We show that doping of hole charge carriers leads to formation of electric dipolar clusters in cuprates. They are created by many-body interactions between the dopant ion outside and holes inside the CuO planes. Because of the two-fold degeneracy holes in the CuO plane cluster into four-particles resonance valence bond plaquettes bound with dopant ions. Such dipoles may order into charge-density waves (CDW) or stripes or form a disordered state depending on doping and temperature. The lowest energy of the ordered system corresponds to a local anti-ferroelectric ordering. The mobility of individual disordered dipoles is very low at low temperatures and they prefer first to bind into dipole-dipole pairs. Electromagnetic radiation interacts strongly with electric dipoles and when the sample is subjected to it the mobility changes significantly. This leads to a fractal growth of dipolar clusters. The existence of electric dipoles and CDW induce two phase transitions with increasing temperature, melting of the ordered state and disappearance of the dipolar state. Ferroelectricity at low doping is a natural consequence of such dipole moments. We develop a theory based on two-level systems and dipole-dipole interaction to explain the behavior of the polarization as a function of temperature and electric field.
Motivated by recent experimental and theoretical progresses of the magnetic properties of iron-based superconductors, we provide a comprehensive analysis of the spin-1 bilinear-biquadratic (BBQ) model on the square lattice. Using variational approach in the mean-field level, we identify the existence of various magnetic phases, including conventional spin dipolar orderings (ferro- or antiferromagnet), novel quadrupolar (spin nematic) orderings and mixed dipolar-quadrupolar orderings. In contrast to the usual Heisenberg model, the elementary excitations of the spin-1 BBQ model are described by …
Strongly correlated quantum particles in lattice potentials are the building blocks for a large variety of quantum insulators, for instance Mott phases and density waves breaking the lattice symmetry. Such collective states are accessible to bosonic and fermionic systems. To expand further the spectrum of accessible quantum matter phases, mixing both species is theoretically appealing, since density order then competes with phase separation. Here we manipulate such Bose-Fermi mixture by confining neutral (boson-like) and charged (fermion-like) dipolar excitons in an artificial square lattice o…
The temperature dependence of electric dipolar susceptibility χ_P is discussed on the basis of the Anderson-Holstein model with the use of a numerical renormalization group (NRG) technique. Note that P is related with phonon Green's function D. In order to obtain correct temperature dependence of P at low temperatures, we propose a method to evaluate P through the Dyson equation from charge susceptibility χ_c calculated by the NRG, in contrast to the direct NRG calculation of D. We find that the irreducible charge susceptibility estimated from χ_c agree with the perturbation calculation, sugge…
Using resonant inelastic x-ray scattering, we observe in the bilayer iridate Sr3Ir2O7, a spin-orbit coupling driven magnetic insulator with a small charge gap, a magnon gap of ~92 meV for both acoustic and optical branches. This exceptionally large magnon gap exceeds the total magnon bandwidth of ~70 meV and implies a marked departure from the Heisenberg model, in stark contrast to the case of the single-layer iridate Sr2IrO4. Analyzing the origin of these observations, we find that the giant magnon gap results from bond-directional pseudo-dipolar interactions that are strongly enhanced near t…
We study the dipolar spin-ice model at fixed density of single excitations, $ρ$, using a Monte Carlo algorithm where processes of creation and annihilation of such excitations are banned. In the limit of $ρ$ going to zero, this model coincides with the usual dipolar spin-ice model at low temperatures, with the additional advantage that a negligible number of monopoles allows for equilibration even at the lowest temperatures. Thus, the transition to the ordered fundamental state found by Melko et al. in 2001 is reached using simple local spin flip dynamics. As the density is increased, the mono…
We study Ising pyrochlores by means of Monte Carlo simulations. We cover a set of exchange constants ranging from the frustrated ferromagnetic case (spin-ice) to the fully-ordered "all-in--all-out" antiferromagnet in the dipolar model, reinterpreting the results --as in an ionic system-- in terms of a temperature vs. magnetic charge density phase diagram. In spite of its spin nature and the presence of both double and single non-conserved magnetic charges, the dipolar model gives place to a phase diagram which is quite comparable with those previously obtained for on-lattice systems of electri…
We study the electron and phonon spectral functions as well as superconductivity for a two dimensional electron gas couped to dipolar phonons via small-momentum transfer scattering. The results reported here are obtained through sign-problem-free quantum Monte-Carlo simulation. Hence aside from modeling there is no further approximations. Our results can be relevant to the high-temperature superconductor at the interface between a unit-cell-thick FeSe and SrTiO3.
