Yanxing Yang, Xin Li, Cheng Tan, Zihao Zhu, Jian Zhang, Zhaofeng Ding, Qiong Wu, Changshen Chen, Toni Shiroka, Yuanhua Xia, Douglas E. MacLaughlin, Chandra M. Varma, Lei Shu
Quantum fluctuations are expected to lead to highly entangled spin-liquid states in certain two-dimensional spin-1/2 compounds. We have synthesized and measured thermodynamic properties and muon spin relaxation rates in the copper-based two-dimensional triangular-lattice spin liquids Lu$_3$Cu$_2$Sb$_3$O$_{14}$ and Lu$_3$CuZnSb$_3$O$_{14}$. The former is the least disordered of this kind discovered to date. Magnetic entropy generation at high temperatures has been ruled out after carefully correcting for the lattice specific heat. Surprisingly, roughly half of the magnetic entropy is missing down to temperatures of O(10$^{-3}$) the exchange energy, independent of magnetic field up to $gμ_B H \gtrsim k_BΘ_W$, where $Θ_W$ is the Weiss temperature. The magnetic specific heat divided by temperature $C_M(T)/T$ and muon spin relaxation rate $λ(T)$ are both temperature-independent at low temperatures, followed by logarithmic decreases with increasing temperature. This behavior can be simply characterized by scale-invariant time-dependent fluctuations with a single parameter. Since no cooperative effects due to impurities are observed, the measured properties are intrinsic. They are evidence that in Lu$_3$Cu$_2$Sb$_3$O$_{14}$ massive quantum fluctuations lead to either a gigantic specific heat peak from singlet excitations at very low temperatures or, perhaps less likely, an extensively degenerate possibly topological singlet ground state.
The family of "Kitaev materials" provides an ideal platform to study quantum spin liquids and their neighboring magnetic orders. Motivated by the possibility of a quantum spin liquid ground state in pressurized hyperhoneycomb iridate $β$-Li$_2$IrO$_3$, we systematically classify and study symmetric quantum spin liquids on the hyperhoneycomb lattice, using the Abrikosov-fermion representation. Among the 176 symmetric $U(1)$ spin liquids (and 160 $Z_2$ spin liquids), we identify 8 "root" $U(1)$ spin liquids in proximity to the ground state of the solvable Kitave model on hyperhonecyomb lattices.…
Spiral spin-liquids are correlated paramagnetic states with degenerate propagation vectors forming a continuous ring or surface in reciprocal space. On the honeycomb lattice, spiral spin-liquids present a novel route to realize emergent fracton excitations, quantum spin liquids, and topological spin textures, yet experimental realizations remain elusive. Here, using neutron scattering, we show that a spiral spin-liquid is realized in the van der Waals honeycomb magnet FeCl$_3$. A continuous ring of scattering is directly observed, which indicates the emergence of an approximate U(1) symmetry i…
Formation of energy gap in higher dimensional spin-orbital liquids
在对称自旋轨道模型下，发展了高维自旋液体的Schwinger玻色子平均场论。自旋，轨道和耦合自旋轨道运营商被同等对待。我们计算了动态关联函数和集体激发谱。由于集体激发具有有限的能隙，我们得出结论，基态是一个具有双重简并度的自旋轨道液体，这打破了离散的自旋轨道对称性。讨论了这种自旋液态对几种实际体系，如CaV $_4$ V $_9$和Na $_2$ Sb $_2$ Ti $_2$ O的可能替代性.
