We describe the structure of relaxation for a steadily driven macroscopic body. The time-evolution is characterized as the zero-cost flow for a nonequilibrium and nonlinear extension of the Onsager-Machlup action governing the dynamical fluctuations. The approach hinges on two main elements: the principle of local detailed balance, which identifies the relevant thermodynamic forces, and the canonical decomposition of the frenesy into a Legendre pair. Notably, it is the time-symmetric component of the Lagrangian, the frenesy, that shapes the structure of the macroscopic evolution for given forcing. We add a simple argument for why the nonequilibrium entropy, which governs the static macroscopic fluctuations of the system, is monotone in time. The results can be interpreted as the steady nonequilibrium extension of GENERIC where relaxation to equilibrium is governed by a dissipative gradient flow superimposed on a Hamiltonian flow.
We study the relaxation of a single colloidal sphere which is periodically driven between two nonequilibrium steady states. Experimentally, this is achieved by driving the particle along a toroidal trap imposed by scanned optical tweezers. We find that the relaxation time after which the probability distributions have been relaxed is identical to that obtained by a steady state measurement. In quantitative agreement with theoretical calculations the relaxation time strongly increases when driving the system further away from thermal equilibrium.
We study the entropy production in a macroscopic nonequilibrium system that undergoes an order-disorder phase transition. Entropy production is a characteristic feature of nonequilibrium dynamics with broken detailed balance. It is found that the entropy production rate per particle vanishes in the disordered phase and becomes positive in the ordered phase following critical scaling laws. We derive the scaling relations for associated critical exponents. Our study reveals that a nonequilibrium ordered state is sustained at the expense of macroscopic time-reversal symmetry breaking with an exte…
We consider nonequilibrium (NEQ) states such as supercooled liquids and glasses that are described with use of internal variables. We classify the latter by state-dependent hierarchy of relaxation times to assess their relevance for irreversible contributions. Given an observation time τ_{obs}, we determine the window of relaxation times that divide the internal variables into active and inactive groups, the former playing a central role in the NEQ thermodynamics. Using this thermodynamics, we determine (i) a bound on the NEQ entropy and on the residual entropy, and (ii) the nature of isotherm…
We study the non-equilibrium relaxational dynamics of a probe particle linearly coupled to a thermally fluctuating scalar field and subject to a harmonic potential, which provides a cartoon for an optically trapped colloid immersed in a fluid close to its bulk critical point. The average position of the particle initially displaced from the position of mechanical equilibrium is shown to feature long-time algebraic tails as the critical point of the field is approached, the universal exponents of which are determined in arbitrary spatial dimensions. As expected, this behavior cannot be captured…
We reconsider a well-known relationship between the fluctuation theorem and the second law of thermodynamics by evaluating a probability measure-valued process. In order to establish a bridge between microscopic and macroscopic behaviors, we consider the thermodynamic limit of a stochastic dynamical system following the fundamental procedure often used in statistical mechanics. The thermodynamic path characterizing a macroscopic dynamical behavior can be formulated as an infimum of the action functional for the probability measure-valued process. In our formulation, the second law of thermodyn…
The fact that macroscopic systems approach thermal equilibrium may seem puzzling, for example, because it may seem to conflict with the time-reversibility of the microscopic dynamics. We here prove that in a macroscopic quantum system for a typical choice of "nonequilibrium subspace", any initial state indeed thermalizes, and in fact does so very quickly, on the order of the Boltzmann time $τ_\mathrm{B}:=h/(k_\mathrm{B}T)$. Therefore what needs to be explained is, not that macroscopic systems approach equilibrium, but that they do so slowly.