Motivated by recent experimental progress in the field of dipolar-Fermi gases, we investigate the quantum phases of dipolar fermions, on a triangular ladder at half filling. Using density matrix renormalization group method, in presence of onsite repulsion and intersite attractive interaction, we find exotic spin-triplet superfluid phase in addition to the usual spin-density and charge-density waves. We examine the stability of spin-triplet superfluid phase by varying hopping along the rungs of the triangle. Possibility of fermionic supersolidity has also been discussed, by considering three- …
Spin ice, a peculiar thermal state of a frustrated ferromagnet on the pyrochlore lattice, has a finite entropy density and excitations carrying magnetic charge. By combining analytical arguments and Monte Carlo simulations, we show that spin ice on the two-dimensional kagome lattice orders in two stages. The intermediate phase has ordered magnetic charges and is separated from the paramagnetic phase by an Ising transition. The transition to the low-temperature phase is of the three-state Potts or Kosterlitz-Thouless type, depending on the presence of defects in charge order.
We investigate bosonic atoms or molecules interacting via dipolar interactions in a planar array of one-dimensional tubes. We consider the situation in which the dipoles are oriented perpendicular to the tubes by an external field. We find various quantum phases reaching from a `sliding Luttinger liquid' phase in which the tubes remain Luttinger liquids to a two-dimensional charge density wave ordered phase. Two different kinds of charge density wave order occur: a stripe phase in which the bosons in different tubes are aligned and a checkerboard phase. We further point out how to distinguish …
Superconductors with kagome lattices have been identified for over 40 years, with a superconducting transition temperature TC up to 7K. Recently, certain kagome superconductors have been found to exhibit an exotic charge order, which intertwines with superconductivity and persists to a temperature being one order of magnitude higher than TC. In this work, we use scanning tunneling microscopy (STM) to study the charge order in kagome superconductor RbV3Sb5. We observe both a 2x2 chiral charge order and nematic surface superlattices (predominantly 1x4). We find that the 2x2 charge order exhibits…
Minimum model calculations on the co-action of hole vanishing Lifshitz transitions and correlation effects in ferropnictides are presented. The calculations predict non-Fermi-liquid behaviour and huge mass enhancements of the charge carriers at the Fermi level. The findings are compared with recent ARPES experiments and with measurements of transport and thermal properties of ferropnictides. The results from the calculation can be also applied to other unconventional superconductors and question the traditional view of quantum critical points.
The idea of spin-charge separation in cuprate superconductors has been recently energized by Senthil and Fisher who formulated a Z_2 gauge theory and, within its context, proposed a ``vison detection'' experiment as a test for topological order in a sample with multiply connected geometry. Here we show that the same experiment can be performed to test for the spin-charge separation in U(1) [but not in SU(2)] theory and argue that vortex core spectroscopy can in fact distinguish between the different symmetries of the fictitious gauge field.
