in a landscape of near-degenerate ground states.
By stating the adiabatic theorem of quantum mechanics in a clear and rigorous way, we establish a necessary condition and a sufficient condition for its validity, where the latter is obtained employing our recently developed adiabatic perturbation theory. Also, we simplify further the sufficient condition into a useful and simple practical test at the expenses of its mathematical rigor. We present results for the most general case of quantum systems, i.e., those with degenerate energy spectra. These conditions are of upmost importance to assess the validity of practical implementations of non-…
Universidade Federal de São Carlos（圣卡洛斯联邦大学）；Institute for Quantum Optics and Quantum Information, Austrian Academy of Sciences（奥地利科学院量子光学与量子信息研究所）；Stockholm University（斯德哥尔摩大学）；California Institute of Technology（加州理工学院）；Université Côte d’Azur（蔚蓝海岸大学）；CNRS, Institut de Physique de Nice（法国国家科学研究中心尼斯物理研究所）
We propose a scheme to dissipatively produce steady-state entanglement in a two-qubit system, via an interaction with a bosonic mode. The system is driven into a stationary entangled state, while we compensate the mode dissipation by injecting energy via a coherent pump field. We also present a scheme which allows us to adiabatically transfer all the population to the desired entangled state. The dynamics leading to the entangled state in these schemes can be understood in analogy with electromagnetically induced transparency (EIT) and stimulated Raman adiabatic passage (STIRAP), respectively.
The topological properties of adiabatic gauge fields for multi-level (three-level in particular) quantum systems are studied in detail. Similar to the result that the adiabatic gauge field for SU(2) systems (e.g. two-level quantum system or angular momentum systems, etc) have a monopole structure, the curvature two-forms of the adiabatic holonomies for SU(3) three-level and SU(3) eight-level quantum systems are shown to have monopole-like (for all levels) or instanton-like (for the degenerate levels) structures.
We show that the difference of adiabatic phases, that are basis-dependent, in noncyclic evolution of non-degenerate quantum systems have to be taken into account to give the correct interference result in the calculation of physical quantities in states that are a superposition of instantaneous eigenstates of energy. To verify the contribution of those adiabatic phases in the interference phenomena, we consider the spin-1/2 model coupled to a precessing external magnetic field. In the model, the adiabatic phase increases in time up to reach the difference of the Berry's phases of the model whe…
Quantum adiabatic evolution, an important fundamental concept inphysics, describes the dynamical evolution arbitrarily close to the instantaneous eigenstate of a slowly driven Hamiltonian. In most systems undergoing spontaneous symmetry-breaking transitions, their two lowest eigenstates change from non-degenerate to degenerate. Therefore, due to the corresponding energy-gap vanishes, the conventional adiabatic condition becomes invalid. Here we explore the existence of quantum adiabatic evolutions in spontaneous symmetry-breaking transitions and derive a symmetry-dependent adiabatic condition.…
The quantum adiabatic theorem incorporating the Berry phase phenomenon can be characterized as a factorization of the time evolution operator into a path-dependent geometric factor, a usual dynamical factor and a non-adiabatic factor that approaches the identity in the adiabatic limit. We study a case where all these three factors can be constructed explicitly and where the instantaneous Hamiltonian has infinitely degenerate energy eigenstates associated with magnetic translation symmetry. Significance of the non-adiabatic factor in terms of transition probabilities is discussed.
The degenerate Landau-Zener-Majorana-Stückelberg model consists of two degenerate energy levels whose energies vary with time and in the presence of an interaction which couples the states of the two levels. In the adiabatic limit, it allows for the populations transfer from states of one level to states of the other level. The presence of an interaction with the environment influences the efficiency of the process. Nevertheless, identification of possible decoherence-free subspaces permits to engineer coupling schemes for which quantum noise can be minimized.
