We report point contact Andreev Reflection (PCAR) measurements on a high-quality single crystal of the non-centrosymmetric superconductor Re6Zr. We observe that the PCAR spectra can be fitted by taking two isotropic superconducting gaps with Delta_1 ~ 0.79 meV and Delta_2 ~ 0.22 meV respectively, suggesting that there are at least two bands which contribute to superconductivity. Combined with the observation of time reversal symmetry breaking at the superconducting transition from muon spin relaxation measurements (Phys. Rev. Lett. 112, 107002 (2014)), our results imply an unconventional superconducting order in this compound: A multiband singlet state that breaks time reversal symmetry or a triplet state dominated by interband pairing.
We show that superconductors with broken time-reversal symmetry have very specific magnetic and electric responses to inhomogeneous heating. A local heating of such superconductors induces a magnetic field with a profile that is sensitive to the presence of domain walls and crystalline anisotropy of superconducting states. A nonstationary heating process produces an electric field and a charge imbalance in different bands. These effects can be measured and used to distinguish $s+is$ and $s+id$ superconducting states in the candidate materials such as Ba$_{1-x}$K$_x$Fe$_2$As$_2$.
We study three-dimensional time-reversal-invariant topological superconductivity in noncentrosymmetric materials such as RhSi, CoSi, and AlPt which host coupled multifold nodes energetically split by the spin-orbit coupling at the same time-reversal-invariant momentum (TRIM). The topological superconductivity arises from the $s_{+} \oplus s_{-}$ gap function, which is $\boldsymbol{k}$ independent, but with opposite signs for the two nodes split at the same TRIM. We consider various electron-electron interactions in the tight-binding model for RhSi and find that the topological superconducting …
Supercurrent Diode Effect in Josephson Interferometers with Multiband Superconductors
CNR-SPIN（意大利国家研究委员会自旋物理学研究所）；Institute for Theoretical Solid State Physics, Leibniz-Institut für Festkörper- und Werkstoffforschung IFW-Dresden（德累斯顿勒布尼兹固体与材料研究所凝聚态物理理论研究所）；Istituto Lombardo “Accademia di Scienze e Lettere”（伦巴第科学院）；NEST Istituto Nanoscienze-CNR and Scuola Normale Superiore（意大利国家研究委员会纳米科学研究所与比萨高等师范学院）；Universitá di Salerno（萨莱诺大学）
We show that multiband superconductors with broken time-reversal symmetry can produce spontaneous currents and magnetic fields in response to the local variations of pairing constants. Considering the iron pnictide superconductor Ba$_{1-x}$K$_x$Fe$_2$As$_2$ as an example we demonstrate that both the point-group symmetric $s+is$ state and the C$_4$-symmetry breaking $s+id$ states produce in general the same magnitudes of spontaneous magnetic fields. In the $s+is$ state these fields are polarized mainly in ab crystal plane, while in the $s+id$ state their ab-plane and c-axis components are of th…
Signatures of time-reversal-symmetry breaking in multiband 2H-TaS2 revealed by zero-field Josephson nonreciprocity
CIC nanoGUNE BRTA（纳米科学中心）；Centro de Física de Materiales – Materials Physics Center (CFM-MPC) CSIC-EHU（材料物理中心）；Istituto di Struttura della Materia, Consiglio Nazionale delle Ricerche（意大利国家研究理事会材料结构研究所）
We discuss the problem of broken time reversal symmetry near grain boundaries in a d-wave superconductor based on a Ginzburg-Landau theory. It is shown that such a state can lead to fractional vortices on the grain boundary. Both analytical and numerical results show the structure of this type of state.
This article reviews theoretical and experimental work on the novel physics in multiband superconductors. Multiband superconductors are characterized by multiple superconducting energy gaps in different bands with interaction between Cooper pairs in these bands. The discovery of prominent multiband superconductors $\mathrm{MgB_2}$ and later iron-based superconductors has triggered enormous interests in multiband superconductors. Most recently discovered superconductors exhibit multiband features. The multiband superconductors possess novel properties that are not shared by their single-band co…
A novel time-reversal symmetry breaking state is found theoretically in the Josephson junction between the two-gap superconductor and the conventional s-wave superconductor. This occurs due to the frustration between the three order parameters analogous to the two antiferromagnetically coupled XY-spins put under a magnetic field. This leads to the interface states with the energies inside the superconducting gap. Possible experimental observations of this state with broken time-reversal symmetry are discussed.