Two-dimensional (2D) moire materials provide a new solid-state platform with unprecedented controllability for studies of correlated quantum phenomena. To date, experimental studies have focused on the correlated electronic states; the correlated bosonic states in moire materials have remained practically unexplored. Here, we report a correlated dipolar excitonic insulator, a charge insulating state driven by the formation of excitons, in a Coulomb-coupled WSe2 monolayer and WSe2/WS2 moire bilayer at total hole doping density equal to the moire density. The system is a Mott insulator when all …
Intense light-field application to solids produces enormous/ultrafast non-linear phenomena such as high-harmonic generations 1, 2 and attosecond charge dynamics 3, 4. They are distinct from conventional photonics. However, main targets have been limited to insulators and semiconductors, although theoretical approaches have been made also for correlated metals and superconductors 5. Here, in a layered organic superconductor, a non-linear charge oscillation driven by a nearly single-cycle strong electric field of >10 megavolts /cm is observed as a stimulated emission. The charge oscillation is d…
We study a system of dipolar bosons in a one-dimensional optical lattice using exact diagonalization and density matrix renormalization group methods. In particular, we analyze low energy properties of the system at an average filling of 3/2 atoms per lattice site. We identify the region of the parameter space where the system has non-Abelian Fibonacci anyon excitations that correspond to fractional domain walls between different charge-density-waves. When such one-dimensional systems are combined into a two-dimensional network, braiding of Fibonacci anyon excitations has potential application…
Motivated by recent experiments in fermionic polar gases, we study the non-equilibrium dynamics of two-component dipolar fermions subject to a quasiperiodic potential. We investigate the localization of charge and spin degrees of freedom time evolving with a long-range spin-SU(2) symmetric fermionic Hamiltonian, by calculating experimentally accessible dynamical observables. To study the non-equilibrium dynamics, we start the time evolution with two initial states at half-filling: (i) product state with doublons $|\uparrow \downarrow 0 \uparrow \downarrow 0 \uparrow \downarrow 0 \uparrow \down…
The competition between intertube hopping processes and density-density interactions is investigated in one-dimensional quantum dipolar bosons systems of N coupled tubes at zero temperature. Using a phenomenological bosonization approach, we show that the resulting competition leads to an exotic quantum phase transition described by a U(1) x Z_N conformal field theory with a fractional central charge. The emerging Z_N parafermionic critical degrees of freedom are highly nontrivial in terms of the original atoms or polar molecules of the model. We further determine the main physical properties …
We develop a theoretical proposal for the charge Kondo effect in mesoscopic normal-superconductor-normal heterostructures, where the superconducting gap exceeds the electrostatic charging energy. Charge-Kondo correlations in these devices alter the conventional temperature-dependence of Andreev reflection and electron cotunneling. We predict typical Kondo temperatures of $\gtrsim 10 {\rm mK}$, and suggest experimental architectures that combine superconducting charge-qubits with semiconducting nanowires at cryogenic temperatures.
The theory of hole superconductivity proposes that the fundamental asymmetry between electrons and holes in solids is responsible for superconductivity. Here we point out a remarkable consequence of this theory: a tendency for negative charge to be expelled from the bulk of the superconductor towards the surface. Experimentally observable consequences of this physics are discussed.
We find chiral charge order in the superconductor 2H-TaS2 using Scanning Tunneling Microscopy and Spectroscopy (STM/S) at 0.1 K. Topographic images show hexagonal atomic lattice and charge density wave (CDW) with clockwise and counterclockwise charge modulations. Tunneling spectroscopy reveals the superconducting density of states, disappearing at Tc = 1.75 K and showing a wide distribution of values of the superconducting gap, centered around Δ=0.28 meV.
Charge-$4e$ superconductivity as a novel phase of matter remains elusive so far. Here we show that charge-$4e$ phase can arise as a vestigial order above the nematic superconducting transition temperature in time-reversal-invariant nematic superconductors. On the one hand, the nontrivial topological defect -- nematic vortex -- is energetically favored over the superconducting phase vortex when the nematic stiffness is less than the superfluid stiffness; consequently the charge-$4e$ phase emerges by proliferation of nematic vortices upon increasing temperatures. On the other hand, the Ginzburg-…
This short review aims to summarize on "What the Charge Density Waves can tell to other inhomogeneous states in strongly correlated systems, particularly to spin-polarized superconductors". We shall update on expanding observations of solitons in quasi 1D CDW conductors and link them to the growing information and demands related to inhomogeneous spin-polarized states in superconductors. The related theory, existent or awaited for, stretches from solitons in 1D models to vortex-like elementary excitations in 2D,3D ordered incommensurate CDWs and superconductors.