We have performed small-angle light-scattering measurements of the static structure factor of a critical binary mixture undergoing diffusive partial remixing. An uncommon scattering geometry integrates the structure factor over the sample thickness, allowing different regions of the concentration profile to be probed simultaneously. Our experiment shows the existence of interface capillary waves throughout the macroscopic evolution to an equilibrium interface, and allows to derive the time evolution of surface tension. Interfacial properties are shown to attain their equilibrium values quickly…
In order to adequately describe molecular rotation far from equilibrium, we have generalized the J-diffusion model by allowing the rotational relaxation rate to be angular momentum dependent. The calculated nonequilibrium rotational correlation functions (CFs) are shown to decay much slower than their equilibrium counterparts, and orientational CFs of hot molecules exhibit coherent behavior, which persists for several rotational periods. As distinct from the results of standard theories, rotational and orientational CFs are found to dependent strongly on the nonequilibrium preparation of the m…
The concept of entropy in nonequilibrium macroscopic systems is investigated in the light of an extended equation of motion for the density matrix obtained in a previous study. It is found that a time-dependent information entropy can be defined unambiguously, but it is the time derivative or entropy production that governs ongoing processes in these systems. The differences in physical interpretation and thermodynamic role of entropy in equilibrium and nonequilibrium systems is emphasized and the observable aspects of entropy production are noted. A basis for nonequilibrium thermodynamics is …
We investigate nonequilibrium relaxations of Ising models at the critical point by using a cluster update. While preceding studies imply that nonequilibrium cluster-flip dynamics at the critical point are universally described by the stretched-exponential function, we find that the dynamics changes from the stretched-exponential to the power function as the dimensionality is increased: The two-, three-, four-, and infinite-dimensional Ising models are numerically studied, and the four- and infinite-dimensional Ising models exhibit the power-law relaxation. We also show that the finite-size sca…
In this paper we present a self-contained macroscopic description of diffusive systems interacting with boundary reservoirs and under the action of external fields. The approach is based on simple postulates which are suggested by a wide class of microscopic stochastic models where they are satisfied. The description however does not refer in any way to an underlying microscopic dynamics: the only input required are transport coefficients as functions of thermodynamic variables, which are experimentally accessible. The basic postulates are local equilibrium which allows a hydrodynamic descript…
Dissipative effects in electromagnetism on macroscopic scales are examined by coarse graining the microscopic Maxwell equations with respect to time. We illustrate a procedure to derive the dissipative effects on the macroscopic scale by using a Green-Kubo type expression in terms of the microscopic fluctuations and the correlations between them. The resulting macroscopic Maxwell equations are formulated within the General Equation for the Non-Equilibrium Reversible-Irreversible Coupling (GENERIC) framework, accounting also for inhomogeneous temperature.
We consider nonequilibrium critical dynamics of the two-dimensional Ising model for which the initial state is prepared by switching on random fields with zero mean and variance $H$. In the initial state there is no magnetic order but the clusters of parallel spins have a percolation transition for small enough $H$. Using heath-bath dynamics we measure the relaxation of the magnetization which shows a reentrance in time. Due to cluster dissolution in the early time regime there is a decrease of the magnetization, followed by an increase due to nonequilibrium domain growth which itself turns to…
Nonequilibrium relaxation behaviors in the Ising model on a square lattice based on the Wolff algorithm are totally different from those based on local-update algorithms. In particular, the critical relaxation is described by the stretched-exponential decay. We propose a novel scaling procedure to connect nonequilibrium and equilibrium behaviors continuously, and find that the stretched-exponential scaling region in the Wolff algorithm is as wide as the power-law scaling region in local-update algorithms. We also find that relaxation to the spontaneous magnetization in the ordered phase is cha…
Colloidal particles are considered ideal building blocks to produce materials with enhanced physical properties. The state-of-the-art techniques for synthesizing these particles provide control over shape, size, and directionality of the interactions. In spite of these advances, there is still a huge gap between the synthesis of individual components and the management of their spontaneous organization towards the desired structures. The main challenge is the control over the dynamics of self-organization. In their kinetic route towards thermodynamically stable structures, colloidal particles …
We study nonequilibrium critical relaxation properties of systems with quenched extended defects, correlated in $ε_d$ dimensions and randomly distributed in the remaining $d-ε_d$ dimensions. Using a field-theoretic renormalization-group approach, we find the scaling behavior of the nonequilibrium response and correlation functions and calculate the initial slip exponents $θ$ and $θ^{\prime}$, which describe the growth of correlations during the initial stage of the critical relaxation, in the two-loop approximation.
