The modern understanding of topological insulators is based on Wannier obstructions in position space. Motivated by this insight, we study topological superconductors from a position-space perspective. For a one-dimensional superconductor, we show that the wave function of an individual Cooper pair decays exponentially with separation in the trivial phase and polynomially in the topological phase. For the position-space Majorana representation, we show that the topological phase is characterized by a nonzero Majorana polarization, which captures an irremovable and quantized separation of Majorana Wannier centers from the atomic positions. We apply our results to diagnose second-order topological superconducting phases in two dimensions. Our work establishes a vantage point for the generalization of Topological Quantum Chemistry to superconductivity.
The coexistence of superconductivity and ferromagnetism has brought about the phenomena of ferromagnetic superconductors. The theory needed to understand the compatibility of such antagonistic phenomena cannot be built until the pairing symmetry of such superconductors is correctly identified. The proper and unambiguous identification of the pairing symmetry of such superconductors is the subject of this paper. This work shows that crossed Andreev reflection can be a very effective tool in order to identify the pairing symmetry of these superconductors.
We have investigated the proximity effect in superconductor/ferromagnet junctions in a systematic manner to discuss the relationship between the zero-energy peak (ZEP) of the local density of states (LDOS) and spin-triplet odd-frequency pairing. By exactly solving the nonlinear Usadel equations, we have found that the ZEP is realized in a wide range of geometrical and material parameters in the case of the noncollinear magnetization. This strongly suggests the robustness of the ZEP induced by spin-triplet odd-frequency pairing in such systems. We also found that the crossover from singlet pair…
We study the behavior of Cooper pair amplitudes that emerge when a two-dimensional superconductor is coupled to two parallel nanowires, focusing on the conditions for realizing odd-frequency pair amplitudes in the absence of spin-orbit coupling or magnetism. In general, any finite tunneling between the superconductor and the two nanowires induces odd-frequency spin-singlet pair amplitudes in the substrate as well as a substantial odd-frequency interwire pairing, both of which vanish locally. Interestingly, in the regime of strong superconductor-nanowire tunneling, we find that the presence of …
We analyze the effect of magnetic fluctuations in superconductors with strong spin-orbit coupling and show that they drive a phase transition between two superconducting states: a conventional phase with zero center-of-mass momentum of Cooper pairs, and an exotic phase with non-zero pair momentum. The latter is found to exhibit persistent currents without magnetic field in doubly connected geometries such as rings. Surprisingly, the transition temperature into the superconducting state can be increased by applying a Zeeman magnetic field.
Fingerprints of unconventional pairing in superconductor-hole-gas heterostructures
Institute of Science and Technology Austria (ISTA)（奥地利科学技术研究所）；Niels Bohr Institute, University of Copenhagen（哥本哈根大学尼尔斯·玻尔研究所）；Department of Physics, Norwegian University of Science and Technology（挪威科技大学物理系）
Superconductors with unconventional pairings have been a fascinating subject of research, for which a central issue is to explore effects that can be used to characterize the pairing. The process of Andreev reflection--the reflection of an electron as a hole at a normal-mental-superconductor interface by transferring a Cooper pair into the superconductor--offers a basic mechanism to probe the pairing through transport. Here we predict that in Andreev reflection from unconventional superconductors, the reflected hole acquires an anomalous spatial shift normal to the plane of incidence, arising …
The topological approach to the understanding of pairing mechanism in high $T_c$ superconductors analyses the relevance of the Berry phase factor in this context. This also gives the evidence for the pairing mechanism to be of magnetic origin.
Phase-sensitive tests of pairing symmetry have provided strong evidence for predominantly d-wave pairing symmetry in both hole- and electron-doped high-Tc cuprate superconductors. Temperature dependent measurements in YBCO indicate that the d-wave pairing dominates, with little if any imaginary component, at all temperatures from 0.5K through Tc. In this article we review some of this evidence and discuss the implications of the universal d-wave pairing symmetry in the cuprates.
