Three-dimensional line-nodal superconductors exhibit nontrivial topology, which is protected by the time-reversal symmetry. Here we investigate four types of short-range interaction between the gapless line-nodal fermionic quasiparticles by carrying renormalization group analysis. We find that such interactions can induce the dynamical breaking of time-reversal symmetry, which alters the topology and might lead to six possible distinct superconducting states, distinguished by the group representations. After computing the susceptibilities for all the possible phase-transition instabilities, we establish that the superconducting pairing characterized by $id_{xz}$-wave gap symmetry is the leading instability in noncentrosymmetric superconductors. Appropriate extension of this approach is promising to pick out the most favorable superconducting pairing during similar topology-changing transition in the polar phase of $^3$He.
Recently, Kaminski et al. have reported that time reversal symmetry is broken in the pseudogap phase in the high temperature superconducting material Bi_2Sr_2CaCu_2O_{2+δ} (Bi-2212). Here we examine the role of translationally invariant broken time reversal states on d_{x^2-y^2} superconductors. In particular, we determine the change in the superconducting order parameter structure. We find that the broken time reversal pseudogap state that is consistent with the experiment of Kaminski et al., gives rise to a novel mixed singlet-triplet pairing d+ip phase. This d+ip state is shown to give rise…
One of the mysteries of modern condenced-matter physics is the nature of the pseudogap state of the superconducting cuprates. Kaminski et al.1 claimed to have observed signatures of time-reversal symmetry breaking in the pseudogap regime in underdoped Bi2Sr2CaCu2O8+d (Bi2212). Here we argue that the observed dichroism is due to the 5x1 superstructure replica of the electronic bands and therefore cannot be considered as evidence for the spontaneous time-reversal symmetry breaking in cuprates.
We study the behavior of spinless fermions in superconducting state, in which the phases of the superconducting order parameter depend on the direction of the link. We find that the energy of the superconductor depends on the phase differences of the superconducting order parameter. The solutions for the phases corresponding to the energy minimuma, lead to a topological superconducting state with the nontrivial Chern numbers. We focus our quantitative analysis on the properties of topological states of superconductors with different crystalline symmetry and show that the phase transition in th…
This paper has been withdrawn by the authors. We performed additional zero-field muon spin relaxation measurements in the superconducting state of CeIrIn$_5$ and found that the spontaneous fields reported previously below $T_c$ are not present. Thus, there is no evidence for a time-reversal-symmetry-violating superconducting order parameter. These new zero-field measurements, as well as new measurements of the penetration depth in this system, will be reported elsewhere. Our zero-field measurements in CeIr$_{0.5}$Rh$_{0.5}$In$_5$, reporting coexistence of superconductivity and magnetic order, …
It is pointed out that erroneous Bardeen-Cooper-Schrieffer model equations have been used by Haranath Ghosh in his recent treatment of time-reversal symmetry-breaking superconductivity. Consequently, his numerical results are misleading, and his conclusions are not to the point.
We report muon spin relaxation measurements on the superconductor Sr2RuO4 that reveal the spontaneous appearance of an internal magnetic field below the transition temperature: the appearance of such a field indicates that the superconducting state in this material is characterized by the breaking of time-reversal symmetry. These results, combined with other symmetry considerations, suggest that superconductivity in Sr2RuO4 is of p-wave (odd-parity) type, analogous to superfluid 3He.
We report on muon spin relaxation measurements of the 4f^2-based heavy-fermion superconductor filled-skutterudite PrOs4Sb12. The results reveal the spontaneous appearance of static internal magnetic fields below the superconducting transition temperature, providing unambiguous evidence for the breaking of time-reversal symmetry in the superconducting state. A discussion is made on which of the spin or orbital component of Cooper pairs carries a nonzero momentum.
Recently a phenomenological Ginzburg-Landau (GL) theory has been proposed to describe the occurrence of a locally time-reversal symmetry (T) breaking state near a Josephson junction between unconventional superconductors. In this paper we derive this type of GL free energy microscopically from the t-J model within a slave-boson mean-field approximation. The resulting GL free energy is shown to satisfy the conditions to have a T-violating surface state. The existence of this junction state may explain some of the recent experiments on High-Tc superconductors.
Surface states of d_{x^2-y^2}-wave superconductors are studied using the Ginzburg-Landau (GL) theory. For a [110] surface it has been known that the time-reversal symmetry (T) breaking surface state, (d+-is)-wave state, can occur if the bare transition temperature of the s-wave order parameter (OP) is positive. We show that even if this bare T_c is negative, it is possible to break T because the coupling to the spontaneously generated magnetic field may induce the s-wave OP. The T-breaking state is favored when the GL parameter (kappa) is small.