We discuss the nature of nonequilibrium phase transitions in the Hamiltonian Mean Field model using detailed numerical simulation of the Vlasov equation and molecular dynamics. Starting from fixed magnetization waterbag initial distributions and varying the energy, the states obtained after a violent relaxation undergoes a phase transition from magnetized to non-magnetized states when going from lower to higher energies. The phase transitions are either first order or composed by a cascade of phase reentrances. This result is at variance with most previous results in the literature mainly base…
We propose a tensor-network algorithm for discrete-time stochastic dynamics of a homogeneous system in the thermodynamic limit. We map a $d$-dimensional nonequilibrium Markov process to a $(d+1)$-dimensional infinite tensor network by using a higher-order singular-value decomposition. As an application of the algorithm, we compute the nonequilibrium relaxation from a fully magnetized state to equilibrium of the one- and two- dimensional Ising models with periodic boundary conditions. Utilizing the translational invariance of the systems, we analyze the behavior in the thermodynamic limit direc…
Excess work is a non-diverging part of the work during transition between nonequilibrium steady states (NESSs). It is a central quantity in the steady state thermodynamics (SST), which is a candidate for nonequilibrium thermodynamics theory. We derive an expression of excess work during quasistatic transitions between NESSs by using the macroscopic linear response relation of NESS. This expression is a line integral of a vector potential in the space of control parameters. We show a relationship between the vector potential and the response function of NESS, and thus obtain a relationship betw…
Recently, the present authors proposed the nonequilibrium-to-equilibrium scaling (NE-ES) scheme for critical Monte Carlo relaxation process, which scales relaxation data in the whole simulation-time regions regardless of functional forms, namely both for the stretched-exponential critical relaxation in cluster algorithms and for the power-law critical relaxation in local-update algorithms. In the present study, we generalize this scheme to off-critical relaxation process, and scale relaxation data for various temperatures in the whole simulation-time regions. This is the first proposal of the …
We study numerically the nonequilibrium dynamical behavior of an Ising model with mixed two-spin and four-spin interactions after a sudden quench from the high-temperature phase to the first-order phase transition point. The autocorrelation function is shown to approach its limiting value, given by the magnetization in the ordered phase at the transition point, m_c, through a stretched exponential decay. On the other hand relaxation of the magnetization starting with an uncorrelated initial state with magnetization, m_i, approaches either m_c, for m_i>0.5, or zero, for m_i<0.5. For small m_i a…
We compare two approaches to nonequilibrium thermodynamics, the two-generator bracket formulation of time-evolution equations for averages and the macroscopic fluctuation theory, for an isothermal driven diffusive system under steady state conditions. The fluctuation dissipation relations of both approaches play an important role for a detailed comparison. The nonequilibrium Helmholtz free energies introduced in these two approaches differ as a result of boundary conditions. A Fokker-Planck equation derived by projection operator techniques properly reproduces long range fluctuations in nonequ…
Although the nonequilibrium relaxation (NER) method has been widely used in Monte Carlo studies on phase transitions in classical spin systems, such studies have been quite limited in quantum phase transitions. The reason is that relaxation process based on cluster-update quantum Monte Carlo (QMC) algorithms, which are now standards in Monte Carlo studies on quantum systems, has been considered "too fast" for such analyses. Recently the present authors revealed that the NER process in classical spin systems based on cluster-update algorithms is characterized by the stretched-exponential critic…
A general theory is developed for describing the nonlinear relaxation of spin systems from a strongly nonequilibrium initial state, when, in addition, the sample is coupled to a resonator. Such processes are characterized by nonlinear stochastic differential equations. This makes these strongly nonequilibrium processes principally different from the spin relaxation close to an equilibrium state, which is represented by linear differential equations. The consideration is based on a realistic microscopic Hamiltonian including the Zeeman terms, dipole interactions, exchange interactions, and a si…
The issue of relaxation has been addressed in terms of ergodic theory in the past. However, the application of that theory to models of physical interest is problematic, especially when dealing with relaxation to nonequilibrium steady states. Here, we consider the relaxation of classical, thermostatted particle systems to equilibrium as well as to nonequilibrium steady states, using dynamical notions including decay of correlations. We show that the condition known as ΩT-mixing is necessary and sufficient to prove relaxation of ensemble averages to steady state values. We then observe that the…
With a nonequilibrium relaxation method, we calculate the dynamic critical exponent z of the two-dimensional Ising model for the Swendsen-Wang and Wolff algorithms. We examine dynamic relaxation processes following a quench from a disordered or an ordered initial state to the critical temperature T_c, and measure the exponential relaxation time of the system energy. For the Swendsen-Wang algorithm with an ordered or a disordered initial state, and for the Wolff algorithm with an ordered initial state, the exponential relaxation time fits well to a logarithmic size dependence up to a lattice si…
The influence of nonequilibrium initial values of the order parameter on its evolution at a critical point is described using a renormalization group approach of the field theory. The dynamic critical exponent $θ'$ of the short time evolution of a system with an $n$-component order parameter is calculated within a dynamical dissipative model using the method of $\varepsilon$-expansion in a three-loop approximation. Numerical values of $θ'$ for three-dimensional systems are determined using the Padé-Borel method for the summation of asymptotic series.
