We investigate the competition between the extended $s_{\pm}$-wave and $d_{x^2-y^2}$-wave pairing order parameters in the iron-based superconductors. Because of the frustrating pairing interactions among the electron and the hole fermi pockets, a time reversal symmetry breaking $s+id$ pairing state could be favored. We analyze this pairing state within the Ginzburg-Landau theory, and explore the experimental consequences. In such a state, spatial inhomogeneity induces supercurrent near a non-magnetic impurity and the corners of a square sample. The resonance mode between the $s_{\pm}$ and $d_{x^2-y^2}$-wave order parameters can be detected through the $B_{1g}$-Raman spectroscopy.
Recent observations of two nodeless gaps in superconducting CeCu$_2$Si$_2$ have raised intensive debates as to its exact gap structure of either sign-reversal ($s^{+-}$) or sign-preserving ($s^{++}$) pairing. Here we investigate the quasiparticle interference (QPI) using realistic Fermi surface topology for both weak and strong interband impurity scatterings. Our calculations of the QPI and integrated antisymmetrized local density of states reveal qualitative distinctions between $s^{+-}$ and $s^{++}$ pairing states, which include the intragap impurity resonance and a significant energy-depend…
Noncentrosymmetric superconductors have sparked significant research interests due to their exciting properties, such as the admixture of spin-singlet and spin-triplet Cooper pairs. Here we report $μ$SR and thermodynamic measurements on the noncentrosymmetric superconductor La7Rh3 which indicate a fully established superconducting gap and spontaneous time-reversal-symmetry breaking at the onset of superconductivity. We show that our results pose severe constraints on any microscopic theory of superconductivity in the system. A symmetry analysis identifies ground states compatible with time-rev…
We report the results of a zero-field muon spin relaxation (ZF-muSR) study of superconducting Ba1-xKxFe2As2 (0.5 < x < 0.9) in search of weak spontaneous internal magnetic fields associated with proposed time-reversal-symmetry breaking mixed pairing states. The measurements were performed on polycrystalline samples, which do not exhibit the mesoscopic phase separation previously observed in single crystals of Ba1-xKxFe2As2. No evidence of spontaneous internal magnetic fields is found in any of the samples at temperatures down to T ~ 0.02 K.
We study time-reversal-invariant topological superconductivity in topological insulator (TI) thin films including both intra- and inter-surface pairing. We find a nontrivial topology for multiple different configurations. For intra-surface pairing a $π$-phase difference between the intra-surface pairing states is required. We show that in this case the resulting topological phase is highly tunable by both an applied electric field and varied chemical potential. For spin-singlet inter-surface pairing, a sign-changing tunnel coupling present in many TI thin films is needed, and again, the topolo…
A detailed analysis of the symmetric tetracrystal geometry used in phase-sensitive pairing symmetry experiments on high Tc superconductors is carried out for both bulk and surface time-reversal symmetry-breaking states, such as the d+id' and d+is states. The results depend critically on the substrate geometry. In the general case, for the bulk d+id' (or d+is) state, the measured flux quantization should in general not be too different from that obtained in the pure d-wave case, provided |d'| << |d| (or |s| << |d|). However, in one particular high symmetry geometry, the d+id' state gives result…
The low energy band structure of the FeAs based superconductors is fitted by a tight binding model with two Fe ions per unit cell and two degenerate orbitals per Fe ion. Based on this, superconductivity with extended s-wave pairing symmetry of the form $\cos k_x +\cos k_y$ is examined. The local density of states near an impurity is also investigated by using T-matrix approach. For the nonmagnetic scattering potential, we found that there exist two major resonances inside the gap. The height of the resonance peaks depends on the strength of the impurity potential. These in-gap resonances are o…
We calculate the tunneling conductance spectra of a ferromagnetic metal/insulator/superconductor using the Blonder-Tinkham-Klapwijk (BTK) formulation. Two possible states for the superconductor are considered with the time reversal symmetry ($\cal{T}$) broken, i.e., $d_{x^2-y^2}+is$, or $d_{x^2-y^2}+id_{xy}$. In both cases the tunneling conductance within the gap is suppressed with the increase of the exchange interaction due to the suppression of the Andreev reflection. In the $(d_{x^2-y^2}+is)$-wave case the peaks that exist when the ferromagnet is a normal metal in the amplitude of the s-wa…
Geometrical frustration leads to novel quantum phenomena such as the spin-liquid phase in triangular and Kagomé lattices. Intra-band and inter-band Fermi surface (FS) nesting can drive unique superconducting (SC) ground states with $d$-wave and $s^{\pm}$ pairing symmetries, respectively, according to the criterion that the SC gap changes sign across the nesting wavevector. For an odd number of FSs, when multiple inter-band nesting is of comparable strength, the sign-reversal criterion between different FS sheets can leads to frustration, which promotes novel SC order parameters. Here we report…
We apply the fermion functional renormalization group method to determine the pairing symmetry and pairing mechanism of the FeAs-Based materials. Within a five band model with pure repulsive interactions, we find an electronic-driven superconducting pairing instability. For the doping and interaction parameters we have examined, extended s-wave, whose order parameter takes on opposite sign on the electron and hole pockets, is always the most favorable pairing symmetry. The pairing mechanism is the inter Fermi surface Josephson scattering generated by the antiferromagnetic correlation.