Motivated by the fully gapped superconductivity in iron-based superconductors with uncompensated electron pockets, we propose a spin singlet, but orbital triplet analogue of the superfluid phase of He-3B. We show that orbital triplets with a nominal d-wave symmetry at the iron sites can transform as s-wave pairs under rotations about the selenium sites. Linear combinations of such d$_{xy}$ and d$_{x^{2}-y^{2}}$ triplets form a fully gapped, topological superconductor. Raman-active excitations are predicted to develop below the superconducting transition temperature.
We present the self-consistent Bogoliubov-de Gennes calculations of an $sπ$ pairing state of two band superconductivity as a model for the FeAs superconductors. The $sπ$ state is an s-wave pairing state with an internal $π$ phase, that is, nodeless gaps on each band but with the opposite sign. The novel features of this state are investigated by calculating the local density of states of the $π$ phase superconductor/normal metal bilayers. Because of the sign reversal between the two condensates, the zero bias conductance peak appears as observed in tunneling spectroscopy experiments on FeAs su…
We theoretically study the effects of spin-orbit interactions on symmetry of a Cooper pair in a spin-singlet d-wave superconductor in two-dimension. The pairing symmetry is analyzed in terms of the anomalous Green's function which is obtained by solving the Gor'kov equation analytically. A spin-orbit interaction induces a spin-triplet p-wave pairing correlation in a uniform superconductor. An odd-frequency spin-triplet s-wave pairing correlation appears at a surface of such superconductor as a result of breaking inversion symmetry locally. We also discuss a close relationship among the odd-fre…
Using selection rules imposed by the Pauli principle, we classify pairing correlations according to their symmetry properties with respect to spin, momentum, and energy. We observe that inhomogeneity always leads to mixing of even- and odd-energy pairing components. We investigate the superconducting pairing correlations present near interfaces between superconductors and ferromagnets, with focus on clean systems consisting of singlet superconductors and either weak or half-metallic ferromagnets. Spin-active scattering in the interface region induces all of the possible symmetry components. In…
Quasi-low-dimensional type II superconductors in parallel magnetic fields are studied when singlet pairing interactions and relatively weak triplet pairing interactions coexist. Singlet and triplet components of order parameter are mixed at high fields, and at the same time an inhomogeneous superconducting state called a Fulde-Ferrell-Larkin-Ovchinnikov state occurs. As a result, the triplet pairing interactions enhance the upper critical field of superconductivity remarkably even at temperatures far above the transition temperature of parallel spin pairing. It is found that the enhancement is…
Since the discovery of high Tc iron-based superconductors in early 2008, more than 15,000 papers have been published as a result of intensive research. This paper describes the current status of iron-based superconductors (IBSC) covering most up-to-date research progress along with the some background research, focusing on materials (bulk and thin film) and pairing mechanism.
We study tunneling conductance in normal metal / insulator / ferromagnetic superconductor junctions. The tunneling spectra show a clear difference between spin-singlet s-wave pairing, spin-triplet opposite spin pairing and spin-triplet equal spin pairing: These pairings exhibit, respectively, gap struture, double peak structure and zero bias peak in the spectra. The obtained result may serve as a tool for determining the pairing symmetry of ferromagnetic superconductors.
The single impurity effect on the graphene-based superconductor is studied theoretically. Four different pairing symmetries are discussed. Sharp resonance peaks are found near the impurity site for the $d+id$-wave pairing symmetry and the $p+ip$-wave pairing symmetry when the chemical potential is large. As the chemical potential decreases, the in-gap states are robust for the $d+id$ pairing symmetry while they disappear for the $p+ip$ pairing symmetry. Such in-gap peaks are absent for the fully gapped extended $s$-wave pairing symmetry and the nodal $f$-wave pairing symmetry. The existence of…
We point out that essentially all multi-band superconductors have an odd-frequency pairing component, as follows from a general symmetry analysis of even- and odd-frequency pairing states. We show that odd-frequency superconducting pairing requires only a finite band hybridization, or scattering, and non-identical intraband order parameters, of which only one band needs to be superconducting. Under these conditions odd-frequency odd-interband pairing is always present. From a symmetry analysis we establish a complete reciprocity between parity in band-index and frequency.