In superconductors with three or more bands, time-reversal symmetry (TRS) may be broken in the presence of repulsive interband couplings, resulting in a pair of degenerate states characterized by opposite chiralities. We consider a Josephson junction between a three-band superconductor with broken TRS and a single-band superconductor. Phenomena such as asymmetric critical currents, subharmonic Shapiro steps and symmetric Fraunhhofer patterns are revealed theoretically. Existing experimental results are discussed in terms of the present work.
We show that under certain conditions multiband superconductors with broken time-reversal symmetry have a new vortex viscosity-generating mechanism which is different from that in conventional superconductors. It appears due to the existence of mixed superfluid phase-density mode inside vortex core. This new contribution is dominant near the time reversal symmetry breaking phase transition. The results could be relevant for three band superconductor $Ba_{1-x}K_{x}Fe_2As_2$.
Spatial distributions of spontaneous magnetic fields near a surface of cuprate high-$T_C$ superconductor YBCO with broken time-reversal symmetry are calculated using the Ginzburg-Landau theory derived from the $t-J$ model. It is found that the magnetic field exists in a narrow region inside the superconductor, and it decays quickly outside the surface. Experimental approaches possible to detect such spontaneous magnetic fields are discussed.
We show that the conclusion reported in Ref. 1, that there are no spontaneous magnetic fields in multiband superconductors that break time reversal symmetry, is incorrect. We demonstrate that the state proposed in Ref. 1 is not a solution of the Ginzburg-Landau equations for the considered model. The reason is that in Ref. 1 one of the Ginzburg-Landau equations is neglected and substituted by the spurious zero current restriction. This restriction together with all of the Ginzburg-Landau equations leads to an overdetermined system which does not have a solution. This inconsistency invalidates …
Comment on "High Resolution Polar Effect Measurements of Sr2RuO4: Evidence for Broken Time-Reversal Symmetry in the Superconducting State" by J. Xia et al., Phys. Rev. Lett. 97, 167002 (2006).
Polar Kerr effect in the spin-triplet superconductor Sr2RuO4 was measured with high precision using a Sagnac interferometer with a zero-area Sagnac loop. We observed non-zero Kerr rotations as big as 65 nanorad appearing below Tc in large domains. Our results imply a broken time reversal symmetry state in the superconducting state of Sr2RuO4, similar to He3-A.
We calculate analytically the spectrum of the Andreev bound states in a half-infinite superconducting wire with an arbitrary number of bands crossing the chemical potential. The normal state of the wire is assumed to have an antiunitary symmetry A (time reversal or its combination with a crystallographic point group operation), with A^2=-1 or +1. This symmetry may be broken by the superconducting order parameter and/or the boundary scattering. We present a model-independent proof of the existence of one Majorana mode near the end of the wire with an odd number of bands.
A procedure to derive the Ginzburg-Landau (GL) theory from the multiband BCS Hamiltonian is developed in a general case with an arbitrary number of bands and arbitrary interaction matrix. It combines the standard Gor'kov truncation and a subsequent reconstruction in order to match accuracies of the obtained terms. This reconstruction recovers the phenomenological GL theory as obtained from the Landau model of phase transitions but offers explicit microscopic expressions for the relevant parameters. Detailed calculations are presented for a three-band system treated as a prototype multiband sup…
Conventional superconductors are strong diamagnets that through the Meissner effect expel magnetic fields. It would therefore be surprising if a superconducting ground state would support spontaneous magnetics fields. Such time-reversal symmetry broken states have been proposed for the high-temperature superconductors, but their identification remains experimentally controversial. Here we show a route to a low-temperature superconducting state with broken time-reversal symmetry that may accommodate currently conflicting experiments. This state is characterised by an unusual vortex pattern in t…
A conventional superconductor is described by a single complex order parameter field which has two fundamental length scales, the magnetic field penetration depth λand the coherence length ξ. Their ratio κdetermines the response of a superconductor to an external field, sorting them into two categories as follows; type-I when κ<1/\sqrt{2} and type-II when κ>1/\sqrt{2} . We overview here multicomponent systems which can possess three or more fundamental length scales and allow a separate "type-1.5" superconducting state when, e.g. in two-component case ξ_1<\sqrt{2}λ<ξ_2. In that state, as a con…
Broken time reversal symmetry (BTRS) in d wave superconductors is studied and is shown to yield current carrying surface states. The corresponding spontaneous magnetization is temperature independent near the critical temperature Tc for weak BTRS, in accord with recent data. For strong BTRS and thin films we expect a temperature dependent spontaneous magnetization with a paramagnetic anomaly near Tc. The Hall conductance is found to vanish at zero wavevector q and finite frequency w, however at finite q,w it has an unusual structure.