We investigate pairing states realized at the (001) interface of a spin-triplet superconductor Sr$_2$RuO$_4$ on the basis of microscopic calculations. Because of a Rashba-type spin-orbit interaction induced at the interface, strong parity-mixing of Cooper pairs between a spin-singlet state and a spin-triplet state occurs in this system. There are also strong inter-band pair correlations between the spin-orbit split bands, in spite of the considerably large spin-orbit splitting. This is due to frustration between the spin-orbit interaction and pairing interactions. In this pairing state, time-r…
A time reversal invariant (TRI) topological superconductor has a full pairing gap in the bulk and topologically protected gapless states on the surface or at the edge. In this paper, we show that in the weak pairing limit, the topological quantum number of a TRI superconductor can be completely determined by the Fermi surface properties, and is independent of the electronic structure away from the Fermi surface. In three dimensions (3D), the integer topological quantum number in a TRI superconductor is determined by the sign of the pairing order parameter and the first Chern number of the Berr…
The multipocket Fermi surfaces of iron-based superconductors promote pairing states with both s_{+-}-wave and d_{x^2-y^2}-wave symmetry. We argue that the competition between these two order parameters could lead to a time-reversal-symmetry breaking state with s+id-pairing symmetry in the iron-based superconductors, and propose serveral scenarios in which this phase may be found. To understand the emergence of such a pairing state on a more rigorous footing, we start from a microscopic 5-orbital description representative for the pnictides. Using a combined approach of functional renormalizati…
We propose a modified Josephson corner-junction experiment which can test whether the order parameter in the iron pnictides changes sign between the electron and hole pockets of the Fermi surface.
We present the self-consistent Bogoliubov-de Gennes calculations of an $sπ$ pairing state of two band superconductivity as a model for the FeAs superconductors. The $sπ$ state is an s-wave pairing state with an internal $π$ phase, that is, nodeless gaps on each band but with the opposite sign. The novel features of this state are investigated by calculating the local density of states of the $π$ phase superconductor/normal metal bilayers. Because of the sign reversal between the two condensates, the zero bias conductance peak appears as observed in tunneling spectroscopy experiments on FeAs su…
Recently, superconductivity with spontaneous time-reversal or parity symmetry breaking is attracting much attention owing to its exotic properties, such as nontrivial topology and nonreciprocal transport. Particularly fascinating phenomena are expected when the time-reversal and parity symmetry are simultaneously broken. This work shows that time-reversal symmetry-breaking mixed-parity superconducting states generally exhibit an unusual asymmetric Bogoliubov spectrum due to nonunitary interband pairing. For generic two-band models, we derive the necessary conditions for the asymmetric Bogoliub…
The induction of an s-wave component in a d-wave superconductor is considered. Near the {110}-oriented edges of such a sample, the induced s-wave order parameter together with d-wave component forms a complex combination d+e^{iϕ} s, which breaks the time reversal symmetry (BTRS) of the pairing state. As a result, the spontaneous current is created. We numerically study the current distribution and the formation of the spontaneous flux induced by the current. We show that the spontaneous flux formed from a number of defect lines with {110} orientation has a measurable strength. This result may …
We study the pairing of fermions by an interaction consisting of a Hubbard repulsion, mimicking a screened Coulomb potential, and a dynamical phonon-mediated attraction. For such interaction, the gap equation allows even- and odd-frequency solutions $Δ_e$ and $Δ_o$. We show that odd-frequency pairing does not develop within the Eliashberg approximation due to over-critical pair-breaking from the self-energy. When vertex corrections are included, the pairing interaction gets stronger, and $Δ_o$ can develop. We argue that even in this case keeping the self-energy is still a must as it cancels ou…