We explore the role of proximity-induced odd-frequency pairing in the thermoelectricity of a ferromagnet when coupled to a conventional $s$-wave spin-singlet superconductor through a spin-active interface. By varying both the polarization and its direction in the ferromagnet and the interfacial spin-orbit interaction strength, we analyze the behavior of all proximity-induced pair amplitudes in the ferromagnet and their contributions to the thermoelectric coefficients. Based on our results for the Seebeck coefficient, we predict that odd-frequency spin-triplet Cooper pairs are much efficient th…
We apply the fermion functional renormalization group method to determine the pairing symmetry and pairing mechanism of the FeAs-Based materials. Within a five band model with pure repulsive interactions, we find an electronic-driven superconducting pairing instability. For the doping and interaction parameters we have examined, extended s-wave, whose order parameter takes on opposite sign on the electron and hole pockets, is always the most favorable pairing symmetry. The pairing mechanism is the inter Fermi surface Josephson scattering generated by the antiferromagnetic correlation.
We study subgap states induced by a single impurity in an s-wave superconductor with suppressed pairing. For concreteness, we consider a bulk superconductor containing a normal spherical region. We find that a point impurity in this system induces two Yu-Shiba-Rusinov states inside the minigap instead of one, which one would have in a homogeneous superconductor. Moreover, the subgap states appear even if the impurity is nonmagnetic. We prove that this result actually holds almost for any superconductor with a real and spatially inhomogeneous order parameter, if the quasiparticle spectrum is ga…
Probing Sign-Changing Order Parameters via Impurity States in unconventional superconductors: Implications for La$_3$Ni$_2$O$_7$ Superconductors with interlayer pairing
The possible pairing symmetries for BiS$_{2}-$based superconductors is investigated by using a minimal two-orbital model with onsite and nearest-neighbor intraorbital attractions $V_{0}$ and $V_{1}$, respectively. By using the mean-field approximation and solving the self-consistent equations, the phase diagram of the pairing symmetry is obtained. It is shown that the model allows three possible pairing symmetries, depending on the values of $V_{0}$ and $V_{1}$: the isotopic $s-$wave pairing [$Δ_{\mathbf{k}}=Δ_{s}$], the anisotropic $s-$wave pairing [$Δ_{\mathbf{k}}=Δ_{s}+\frac{Δ_{xs}}{2}(\cos…
We study the effect of site diagonal disorder on the pairing amplitude by a perturbation method. Using an extended Hubbard model with the intersite attraction we analyze fluctuations of order parameter in presence of non-magnetic disorder and discuss the instability of various solutions with p-wave paring.
Conventional topological superconductors are fully gapped in the bulk but host gapless Majorana modes on their boundaries. We instead focus on a new class of superconductors, second-order topological superconductors, that have gapped, topological surfaces and gapless Majorana modes instead on lower-dimensional boundaries, i.e., corners of a two-dimensional system or hinges for a three-dimensional system. Here we propose two general scenarios in which second-order topological superconductivity can be realized spontaneously with weak-pairing instabilities. First, we show that $p_x+ip_y$-wave pai…
Within the spin-fermion model for cuprate superconductors, the influence of the intersite Coulomb interactions $V_2$ and $V_2'$ between holes located at the next-nearest-neighbor oxygen ions of CuO$_2$ plane on the implementation of the d_{x^2-y^2}-wave pairing is studied. It is shown that d-wave pairing can be suppressed only for unphysically large values of $V_2$ and $V_2'$.
By applying an exact unitary transformation to a two-band hamiltonian which also includes the effects due to large pnictogen polarizabilities, we show that an attractive spin-mediated Hubbard term appears in the $d_{xz}$, $d_{yz}$ nearest-neighbour channel. This pairing mechanism implies a singlet superconducting order parameter in iron pnictides.