Besides the traditional circuit-based model of quantum computation, several quantum algorithms based on a continuous-time Hamiltonian evolution have recently been introduced, including for instance continuous-time quantum walk algorithms as well as adiabatic quantum algorithms. Unfortunately, very little is known today on the behavior of these Hamiltonian algorithms in the presence of noise. Here, we perform a fully analytical study of the resistance to noise of these algorithms using perturbation theory combined with a theoretical noise model based on random matrices drawn from the Gaussian O…
We show that the adiabatic motion of ultra-cold, multi-level atoms in spatially varying laser fields can give rise to effective non-Abelian gauge fields if degenerate adiabatic eigenstates of the atom-laser interaction exist. A pair of such degenerate dark states emerges e.g. if laser fields couple three internal states of an atom to a fourth common one under pairwise two--photon-resonance conditions. For this so-called tripod scheme we derive general conditions for truly non-Abelian gauge potentials and discuss special examples. In particular we show that using orthogonal laser beams with orb…
We explore protocols for three-state adiabatic passage where the tunnel matrix elements are varied digitally, rather than smoothly as is the case with conventional adiabatic passage. In particular, we focus on the STIRAP and related three-state schemes where the control is applied stepwise, with either equal spaced levels for the tunnel matrix elements or uniform pulse lengths. Our results show that the evolution typically shows the hallmarks of conventional adiabatic passage, although with additional resonances exhibiting no state transfer.
We extend the work of Hen for the Bernstein-Vazirani problem and Simon's problem on an adiabatic quantum computer. Our results are based on the Ising objective function for quantum annealing. For each problem we determine its objective function, describe its Hamiltonian matrix, and show the Hamiltonian matrix for a small problem. Following the pattern of Hen, we discuss factoring of integers, particularly Shor's factoring algorithm in an adiabatic quantum computing environment.
We apply a flexible numerical integrator to the simulation of adiabatic quantum computation with nonlinear paths. We find that a nonlinear path may significantly improve the performance of adiabatic algorithms versus the conventional straight-line interpolations. The employed integrator is suitable for solving the time-dependent Schrödinger equation for any qubit Hamiltonian. Its flexible storage format significantly reduces cost for storage and matrix-vector multiplication in comparison to common sparse matrix schemes.
The difficulty in producing precisely timed and controlled quantum gates is a significant source of error in many physical implementations of quantum computers. Here we introduce a simple universal primitive, adiabatic gate teleportation, which is robust to timing errors and many control errors and maintains a constant energy gap throughout the computation above a degenerate ground state space. Notably this construction allows for geometric robustness based upon the control of two independent qubit interactions. Further, our piecewise adiabatic evolution easily relates to the quantum circuit m…
A five-level four-pulse phase-sensitive extended stimulated Raman adiabatic passage scheme is proposed to realize complete control of the population transfer branching ratio between two degenerate target states. The control is achieved via a three-node null eigenstate that can be correlated with an arbitrary superposition of the target states. Our results suggest that complete suppression of the yield of one of two degenerate product states, and therefore absolute selectivity in photochemistry, is achievable and predictable, even without studying the properties of the unwanted product state be…
This work derives an analytical formula for the asymptotic state---the quantum state resulting from an infinite number of applications of a general quantum channel on some initial state. For channels admitting multiple fixed or rotating points, conserved quantities---the left fixed/rotating points of the channel---determine the dependence of the asymptotic state on the initial state. The formula stems from a Noether-like theorem stating that, for any channel admitting a full-rank fixed point, conserved quantities commute with that channel's Kraus operators up to a phase. The formula is applied…
We present an analysis of the quantum adiabatic algorithm for solving hard instances of 3-SAT (an NP-complete problem) in terms of Random Matrix Theory (RMT). We determine the global regularity of the spectral fluctuations of the instantaneous Hamiltonians encountered during the interpolation between the starting Hamiltonians and the ones whose ground states encode the solutions to the computational problems of interest. At each interpolation point, we quantify the degree of regularity of the average spectral distribution via its Brody parameter, a measure that distinguishes regular (i.e., Poi…
A method is proposed for preparing any pure and a wide class of mixed quantum states in the decoherence-free ground-state subspace of a degenerate multilevel lambda system. The scheme is a combination of optical pumping and a series of coherent excitation processes, and for a given pulse sequence the same final state is obtained regardless of the initial state of the system. The method is robust with respect to the fluctuation of the pulse areas, like in adiabatic methods, however, the field amplitude can be adjusted in a larger range.