The results from muon spin relaxation experiments on the non-centrosymmetric intermetallic superconductor LaNiC$_2$ are reported. We find that the onset of superconductivity coincides with the appearance of spontaneous magnetic fields, implying that in the superconducting state time reversal symmetry is broken. An analysis of the possible pairing symmetries suggests only four triplet states compatible with this observation, all of which are non-unitary. They include the intriguing possibility of triplet pairing with the full point group symmetry of the crystal, which is only possible in a non-…
We study the possibility of topological superconductivity in the noncentrosymmetric monolayer and trilayer TaS$_2$ with out-of-plane mirror symmetry. A gapless time-reversal invariant f+s-wave pairing state with even mirror parity is found to be a promising candidate. This mixing state holds 12(36) nodes at the Fermi pockets around $Γ$ for monolayer(trilayer) case and its unconventional superconductivity is consistent with the STM experiments observed in 2$H$-TaS$_2$ thin flakes. Furthermore, with doping or under uniaxial pressure for trilayer 2$H$-TaS$_2$, large-Chern-number time-reversal sym…
We here examine the relation between odd-frequency spin-triple even-parity (OTE) Cooper pairs and anomalous surface magnetic response in time-reversal invariant (TRI) spin-triplet superfluids and superconductors. The spin susceptibility generally consists of two contributions: Even-frequency odd-parity pair amplitudes and odd-frequency even-parity pair amplitudes. The OTE pair amplitudes are absent in the bulk region, but ubiquitously exist in the surface and interface region as Andreev bound states. We here clarify that additional discrete symmetries, originating from the internal symmetry an…
Thin sheets deposited on a substrate and interfaces of correlated materials offer a plethora of routes towards the realization of exotic phases of matter. In these systems, inversion symmetry is broken which strongly affects the properties of possible instabilities -- in particular in the superconducting channel. By combining symmetry and energetic arguments, we derive general and experimentally accessible selection rules for Cooper instabilities in noncentrosymmetric systems which yield necessary and sufficient conditions for spontaneous time-reversal-symmetry breaking at the superconducting …
We report a $μ$SR investigation of a non-centrosymmetric superconductor (LaNiC$_2$) in single crystal form. Compared to previous $μ$SR studies of non-centrosymmetric superconducting polycrystalline and powder samples, the unambiguous orientation of single crystals enables a simultaneous determination of the absolute value of the magnetic penetration depth and the vortex core size from measurements that probe the magnetic field distribution in the vortex state. The magnetic field dependence of these quantities unambiguously demonstrates the presence of two nodeless superconducting energy gaps. …
We consider a generic two-dimensional system of fermionic particles with attractive interactions and no disorder. If time-reversal symmetry is absent, it is possible to obtain incompressible insulating states in addition to the superfluid at zero temperature. The superfluid-insulator phase transition is found to be second order in type-II systems using a perturbative analysis of Cooper pairing instability in quantum Hall states of unpaired fermions. We obtain the pairing phase diagram as a function of chemical potential (density) and temperature. However, a more careful analysis presented here…
We study the pairing symmetry of Sr$_2$RuO$_4$ through the group-theoretical approach. We emphasize the role of pairing interaction between the quasi-one-dimensional(Q1D) $d_{xz/yz}$ and quasi-two-dimensional(Q2D) $d_{xy}$ orbitals. It is found that two degenerate inter-orbital time-reversal-invariant(TRI) p-wave pairings, one is spin-singlet and the other spin-triplet with out-of-plane $\bm{d}$-vector, could be the most promising candidates. Several important physical quantities are presented, including the near-nodal gap structure, the unchanged out-of-plane Knight shift, and no split transi…
In a recent Letter [PRL 103, 186402 (2009)], the energy band structure of Fe-As-based superconductors is fitted with a tight-binding model with two Fe ions per unit cell and two degenerate xz and yz orbitals per Fe ion. The author claims that the proposed model, which differs markedly from a model previously used by other authors for the same two orbitals in the same compounds, possesses the symmetry required to describe the Fe-As planes in iron-pnictide superconductors. In this comment we argue that this is not the case.