In this contribution we review recent ARPES results on the dressing of the charge carriers in high-temperature superconductors. After an introduction into the cuprates and their electronic structure, ARPES, the spectral function and the self-energy function in the normal state and in the superconducting state is discussed.. Finally results on the dressing of the charge carriers in the system Bi2Sr2caCu2O7 at the nodal and the antinodal point are presented.
Quadrupolar and dipolar phases of excitons in transition-metal dichalcogenide trilayer heterostructures
The Racah Institute of Physics, The Hebrew University of Jerusalem（拉卡物理研究所，耶路撒冷希伯来大学）；Department of Physics, Technion（理工学院物理系）；The Fritz Haber Research Center for Molecular Dynamics, The Hebrew University of Jerusalem（分子动力学弗里茨·哈伯研究中心，耶路撒冷希伯来大学）
The theory of hole superconductivity proposes that superconductivity originates in the fundamental electron-hole asymmetry of condensed matter and that it is an 'undressing' transition. Here we propose that a natural consequence of this theory is that superconductors behave as giant atoms. The model predicts that the charge distribution in superconductors is inhomogeneous, with higher concentration of negative charge near the surface. Some of this negative charge will spill out, giving rise to a negative electron layer right outside the surface of the superconductor, which should be experiment…
We report a first experimental evidence that a vortex in the high temperature superconductors (HTSC) traps a finite electric charge from the high resolution measurements of the nuclear quadrupole frequencies. In slightly overdoped YBa_2Cu_3O_7 the vortex is negatively charged by trapping electrons, while in underdoped YBa_2Cu_4O_8 it is positively charged by expelling electrons. The sign of the trapped charge is opposite to the sign predicted by the conventional BCS theory. Moreover, in both materials, the deviation of the magnitude of the charge from the theory is also significant. These unex…
Charge ordering is one of the most intriguing and extensively studied phenomena in correlated electronic materials because of its strong impact on electron transport properties including superconductivity. Despite its ubiquitousness in correlated systems, the occurrence of charge ordering in iron-based superconductors is still unresolved. Here we use scanning tunneling microscopy to reveal a long-range charge-stripe order and a highly anisotropic dispersion of electronic states in the ground state of stoichiometric FeTe, the parent compound of the Fe(Te, Se, S) superconductor family. The forma…
Neutron scattering experiments have played a crucial role in characterizing the spin and charge correlations in copper-oxide superconductors. While the data are often interpreted with respect to specific theories of the cuprates, an attempt is made here to distinguish those facts that can be extracted empirically, and the connections that can be made with minimal assumptions.
The theory of hole superconductivity predicts that when a metal goes superconducting negative charge is expelled from its interior towards the surface. As a consequence the superconductor in its ground state is predicted to have a non-homogeneous charge distribution and an outward pointing electric field in its interior. Here we propose equations to describe the behavior of the charge density and electric field in superconductors, and solve them for a spherical geometry. The magnitude of the predicted interior electric field depends on superconducting parameters such as the condensation energy…
The recent development of x-ray scattering techniques revealed the charge-excitation spectrum in high-$T_c$ cuprate superconductors. While the presence of a dispersive signal in the high-energy charge-excitation spectrum is well accepted in the electron-doped cuprates, its interpretation and universality are controversial. Since charge fluctuations are observed ubiquitously in cuprate superconductors, the understanding of its origin is a pivotal issue. Here, we employ the layered $t$-$J$ model with the long-range Coulomb interaction and show that an acoustic-like plasmon mode with a gap at in-…
We study the electrodynamics of spin triplet superconductors including dipolar interactions, which give rise to an interplay between the collective spin dynamics of the condensate and orbital Meissner screening currents. Within this theory, we identify a class of spin waves that originate from the coupled dynamics of the spin-symmetry breaking triplet order parameter and the electromagnetic field. In particular, we study magnetostatic spin wave modes that are localized to the sample surface. We show that these surface modes can be excited and detected using experimental techniques such as micr…
We report Raman scattering measurement of charge nematic fluctuations in the tetragonal phase of BaFe$_2$As$_2$ and Sr(Fe$_{1-x}$Co$_x$)$_2$As$_2$ (x=0.04) single crystals. In both systems, the observed nematic fluctuations are found to exhibit divergent Curie-Weiss like behavior with very similar characteristic temperature scales, indicating a universal tendency towards charge nematic order in 122 iron-based superconductors.
