Dissipative effects in electromagnetism on macroscopic scales are examined by coarse graining the microscopic Maxwell equations with respect to time. We illustrate a procedure to derive the dissipative effects on the macroscopic scale by using a Green-Kubo type expression in terms of the microscopic fluctuations and the correlations between them. The resulting macroscopic Maxwell equations are formulated within the General Equation for the Non-Equilibrium Reversible-Irreversible Coupling (GENERIC) framework, accounting also for inhomogeneous temperature.
We derive some nonequilibrium identities such as the integral fluctuation theorem and the Jarzynski equality starting from a nonequilibrium state for dissipative classical systems. Thanks to the existence of the integral fluctuation theorem we can naturally introduce an entropy-like quantity for dissipative classical systems in far from equilibrium states. We also derive the generalized Green-Kubo formula as a nonlinear response theory for a steady dynamics around a nonequilibrium state. We numerically verify the validity of the derived formulas for sheared frictionless granular particles.
The problem of response of nonequilibrium systems is currently under intense investigation. We propose a general method of solution of the Liouville Equation for thermostatted particle systems subjected to external forces which retains only the slow degrees of freedom, by projecting out the majority of fast variables. Response formulae, extending the Green-Kubo relations to dissipative dynamics are provided, and comparison with numerical data is presented.
Chaos is usually referred to the sensitivity to initial conditions in which the nonlinearity plays a crucial role. Beyond such a mathematical description, the understanding of the underlying physical origin of the chaos is still not very clear. Here we study the dissipative chaos from the perspective of the nonequilibrium dynamics. This was not fully investigated in the traditional chaos theory, despite of the Lorenz's original discovery of chaos from the nonequilibrium atmosphere. We found that the nonequilibriumness as the degree of detailed balance breaking can be quantified by the appearan…
We give a decomposition expression for dissipative heat using the instantaneous diffusion coefficient in a nonequilibrium steady state. The dissipative heat can be expressed using three diffusion coefficients: instantaneous, equilibrium, and drift. An experimental application of the decomposition expression permits us to evaluate the heat dissipation rate from single-trajectory data only. We also numerically demonstrate this method.
How can we derive the evolution equations of dissipative systems? What is the relation between the different approaches? How much do we understand the fundamental aspects of a second law based framework? Is there a hierarchy of dissipative and ideal theories at all? How far can we reach with the new methods of nonequilibrium thermodynamics?
Theoretical studies of nonequilibrium systems are complicated by the lack of a general framework. In this work we first show that a transformation introduced by Ao recently (J. Phys. A {\bf 37}, L25 (2004)) is related to previous works of Graham (Z. Physik B {\bf 26}, 397 (1977)) and Eyink {\it et al.} (J. Stat. Phys. {\bf 83}, 385 (1996)), which can also be viewed as the generalized application of the Helmholtz theorem in vector calculus. We then show that systems described by ordinary stochastic differential equations with white noise can be mapped to thermostated Hamiltonian systems. A stea…
Using the path integral approach to equilibrium statistical physics the effect of dissipation on Landau diamagnetism is calculated. The calculation clarifies the essential role of the boundary of the container in which the electrons move. Further, the derived result for diamagnetization also matches with the expression obtained from a time-dependent quantum Langevin equation in the asymptotic limit, provided a certain order is maintained in taking limits. This identification then unifies equilibrium and nonequilibrium statistical physics for a phenomenon like diamagnetism, which is inherently …
The exact large deviation function (ldf) for the fluctuations of the energy density field is computed for a chain of Ising (or more generally Potts) spins driven by a zero-temperature (dissipative) Glauber dynamics and sustained in a non trivial stationary regime by an arbitrary energy injection mechanism at the boundary of the system. It is found that this ldf is independent of the dynamical details of the energy injection, and that the energy fluctuations, unlike conservative systems in a nonequilibrium state, are not spatially correlated in the stationary regime.
We study an extended system that without noise shows a monostable dynamics, but when submitted to an adequate multiplicative noise, an effective bistable dynamics arise. The stochastic resonance between the attractors of the \textit{noise-sustained dynamics} is investigated theoretically in terms of a two-state approximation. The knowledge of the exact nonequilibrium potential allows us to obtain the output signal-to-noise ratio. Its maximum is predicted in the symmetric case for which both attractors have the same nonequilibrium potential value.