The cradle of quantum spin liquids, triangular antiferromagnets show strong proclivity to magnetic order and require deliberate tuning to stabilize a spin-liquid state. In this brief review, we juxtapose recent theoretical developments that trace the parameter regime of the spin-liquid phase, with experimental results for Co-based and Yb-based triangular antiferromagnets. Unconventional spin dynamics arising from both ordered and disordered ground states is discussed, and the notion of a geometrically perfect triangular system is scrutinized to demonstrate non-trivial imperfections that may as…
Spiral spin liquids are unique classical spin liquids that occur in many frustrated spin systems, but do not comprise a new phase of matter. Owing to extensive classical ground-state degeneracy, the spins in a spiral spin liquid thermally fluctuate cooperatively from a collection of spiral configurations at low temperatures. These spiral propagation wavevectors form a continuous manifold in reciprocal space, \textit{i.e.}, a spiral contour or a spiral surface, that strongly governs the low-temperature thermal fluctuations and magnetic physics. In this paper, the relevant spin models conveying …
Low energy inelastic neutron scattering on single crystals of the kagome spin liquid compound ZnCu3(OD)6Cl2 (Herbertsmithite) reveals antiferromagnetic correlations between impurity spins for energy transfers E < 0.8 meV (~J/20). The momentum dependence differs significantly from higher energy scattering which arises from the intrinsic kagome spins. The low energy fluctuations are characterized by diffuse scattering near wavevectors (1 0 0) and (0 0 3/2), which is consistent with antiferromagnetic correlations between pairs of nearest neighbor Cu impurities on adjacent triangular (Zn) interlay…
A projective symmetry group (PSG) has been regarded as a classification theory of spin liquids. However, it does not include a symmetry-protected topological order of fermionic spinon excitations, and thus the classification of gapped spin liquids is incomplete. We demonstrate the classification beyond PSG by utilizing the Kitaev model on the squareoctagon lattice, where two gapped spin liquids are distinguished by a topological $Z_2$ invariant. This $Z_2$ invariant can be defined solely by the time-reversal and translation symmetries on condition that the time-reversal symmetry is implemented…
While phase transitions between magnetic analogs of three states of matter --- a long-range ordered state, paramagnet, and spin liquid --- have been extensively studied, the possibility of "liquid-liquid" transitions, namely, between different spin liquids, remains elusive. By introducing the additional Ising coupling into the honeycomb Kitaev model with bond asymmetry, we discover that the Kitaev spin liquid turns into a spin-nematic quantum paramagnet before a magnetic order is established by the Ising coupling. The quantum phase transition between the two liquid states accompanies a topolog…
We point out that the Kitaev materials may not necessarily support Kitaev spin liquid. It is well-known that having a Kitaev term in the spin interaction is not the sufficient condition for the Kitaev spin liquid ground state. Many other spin liquids may be stabilized by the competing spin interactions of the systems. We thus explore the possibilities of non-Kitaev spin liquids in the honeycomb Kitaev materials. We carry out a systematic classification of gapped $\mathbb{Z}_2$ spin liquids using the Schwinger boson representation for the spin variables. The presence of strong spin-orbit coupli…
Motivated by the recent progress on the spin-orbit-coupled triangular lattice spin liquid candidate YbMgGaO4, we carry out a systematic projective symmetry group analysis and mean-field study of candidate U(1) spin liquid ground states. Due to the spin-orbital entanglement of the Yb moments, the space group symmetry operation transforms both the position and the orientation of the local moments, and hence brings different features for the projective realization of the lattice symmetries from the cases with spin-only moments. Among the eight U(1) spin liquids that we find with the fermionic par…
Quantum spin liquids are long-range entangled phases whose magnetic correlations are determined by strong quantum fluctuations. While an overarching principle specifying the precise microscopic coupling scenarios for which quantum spin-liquid behavior arises is unknown, it is well-established that they are preferably found in spin systems where the corresponding classical limit of spin magnitudes $S\rightarrow\infty$ exhibits a macroscopic ground state degeneracy, so-called classical spin liquids. Spiral spin liquids represent a special family of classical spin liquids where degenerate manifol…
我们发现，在石墨烯中的局部相互作用允许半金属和反铁磁Mott绝缘相之间的新的自旋液体，分别与代数自旋液体和Z $_{2}$自旋液体。我们认为，代数自旋液体可以被看作是二维实现的一维自旋动力学，反铁磁相关显示完全相同的幂律依赖的价键相关。Z $_{2}$自旋液体的性质证明是$d + i d'$单线态配对，但保留了时间反演对称性，在一个谷中取$d + i d'$，在另一个谷中取$d - i d'$。我们提出量子化的热谷霍尔效应作为这种带隙自旋液态的一个基本特征。半金属、代数自旋液体和Z $_{2}$自旋液体之间的量子相变被证明是连续的，而从Z $_{2}$自旋液体到反铁磁莫特绝缘体的相变被证明是一阶的。我们强调，代数自旋液体和$d \pm id'$ Z $_{2}$自旋液体都可以通过量子蒙特卡罗模拟得到验证，显示了代数自旋液体中增强的对称性和Z $_{2}$自旋液体中量子化的热谷霍尔效应.