We give a pedagogical introduction to a selection of recently discussed topics in nonequilibrium statistical mechanics, concentrating mostly on formal structures and on general principles. Part I contains an overview of the formalism of lattice gases that we use to explain various symmetries and inequalities generally valid for nonequilibrium systems, including the fluctuation symmetry, Jarzynski equality, and the direction of currents. In Part II we concentrate on the macroscopic state and how entropy provides a bridge between microscopic dynamics and macroscopic irreversibility; included is …
In this work, we study the nonequilibrium statistical properties of the relaxation dynamics of a nanoparticle trapped in a harmonic potential. We report an exact time-dependent analytical solution to the Langevin dynamics that arises from the stochastic differential equation of our system's energy in the underdamped regime. By utilizing this stochastic thermodynamics approach, we are able to completely describe the heat exchange process between the nanoparticle and the surrounding environment. As an important consequence of our results, we observe the validity of the heat exchange fluctuation …
We study microscopic and macroscopic dynamical properties of a frustrated lattice gas, strictly related to usual spin glasses, showing the violation of Stokes-Einstein law. The glassy behaviors are analyzed and related with experimental results in glass former systems.
We study a simple transport model driven out of equilibrium by reservoirs at the boundaries, corresponding to the hydrodynamic limit of the symmetric simple exclusion process. We show that a nonlocal transformation of densities and currents maps the large deviations of the model into those of an open, isolated chain satisfying detailed balance, where rare fluctuations are the time reversals of relaxations. We argue that the existence of such a mapping is the immediate reason why it is possible for this model to obtain an explicit solution for the large-deviation function of densities through e…
We employ Monte Carlo simulations to investigate the two-time density autocorrelation function for the two-dimensional Coulomb glass. We find that the nonequilibrium relaxation properties of this highly correlated disordered system can be described by a full aging scaling ansatz. The scaling exponents are non-universal, and depend on temperature and charge density.
The Binder ratios exhibit discrepancy from the Gaussian behavior of the magnetic cumulants, and their size independence at the critical point has been widely utilized in numerical studies of critical phenomena. In the present article we reformulate the nonequilibrium relaxation (NER) analysis in cluster algorithms using the $(2,1)$-Binder ratio, and apply this scheme to the two- and three-dimensional Ising models. Although the stretched-exponential relaxation behavior at the critical point is not explicitly observed in this quantity, we find that there exists a logarithmic finite-size scaling …
The static and dynamic critical properties of the ferromagnetic q-state Potts models on a square lattice with q = 2 and 3 are numerically studied via the nonequilibrium relaxation method. The relaxation behavior of both the order parameter and energy as well as that of the second moments are investigated, from which static and dynamic critical exponents can be obtained. We find that the static exponents thus obtained from the relaxation of the order parameter and energy together with the second moments of the order parameter exhibit a close agreement with the exact exponents, especially for th…
We study the critical relaxation of the two-dimensional Ising model from a fully ordered configuration by series expansion in time t and by Monte Carlo simulation. Both the magnetization (m) and energy series are obtained up to 12-th order. An accurate estimate from series analysis for the dynamical critical exponent z is difficult but compatible with 2.2. We also use Monte Carlo simulation to determine an effective exponent, z_eff(t) = - {1/8} d ln t /d ln m, directly from a ratio of three-spin correlation to m. Extrapolation to t = infinity leads to an estimate z = 2.169 +/- 0.003.