Dissipative preparation of a pure steady state usually involves a commutative action of a coherent and a dissipative dynamics on the target state. Namely, the target pure state is an eigenstate of both the coherent and dissipative parts of the dynamics. We show that working in the Zeno regime, i.e. for infinitely large dissipative coupling, one can generate a pure state by a non commutative action, in the above sense, of the coherent and dissipative dynamics. A corresponding Zeno regime pureness criterion is derived. We illustrate the approach, looking at both its theoretical and applicative a…
Controlling thermodynamic cycles to minimize the dissipated heat is a longstanding goal in thermodynamics, and more recently, a central challenge in stochastic thermodynamics for nanoscale systems. Here, we introduce a theoretical and computational framework for optimizing nonequilibrium control protocols that can transform a system between two distributions in a minimally dissipative fashion. These protocols optimally transport a system along paths through the space of probability distributions that minimize the dissipative cost of a transformation. Furthermore, we show that the thermodynamic…
The nonexponential relaxation and aging inherent to complex dynamics manifested in a wide variety of dissipative systems is analyzed through a model of diffusion in phase space in the presence of a nonconservative force. The action of this force establishes a heat flow which maintains the system away from equilibrium. The inability of the system to find its equilibrium state becomes apparent through the presence of an effective temperature field. This is the temperature of the stationary nonequilibrium state reached by the system satisfying a generalyzed version of the fluctuation-dissipation …
Laser technology has developed and accelerated photo-induced nonequilibrium physics from both scientific and engineering viewpoints. The Floquet engineering, i.e., controlling material properties and functionalities by time-periodic drives, is a forefront of quantum physics of light-matter interaction, but limited to ideal dissipationless systems. For the Floquet engineering extended to a variety of materials, it is vital to understand the quantum states emerging in a balance of the periodic drive and energy dissipation. Here we derive the general description for nonequilibrium steady states (…
The nonequilibrium dynamics of correlated charge transfer along a one-dimensional chain in presence of a phonon environment is investigated within a dissipative Hubbard model. For this generalization of the ubiquitous spin-boson model the crucial role of symmetries is analysed in detail and corresponding invariant subspaces are identified. It is shown that the time evolution typically occurs in each of the disjunct subspaces independently leading e.g. asymptotically to a non-Boltzmann equilibrium state. Based on these findings explicit results are obtained for two interacting electrons by mean…
Studying the role of activity parameters and the nature of time-symmetric path-variables constitutes an important part of nonequilibrium physics, so we argue. The relevant variables are residence times and the undirected traffic between different states. Parameters are the reactivities, escape rates and accessibilities and how those possibly depend on the imposed driving. All those count in the frenetic contribution to statistical forces, response and fluctuations, operational even in the stationary distribution when far enough from equilibrium. As these time-symmetric aspects can vary indepen…
The separation of substances into different phases is ubiquitous in nature and important scientifically and technologically. This phenomenon may become drastically different if the species involved, whether molecules or supramolecular assemblies, interconvert. In the presence of an external force large enough to overcome energetic differences between the interconvertible species (forced interconversion), the two alternative species will be present in equal amounts, and the striking phenomenon of steady-state, restricted phase separation into mesoscales is observed. Such microphase separation i…
For open quantum systems, the Gaussian environmental dissipative effect can be represented by statistical quasi-particles, namely, dissipatons. We exploit this fact to establish the dissipaton thermofield theory. The resulting generalized Langevin dynamics of absorptive and emissive thermofield operators are effectively noise-resolved. The system-bath entanglement theorem is then readily followed between an important class of nonequilibrium steady-state correlation functions. All these relations are validated numerically. A simple corollary is the transport current expression, which exactly re…
We investigate a dissipatively driven XYZ spin-1/2 chain in the Zeno limit of strong dissipation, described by Lindblad master equation. The nonequilibrium steady state is expressed in terms of a matrix product ansatz using novel site-dependent Lax operators. The components of Lax operators satisfy a simple set of linear recurrence equations that generalize the defining algebraic relations of the quantum group $U_q(sl_2)$. We reveal connection between the nonequilibrium steady state of the nonunitary dynamics and the respective integrable model with edge magnetic fields, described by coherent …
We show that intensive thermodynamic parameters associated to additive conserved quantities can be naturally defined from a statistical approach in far-from-equilibrium steady-state systems, under few assumptions, and without any detailed balance requirement. It may apply, e.g., to dissipative systems like granular gases where volume or mass is still conserved, or to systems with periodic boundary conditions where fluxes of conserved quantities are present. We emphasize the usefulness of this concept to characterize the coexistence of different nonequilibrium phases, and discuss the influence …