Kitaev's honeycomb lattice spin model is a remarkable exactly solvable model, which has a particular type of spin liquid (Kitaev spin liquid) as the ground state. Although its possible realization in iridates and $α$-RuCl$_3$ has been vigorously discussed recently, these materials have substantial non-Kitaev direct exchange interactions and do not have a spin liquid ground state. We propose metal-organic frameworks (MOFs) with Ru$^{3+}$ (or Os$^{3+}$) forming the honeycomb lattice as promising candidates for a more ideal realization of Kitaev-type spin models where the direct exchange interact…
Recently Han et al. have provided an analysis of the observed behavior of $\rm ZnCu_{3}(OH)_6Cl_2$ Herbertsmithite based on a separation of the contributions to its thermodynamic properties due to impurities from those due to the kagome lattice. The authors developed an impurity model to account for the experimental data and claimed that it is compatible with the presence of a small spin gap in the kagome layers. We argue that the model they advocate is problematic, conflicting with the intrinsic properties of $\rm ZnCu_{3}(OH)_6Cl_2$ as observed and explained in recent experimental and theore…
Na$_4$Ir$_3$O$_8$ provides a material platform to study three-dimensional quantum spin liquids in the geometrically frustrated hyperkagome lattice of Ir$^{4+}$ ions. In this work, we consider quantum spin liquids on hyperkagome lattice for generic spin models, focusing on the effects of anisotropic spin interactions. In particular, we classify possible $\mathbb{Z}_2$ and $U(1)$ spin liquid states, following the projective symmetry group analysis in the slave-fermion representation. There are only three distinct $\mathbb{Z}_2$ spin liquids, together with 2 different $U(1)$ spin liquids. The non…
Despite the apparent ubiquity and variety of quantum spin liquids in theory, experimental confirmation of spin liquids remains to be a huge challenge. Motivated by the recent surge of evidences for spin liquids in a series of candidate materials, we highlight the experimental schemes, involving the thermal Hall transport and spectrum measurements, that can result in smoking-gun signatures of spin liquids beyond the usual ones. For clarity, we investigate the square lattice spin liquids and theoretically predict the possible phenomena that may emerge in the corresponding spin liquids candidates…
Motivated by spin-wave continuum (SWC) observed in recent neutron scattering experiments in Herbertsmithite, we use Gutzwiller-projected wave functions to study dynamic spin structure factor $S(\mathbf{q},ω)$ of spin liquid states on the kagome lattice. Spin-1 excited states in spin liquids are represented by Gutzwiller-projected two-spinon excited wave functions. We investigate three different spin liquid candidates, spinon Fermi-surface spin liquid (FSL), Dirac spin liquid (DSL) and random-flux spin liquid (RSL). FSL and RSL have low energy peaks in $S(\mathbf{q},ω)$ at $K$ points in the ext…
Motivated by the recent proposal of the spinon Fermi surface spin liquids for several candidate materials such as YbMgGaO4, we explore the experimental consequences of the external magnetic fields on this exotic state. Specifically, we focus on the weak field regime where the spin liquid state is well preserved and the spinon remain to be a good description of the magnetic excitations. From the spin-1/2 nature of the spinon excitation, we predict the unique features of the spinon continuum when the weak magnetic field is applied to the system. Due to the small energy scale of the exchange inte…
Spin liquid is a state of electron spins in which quantum fluctuation breaks magnetic ordering while maintaining spin correlation. It has been a central topic in magnetism because of its relevance to high-Tc superconductivity and topological states. However, utilizing spin liquid has been quite difficult. Typical spin liquid states are realized in one-dimensional spin systems, called quantum spin chains. Here, we show that a spin liquid in a spin-1/2 quantum chain generates and carries spin current via its long-range spin fluctuation. This is demonstrated by observing an anisotropic negative s…