We propose a model for charge density waves in ring shaped crystals, which depicts frustration between intra- and inter-chain couplings coming from cylindrical bending. It is then mapped to a three dimensional uniformly frustrated XY model with one dimensional anisotropy in connectivity. The nonequilibrium relaxation dynamics is investigated by Monte Carlo simulations to find a phase transition which is quite different from that of usual whisker crystal. We also find that the low temperature state is a three dimensional phase vortex lattice with a two dimensional phase coherence in a cylindric…
Granular fluids consist of collections of activated mesoscopic or macroscopic particles (e.g., powders or grains) whose flows often appear similar to those of normal fluids. To explore the qualitative and quantitative description of these flows an idealized model for such fluids, a system of smooth inelastic hard spheres, is considered. The single feature distinguishing granular and normal fluids being explored in this way is the inelasticity of collisions. The dominant differences observed in real granular fluids are indeed captured by this feature. Following a brief introductory description …
We study the problem of the approach to equilibrium in a macroscopic quantum system in an abstract setting. We prove that, for a typical choice of "nonequilibrium subspace", any initial state (from the energy shell) thermalizes, and in fact does so very quickly, on the order of the Boltzmann time $τ__\mathrm{B}:=h/(k_\mathrm{B}T)$. This apparently unrealistic, but mathematically rigorous, conclusion has the important physical implication that the moderately slow decay observed in reality is not typical in the present setting. The fact that macroscopic systems approach thermal equilibrium may s…
The finite-size scaling method in the equilibrium Monte Carlo(MC) simulations and the finite-time scaling method in the nonequilibrium-relaxation simulations are compromised. MC time data of various physical quantities are scaled by the MC time data of the dynamic correlation length, which corresponds to changing the system size in the finite-size scaling method. This scaling method is tested in the three-dimensional ferromagnetic Ising spin model and in the three dimensional $\pm J$ Ising spin-glass model. The transition temperature and the critical exponents, $η$ and $ν$, are obtained by the…
We study relaxation phenomena in the ferromagnetically ordered state of the Ising-like Heisenberg kagome antiferromagnets. We introduce the "weathervane loop" in order to characterize macroscopic degenerate ordered states and study the microscopic mechanism of the slow relaxation from a view point of the dynamics of the weathervane loop configuration. This mechanism may give a possible origin of the slow relaxation reported in recent experiments.
A quantum mechanical explanation of the relaxation to equilibrium is shown for macroscopic systems for nonintegrable cases and numerically verified. The macroscopic system is initially in an equilibrium state, subsequently externally perturbed during a finite time, and then isolated for a sufficiently long time. We show a quantitative explanation that the initial microcanonical state typically reaches to a state whose expectation values are well-approximated by the average over another microcanonical ensemble.
A recent theory by Bertini, De Sole, Gabrielli, Jona-Lasinio and Landim predicts a temporal asymmetry in the fluctuation-relaxation paths of certain observables of nonequilibrium systems in local thermodynamic equilibrium. We find temporal asymmetries in the fluctuation-relaxation paths of a form of local heat flow, in the nonequilibrium FPU-$\zb$ model of Lepri, Livi and Politi.
Effect of exchange anisotropy on the relaxation time of spin and vector chirality is studied for the antiferromagnetic classical Heisenberg model on the triangular lattice by using the nonequilibrium relaxation Monte Carlo method. We identify the Berezinskii-Kosterlitz-Thouless (BKT) transition and the chiral transition in a wide range of the anisotropy, even for very small anisotropy of $\sim$ 0.01%. As the anisotropy decreases, both the critical temperatures steeply decrease, while the BKT critical region becomes divergently wide. We elucidate a sharp "V shape" of the phase diagram around th…
With Monte Carlo simulations, we investigate the relaxation dynamics with a domain wall for magnetic systems at the critical temperature. The dynamic scaling behavior is carefully analyzed, and a dynamic roughening process is observed. For comparison, similar analysis is applied to the relaxation dynamics with a free or disordered surface.