Superconductivity occurs in systems that have a lot of negative charge: the highly negatively charged $(CuO2)^{--}$ planes in the cuprates, negatively charged $(FeAs)^-$ planes in the iron arsenides, and negatively charged $B^-$ planes in magnesium diboride. And, in the nearly filled (with negative electrons) bands of almost all superconductors, as evidenced by their positive Hall coefficient in the normal state. According to the theory of hole superconductivity, metals become superconducting because they are driven to expel negative charge (electrons) from their interior. This is why NIS tunn…
A charge-$4e$ superconductor forms due to the condensation of quartets of electrons. While in previous works the mechanism for the formation of charge-$4e$ superconductivity has been analyzed in terms of the binding of Cooper pairs in unconventional superconductors, its properties in the fermionic sector have not been studied systematically due to its inherently interacting nature even at the mean-field level. Here we propose a solvable model for a charge-$4e$ superconductor -- a spinful version of the Sachdev-Ye-Kitaev model with an anomalous quartic term. We show that the ground state is gap…
In recent work we formulated a new set of electrodynamic equations for superconductors as an alternative to the conventional London equations, compatible with the prediction of the theory of hole superconductivity that superconductors expel negative charge from the interior towards the surface. Charge expulsion results in a macroscopically inhomogeneous charge distribution and an electric field in the interior, and because of this a spin current is expected to exist. Furthermore, we have recently shown that a dynamical explanation of the Meissner effect in superconductors leads to the predicti…
We present the first infrared and optical study in the normal state of ab-plane oriented single crystals of the iron-oxypnictide superconductor LaFePO. We find that this material is a low carrier density metal with a moderate level of correlations and exhibits signatures of electron-boson coupling. The data is consistent with the presence of coherent quasiparticles in LaFePO.
Recent neutron scattering, nuclear magnetic resonance, and scanning tunneling microscopy experiments have yielded valuable new information on the interplay between charge and spin density wave order and superconductivity in the cuprate superconductors, by using an applied perpendicular magnetic field to tune the ground state properties. We compare the results of these experiments with the predictions of a theory which assumed that the ordinary superconductor was proximate to a quantum transition to a superconductor with co-existing spin/charge density wave order.
In this paper we study a novel superconductor-ferromagnet-superconductor (SC-FM-SC) Josephson junction array deposited on top of a two-dimensional quantum spin Hall (QSH) insulator. The existence of Majorana bound states at the interface between SC and FM gives rise to charge-e tunneling, in addition to the usual charge-2e Cooper pair tunneling, between neighboring superconductor islands. Moreover, because Majorana fermions encode the information of charge number parity, an exact Z_2 gauge structure naturally emerges and leads to many new insulating phases, including a deconfined phase where e…
We present a microscopic derivation of the nematic charge-density-wave (CDW) formation in cuprate superconductors based on the three-orbital d-p Hubbard model, by introducing the vertex correction (VC) into the charge susceptibility. The CDW instability at $q=(Δ_{FS},0)$, $(0,Δ_{FS})$ appears when the spin fluctuations are strong, due to the strong charge-spin interference represented by the VC. Here, $Δ_{FS}$ is the wavenumber between the neighboring hot spots. The obtained spin-fluctuation-driven CDW is expressed as the "intra-unit-cell orbital order" accompanied by the charge transfer betwe…
We study braiding statistics between quasiparticles and vortices in two-dimensional charge-$2m$ (in units of $e$) superconductors that are coupled to a $\mathbb Z_{2m}$ dynamical gauge field, where $m$ is any positive integer. We show that there exist $16m$ types of braiding statistics when $m$ is odd, but only $4m$ types when $m$ is even. Based on the braiding statistics, we obtain a classification of topological phases of charge-$2m$ superconductors---or formally speaking, a classification of symmetry-protected topological phases, as well as invertible topological phases, of two-dimensional …
Charge and spin stripe order is a type of electronic crystal observed in certain layered cuprates associated with high-temperature superconductivity. Quantum-disordered stripes could be relevant for understanding the superconductivity. Here I discuss recent experimental characterizations of the stripe-ordered state in La(1.875)Ba(0.125)CuO(4), and compare them with properties of superconducting compositions.