Quantum spin liquid states, in which spins are quantum-mechanically delocalized in direction, have been so far studied for charge-localized Mott insulators arising from strong repulsive interaction. Recently, however, it was found that the doped Mott insulator with a triangular lattice, $κ$-(ET)$_4$Hg$_{2.89}$Br$_8$, exhibits both spin-liquid-like magnetism and metallic electrical conduction. Thus, it is now possible to experimentally explore how the spin liquidity affects the electrical conduction, an issue that has received a great deal of theoretical attention. Here, with a newly developed …
A Fermi liquid with spin-orbit coupling (SOC) is expected to support a new kind of collective modes: oscillations of magnetization in the absence of the magnetic field. We show that these modes are damped by the electron-electron interaction even in the limit of an infinitely long wavelength (q = 0). The linewidth of the collective mode is on the order of Δ^2=E_F , where Δ is a characteristic spin-orbit energy splitting and E_F is the Fermi energy. Such damping is in a stark contrast to known damping mechanisms of both charge and spin collective modes in the absence of SOC, all of which disapp…
Quantum spin-liquid van der Waals magnets such as TaS$_2$, TaSe$_2$, and RuCl$_3$ provide a natural platform to explore new exotic phenomena associated with spinon physics, whose properties can be controlled by exchange proximity with ferromagnetic insulators such as CrBr$_3$. Here we put forward a twisted van der Waals heterostructure based on a quantum spin-liquid bilayer encapsulated between ferromagnetic insulators. We demonstrate the emergence of spinon flat bands and topological spinon states in such heterostructure, where the emergence of a topological gap is driven by the twist. We fur…
Spin liquid crystals are magnetic analogs of liquid crystals, possessing properties of both liquids and solids, a typical example of which are spin nematics. Spin nematics share many features with spin liquids, and the interplay between them is a promising, but little explored, route to uncovering new phases of matter. Here, we address this question in the context of a spin-$1$ magnet on the honeycomb lattice, by considering a model with both biquadratic interactions, favouring spin-nematic states, and Kitaev-like interactions, supporting spin liquids. Accompanying these, where dipole and quad…
By using the density matrix renormalization group, we study the spin-liquid phases of spin-$1/2$ XXZ kagome antiferromagnets. We find that the emergence of spin liquid phase does not depend on the anisotropy of the XXZ interaction. In particular, the two extreme limits---Ising (strong $S^z$ interaction) and XY (zero $S^z$ interaction)---host the same spin-liquid phases as the isotropic Heisenberg model. Both the time-reversal-invariant spin liquid and the chiral spin liquid with spontaneous time-reversal symmetry breaking are obtained. We show they evolve continuously into each other by tuning…
Recent theoretical studies have found quantum spin liquid states with spinon Fermi surfaces upon the application of a magnetic field on a gapped state with topological order. We investigate the thermal Hall conductivity across this transition, describing how the quantized thermal Hall conductivity of the gapped state changes to an unquantized thermal Hall conductivity in the gapless spinon Fermi surface state. We consider two cases, both of potential experimental interest: the state with non-Abelian Ising topological order on the honeycomb lattice, and the state with Abelian chiral spin liquid…
In quantum spin liquids, fractional spinon excitations carry half-integer spins and other fractional quantum numbers of lattice and time-reversal symmetries. Different patterns of symmetry fractionalization distinguish different spin liquid phases. In this work, we derive a general constraint on the symmetry fractionalization of spinons in a gapped spin liquid, realized in a system with an odd number of spin-$1/2$ per unit cell. In particular, when applied to kagome/triangular lattices, we obtain a complete classification of symmetric gapped $\mathbb{Z_2}$ spin liquids.