We propose a class of topological superconductivity in which the pairing order is $\mathbb{Z}_2$ topologically obstructed in a three-dimensional time-reversal invariant system. When two Fermi surfaces are related by time-reversal and mirror symmetries, such as those in a $\mathbb{Z}_2$ Dirac semimetal, the inter-Fermi-surface pairing in the weak-coupling regime inherits the band topological obstruction. As a result, the pairing order cannot be well-defined over the entire Fermi surface and forms a time-reversal invariant generalization of U($1$) monopole harmonic pairing. A tight-binding model…
We study a tight-binding model on the honeycomb lattice of chiral $d$-wave superconductivity that breaks time-reversal symmetry. Due to its nontrivial sublattice structure, we show that it is possible to construct a gauge-invariant time-reversal-odd bilinear of the pairing potential. The existence of this bilinear reflects the sublattice polarization of the pairing state. We show that it generates persistent loop current correlations around each lattice site and opens a topological mass gap at the Dirac points, resembling Haldane's model of the anomalous quantum Hall effect. In addition to the…
We investigate the nature of the time-reversal breaking pairing state in the hole-doped monolayer MoS$_{2}$ on the basis of the realistic three-orbital attractive Hubbard-like model with the atomic spin-orbit coupling. Due to the multi-band features arising from the Mo $d$ orbitals in the noncentrosymmetric crystal structure, the Lifshitz transition takes place upon hole doping. Across the Lifshitz transition point, the sign of the relative phase between the Cooper-pair components drastically changes, leading to the emergence of the time-reversal breaking phase with complex gap functions. It i…
The Janus monolayer transition metal dichalcogenides[TMDs] MXY[M=Mo,W, etc. and X,Y=S,Se, etc.] has been synthesized recently, and the Rashba spin splitting arises in it owing to the breaking of out-of-plane mirror symmetry[\href{https://journals.aps.org/prb/abstract/10.1103/PhysRevB.97.235404}{Phys. Rev. B 97, 235404 (2018)}]. Here we study the pairing symmetry of superconducting Janus monolayer H-TaSSe by solving the linearized gap equation at the critical temperature $T_c$. We find that the strong Rashba effect in H-TaSSe could produce topological superconducting states which differs from t…
We report the study of spontaneous magnetization (i.e., spin-polarization) for time-reversal symmetry (TRS)-breaking superconductors with unitary pairing potentials, in the absence of external magnetic fields or Zeeman fields. Spin-singlet ($Δ_s$) and spin-triplet ($Δ_t$) pairings can coexist in superconductors whose crystal structure lacks inversion symmetry. The TRS can be spontaneously broken once a relative phase of $\pmπ/2$ is developed, forming a TRS-breaking unitary pairing state ($Δ_s\pm iΔ_t$). We demonstrate that such unitary pairing could give rise to spontaneous spin-polarization w…
We report a sudden reversal in the pressure dependence of Tc in the iron-based superconductor CsFe2As2, similar to that discovered recently in KFe2As2 [Tafti et al., Nat. Phys. 9, 349 (2013)]. As in KFe2As2, we observe no change in the Hall coefficient at the zero temperature limit, again ruling out a Lifshitz transition across the critical pressure Pc. We interpret the Tc reversal in the two materials as a phase transition from one pairing state to another, tuned by pressure, and investigate what parameters control this transition. Comparing samples of different residual resistivity, we find …
Effects of impurity scattering on tunneling conductance in dirty normal-metal/insulator/superconductor junctions are studied based on the Kubo formula and the recursive Green function method. The zero-bias conductance peak (ZBCP) is a consequence of the unconventional pairing symmetry in superconductors. The impurity scattering in normal metals suppresses the amplitude of the ZBCP. The degree of the suppression agrees well with results of the quasiclassical Green function theory. When superconductors have $d$+is-wave pairing symmetry, the time-reversal symmetry is broken in superconductors and…