Recently we showed that the critical nonequilibrium relaxation in the Swendsen-Wang algorithm is widely described by the stretched-exponential relaxation of physical quantities in the Ising or Heisenberg models. Here we make a similar analysis in the Berezinsky-Kosterlitz-Thouless phase transition in the two-dimensional (2D) XY model and in the first-order phase transition in the 2D $q=5$ Potts model, and find that these phase transitions are described by the simple exponential relaxation and power-law relaxation of physical quantities, respectively. We compare the relaxation behaviors of thes…
We present results on dynamical processes that exhibit a stretched exponential relaxation. When the relaxation is a result of two competing exponential processes, the size of the system, although macroscopic, play a dominant role. There exist a crossover time tx that depends logarithmically on the size of the system, above which, the relaxation changes from a stretched exponential to a simple exponential decay. The decay rate also depends logarithmically on the size of the system. The results are relevant to large-scale Monte-Carlo simulations and should be amenable to experiments in low-dimen…
The main subject of the thesis is the study of stationary nonequilibrium states trough the use of microscopic stochastic models that encode the physical interaction in the rules of Markovian dynamics for particles configurations. These models are known as interacting particles systems and are simple enough to be treated analytically but also complex enough to capture essential physical behaviours. The thesis is organized in two parts. The part 1 is devoted to the microscopic theory of the stationary states. We characterize these states developing some general structures that have an interest i…
Nonequilibrium stationary states of thermodynamic systems dissipate a positive amount of energy per unit of time. If we consider transformations of such states that are realized by letting the driving depend on time, the amount of energy dissipated in an unbounded time window becomes then infinite. Following the general proposal by Oono and Paniconi and using results of the macroscopic fluctuation theory, we give a natural definition of a renormalized work performed along any given transformation. We then show that the renormalized work satisfies a Clausius inequality and prove that equality i…
Mode-coupling theory for uniformly sheared underdamped systems with an isothermal condition is presented. As a result of the isothermal condition, it is shown that the shear stress exhibits significant relaxation at the alpha-relaxation regime due to the cooling effect which is accompanied by the growth of the current fluctuation. This indicates that nonequilibrium underdamped MCT is not equivalent to the corresponding overdamped MCT, even at long time-scales after the early stage of the beta relaxation. It is verified that the effect of correlations to the density-current modes is, however, n…
We consider a macroscopic system in contact with boundary reservoirs and/or under the action of an external field. We discuss the case in which the external forcing depends explicitly on time and drives the system from a nonequilibrium state to another one. In this case the amount of energy dissipated along the transformation becomes infinite when an unbounded time window is considered. Following the general proposal by Oono and Paniconi and using results of the macroscopic fluctuation theory, we give a natural definition of a renormalized work. We then discuss its thermodynamic relevance by s…
This Chapter contains an overview of the effects of nonlinear interactions in selected problems of non-equilibrium statistical mechanics. Most of the emphasis is put on open setups, where energy is exchanged with the environment. With reference to a few models of classical coupled anharmonic oscillators, we review anomalous but general properties such as extremely slow relaxation processes, or non-Fourier heat transport.
This paper studies a mathematical formalism of nonequilibrium thermodynamics for chemical reaction models with $N$ species, $M$ reactions, and general rate law. We establish a mathematical basis for J. W. Gibbs' macroscopic chemical thermodynamics under G. N. Lewis' kinetic law of entire equilibrium (detailed balance in nonlinear chemistry kinetics). In doing so, the equilibrium thermodynamics is then naturally generalized to nonequilibrium settings without detailed balance. The kinetic models are represented by a Markovian jumping process. A generalized macroscopic chemical free energy functi…
In this contribution we show that a suitably defined nonequilibrium entropy of an N-body isolated system is not a constant of the motion in general and its variation is bounded, the bounds determined by the thermodynamic entropy, i.e., the equilibrium entropy. We define the nonequilibrium entropy as a convex functional of the set of n-particle reduced distribution functions (n=0,......., N) generalizing the Gibbs fine-grained entropy formula. Additionally, as a consequence of our microscopic analysis we find that this nonequilibrium entropy behaves as a free entropic oscillator. In the approac…
We analyze the equilibration process between two either fermionic or bosonic reservoirs containing ultracold atoms with a fixed total number of particles that are weakly connected via a few-level quantum system. We allow for both the temperatures and particle densities of the reservoirs to evolve in time. Subsequently, linearizing the resulting equations enables us to characterize the equilibration process and its time scales in terms of equilibrium reservoir properties and linear-response transport coefficients. Additionally, we investigate the use of such a device as particle transistor or p…
In nonequilibrium thermodynamics macroscopic entropy creation plays an important role. Here we study, from various viewpoints, its relation with the phase space contraction, which has been recently proposed as an apparently alternative quantity. quantity.
From the early days of many-body physics, it was realized that the self-energy governs the relaxation or lifetime of the retarded Green$'$s function. So it seems reasonable to directly extend those results into the nonequilibrium domain. But experiments and calculations of the response of quantum materials to a pump show that the relationship between the relaxation and the self-energy only holds in special cases. Experimentally, the decay time for a population to relax back to equilibrium and the linewidth measured in a linear-response angle-resolved photoemission spectroscopy differ by large …