The smallness of the variation rate of the hamiltonian matrix elements compared to the (square of the) energy spectrum gap is usually believed to be the key parameter for a quantum adiabatic evolution. However it is only perturbatively valid for scaled timed hamiltonian and resonance processes as well as off resonance possible constructive Stückelberg interference effects violate this usual condition for general hamiltionian. More general adiabatic condition and exact bounds for adiabatic quantum evolution are derived and studied in the framework of a two-level system. The usual criterion is r…
Quantum adiabatic evolution is a dynamical evolution of a quantum system under slow external driving. According to the quantum adiabatic theorem, no transitions occur between non-degenerate instantaneous eigen-energy levels in such a dynamical evolution. However, this is true only when the driving rate is infinitesimally small. For a small nonzero driving rate, there are generally small transition probabilities between the energy levels. We develop a classical mechanics framework to address the small deviations from the quantum adiabatic theorem order by order. A hierarchy of Hamiltonians are …
A new simple proof of the adiabatic theorem is given in the finite dimensional case for nondegenerate as well as degenerate states. The explicitly integrable two level system is considered as an example. It is demonstrated that the error estimate given by the adiabatic theorem can not be improved.
We study the eigenlevel spectrum of quantum adiabatic algorithm for 3-satisfiability problem, focusing on single-solution instances. The properties of the ground state and the associated gap, crucial for determining the running time of the algorithm, are found to be far from the predictions of random matrix theory. The distribution of gaps between the ground and the first excited state shows an abundance of small gaps. Eigenstates from the central part of the spectrum are, on the other hand, well described by random matrix theory.
It is believed that the presence of anticrossings with exponentially small gaps between the lowest two energy levels of the system Hamiltonian, can render adiabatic quantum optimization inefficient. Here, we present a simple adiabatic quantum algorithm designed to eliminate exponentially small gaps caused by anticrossings between eigenstates that correspond with the local and global minima of the problem Hamiltonian. In each iteration of the algorithm, information is gathered about the local minima that are reached after passing the anticrossing non-adiabatically. This information is then used…
We describe a many-body quantum system which can be made to quantum compute by the adiabatic application of a large applied field to the system. Prior to the application of the field quantum information is localized on one boundary of the device, and after the application of the field this information has propagated to the other side of the device with a quantum circuit applied to the information. The applied circuit depends on the many-body Hamiltonian of the material, and the computation takes place in a degenerate ground space with symmetry-protected topological order. Such adiabatic quantu…
In this paper we introduce the use of Sylvester's formula for systems with degenerate eigenvalues in relation to obtaining their analytical solutions. To appreciate the use we include two other forms of analytical solutions namely adiabatic and Magnus approximations. In quantum mechanics, the Schrödinger equation is a mathematical equation that describes the evolution over time of a physical system in which quantum effects, such as wave--particle duality, are significant. The equation is a mathematical formulation for studying quantum mechanical systems. Just like Newtons's laws govern the mot…
We show that it is possible to use a classical computer to efficiently simulate the adiabatic evolution of a quantum system in one dimension with a constant spectral gap, starting the adiabatic evolution from a known initial product state. The proof relies on a recently proven area law for such systems, implying the existence of a good matrix product representation of the ground state, combined with an appropriate algorithm to update the matrix product state as the Hamiltonian is changed. This implies that adiabatic evolution with such Hamiltonians is not useful for universal quantum computati…
Starting from a simple mapping of a generator of local stochastic dynamics to a quantum Hamiltonian, we derive a condition, which allows us to use the quasi-adiabatic evolution and so relate gapped quantum phases with non-equilibrium's. This leads us to a study of invertible matrix product operators. Finally, we present an ansatz for constructing local stochastic dynamics for which the Perron-Frobenius vector has a Matrix Product Representation. Additionally, we get for free that the dynamics satisfy a generalized form of detailed balance.