A detection of bosonic metallic state that breaks the $Z_2$ time-reversal symmetry has been recently reported in Ba$_{1-x}$K$_x$Fe$_2$As$_2$ with a doping level $x \approx 0.8$. This is a metallic state of fermionic quadruplets that breaks time-reversal symmetry. As such, it has no condensate of Cooper pairs but has a long-range order between fermionic quartets. In the present manuscript, we investigate the emergence of this phase in a two-component London model via Monte Carlo simulations as a function of various intercomponent couplings.
We argue that that in their recent experiment in which they claim to have found evidence for a time-reversal symmetry broken state, Kaminski et al. overlooked small temperature dependent changes in the superstructure of Bi2212. These subtle changes may manifest themselves by changing the final state configurations of the photoemission process and thus invalidate their ultimate conclusions.
I study the effects of disorder on the superconductivity of a three-band model with repulsive interband pairing. Such a model can support several possible superconducting order parameters, including a complex time-reversal symmetry breaking (TRSB) state. Impurity scattering suppresses the critical temperature of all these states, but the complex state survives, and remains a part of the phase diagram of the model even in the presence of moderate amount of disorder. This means that the TRSB states could be experimentally accessible in multiband materials like iron pnictides and chalcogenides.
In a recent comment [1], Armitage and Hu have suggested that our experiment observing dichroism in angle resolved photoemission (ARPES) [2] could not be conclusively interpreted as arising from time reversal symmetry breaking, arguing that our observations are likely due to structural effects. The concerns expressed by Armitage and Hu that our results could be due to a change in the mirror plane are as important as they are obvious. In fact the first part of their comment merely restates the results of Simon and Varma [3] about the relationship and contrast of effects due to time reversal symm…
We study time reversal symmetry breaking superconductivity with $Δ_k = Δ_{x^2-y^2} (k) +e^{iθ} Δ_α$ ($α= s$ or $d_{xy}$) symmetries. It is shown that the behavior of such superconductors could be {\em qualitatively} different depending on the minor components ($α$) and its phase at lower temperatures. It is argued that such {\em qualitatively different} behaviors in thermal as well as in angular dependencies could be a {\em source} of consequences in transport and Josephson physics. Orthorhombicity is found to be a strong mechanism for mixed phase (in case of $α= s$). We show that due to elect…
Recent experiments have pointed to a chiral p-wave-like superconductivity in epitaxial Bi/Ni bilayers that are spontaneously time-reversal symmetry breaking (TRSB), making it a promising platform for exploring physics useful for topologically protected quantum computing. Quite intriguingly, evidence has emerged that in non-epitaxial Bi/Ni bilayers, superconductivity arises due to the formation of NiBi3, which has been reported to host coexisting ferromagnetic and superconducting orders at the surface. We perform high resolution surface magneto-optic Kerr effect (SMOKE) measurements using a Sag…
Superconductivity and magnetism are antagonistic states of matter. The presence of spontaneous magnetic fields inside the superconducting state is, therefore, an intriguing phenomenon prompting extensive experimental and theoretical research. In this review, we discuss recent experimental discoveries of unconventional superconductors which spontaneously break time-reversal symmetry and theoretical efforts in understanding their properties. We discuss the main experimental probes and give an extensive account of theoretical approaches to understand the order parameter symmetries and the corresp…
A novel route to a one-dimensional Fulde-Ferrell-Larkin-Ovchinnikov (1D-FFLO) state in the absence of broken time-reversal symmetry is proposed in this paper. At present such a state may be encouraged in a clean AlAs quantum wire. Using the AlAs quantum wire as an example it is shown using bosonization and the renormalization group approach that the 1D-FFLO state can arise due to a combination of Coulomb interactions and the unique bandstructure arrangement of the AlAs quantum wire. The present theoretical proposal is very general and is applicable to other systems with similar fermionic inter…
Time-reversal symmetry breaking superconductivity in the presence of loop-current fluctuations