A prime category of superconducting materials in which to look for spin-triplet pairing and topological superconductivity are superconductors without inversion symmetry. It is predicted that the breaking of parity symmetry gives rise to an admixture of spin-singlet / spin-triplet pairing states; a triplet pairing component, being substantial, seems all but guaranteed. However, the experimental confirmation of pair mixing in any particular material remains elusive. In this work, we perform phase-sensitive experiment to examine the pairing state of noncentrosymmetric superconductor $α-$BiPd. The…
A review is given on theoretical studies concerning the pairing symmetry in organic superconductors. In particular, we focus on (TMTSF)$_2$X and $κ$-(BEDT-TTF)$_2$X, in which the pairing symmetry has been extensively studied both experimentally and theoretically. Possibilities of various pairing symmetry candidates and their possible microscopic origin are discussed. Also some tests for determining the actual pairing symmtery are surveyed.
We theoretically propose a method to identify $\pm s$-wave order parameter in recently discovered Fe-pnictide superconductors. Our idea uses the Riedel anomaly in ac-Josephson current through an SI($\pm$ S) (single-band s-wave superconductor/insulator/$\pm$s-wave two-band superconductor) junction. We show that the Riedel peak effect leads to vanishing ac-Josephson current at some values of biased voltage. This phenomenon does not occur in the case when the $\pm s$-wave superconductor is replaced by a conventional s-wave one, so that the observation of this vanishing Josephson current would be …
One of the outstanding problems in Iron pnictide research is the unambiguous detection of its pairing symmetry. The most probable candidates are the two-band s$++$ and sign reversed s$\pm$ wave pairing. In this work, the Andreev conductance and shot noise are used as a probe for the pairing symmetry of Iron pnictide superconductors. Clear differences emerge in both the zero bias differential conductance and the shot noise in the tunneling limit for the two cases enabling an effective distinction between the two.
We study the momentum-integrated quasiparticle interference (QPI) in the FeSe-based superconductors. This method was recently proposed theoretically and has been applied to determine the pairing symmetry in these materials experimentally. Our findings suggest that, if the incipient bands and the superconducting (SC) pairing on them are taken into consideration, then the experimentally measured bound states and momentum-integrated QPI can be well fitted, even if the SC order parameter does not change sign on the Fermi surfaces. Therefore, we offer an alternative explanation to the experimental …
We propose a method for an analysis of the angle-resolved photoemission data in two-dimensional anisotropic superconductors which directly yields the spectral function of the bosons mediating Cooper pairing. The method includes a self-consistency check for the validity of the approximations made in the analysis. We explicitly describe the experimental data needed for implementing the proposed procedure.
Contrary to the usual assumption, the electron Bloch states in crystals with spin-orbit coupling do not always transform under symmetry operations in the same way as the pure spin-1/2 states. This has profound consequences for the symmetry properties and nodal structure of superconductors, especially for the interband gap functions. Focusing on tetragonal superconductors, we show that the interband pairing in the conventional (s-wave) channel can have features which are traditionally associated with unconventional pairing, such as triplet components and odd parity, and can produce line nodes i…
In this paper we present a real space pairing glue for the iron-based layered superconductors. It is shown that two static electrons embedded symmetrically into two adjacent Fe plaquettes of the superconductor can be bounded due to the Coulombic interaction. The pairing mechanism favors the existence of the pseudogap in the underdoped FeAs superconductors. A criterion is introduced to distinguish whether or not the pseudogap can open in a material.
The spin susceptibility in the uranium ferromagnet superconductors is calculated. There is shown that the absence of superconductivity paramagnetic limitation for the field directions perpendicular to the direction of the spontaneous magnetization is explained by the itinerant ferromagnet band splitting rather than by a rotation of magnetization toward the external field direction. The qualitative description of the upper critical field temperature dependence is given.
In this work, we establish a few exact identities through commutation of intra-orbital and inter-orbital on-site pairings with a two-orbital model describing newly discovered FeAs-based superconductors. Applying the conclusion drawn from rigorous relation and physical interpretation, we give constraints on the possible symmetries of the superconducting pairing of the model. Hence the favorable pairings in newly discovered high-temperature oxypnictide superconductors are proposed.