Frustrated magnetic systems exhibit many fascinating phases. Prime among them are quantum spin liquids, where the magnetic moments do not order even at zero temperature. A subclass of quantum spin liquids called Kitaev spin liquids are particularly interesting, because they are exactly solvable, can be realized in certain materials, and show a large variety of gapless and gapped phases. Here, we show that non-symmorphic symmetries can enrich spin liquid phases, such that the low-energy spinon degrees of freedom form three-dimensional Dirac cones or nodal chains. In addition, we suggest how suc…
Quantum spin systems are by now known to exhibit a large number of different classes of spin liquid phases. By contrast, for \textit{classical} Heisenberg models, only one kind of fractionalised spin liquid phase, the so-called Coulomb or $U(1)$ spin liquid, has until recently been identified: this exhibits algebraic spin correlations and impurity moments, `orphan spins', whose size is a fraction of that of the underlying microscopic degrees of freedom. Here, we present two Heisenberg models exhibiting fractionalisation in combination with exponentially decaying correlations. These can be thou…
We describe electron spin resonance in a quantum spin liquid with significant spin-orbit coupling. We find that the resonance directly probes spinon continuum which makes it an efficient and informative probe of exotic excitations of the spin liquid. Specifically, we consider spinon resonance of three different spinon mean-field Hamiltonians, obtained with the help of projective symmetry group analysis, which model a putative quantum spin liquid state of the triangular rare-earth antiferromagnet YbMgGaO4. The band of absorption is found to be very broad and exhibit strong van Hove singularitie…
Quantum spin liquid is an exotic quantum state of matter in magnets. This state is a spin analogue of the liquid helium which does not solidify down to the lowest temperature due to strong quantum fluctuations. In conventional fluids, liquid and gas possess the same symmetry and adiabatically connect to each other by bypassing the critical end point. We find that the situation is qualitatively different in quantum spin liquids realizing in a three-dimensional Kitaev model; both gapless and gapped quantum spin liquid phases at low temperatures are always distinguished from the high-temperature …
We numerically study the Heisenberg models on triangular lattices by extending it from the simplest equilateral lattice with only the nearest-neighbor exchange interaction. We show that, by including an additional weak next-nearest-neighbor interaction, a quantum spin-liquid phase is stabilized against the antiferromagnetic order. The spin gap (triplet excitation gap) and spin correlation at long distances decay algebraically with increasing system size at the critical point between the antiferromagnetic phase and the spin-liquid phase. This algebraic behavior continues in the spin-liquid phas…
Recent experiments suggest a quantum spin liquid ground state in the material PbCuTe$_2$O$_6$, where $S=1/2$ moments are coupled by antiferromagnetic Heisenberg interactions into a three dimensional structure of corner sharing triangles dubbed the hyper-hyperkagome lattice. It exhibits a richer connectivity, and thus likely a stronger geometric frustration, than the relatively well studied hyperkagome lattice. Here, we investigate the possible quantum spin liquids in the $S=1/2$ hyper-hyperkagome magnet using the complex fermion mean field theory. Extending the results of a previous projective…
We study the effects of bond randomness in the spin-$1/2$ $J_1-J_2$ triangular Heisenberg model using exact diagonalization and density matrix renormalization group. With increasing bond randomness, we identify a randomness induced spin-liquid-like phase without any magnetic order, dimer order, spin glass order, or valence-bond glass order. The finite-size scaling of gaps suggests the gapless nature of both spin triplet and singlet excitations, which is further supported by the broad continuum of dynamical spin structure factor. By studying the bipartite entanglement spectrum of the system on …