We studied the effects of multiband electronic structure on the thermoelectric and electrical transport properties in the normal state of kagome superconductors $A$V$_3$Sb$_5$ ($A$ = K, Rb, Cs). In all three members, the multiband nature is manifested by sign changes in the temperature dependence of the Seebeck and Hall resistivity, together with sublinear response of the isothermal Nernst and Hall effects to external magnetic fields in the charge ordered state. Moreover, ambipolar transport effects appear ubiquitously in all three systems, giving rise to sizable Nernst signal. Finally, possib…
Broken time reversal symmetry (BTRS) in d+id' as well as in d+is superconductors is studied and is shown to yield current carrying surface states. We evaluate the temperature and thickness dependence of the resulting spontaneous magnetization and show a marked difference between weak and strong BTRS. We also derive the Hall conductance which vanishes at zero wavevector q and finite frequency w, however at finite q,w it has an unusual structure. The chirality of the surface states leads to quantum Hall effects for spin and heat transport in d+id' superconductors.
Bulk TiSe$_2$ is an intrinsically layered transition metal dichalcogenide (TMD) hosting both superconducting and charge density wave (CDW) ordering. Motivated by the recent progress in preparing two-dimensional TMDs, we study these frustrated orderings in {\it single} trilayer of TiSe$_2$ within a renormalization group approach. We establish that a novel state with time-reversal symmetry broken chiral superconductivity can emerge from the strong competition between CDW formation and superconductivity. Its stability depends on the precise strength and screening of the electron-electron interact…
We demonstrate that films of unconventional (d-wave) superconductor at temperatures $T\lesssim 0.43 T_c$ can exhibit unusual superconducting phases. The new ground states beside the broken gauge and the point group symmetries can spontaneously break (i) continuous translational symmetry and form periodic order parameter structures in the plane of the film, or (ii) time-reversal symmetry and develop supercurrent flowing along the film. These states are result of the strong transverse inhomogeniety present in films with thickness of several coherence lengths. We show a natural similarity between…
In three-band BCS superconductors with repulsive interband interactions, frustration between the bands can lead to an inherently complex gap function, arising out of a phase difference between the bands in the range 0 and π. Since the complex conjugate of this state is also a solution, the ground state is degenerate, and there appears a time-reversal-symmetry-broken state. In this paper we investigate the existence of this state as a function of interband coupling strength and show how a new phase transition appears between the TRSB and conventional BCS states.