The electron paramagnetic resonance study for an organic superconductor $β''$-(BEDT-TTF)$_{4}$[(H$_3$O)Ga(C$_2$O$_4$)$_3$]$\cdot$C$_6$H$_5$NO$_2$ reveals that superconductivity coexists uniformly with the charge ordered state in one material. In the charge ordered state, the interplane spin exchange is gapped, while the in-plane conductivity is not significantly modified. This anisotropic behavior is explained by the exotic charge ordered state, in which molecular-site selective carrier localization coexists with conducting carriers on other molecules. Relationship between superconductivity an…
We present a theory of Kondo effect caused by an induced magnetic moment near non-magnetic impurities such as Zn and Li in the cuprate superconductors. Based on the co-existence of charge order and superconductivity, a natural description of the induced moment and the resulting Kondo effect is obtained in the framework of bond-operator theory of microscopic t-J-V Hamiltonian. The local density of state near impurities is computed in a self-consistent Bogoliubov-de Gennes theory which shows a low-energy peak in the middle of superconducting gap. Our theory also suggests that the charge order ca…
In a multiorbital model of the cuprate high-temperature superconductors soft antiferromagnetic (AF) modes are assumed to reconstruct the Fermi surface to form nodal pockets. The subsequent charge ordering transition leads to a phase with a spatially modulated transfer of charge between neighboring oxygen p_x and p_y orbitals and also weak modulations of the charge density on the copper d_{x^2-y^2} orbitals. As a prime result of the AF Fermi surface reconstruction, the wavevectors of the charge modulations are oriented along the crystalline axes with a periodicity that agrees quantitatively wit…
Spin transfer torques (STT) occur when electric currents travel through inhomogeneously magnetized systems and are important for the motion of magnetic textures such as domain walls. Since superconductors are easy-plane ferromagnets in particle-hole (charge) space, it is natural to ask whether any charge duals of STT phenomena exist therein. We find that the superconducting analogue of the adiabatic STT vanishes in a bulk superconductor with a momentum-independent order parameter, while the superconducting counterpart of the nonadiabatic STT does not vanish. This nonvanishing superconducting t…
We study the phase diagram of a dipolar fermi gas at half-filling in a cubic optical lattice with dipole moments aligned along the z-axis. The anisotropic dipole-dipole interaction leads to the competition between pz-wave superfluid and nematic charge-density-wave (CDW) orders at low temperatures. We find that the superfluid phase survives with weak interactions and the CDW phase dominates with strong interactions. In between, the supersolid phase appears as a balance between superfluid and CDW orders. The superfluid density is anisotropic in the supersolid and superfluid phases. In the CDW ph…
Topological Charge-2ne Superconductivity and Clustering Hierarchy
University of California, Berkeley（加州大学伯克利分校）；University of Maryland, College Park（马里兰大学帕克分校）；Johns Hopkins University（约翰斯·霍普金斯大学）；University of Pittsburgh（匹兹堡大学）；Westlake University（西湖大学）；Westlake Institute for Advanced Study（西湖高等研究院）