Chemical processes in closed systems are poorly controllable since they always relax to equilibrium. Living systems avoid this fate and give rise to a much richer diversity of phenomena by operating under nonequilibrium conditions. Recent experiments in dissipative self-assembly also demonstrated that by opening reaction vessels and steering certain concentrations, an ocean of opportunities for artificial synthesis and energy storage emerges. To navigate it, thermodynamic notions of energy, work and dissipation must be established for these open chemical systems. Here, we do so by building upo…
We derive a class of mesoscopic virial equations governing energy partition between conjugate position and momentum variables of individual degrees of freedom. They are shown to apply to a wide range of nonequilibrium steady states with stochastic (Langevin) and deterministic (Nosé--Hoover) dynamics, and to extend to collective modes for models of heat-conducting lattices. A generalised macroscopic virial theorem ensues upon summation over all degrees of freedom. This theorem allows for the derivation of nonequilibrium state equations that involve dissipative heat flows on the same footing wit…
We examine the question of whether the formal expressions of equilibrium statistical mechanics can be applied to time independent non-dissipative systems that are not in true thermodynamic equilibrium and are nonergodic. By assuming the phase space may be divided into time independent, locally ergodic domains, we argue that within such domains the relative probabilities of microstates are given by the standard Boltzmann weights. In contrast to previous energy landscape treatments, that have been developed specifically for the glass transition, we do not impose an a priori knowledge of the inte…
A defining feature of living matter is the ability to harness energy to self-organize multiscale structures whose functions are facilitated by irreversible nonequilibrium dynamics. While progress has been made in elucidating the underlying principles, what remains unclear is the role that thermodynamics plays in shaping these structures and their ensuing functions. Here, we unravel how a fundamental thermodynamic connection between the physical energy dissipation sustaining a nonequilibrium system and a measure of statistical irreversibility (arrow of time), can provide quantitative insight in…
The interplay of synchronization and topological band structures with symmetry protected midgap states under the influence of driving and dissipation is largely unexplored. Here we consider a trimer chain of electron shuttles, each consisting of a harmonic oscillator coupled to a quantum dot positioned between two electronic leads. Each shuttle is subject to thermal dissipation and undergoes a bifurcation towards self-oscillation with a stable limit cycle if driven by a bias voltage between the leads. By mechanically coupling the oscillators together, we observe synchronized motion at the ends…
We describe a particular approach for the construction of a nonequilibrium statistical ensemble formalism for the treatment of dissipative many-body systems. This is the so-called Nonequilibrium Statistical Operator Method, based on the seminal and fundamental ideas set forward by Boltzmann and Gibbs. The existing approaches can be unified under a unique variational principle, namely, MaxEnt, which we consider here. The main six basic steps that are at the foundations of the formalism are presented and the fundamental concepts are discussed. The associated nonlinear quantum kinetic theory and …
Variational principles play a fundamental role in deriving evolution equations of physics. They are working well in case of nondissipative evolution but for dissipative systems they are not unique, not predictive and not constructive. With methods of modern nonequilibrium thermodynamics, one can derive evolution equations for dissipative phenomena and, surprisingly, can also reproduce the Euler-Lagrange form of the evolution equations for ideal processes. In this work, we examine some demonstrative examples and compare thermodynamic and variational techniques. Then, we argue that instead of se…
We propose that nonequilibrium quantum criticality in open systems at both zero and finite temperatures can be described by a master equation of the Lindblad form. We derive this equation from a system coupling microscopic to a heat bath. It is suggested to be valid generally for studying dynamical quantum criticality and is thus designated as Model Q upon generalizing Hohenberg and Halperin's classification of classical critical dynamics. We find that the dissipation rate in the equation must be included in the scaling forms as an indispensable additional scaling variable in order to correctl…
We develop a general framework for the steady-state response of dissipative quantum systems. We concretely derive three different, but equivalent, forms of the quantum response function. We discuss for each of them the role of the noncommutativity of quantum operators and establish links to the Kubo response theory for closed quantum systems. We show in particular that the equilibrium response vanishes for perturbations that commute with the unperturbed Hamiltonian while the steady-state response does not, highlighting the profound difference between the two.
Fundamental interactions are either fully or nearly symmetric under time reversal. But macroscopic phenomena have a definite arrow of time. Though there is no convergence on the origin of time's preferential direction, many researchers believe that the direction of time is towards increasing entropy. In this paper, we provide an alternate point of view. In driven-dissipative nonequilibrium systems forced at large scale, the energy flows from large scales to dissipative scales. This generic and multiscale process breaks time reversal symmetry and principle of detailed balance, thus can yield an…
We study the nonequilibrium dynamics of a mesoscopic metallic ring threaded by a time-dependent magnetic field and coupled to an electronic reservoir. We analyze the relation between the (non-stationary) real-time Keldysh and retarded Green functions and we find that, in the linear response regime with weak heat transfer to the environment, an effective temperature accounts for the modification of the equilibrium fluctuation-dissipation relation. We discuss possible extensions of this analysis.