School of Physics and Astronomy, Beijing Normal University(北京师范大学物理与天文学院);Key Laboratory of Multiscale Spin Physics (Beijing Normal University), Ministry of Education(教育部多尺度自旋物理重点实验室(北京师范大学));Beijing Computational Science Research Center(北京计算科学研究中心);New Cornerstone Science Laboratory, Department of Physics, School of Science, Westlake University(西湖大学理学院物理系新基石科学实验室);Institute for Theoretical Sciences, Westlake University(西湖大学理论科学研究院);Key Laboratory for Quantum Materials of Zhejiang Province, School of Science, Westlake University(西湖大学理学院浙江省量子材料重点实验室);Institute of Natural Sciences, Westlake Institute for Advanced Study(西湖高等研究院自然科学研究院)
We show that the observed time-reversal symmetry breaking (TRSB) of the superconducting state in $\mathrm{Sr}_{2}\mathrm{Ru}\mathrm{O}_{4}$ can be understood as originating from inhomogeneous strain fields near edge dislocations of the crystal. Specifically, we argue that, without strain inhomogeneities, $\mathrm{Sr}_{2}\mathrm{Ru}\mathrm{O}_{4}$ is a single-component, time-reversal symmetric superconductor, likely with $d_{x^{2}-y^{2}}$ symmetry. However, due to the strong strain inhomogeneities generated by dislocations, a slowly-decaying sub-leading pairing state contributes to the condensa…
We show that an isolated impurity in a spin singlet d_{x2-y2} superconductor generates a d_{xy} order parameter with locally broken time-reversal symmetry. The origin of this effect is a coupling between the d_{x2-y2} and the d_{xy} order parameter induced by spin-orbit scattering off the impurity. The signature of locally broken time-reversal symmetry is an induced orbital charge current near the impurity, which generates a localized magnetic field in the vicinity of the impurity. We present a microscopic theory for the impurity induced d_{xy} component, discuss its spatial structure as well …
We study magnetization reversal in a $φ_0$ Josephson junction with direct coupling between magnetic moment and Josephson current. Our simulations of magnetic moment dynamics show that by applying an electric current pulse, we can realize the full magnetization reversal. We propose different protocols of full magnetization reversal based on the variation of the Josephson junction and pulse parameters, particularly, electric current pulse amplitude, damping of magnetization and spin-orbit interaction. We discuss experiments which can probe the magnetization reversal in $φ_0$-junctions.
We propose a mechanism that helps stabilize a superconducting state with broken time-reversal symmetry, which was predicted to realize in a d-wave superconducting film [A. B. Vorontsov, Phys. Rev. Lett. 102, 177001 (2009)]. In this superconducting phase, the time-reversal symmetry breaking is accompanied by spontaneous breaking of the translation symmetry along the film surface. We examine how the normal-superconducting phase boundary in the thickness-temperature phase diagram of the film is modified depending on the Fermi surface shape. In particular, the nonuniform superconducting phase is f…
We discuss the phase diagram and phase transitions in $U(1)\times \groupZ{2}$ three-band superconductors with broken time reversal symmetry. We find that beyond mean field approximation and for sufficiently strong frustration of interband interactions there appears an unusual metallic state precursory to a superconducting phase transition. In that state, the system is not superconducting. Nonetheless, it features a spontaneously broken $\groupZ{2}$ time reversal symmetry. By contrast, for weak frustration of interband coupling the energy of a domain wall between different $\groupZ{2}$ states i…
Strong-coupling approach to temperature dependence of competing orders of superconductivity: Possible time-reversal symmetry breaking and nontrivial topology
The multipocket Fermi surfaces of iron-based superconductors promote pairing states with both s_{+-}-wave and d_{x^2-y^2}-wave symmetry. We argue that the competition between these two order parameters could lead to a time-reversal-symmetry breaking state with s+id-pairing symmetry in the iron-based superconductors, and propose serveral scenarios in which this phase may be found. To understand the emergence of such a pairing state on a more rigorous footing, we start from a microscopic 5-orbital description representative for the pnictides. Using a combined approach of functional renormalizati…
Elemental rhenium exhibiting type-II superconductivity has been previously reported to break time-reversal symmetry in the superconducting state. We have investigated an arc-melted sample of rhenium exhibiting type-I superconductivity. Low temperature zero-field muon-spin relaxation measurements indicate that time-reversal symmetry is preserved in the superconducting state. Muon diffusion is observed, which is due to quantum mechanical tunneling between interstitial sites. The normal state behavior is characterized by the conduction electrons screening the muons and thermal broadening, and is …
Comment on "High Resolution Polar Effect Measurements of Sr2RuO4: Evidence for Broken Time-Reversal Symmetry in the Superconducting State" by J. Xia et al., Phys. Rev. Lett. 97, 167002 (2006).