A detailed analysis of the symmetric tetracrystal geometry used in phase-sensitive pairing symmetry experiments on high Tc superconductors is carried out for both bulk and surface time-reversal symmetry-breaking states, such as the d+id' and d+is states. The results depend critically on the substrate geometry. In the general case, for the bulk d+id' (or d+is) state, the measured flux quantization should in general not be too different from that obtained in the pure d-wave case, provided |d'| << |d| (or |s| << |d|). However, in one particular high symmetry geometry, the d+id' state gives result…
Using Monte Carlo simulations, we explore the phase diagram and the phase transitions in $\groupUZ$ $n$-band superconductors with spontaneously broken time-reversal symmetry (also termed $s+is$ superconductors), focusing on the three-band case. In the limit of infinite penetration length, the system under consideration can, for a certain parameter regime, have a single first order phase transition from a $\groupUZ$ broken state to a normal state due to a nontrivial interplay between $\groupU$ vortices and $\groupZ$ domain walls. This regime may also apply to multicomponent superfluids. For oth…
Type II Lifshitz invariant and optically active Higgs mode in time-reversal symmetry broken superconductors
Institute for Theory of Condensed Matter, Karlsruhe Institute of Technology（卡尔斯鲁厄理工学院凝聚态理论研究所）；Department of Physics, University of Tokyo（东京大学物理学系）；RIKEN Center for Emergent Matter Science (CEMS)（理化学研究所新兴物质科学中心）；Trans-Scale Quantum Science Institute, University of Tokyo（东京大学跨尺度量子科学研究所）
Exotic superconductors, such as high T$_C$, topological, and heavy-fermion superconductors, require phase sensitive measurements to determine the underlying pairing. Here we investigate the proximity-induced superconductivity in nanowires of SnTe, where an $s\pm is^{\prime}$ superconducting state is produced that lacks the time-reversal and valley-exchange symmetry of the parent SnTe. This effect, in conjunction with a ferroelectric distortion of the lattice at low temperatures, results in a marked alteration of the properties of Josephson junctions fabricated using SnTe nanowires. This work e…
Over the last years a lot of theoretical and experimental efforts have been made to find states with broken time reversal symmetry (BTRS) in multi-band superconductors. In particular, it was theoretically proposed that in the Ba$_{1-x}$K$_{x}$Fe$_2$As$_2$ system either an $s+is$ or an $s+id$ BTRS state may exist at high doping levels in a narrow region of the phase diagram. Here we report the observation of an enhanced zero field muon spin relaxation rate below the superconducting transition temperature for a high quality crystalline sample with $x \approx$ 0.73. This indicates that indeed the…
In order to examine the influences of the spatial dependence of the pair potential, the d.c. Josephson current in d-wave superconductors is calculated using self-consistently determined pair potentials. The results show that the suppression of the d-wave pair potential near the insulator does not have serious effect on the properties of the Josephson current. On the other hand, drastic changes are obtained due to the inducement of a subdominant s-wave component, which spontaneously breaks time reversal symmetry. Especially, a rapid enhancement of the Josephson current at low temperature predic…
The symmetry properties of the order parameter characterize different phases of unconventional superconductors. In the case of the heavy-fermion superconductor UPt$_3$, a key question is whether its multiple superconducting phases preserve or break time-reversal symmetry (TRS). We tested for asymmetry in the phase shift between left and right circularly polarized light reflected from a single crystal of UPt$_3$ at normal incidence, finding that this so-called polar Kerr effect appears only below the lower of the two zero-field superconducting transition temperatures. Our results provide eviden…
We report the results of a search for spontaneous magnetism due to a time reversal symmetry breaking phase in the superconducting state of (110)-oriented YBCO films, expected near the surface in this geometry. Zero field and weak transverse field measurements performed using the low-energy muon spin rotation technique with muons implanted few nm inside optimally-doped YBCO-(110) films show no appearance of spontaneous magnetic fields below the superconducting temperature down to 2.9 K. Our results give an upper limit of ~0.02 mT for putative spontaneous internal fields.
The cryptoferromagnetic state (the state with intrinsic domain structure) in superconducting ferromagnets subjected to external magnetic field is studied theoretically. Ferromagnetism originates either from electron spin or the intrinsic angular momentum of Cooper pairs (chiral p-wave superconductors like $\mathrm{Sr_2 Ru O_4}$). The phase transitions towards the Meissner and the mixed states are investigated, and the magnetic phase diagrams are obtained. Cryptoferromagnetism, as a form coexistence of superconductivity and ferromagnetism, can be detected by observation of magnetization curves …
