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arXiv 1908.04609cond-mat.str-el
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DyMn $_2$ O $_5$的磁电行为:空穴掺杂效应

Magnetic and electric behaviors of DyMn$_2$O$_5$: effect of hole doping

P. Dutta, M. Das, S. Mukherjee, S. Chatterjee, S. Giri, S. Majumdar

摘要:

DyMn $_2$ O $_5$是一种有趣的多铁性材料,具有多种磁、电和结构转变。本文通过磁性和介电测量系统地研究了Sr掺杂对DyMn $_2$ O $_5$中Dy位的影响。在Dy位点处掺杂二价Sr预期提高Mn $^{4+}$:Mn $^{3+}$比率,并且其还将稀释Dy位点。我们的研究表明,在接近43 K,我们认为这是与增加的铁磁相关Sr掺杂的磁异常的大增强。在3 K的矫顽场的逐渐增加与Sr掺杂和相邻的Mn $^{4+}$离子的键长的减少进一步支持系统中的铁磁相关性的增强。母体样品在12 K附近表现出较大的磁热效应,其幅度随着Sr浓度的增加而减小。掺杂还增强了在介电常数与温度数据中观察到的在28 K左右的异常,并且这种异常早先被认为与自旋重取向以及从一种铁电状态到另一种铁电状态的同时转变有关。发现在25 K以下观察到的电有序对外加磁场敏感,并支持Ratcliff II { \it et al.}(Phys. Rev. B { \bf 72},060407(R)(2005))中描述了与多个电跃迁相关联的磁结构中的伴随变化。

英文摘要:

DyMn$_2$O$_5$ is an intriguing multiferroic material showing multiple magnetic, electric and structural transitions. We present here the systematic study on the effect of Sr doping at the Dy site of DyMn$_2$O$_5$ through magnetic and dielectric measurements. Doping of divalent Sr at the Dy site is expected to enhance the Mn$^{4+}$:Mn$^{3+}$ ratio and it will also dilute the Dy site. Our study indicates large enhancement in the magnetic anomaly observed close to 43 K, which we believe to be related to the increased ferromagnetic correlations on Sr doping. Gradual increase in coercive field at 3 K with the Sr doping and decrease in bond length of adjacent Mn$^{4+}$ ions further support the enhancement of ferromagnetic corelations in the system. The parent sample shows a large magnetocaloric effect around 12 K, the magnitude of which found to decrease with increasing Sr concentration. The doping also enhances the anomaly at around 28 K observed in the dielectric permittivity versus temperature data, and this anomaly was earlier claimed to be associated with the spin reorientation as well as a simultaneous transition from one ferroelectric state to other. The electric orderings observed below 25 K are found to be susceptible to the applied magnetic field, and supports the view of Ratcliff II {\it et al.}(Phys. Rev. B {\bf 72}, 060407(R)(2005)) of concomitant changes in the magnetic structure associated with the multiple electric transitions.

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