Quantum computation has revolutionary potential for speeding algorithms and for simulating quantum systems such as molecules. We report here a quantum computer design that performs universal quantum computation within a single non-degenerate ground state protected from decohering noise by an energy gap that we argue is system-size-independent. Closely analogous to a traditional electric circuit, it substantially changes the requirements for quantum computer construction, easing measurement, timing, and heating problems. Using the standard adiabatic condition, we present evidence that this desi…
The method of calculation of the resonance characteristics is developed for the metastable states of the Coulomb three-body (CTB) system with two disintegration channels. The energy dependence of K-matrix in the resonance region is calculated with the use of the stabilization method. Resonance position and partial widths are obtained by fitting the numerically calculated K(E)-matrix with the help of the generalized Breit-Wigner formula.
We propose a scheme to realize high-precision quantum interferometry with entangled non-Gaussian states by driving the system through quantum phase transitions. The beam splitting, in which an initial non-degenerate groundstate evolves into a highly entangled state, is achieved by adiabatically driving the system from a non-degenerate regime to a degenerate one. Inversely, the beam recombination, in which the output state after interrogation becomes gradually disentangled, is accomplished by adiabatically driving the system from the degenerate regime to the non-degenerate one. The phase shift,…
We expand upon the standard quantum adiabatic theorem, examining the time-dependence of quantum evolution in the near-adiabatic limit. We examine a Hamiltonian that evolves along some fixed trajectory from $\hat{H}_0$ to $\hat{H}_1$ in a total evolution-time $τ$, and our goal is to determine how the final state of the system depends on $τ$. If the system is initialized in a non-degenerate ground state, the adiabatic theorem says that in the limit of large $τ$, the system will stay in the ground state. We examine the near-adiabatic limit where the system evolves slowly enough that most but not …
We present a formal geometric framework for the study of adiabatic quantum mechanics for arbitrary finite-dimensional non-degenerate Hamiltonians. This framework generalizes earlier holonomy interpretations of the geometric phase to non-cyclic states appearing for non-Hermitian Hamiltonians. We start with an investigation of the space of non-degenerate operators on a finite-dimensional state space. We then show how the energy bands of a Hamiltonian family form a covering space. Likewise, we show that the eigenrays form a bundle, a generalization of a principal bundle, which admits a natural co…
We have developed an adiabatic Abelian geometric quantum computation strategy based on the non-degenerate energy eigenstates in (but not limited to) superconducting phase-qubit systems. The fidelity of the designed quantum gate was evaluated in the presence of simulated thermal fluctuation in superconducting phase qubits circuit and was found to be rather robust against the random errors. In addition, it was elucidated that the Berry phase in the designed adiabatic evolution may be detected directly via the quantum state tomography developed for superconducting qubits.
Nonadiabatic dressed states of a quantum system interacting with an external electromagnetic field and the environment are presented. The relevant matrix elements within the specified states are found. A closed form expression of the quantum transitions based on the nonadiabatic dressed states is proposed for the first time.
We analyze the crossing of a quantum critical point based on exact results for the transverse XY model. In dependence of the change rate of the driving field, the evolution of the ground state is studied while the transverse magnetic field is tuned through the critical point with a linear ramping. The excitation probability is obtained exactly and is compared to previous studies and to the Landau-Zener formula, a long time solution for non-adiabatic transitions in two-level systems. The exact time dependence of the excitations density in the system allows to identify the adiabatic and diabatic…
Resonant transverse driving of a two-level system as viewed in the rotating frame couples two degenerate states at the Rabi frequency, an amazing equivalence that emerges in quantum mechanics. While spectacularly successful at controlling natural and artificial quantum systems, certain limitations may arise (e.g., the achievable gate speed) due to non-idealities like the counter-rotating term. Here, we explore a complementary approach to quantum control based on non-resonant, non-adiabatic driving of a longitudinal parameter in the presence of a fixed transverse coupling. We introduce a superc…
We investigate the origin of quantum geometric phases, gauge fields and forces beyond the adiabatic regime. In particular, we extend the notions of geometric magnetic and electric forces discovered in studies of the Born-Oppenheimer approximation to arbitrary quantum systems described by matrix valued quantum Hamiltonians. The results are illustrated by several physical relevant examples.