To identify the superconducting gap symmetry in CeCoIn5 (Tc=2.3 K), we performed angle-resolved specific heat (C_ϕ) measurements in a field rotated around the c-axis down to very low temperatures 0.05Tc and detailed theoretical calculations. In a field of 1 T, a sign reversal of the fourfold angular oscillation in C_ϕhas been observed at T ~ 0.1Tc on entering a quasiclassical regime where the maximum of C_ϕcorresponds to the antinodal direction, coinciding with the angle-resolved density of states (ADOS) calculation. The C_ϕbehavior, which exhibits minima along [110] directions, unambiguously …
As an extension of our previous work on the holon pairing instability in the t-J Hamiltonian [Phys. Rev. B {\bf 66}, 054427 (2002)], we examine the orbital symmetries of holon pairing order parameters in high $T_c$ superconductivity by examining the energy poles of t-matrix. We find that both $s$- and d-wave symmetries in holon pair order parameter occur at low lying energy states corresponding to the higher energy poles of t-matrix while only the s-wave symmetry appears at the lowest energy pole and that this results in the d-wave symmetry in the Cooper pair order which is a composite of the …
In many unconventional superconductors, the pairing of electrons is driven by the repulsive interaction, which leads to the sign reversal of superconducting gaps along the Fermi surfaces (FS) or between them. However, to measure this sign change is not easy and straightforward. It is known that, in superconductors with sign reversal gaps, non-magnetic impurities can break Cooper pairs leading to the quasiparticle density of states in the superconducting state. The standing waves of these quasiparticles will interfere each other leading to the quasiparticle interference (QPI) pattern which carr…
Epitaxial bilayer films of Bi(110) and Ni host a time-reversal symmetry (TRS) breaking superconducting order with an unexpectedly high transition temperature $T_c = 4.1$ K. Using time-domain THz spectroscopy, we measure the low energy electrodynamic response of a Bi/Ni bilayer thin film from $0.2$ THz to $2$ THz as a function of temperature and magnetic field. We analyze the data in the context of a BCS-like superconductor with a finite normal-state scattering rate. In zero magnetic field, all states in the film become fully gapped, providing important constraints into possible pairing symmetr…
In this work, we establish a few exact identities through commutation of intra-orbital and inter-orbital on-site pairings with a two-orbital model describing newly discovered FeAs-based superconductors. Applying the conclusion drawn from rigorous relation and physical interpretation, we give constraints on the possible symmetries of the superconducting pairing of the model. Hence the favorable pairings in newly discovered high-temperature oxypnictide superconductors are proposed.
The single helical Fermi surface on the surface state of three-dimensional topological insulator Bi2Se3 is constrained by the time-reversal invariant bulk topology to possess a spin-singlet superconducting pairing symmetry. In fact, the Cu-doped, and pressure-tuned superconducting Bi2Se3 show no evidence of the time reversal symmetry breaking. We report on the detection of the time reversal symmetry (TRS) breaking in the topological superconductor Sr0.1Bi2Se3 , probed by zero-field (ZF) μSR measurements. The TRS breaking provides strong evidence for the existence of spin-triplet pairing state.…
The symmetries of superconducting gap functions remain an important question of iron-based superconductivity. Motivated by the recent angle-resolved photoemission spectroscopic measurements on iron-chalcogenide superconductors, we investigate the influence of pairing symmetries on the topological surface state. If the surface Dirac cone becomes gapped in the superconducting phase, it implies magnetization induced from time-reversal symmetry breaking pairing via spin-orbit coupling. Based on the crystalline symmetry constraints on the Ginzburg-Landau free energy, the gap function symmetries are…
In this paper we present a real space pairing glue for the iron-based layered superconductors. It is shown that two static electrons embedded symmetrically into two adjacent Fe plaquettes of the superconductor can be bounded due to the Coulombic interaction. The pairing mechanism favors the existence of the pseudogap in the underdoped FeAs superconductors. A criterion is introduced to distinguish whether or not the pseudogap can open in a material.