Starting from a two-orbital model and based on the random phase approximation, spin excitations in the superconducting state of the newly discovered BiS$_2$ superconductors with three possible pairing symmetries are studied theoretically. We show that spin response is uniquely determined by the pairing symmetry. Possible spin resonance excitations might occur for the d-wave symmetry at an incommensurate momentum about $(0.7π,0.7π)$. For the p-wave symmetry the transverse spin excitation near $(0,0)$ is enhanced. For the s-wave pairing symmetry there is no spin resonance signature. These distin…
A theoretical study is presented on the odd-frequency spin-singlet pairing that arises in nonuniform even-frequency superconductors as a consequence of broken translation symmetry. The effect of the odd-frequency pairing on the superfluid density and the spin susceptibility is analyzed by using the quasiclassical theory of superconductivity. It is shown that (1) the superfluid density is reduced by the formation of the odd-frequency singlet pairs and (2) the odd-frequency pairing increases the spin susceptibility even though its spin symmetry is singlet. The two unusual phenomena are related t…
We investigate the competition between the extended $s_{\pm}$-wave and $d_{x^2-y^2}$-wave pairing order parameters in the iron-based superconductors. Because of the frustrating pairing interactions among the electron and the hole fermi pockets, a time reversal symmetry breaking $s+id$ pairing state could be favored. We analyze this pairing state within the Ginzburg-Landau theory, and explore the experimental consequences. In such a state, spatial inhomogeneity induces supercurrent near a non-magnetic impurity and the corners of a square sample. The resonance mode between the $s_{\pm}$ and $d_{…
We propose an effective single-band model for the newly discovered iron selenide superconductors A$_x$Fe$_{2-y}$Se$_2$ (A=Tl,K,Rb,Cs). Based on this minimum model and the random phase approximation, the $d_{x^2-y^2}$ pairing symmetry is revealed theoretically, which may be understood in the framework of Fermi surface topology. A common origin of superconductivity is elucidated for this compound and other high-T$_c$ materials. The spin excitations at $(π,π/2)$ in superconducting states are observed, in good agreement with the neutron scattering experiments. The spin resonance is indicated to sh…
We present a relativistic symmetry analysis of the allowed pairing states in the noncentroymmetric superconductor LaNiC$_2$. The case of zero spin-orbit coupling (SOC) is discussed first and then the evolution of the symmetry-allowed superconducting instabilities as SOC is adiabatically turned on is described. In addition to mixing singlet with triplet pairing, SOC splits some triplet pairing states with degenerate order parameter spaces into non-degenerate pairing states with different critical temperatures. We address the breaking of time-reversal symmetry (TRS) detected in recent muon spin …
We show that the phase information contained in coherent phonon oscillations generated by a laser pulse in a multi- orbital superconductor can be used as an experimental tool to probe super- conductivity and pairing symmetries. The phase difference between the normal and superconducting states is proportional to the superconducting order parameter just below the superconducting transition temperature, Tc. It also exhibits different behaviors for superconducting states with different pairing symmetries. In particular, if there is an orbital-dependent internal sign change state, the phase differ…
We use the microscopic weak coupling theory to predict the pairing state in superconductors of cubic, hexagonal, or tetragonal symmetry, where the order parameter is multicomponent, i.e., transforms according to either a 2-dimensional or a 3-dimensional representation of the crystal point group. We show that the superconducting phase usually breaks the time-reversal symmetry for singlet multicomponent superconductors. The superconducting order parameter for triplet superconductors in most cases turns out to be non-magnetic.
Results are presented for the temperature and frequency dependence of the real and imaginary parts of the diagonal self energy for a d-wave superconductor. An Eliashberg analysis, which has been successful in recent fitting of superconductor-insulator-superconductor tunnel junction conductances for BiSrCaCuO (Bi-2212), is extended to finite temperatures. The effect of the temperature dependence of the 40 meV spin resonance mode, measured in inelastic neutron scattering (INS) in Bi-2212, on the finite temperature self energies is investigated.