Non-Abelian holonomy in dynamical systems may arise in adiabatic transport of energetically degenerate sets of states. We examine such a holonomy structure for mixtures of energetically degenerate quantal states. We demonstrate that this structure has a natural interpretation in terms of the standard Wilczek-Zee holonomy associated with a certain class of Hamiltonians that couple the system to an ancilla. The mixed state holonomy is analysed for holonomic quantum computation using ion traps.
We consider the problem of the implementation of Stimulated Raman Adiabatic Passage (STIRAP) processes in degenerate systems, with a view to be able to steer the system wave function from an arbitrary initial superposition to an arbitrary target superposition. We examine the case a $N$-level atomic system consisting of $ N-1$ ground states coupled to a common excited state by laser pulses. We analyze the general case of initial and final superpositions belonging to the same manifold of states, and we cover also the case in which they are non-orthogonal. We demonstrate that, for a given initial…
Motivated by a recent experiment [Chikkatur, et al. Science, 296, 2193 (2002)] on the merging of atomic condensates, we investigate how two independent condensates with random initial phases can develop a unique relative phase when we move them together. In the adiabatic limit, the uniting of independent condensates can be understood from the eigenstate evolution of the governing Hamiltonian, which maps degenerate states (corresponding to fragmented condensates) to a single state (corresponding to a united condensate) . In the non-adiabatic limit corresponding to the practical experimental con…
Direct dynamics methods using Gaussian wavepackets have to rely only on local properties, such as gradients and hessians at the center of the wavepacket, so as to be compatible with the usual quantum chemistry methods. Matrix elements of the potential energy surfaces between wavepackets therefore usually have to be approximated. It is shown, that if a modified form of valence bond theory is used instead of the usual MO-based theories, the matrix elements can be obtained exactly. This is so because the molecular Hamiltonian only contains the Coulomb potential, for which matrix elements between …
We investigate a simple and robust scheme for choosing the phases of adiabatic electronic states smoothly (as a function of geometry) so as to maximize the performance of ab initio non-adiabatic dynamics methods. Our approach is based upon consideration of the overlap matrix ($\mathbf{U}$) between basis functions at successive points in time and selecting the phases so as to minimize the matrix norm of $\log(\mathbf{U})$. In so doing, one can extend the concept of parallel transport to cases with sharp curve crossings. We demonstrate that this algorithm performs well under extreme situations w…
The geometry and topology of quantum systems have deep connections to quantum dynamics. In this paper, I show how to measure the non-Abelian Berry curvature and its related topological invariant, the second Chern number, using dynamical techniques. The second Chern number is the defining topological characteristic of the four-dimensional generalization of the quantum Hall effect and has relevance in systems from three-dimensional topological insulators to Yang-Mills field theory. I illustrate its measurement using the simple example of a spin-3/2 particle in an electric quadrupole field. I sho…
We present a new approach to calculate real-time quantum dynamics in complex systems. The formalism is based on the partitioning of a system's environment into "core" and "reservoir" modes, with the former to be treated quantum mechanically and the latter classically. The presented method only requires the calculation of the system's reduced density matrix averaged over the quantum core degrees of freedom which is then coupled to a classically evolved reservoir to treat the remaining modes. We demonstrate our approach by applying it to the spin-boson problem using the noninteracting blip appro…
We consider a finite quantum system under slow driving and weakly coupled to thermal reservoirs at different temperatures. We present a systematic derivation of the quantum master equation for the density matrix and the out-of-time-order correlators. We start from the microscopic Hamiltonian and we formulate the equations ruling the dynamics of these quantities by recourse to the Schwinger-Keldysh non-equilibrium Green's function formalism, performing a perturbative expansion in the coupling between the system and the reservoirs. We focus on the adiabatic dynamics, which corresponds to conside…