The isotope effects for Fe based superconductors are considered by including the phonon and magnetic fluctuations within the two band Eliashberg theory. We show that the recently observed inverse isotope effects of Fe, $α_{Fe} \approx -0.18 \pm 0.03 $,\cite{Shirage0903.3515} as well as the large positive isotope exponent ($α\approx 0.35$) can naturally arise for the magnetically induced sign revered s-wave pairing state within reasonable parameter range. Either experimental report can not be discarded from the present analysis based on the parameter values they require. The inverse and positiv…
The nature of the pairing states of superconducting LaNiC$_2$ and LaNiGa$_2$ has to date remained a puzzling question. Broken time reversal symmetry has been observed in both compounds and a group theoretical analysis implies a non-unitary triplet pairing state. However all the allowed non-unitary triplet states have nodal gap functions but most thermodynamic and NMR measurements indicate fully gapped superconductivity in LaNiC$_2$. Here we probe the gap symmetry of LaNiGa$_2$ by measuring the London penetration depth, specific heat and upper critical field. These measurements demonstrate two-…
Three-dimensional line-nodal superconductors exhibit nontrivial topology, which is protected by the time-reversal symmetry. Here we investigate four types of short-range interaction between the gapless line-nodal fermionic quasiparticles by carrying renormalization group analysis. We find that such interactions can induce the dynamical breaking of time-reversal symmetry, which alters the topology and might lead to six possible distinct superconducting states, distinguished by the group representations. After computing the susceptibilities for all the possible phase-transition instabilities, we…
We study superconductivity in the two-dimensional 16-band d-p model extracted from a tight-binding fit to the band structure of LaFeAsO, using the random phase approximation. When the intraorbital repulsion U is larger than the interorbital one U', an extended s-wave (s+--wave) pairing with sign reversal of order parameter is mediated by antiferromagnetic spin fluctuations, while when U<U' another kind of s-wave (s++-wave) pairing without sign reversal is mediated by ferro-orbital fluctuations. The s++-wave pairing is enhanced due to the electron-phonon coupling and then can be expanded over t…
Recently developed parity (P) and time-reversal (T) symmetric non-Hermitian systems govern a rich variety of new and characteristically distinct physical properties, which may or may not have a direct analog in their Hermitian counterparts. We study here a non-Hermitian, PT-symmetric superconducting Hamiltonian that possesses real quasiparticle spectrum in the PT-region of the Brillouin zone. Within a single-band mean-field theory, we find that real quasiparticle energies are possible when the superconducting order parameter itself is either Hermitian or anti-Hermitian. Within the correspondin…
We investigate hybrid structures based on a bilayer quantum spin Hall system in proximity to an s-wave superconductor as a platform to mimic time-reversal symmetric topological superconductors. In this bilayer setup, the induced pairing can be of intra- or inter-layer type, and domain walls of those different types of pairing potentials host Kramers partners (time-reversal conjugate pairs) of Majorana bound states. Interestingly, we discover that such topological interfaces providing Majorana bound states can also be achieved in an otherwise homogeneous system by a spatially dependent inter-la…
The single impurity effect on the graphene-based superconductor is studied theoretically. Four different pairing symmetries are discussed. Sharp resonance peaks are found near the impurity site for the $d+id$-wave pairing symmetry and the $p+ip$-wave pairing symmetry when the chemical potential is large. As the chemical potential decreases, the in-gap states are robust for the $d+id$ pairing symmetry while they disappear for the $p+ip$ pairing symmetry. Such in-gap peaks are absent for the fully gapped extended $s$-wave pairing symmetry and the nodal $f$-wave pairing symmetry. The existence of…
We report point contact Andreev Reflection (PCAR) measurements on a high-quality single crystal of the non-centrosymmetric superconductor Re6Zr. We observe that the PCAR spectra can be fitted by taking two isotropic superconducting gaps with Delta_1 ~ 0.79 meV and Delta_2 ~ 0.22 meV respectively, suggesting that there are at least two bands which contribute to superconductivity. Combined with the observation of time reversal symmetry breaking at the superconducting transition from muon spin relaxation measurements (Phys. Rev. Lett. 112, 107002 (2014)), our results imply an unconventional super…