We study theoretically the spatial distribution of spontaneous magnetic fields near a (110) surface of cuprate high-$T_C$ superconductor YBCO by treating a bilayer $t-J$ model with the Bogoliubov-de Gennes method. Near a (110) surface where $d_{x^2-y^2}$-wave superconductivity is strongly suppressed, flux phase order occurs locally leading to a time-reversal symmetry broken surface state. Since the spontaneous currents flowing in the flux phase in two layers are antiparallele, resulting spontaneous magnetic fields are quite small. They exist in a narrow region inside the superconductor, and es…
Symmetry of the order parameter in some triplet superconductors corresponds to doubly-degenerate chiral states. We predict that in a sufficiently small sample this degeneracy can be lifted via macroscopic quantum tunneling. Moreover, if the initial state is prepared correspondingly, 'instanton'-like quantum behavior is possible in a single-domain sample. In this case coherent oscillations of magnetic momentum should take place, as well as the sign alternations of the boundary currents. In particular, spontaneous Hall-effect recently predicted for ruthenates should posses the oscillating voltag…
The order of the superconducting phase transition is a classical problem. Single-component type-2 superconductors exhibit a continuous "inverted-XY" phase transition, as was first demonstrated for U(1) lattice London superconductors by a celebrated duality mapping with subsequent backing by numerical simulations. Here we study this problem in multiband U(1) London superconductors and find evidence that by contrast the model has a tricritical point. The superconducting phase transition becomes first-order when the Josephson length is sufficiently large compared to the magnetic field penetration…
Time-Reversal Symmetry Breaking Superconducting State and Collective Modes in Kagome Superconductors
Capital Normal University（首都师范大学）；Kavli Institute for Theoretical Sciences, University of Chinese Academy of Sciences（中国科学院大学理论科学研究所）；Beijing National Laboratory for Condensed Matter Physics and Institute of Physics, Chinese Academy of Sciences（中国科学院物理研究所北京凝聚态物理国家研究中心）；School of Physical Sciences, University of Chinese Academy of Sciences（中国科学院大学物理科学学院）；Institute of Theoretical Physics, Chinese Academy of Sciences（中国科学院理论物理研究所）
In this paper we study the order parameter and density of states near a grain boundary between two $d_{x^2-y^2}$ superconductors. We examine broken time reversal symmetry near the interface. In particular we show that, under suitable circumstances, time reversal symmetry must be broken even when the order parameter is purely $d_{x^2-y^2}$ everywhere in space.
Effects of impurity scattering on tunneling conductance in dirty normal-metal/insulator/superconductor junctions are studied based on the Kubo formula and the recursive Green function method. The zero-bias conductance peak (ZBCP) is a consequence of the unconventional pairing symmetry in superconductors. The impurity scattering in normal metals suppresses the amplitude of the ZBCP. The degree of the suppression agrees well with results of the quasiclassical Green function theory. When superconductors have $d$+is-wave pairing symmetry, the time-reversal symmetry is broken in superconductors and…
The noncentrosymmetric superconductor Re$_6$Zr has attracted much interest due to the observation of broken time-reversal symmetry in the superconducting state. Here we report an investigation of the superconducting gap structure of Re$_6$Zr single crystals by measuring the magnetic penetration depth shift $Δλ(T)$ and electronic specific heat $C_e(T)$. $Δλ(T)$ exhibits an exponential temperature dependence behavior for $T~\ll~T_c$, which indicates a fully-open superconducting gap. Our analysis shows that a single gap $s$-wave model is sufficient to describe both the superfluid density $ρ_s(T)$…
We discuss the phase diagram and phase transitions in $U(1)\times \groupZ{2}$ three-band superconductors with broken time reversal symmetry. We find that beyond mean field approximation and for sufficiently strong frustration of interband interactions there appears an unusual metallic state precursory to a superconducting phase transition. In that state, the system is not superconducting. Nonetheless, it features a spontaneously broken $\groupZ{2}$ time reversal symmetry. By contrast, for weak frustration of interband coupling the energy of a domain wall between different $\groupZ{2}$ states i…
We calculate the tunneling conductance spectra of a ferromagnetic metal/insulator/superconductor using the Blonder-Tinkham-Klapwijk (BTK) formulation. Two possible states for the superconductor are considered with the time reversal symmetry ($\cal{T}$) broken, i.e., $d_{x^2-y^2}+is$, or $d_{x^2-y^2}+id_{xy}$. In both cases the tunneling conductance within the gap is suppressed with the increase of the exchange interaction due to the suppression of the Andreev reflection. In the $(d_{x^2-y^2}+is)$-wave case the peaks that exist when the ferromagnet is a normal metal in the amplitude of the s-wa…