Polar Kerr effect in the spin-triplet superconductor Sr2RuO4 was measured with high precision using a Sagnac interferometer with a zero-area Sagnac loop. We observed non-zero Kerr rotations as big as 65 nanorad appearing below Tc in large domains. Our results imply a broken time reversal symmetry state in the superconducting state of Sr2RuO4, similar to He3-A.
Time-reversal symmetry breaking (TRSB) with a Bardeen-Cooper-Schrieffer (BCS) -like superconductivity occurs in a small, but growing number of noncentrosymmetric (NCS) materials, although the mechanism is poorly understood. We present heat capacity, magnetization, resistivity, and muon spin resonance/relaxation ($μ$SR) measurements on polycrystalline samples of NCS La$_{7}$Pd$_{3}$. Transverse-field $μ$SR and heat capacity data show La$_{7}$Pd$_{3}$ is a type-II superconductor with a BCS-like gap structure, while zero-field $μ$SR results provide evidence of TRSB. We discuss the implications of…
We report the discovery of Zr$_3$Ir as a new type of unconventional noncentrosymmetric superconductor (with $T_c = 2.3$ K), here investigated mostly via muon-spin rotation/relaxation ($μ$SR) techniques. Its superconductivity was characterized using magnetic susceptibility, electrical resistivity, and heat capacity measurements. The low-temperature superfluid density, determined via transverse-field $μ$SR and electronic specific heat, suggests a fully-gapped superconducting state. The spontaneous magnetic fields, revealed by zero-field $μ$SR below $T_c$, indicate the breaking of time-reversal s…
Competition between the vortex lattice and a lattice of asymmetric artificial defects is shown to play a crucial role in ratchet experiments in superconducting films. We present a novel and collective mechanism for current reversal based on a reconfiguration of the vortex lattice. In contrast to previous models of vortex current reversal, the mechanism is based on the global response of the vortex lattice to external forces.
The antisymmetrised two-electron functions are constructed for the point group T$_{h}$, i.e. the symmetry group of unconventional superconductor PrOs$% _{4}$Sb$_{14}$., and its subgroup D$_{2h}$.The nodal structure of these function depending on the wavevector group is investigated. Theoretical nodal structure of these functions made possible to explain the experimental nodal structure PrOs$_{4}$Sb$_{14}$. as a result of time-reversal symmetry violation.
In this paper we study the order parameter and density of states near a grain boundary between two $d_{x^2-y^2}$ superconductors. We examine broken time reversal symmetry near the interface. In particular we show that, under suitable circumstances, time reversal symmetry must be broken even when the order parameter is purely $d_{x^2-y^2}$ everywhere in space.
Recent experimental and theoretical interest in the superconducting phase of the heavy fermion material URu$_2$Si$_2$ has led to a number of proposals in which the superconducting order parameter breaks time-reversal symmetry (TRS). In this study we measured polar Kerr effect (PKE) as a function of temperature for several high-quality single crystals of URu$_2$Si$_2$. We find an onset of PKE below the superconducting transition that is consistent with a TRS-breaking order parameter. This effect appears to be independent of an additional, possibly extrinsic, PKE generated above the hidden order…
We have investigated the superconducting state of the non-centrosymmetric compound Re6Zr using magnetization, heat capacity, and muon-spin relaxation/rotation (muSR) measurements. Re6Zr has a superconducting transition temperature, Tc = 6.75 K. Transverse-field muSR experiments, used to probe the superfluid density, suggest an s-wave character for the superconducting gap. However, zero and longitudinal-field muSR data reveal the presence of spontaneous static magnetic fields below Tc indicating that time-reversal symmetry is broken in the superconducting state and an unconventional pairing mec…
Recent mean-field calculations suggest that the superconducting state of twisted bilayer graphene exhibits either a nematic order or a spontaneous breakdown of the time-reversal symmetry. The two-dimensional character of the material and the large critical temperature relative to the Fermi energy dictate that the material should have significant fluctuations. We study the effects of these fluctuations using Monte Carlo simulations. We show that in a model proposed earlier for twisted bilayer graphene there is a fluctuation-induced phase with quadrupling fermionic order for all considered param…
We consider a Rashba spin-orbit coupled nanowire with anisotropic spin-singlet superconducting pairing and time-reversal-invariant symmetry. We explore the evolution of the topological superconducting phases of this system due to geometric deformations for the representative case of a wire bent in a semielliptical shape. We find that when the system is in its topological superconducting phase, strong inhomogeneities in the profile curvature can produce a pair of localized eigenmodes, which can be attributed to a nonuniform topological phase. The curved geometric profile also allows to tune the…