In this paper, we explore the relationship between strong spin-orbit coupling and spin liquid physics. We study a very general model on the triangular lattice where spin-orbit coupling leads to the presence of highly anisotropic interactions. We use variational Monte Carlo to study both $U(1)$ quantum spin liquid states and ordered ones, via the Gutzwiller projected fermion construction. We thereby obtain the ground state phase diagram in this phase space. We furthermore consider effects beyond the Gutzwiller wavefunctions for the spinon Fermi surface quantum spin liquid, which are of particul…
We show that the best variational ground state of the spin-$\frac{1}{2}$ Kagome antiferromagnetic Heisenberg model with nearest-neighboring exchange coupling(NN-KAFH) is a $Z_{2}$ spin liquid state, rather than the widely believed $U(1)$ Dirac spin liquid state. The spinon excitation in the $Z_{2}$ spin liquid state has a small gap of about $1/40$ of the spinon band width. We find that while the $Z_{2}$ and the $U(1)$ spin liquid state have a large overlap on finite clusters and are thus very close in energy, they host totally different spinon excitation spectrum. The strength of the RVB theor…
The spin liquid phase is one of the prominent strongly interacting topological phases of matter whose unambiguous confirmation is yet to be reached despite intensive experimental efforts on numerous candidate materials. Recently, a new family of correlated honeycomb materials, in which strong spin-orbit coupling allows for various bond-dependent spin interactions, have been promising candidates to realize the Kitaev spin liquid. Here we study a model with bond-dependent spin interactions and show numerical evidence for the existence of an extended quantum spin liquid region, which is possibly …
Topological spin liquids in two spatial dimensions are stable phases in the presence of a small magnetic field, but may give way to field-induced phenomena at intermediate field strengths. Sandwiched between the low-field spin liquid physics and the high-field spin-polarized phase, the exploration of magnetic phenomena in this intermediate regime however often remains elusive to controlled analytical approaches. Here we numerically study such intermediate-field magnetic phenomena for two representative Kitaev models (on the square-octagon and decorated honeycomb lattice) that exhibit either Ab…
In quasi-1D conducting nanowires spin-orbit coupling destructs spin-charge separation, intrinsic to Tomonaga-Luttinger liquid (TLL). We study renormalization of a single scattering impurity in a such liquid. Performing bosonization of low-energy excitations and exploiting perturbative renormalization analysis we extend the phase portrait in $K_s$ - $K_c$ space, obtained previously for TLL with decoupled spin-charge channels.
Spin systems with frustrated anisotropic interactions are of significant interest due to possible exotic ground states. We have explored their phase diagram on a nearest-neighbor triangular lattice using the density-matrix renormalization group and mapped out the topography of the region that can harbor a spin liquid. We find that this spin-liquid phase is continuously connected to a previously discovered spin-liquid phase of the isotropic $J_1\!-\!J_2$ model. The two limits show nearly identical spin correlations, making the case that their respective spin liquids are isomorphic to each other…
Metallic spin liquid has been reported in several correlated metals, but a satisfactory theoretical description is not yet available. Here we propose a potential route to realize the metallic spin liquid and construct an effective $\mathbb{Z}_2$ gauge theory with charged fractionalized excitations on the triangular Kondo lattice. This leads to a $\mathbb{Z}_2$ metallic spin liquid featured with long-lived, heavy holon excitations of spin 0 and charge $+e$ and a partially enlarged electron Fermi surface. It differs from the weak-coupling FL$^*$ state proposed earlier and may be viewed as a frac…
Mott insulators under sufficiently strong spin-orbit coupling can display quantum spin liquid phases with topological order and fractional excitations. Quantum magnets with pure Kitaev spin exchange interactions can host a gapped quantum spin liquid with a single Majorana edge mode propagating in the counter-clockwise direction when a small positive magnetic field is applied. Here, we show how under a sufficiently strong positive magnetic field a topological transition into a gapped quantum spin liquid with two Majorana edge modes propagating in the clockwise direction occurs. The Dzyaloshinsk…