The nonequilibrium dynamics of a small quantum system coupled to a dissipative environment is studied. We show that (1) the oscillatory dynamics close to a coherent-to-incoherent transition is surprisingly different from the one of the classical damped harmonic oscillator and that (2) non-markovian memory plays a prominent role in the time evolution after a quantum quench.
Quantum jump correlations in long-range dissipative spin systems via cluster and cumulant expansions
Scuola Superiore Meridionale（南方高等学院）；SISSA（国际高等研究院）；CNRS, Collège de France（法国国家科学研究中心，法兰西公学院）；The Abdus Salam International Centre for Theoretical Physics (ICTP)（阿卜杜斯·萨拉姆国际理论物理中心）；Université Paris Cité, CNRS, Matériaux et Phénomènes Quantiques（巴黎西岱大学，法国国家科学研究中心，材料与量子现象研究所）；Dipartimento di Fisica “E. Pancini”, Università di Napoli “Federico II”（那不勒斯费德里科二世大学，E. Pancini物理系）；Pitaevskii BEC Center, CNR-INO and Dipartimento di Fisica, Università di Trento（皮塔耶夫斯基玻色-爱因斯坦凝聚中心，意大利国家研究委员会光电子学与纳米技术研究所，特伦托大学物理系）；INFN-TIFPA, Trento Institute for Fundamental Physics and Applications（意大利国家核物理研究所，特伦托基础物理与应用研究所）
In nonequilibrium classical thermostatistics, the state of a system may be described by not only dynamical/thermodynamical variables but also a kinetic distribution function. This "double structure" bears some analogy with that in quantum thermodynamics, where both dynamical variables and the Hilbert space are involved. Recently, the concept of weak invariants has repeatedly been discussed in the context of quantum thermodynamics. A weak invariant is defined in such a way that its value changes in time but its expectation value is conserved under time evolution prescribed by a kinetic equation…
The effects of a local magnetic field on nonequilibrium stationary states (NESS) of the open quantum $XXZ$ spin chain are investigated with a Lindblad master equation approach in the limit of strong dissipation. The local magnetic field is applied to a single bulk spin of the chain while the ends are kept at fixed polarizations by dissipation. We show that suitable changes of the local magnetic field permit to invert the spin current by switching pure NESS with opposite chiralities, while preserving the state purity and achieving optimal transport.
A new type of quantum transfer matrix, arising as a Cholesky factor for the steady state density matrix of a dissipative Markovian process associated with the boundary-driven Lindblad equation for the isotropic spin-1/2 Heisenberg (XXX) chain, is presented. The transfer matrix forms a commuting family of non-Hermitian operators depending on the spectral parameter which is essentially the strength of dissipative coupling at the boundaries. The intertwining of the corresponding Lax and monodromy matrices is performed by an infinitely dimensional Yang-Baxter R-matrix which we construct explicitly…
By assuming that a particle of energy hbar.omega is actually a dissipative system maintained in a nonequilibrium steady state by a constant throughput of energy (heat flow), the exact Schroedinger equation is derived, both for conservative and nonconservative systems. Thereby, only universal properties of oscillators and nonequilibrium thermostatting are used, such that a maximal model independence of the hypothesised sub-quantum physics is guaranteed. It is claimed that this represents the shortest derivation of the Schroedinger equation from (modern) classical physics in the literature, and …
We investigate two prototypical dissipative bosonic systems under slow driving and arbitrary system-bath coupling strength, recovering their dynamic evolution as well as the heat and work rates, and we verify that thermodynamic laws are respected. Specifically, we look at the damped harmonic oscillator and the damped two-level system. For the former, we study independently the slow time- dependent perturbation in the oscillator frequency and in the coupling strength. For the latter, we concentrate on the slow modulation of the energy gap between the two levels. Importantly, we are able to find…
Local quantum master equations provide a simple description of interacting subsystems coupled to different reservoirs. They have been widely used to study nonequilibrium critical phenomena in open quantum systems. We here investigate the validity of such a local approach by analyzing a paradigmatic system made of two harmonic oscillators each in contact with a heat bath. We evaluate the steady-state mean occupation number for varying temperature differences and find that local master equations generally fail to reproduce the results of an exact quantum-Langevin-equation description. We relate …