We demonstrate that films of unconventional (d-wave) superconductor at temperatures $T\lesssim 0.43 T_c$ can exhibit unusual superconducting phases. The new ground states beside the broken gauge and the point group symmetries can spontaneously break (i) continuous translational symmetry and form periodic order parameter structures in the plane of the film, or (ii) time-reversal symmetry and develop supercurrent flowing along the film. These states are result of the strong transverse inhomogeniety present in films with thickness of several coherence lengths. We show a natural similarity between…
Odd-frequency superconductivity describes a class of superconducting states where the superconducting gap is an odd function in relative time and Matsubara frequency. We present a group theoretical analysis based on the linearized gap equation in terms of Shubnikov groups of the second kind. By discussing systems with spin-orbit coupling and an interaction kernel which is symmetric under the reversal of relative time, we show that both even- and odd-frequency gaps are allowed to occur. Specific examples are discussed for the square lattice, the octahedral lattice, and the tetragonal lattice. F…
The single helical Fermi surface on the surface state of three-dimensional topological insulator Bi2Se3 is constrained by the time-reversal invariant bulk topology to possess a spin-singlet superconducting pairing symmetry. In fact, the Cu-doped, and pressure-tuned superconducting Bi2Se3 show no evidence of the time reversal symmetry breaking. We report on the detection of the time reversal symmetry (TRS) breaking in the topological superconductor Sr0.1Bi2Se3 , probed by zero-field (ZF) μSR measurements. The TRS breaking provides strong evidence for the existence of spin-triplet pairing state.…
We solve the Bogoliubov-de Gennes equations self-consistently for d-wave superconductors with [110] surfaces. We find spontaneous breaking of time-reversal symmetry (TRS) caused by the spontaneous occurrence of a complex order parameter with an extended s-wave symmetry along the [110] surfaces. In the TRS-breaking phase, the d-wave order parameter itself becomes complex. We also show that vortex-antivortex pairs can appear along the [110] surfaces of nanoribbons. These pairs are detectable with surface sensitive probes.
The noncentrosymmetric superconductor Re$_{24}$Ti$_{5}$, a time-reversal symmetry (TRS) breaking candidate with $T_c = 6$\,K, was studied by means of muon-spin rotation/relaxation ($μ$SR) and tunnel-diode oscillator (TDO) techniques. At a macroscopic level, its bulk superconductivity was investigated via electrical resistivity, magnetic susceptibility, and heat capacity measurements. The low-temperature penetration depth, superfluid density and electronic heat capacity all evidence an $s$-wave coupling with an enhanced superconducting gap. The spontaneous magnetic fields revealed by zero-field…
We investigate the nature of the time-reversal breaking pairing state in the hole-doped monolayer MoS$_{2}$ on the basis of the realistic three-orbital attractive Hubbard-like model with the atomic spin-orbit coupling. Due to the multi-band features arising from the Mo $d$ orbitals in the noncentrosymmetric crystal structure, the Lifshitz transition takes place upon hole doping. Across the Lifshitz transition point, the sign of the relative phase between the Cooper-pair components drastically changes, leading to the emergence of the time-reversal breaking phase with complex gap functions. It i…
We consider different effects that arise when time-reversal symmetry breaking superconductors are subjected to an external magnetic field, thus rendering the superconductor to be in the mixed state. We focus in particular on two time-reversal symmetry breaking order parameters which are believed to be realized in actual materials: $p+ıp'$-wave and $d+ıs$- or $d+ıd'$-wave. The first order parameter is relevant for Sr$_2$RuO$_4$, while the latter order parameters have been suggested to exist near surfaces in some of the high-$T_c$ cuprates. We investigate the interplay between surface states and…
We report the results of a zero-field muon spin relaxation (ZF-muSR) study of superconducting Ba1-xKxFe2As2 (0.5 < x < 0.9) in search of weak spontaneous internal magnetic fields associated with proposed time-reversal-symmetry breaking mixed pairing states. The measurements were performed on polycrystalline samples, which do not exhibit the mesoscopic phase separation previously observed in single crystals of Ba1-xKxFe2As2. No evidence of spontaneous internal magnetic fields is found in any of the samples at temperatures down to T ~ 0.02 K.