The spin-fluctuation based pairing mechanism has proven successful in explaining the pairing symmetries due to Fermi surface nesting of both cuprates and iron-based materials. In this work, we study signatures of a spin-fluctuation mediated pairing at the local scale. Specifically, we focus on magnetic impurities and calculate both the local antiferromagnetism and the resulting modulated pairing interaction. The latter gives rise to distinct local enhancements of the superconducting gap in the immediate vicinity of the impurities. Our results show that Coulomb-driven pairing naturally leads to…
A phenomenological theory of tunneling spectroscopy for Fe-pnictide superconductors is developed by taking into consideration of asymmetric interface scattering between particle and holes. It is shown that in consistent with anti-phase $s^{\pm}$-wave pairing, appreciable zero-energy surface bound states exist on the [100] surface of Fe-pnictide superconductors. However, in contrast to the [110] bound states in $d$-wave cuprate superconductors, these bound states arise as a result of non-conservation of momentum perpendicular to the interface for tunneling electrons and the $s^{\pm}$ pairing, a…
We suggest a mechanism which promotes the existence of a phase soliton -- topological defect formed in the relative phase of superconducting gaps of a two-band superconductor with s+- type of pairing. This mechanism exploits the proximity effect with a conventional s-wave superconductor which favors the alignment of the phases of the two-band superconductor which, in the case of s+- pairing, are pi-shifted in the absence of proximity. In the case of a strong proximity such effect can be used to reduce soliton's energy below the energy of a soliton-free state thus making the soliton thermodynam…
Pairing symmetry is important to indentify the pairing mechanism. The analysis becomes particularly timely and important for the newly discovered iron-based multi-orbital superconductors. From group theory point of view we classified all pairing matrices (in the orbital space) that carry irreducible representations of the system. The quasiparticle gap falls into three categories: full, nodal and gapless. The nodal-gap states show conventional Volovik effect even for on-site pairing. The gapless states are odd in orbital space, have a negative superfluid density and are therefore unstable. In c…
We study theoretically single-particle spectra of Weyl superconductors. Three different superconducting pairing states are addressed, which are the BCS-type states with the $s$-wave pairing symmetry and the $p+ip$-wave pairing symmetry, and the FFLO pairing state. We elaborate that these three states can be resolved well based on the bulk and surface spectral functions as well as the local density of states. The single impurity effect is also explored, which may help us to differentiate the BCS-type pairing states and the FFLO state further.
We study the effect of a single non-magnetic impurity in A$_{y}$Fe$_{2-x}$Se$_{2}$ (A=K, Rb, or Cs) superconductors by considering various pairing states based on a three-orbital model consistent with the photoemission experiments. The local density of states on and near the impurity site has been calculated by solving the Bogoliubov-de Gennes equations self-consistently. The impurity-induced in-gap bound states are found only for attractive impurity scattering potential, as in the cases of doping of Co or Ni, which is characterized by the strong particle-hole asymmetry, in the nodeless $d_{x^…
Theoretical studies of a planar tunnel junction between two superconductors with antisymmetric spin-orbit coupling are presented. The half-space Green's function for such a superconductor is determined. This is then used to derive expressions for the dissipative current and the Josephson current of the junction. Numerical results are presented in the case of the Rashba spin-orbit coupling, relevant to the much studied compound CePt$_3$Si. Current-voltage diagrams, differential conductance and the critical Josephson current are presented for different crystallographic orientations and different…
The discovery of the new class of pnictide superconductors has engendered a controversy about their pairing symmetry, with proposals ranging from an extended s-wave or "s$_{\pm}$" symmetry to nodal or nodeless d-wave symmetry to still more exotic order parameters such as p-wave. In this paper, building on the earlier, similar work performed for the cuprates, we propose several phase-sensitive Josephson interferometry experiments, each of which may allow resolution of the issue.
Measurements of transport properties of amorphous insulating indium oxide thin films have been interpreted as evidence of the presence of superconducting islands on the insulating side of a disorder-tuned superconductor-insulator transition. Although the films are not granular, the behavior is similar to that observed in granular films. The results support theoretical models in which the destruction of superconductivity by disorder produces spatially inhomogenous pairing with a spectral gap.