Weak spontaneous magnetic fields are observed near the surface of YBCO films using Beta-detected Nuclear Magnetic Resonance. Below Tc, the magnetic field distribution in a silver film evaporated onto the superconductor shows additional line broadening, indicating the appearance of small disordered magnetic fields. The line broadening increases linearly with a weak external magnetic field applied parallel to the surface, and is depth-independent up to 45 nm from the Ag/YBCO interface. The magnitude of the line broadening at 10 K extrapolated to zero applied field is less than 0.2 G, and is clos…
We analyze edge currents and edge bands at the surface of a time-reversal symmetry breaking d_{x^2-y^2}+id_{xy} superconductor. We show that the currents have large Friedel oscillations with two interfering frequencies: \sqrt{2}k_F from sub-gap states, and 2 k_F from the continuum. The results are based independently on a self-consistent slave-boson mean field theory for the t-J model on a triangular lattice, and on a T-matrix scattering theory calculation. The shape of the edge-state band, as well as the particular frequency \sqrt{2}k_F of the Friedel oscillations are attributes unique for th…
It is commonly believed that in the absence of disorder or an external magnetic field, there are three possible types of superconducting excitation gaps: the gap is nodeless, it has point nodes, or it has line nodes. Here, we show that for an even-parity nodal superconducting state which spontaneously breaks time-reversal symmetry, the low-energy excitation spectrum generally does not belong to any of these categories, instead it has extended Bogoliubov Fermi surfaces. These Fermi surfaces can be visualized as two-dimensional surfaces generated by "inflating" point or line nodes into spheroids…
Recent experimental and theoretical interest in the superconducting phase of the heavy fermion material URu$_2$Si$_2$ has led to a number of proposals in which the superconducting order parameter breaks time-reversal symmetry (TRS). In this study we measured polar Kerr effect (PKE) as a function of temperature for several high-quality single crystals of URu$_2$Si$_2$. We find an onset of PKE below the superconducting transition that is consistent with a TRS-breaking order parameter. This effect appears to be independent of an additional, possibly extrinsic, PKE generated above the hidden order…
We show that three-band superconductors with broken time reversal symmetry allow magnetic flux-carrying stable topological solitons which have only a slightly higher energy than ordinary vortices. Therefore they can be induced by fluctuations or quenching the system through a phase transition. It can provide an experimental signature of the time reversal symmetry breakdown.
A novel superconducting state under the broken time-reversal symmetry is studied in conventional phonon-mediated superconductors. By solving the Eliashberg equation self-consistently with the mass renormalization effect, it is found that the even- and odd-frequency components of the order parameter coexist in the bulk system as a consequence of the broken time-reversal symmetry. This finding would direct more attention to the odd-frequency pairing that affects physical quantities, especially in strong coupling superconductors.
We report results of zero-field muon spin relaxation experiments on the filled-skutterudite superconductors~Pr$_{1-x}$Ce$_{x}$Pt$_4$Ge$_{12}$, $x = 0$, 0.07, 0.1, and 0.2, to investigate the effect of Ce doping on broken time-reversal symmetry (TRS) in the superconducting state. In these alloys broken TRS is signaled by the onset of a spontaneous static local magnetic field~$B_s$ below the superconducting transition temperature. We find that $B_s$ decreases linearly with $x$ and $\to 0$ at $x \approx 0.4$, close to the concentration above which superconductivity is no longer observed. The (Pr,…
Recently, Kaminski et al. have reported that time reversal symmetry is broken in the pseudogap phase in the high temperature superconducting material Bi_2Sr_2CaCu_2O_{2+δ} (Bi-2212). Here we examine the role of translationally invariant broken time reversal states on d_{x^2-y^2} superconductors. In particular, we determine the change in the superconducting order parameter structure. We find that the broken time reversal pseudogap state that is consistent with the experiment of Kaminski et al., gives rise to a novel mixed singlet-triplet pairing d+ip phase. This d+ip state is shown to give rise…
Motivated by the spin-triplet superconductor Sr2RuO4, the thermal Hall conductivity is investigated for several pairing symmetries with broken time-reversal symmetry. In the chiral p-wave phase with a fully opened quasiparticle excitation gap, the temperature dependence of the thermal Hall conductivity has a temperature linear term associated with the topological property directly, and an exponential term, which shows a drastic change around the Lifshitz transition. Examining f-wave states as alternative candidates with $\bm d=Δ_0\hat{z}(k_x^2-k_y^2)(k_x\pm ik_y)$ and $\bm d=Δ_0\hat{z}k_xk_y(k…