We have studied the electronic properties of ScS, a transition-metal monochalcogenide with rocksalt crystal structure, using magnetization, specific heat, transport, and muon spin rotation/relaxation ($μ$SR) measurements. All measurements confirm the bulk superconducting in ScS with a transition temperature of $T_{C}$ = 5.1(5) K. Specific heat together with transverse-field $μ$SR measurements indicate a full gap, while our zero-field $μ$SR study reveals the presence of spontaneous static or quasi-static magnetic fields emerging when entering the superconducting state. We discuss various possib…
We have investigated the superconducting state of the noncentrosymmetric superconductor Re6Ti (Tc = 6.0 K) using muon-spin rotation/relaxation (muSR) technique. The zero-field muon experiment shows the presence of spontaneous magnetic fields in the superconducting state, indicating time-reversal symmetry breaking (TRSB). However, the low-temperature transverse field muon measurements suggest nodeless s-wave superconductivity. The time reversal symmetry breaking further confirmed in the stoichiometric composition Re24Ti5. These results indicate that the pairing symmetry is not affected by spin-…
We study the boundary Majorana modes for the single component p-wave weak topological superconductors or superfluids, which form zero energy flat bands protected by time-reversal symmetry in the orbital channel. However, due to the divergence of density of states, the band flatness of the edge Majorana modes is unstable under spontaneously generated spatial variations of Cooper pairing phases. Staggered current loops appear near the boundary and thus time-reversal symmetry is spontaneously broken in the orbital channel. This effect can appear in both condensed matter and ultra-cold atom system…
Noncentrosymmetric superconductors have sparked significant research interests due to their exciting properties, such as the admixture of spin-singlet and spin-triplet Cooper pairs. Here we report $μ$SR and thermodynamic measurements on the noncentrosymmetric superconductor La7Rh3 which indicate a fully established superconducting gap and spontaneous time-reversal-symmetry breaking at the onset of superconductivity. We show that our results pose severe constraints on any microscopic theory of superconductivity in the system. A symmetry analysis identifies ground states compatible with time-rev…
A topological argument is presented for nodal structures of superconducting states with time-reversal invariance. A generic Hamiltonian which describes a quasiparticle in superconducting states with time-reversal invariance is derived, and it is shown that only line nodes are topologically stable in single-band descriptions of superconductivity. Using the time-reversal symmetry, we introduce a real structure and define topological numbers of line nodes. Stability of line nodes is ensured by conservation of the topological numbers. Line nodes in high-Tc materials, the polar state in p-wave pari…
Zero and longitudinal field muon spin rotation (muSR) experiments were performed on the superconductors PrPt4Ge12 and LaPt4Ge12. In PrPt4Ge12 below Tc a spontaneous magnetization with a temperature variation resembling that of the superfluid density appears. This observation implies time-reversal symmetry (TRS) breaking in PrPt4Ge12 below Tc = 7.9 K. This remarkably high Tc for an anomalous superconductor and the weak and gradual change of Tc and of the related specific heat anomaly upon La substitution in La_(1-x)Pr_xPt_4Ge_(12) suggests that the TRS breaking is due to orbital degrees of free…
The emergence of superconductivity in doped Mott insulators has been debated for decades. In this paper, we report the theoretical discovery of a time-reversal symmetry breaking superconducting ground state in the doped Mott insulator (described by the well known t-J model) on honeycomb lattice, based on a recently developed variational method: the Grassmann tensor product state approach. As a benchmark, we use exact diagonalization and density-matrix renormalization methods to check our results on small clusters. We find systematic consistency for the ground-state energy as well as other phys…
The discovery of new families of unconventional superconductors is important both experimentally and theoretically, especially if it challenges current models and thinking. By using muon spin relaxation in zero-field, time-reversal symmetry breaking has been observed in Re6Hf. Moreover, the temperature dependence of the superfluid density exhibits s-wave superconductivity with an enhanced electron-phonon coupling. This, coupled with the results from isostructural Re6Zr, shows that the Re6X family are indeed a new and important group of unconventional superconductors.
We have measured the field dependence of the Zero Bias Conductance Peak (ZBCP) of tunnel junctions prepared on (110) oriented Y1Ba2Cu3O7-d films of various thickness. We have found that the field splitting of the ZBCP, believed to be due to the Time Reversal Symmetry Breaking (TRSB) of Andreev surface bound states, is independent of film thickness. This rules out that Meissner screening currents are at the origin of TRSB. We conclude that TRSB must, instead, be due to a field-induced modification of the Order parameter. Different possibilities involving an imaginary component are discussed.