Pyrochlore iridates and pyrochlore ices are two families of materials where novel quantum phenomena are intertwined with strong spin-orbit coupling, substantial electron correlation and geometrical frustration. Motivated by the puzzling experiments on two pyrochlore systems Pr2Ir2O7 and Yb2Ti2O7, we study the proximate Ising orders and the quantum phase transition out of quantum spin ice U(1) quantum spin liquid (QSL). We apply the electromagnetic duality of the compact quantum electrodynamics to analyze the "magnetic monopoles" condensation for U(1) QSL. The monopole condensation transition represents a unconventional quantum criticality with unusual scaling laws. It naturally leads to the Ising orders that belong to the "2-in 2-out" spin ice manifold and generically have an enlarged magnetic unit cell. We demonstrate that the antiferormagnetic Ising state with the ordering wavevector ${\bf Q} = 2π(001)$ is proximate to U(1) QSL while the ferromagnetic Ising state with ${\bf Q}=(000)$ is not proximate to U(1) QSL. This implies that if there exists a direct transition from U(1) QSL to the ferromagnetic Ising state, the transition must be strongly first order. We apply the theory to Pr2Ir2O7 and Yb2Ti2O7.
Thermal conductivity of quantum magnetic monopoles in the frustrated pyrochlore Yb2Ti2O7
我们报道了烧绿石Yb $_2$ Ti $_2$ O $_7$的低温热导率$κ$,其中包含具有显著量子涨落的受抑自旋冰关联。在无序自旋液体区域,$κ(H)$表现出非单调的磁场依赖性,这是很好地解释了强的自旋-声子散射和量子相干激发。我们发现量子单极子的激发能比无色散的经典单极子的激发能有很强的抑制。此外,与扩散的经典单极子形成鲜明对比的是,量子单极子具有很长的平均自由程,我们推断量子单极子是一种新的重粒子,可能是玻色子,它在三维自旋液体中是高度可动的。
Spin crossover molecules have two accessible states: high spin (HS) and low spin (LS). We show that, on the pyrochlore lattice, elastic interactions between SCO molecules can give rise to three spin-state ice phases. Each is a ``Coulomb phase'' where a local ice-rule can be mapped to a divergence free gauge field and the low energy excitations carry a spin fractionalized midway between the LS and HS states. The unique nature of spin crossover materials allows temperature to change the ice rules allowing straightforward access to Coulomb phases not yet observed in water or spin ices.
We report experimental signatures of topological transitions among the Weyl semimetal states of pyrochlore Pr2Ir2O7, where the Kondo coupling between the Ir topological electrons and the spin-ice like orders of Pr moments plays a decisive role. The magnetic-field dependence of resistivity and the Hall conductivity exhibits a plateau and a sharp jump associated with a magnetic-field hysteresis, similar to a liquid-gas-like transition in dipolar spin ice system. Furthermore, the Kondo coupling is controlled by the hydrostatic pressure, revealing that the field-induced displacement of Weyl points…
We study a spin-ice Kondo lattice model on a breathing pyrochlore lattice with classical localized spins. The highly efficient kernel polynomial expansion method, together with a classical Monte Carlo method, is employed in order to study the magnetic phase diagram at four representative values of the number density of itinerant electrons. We tune the breathing mode by varying the hopping ratio -- the ratio of hopping parameters for itinerant electrons along inequivalent paths. Several interesting magnetic phases are stabilized in the phase diagram parameterized by the hopping ratio, Kondo cou…
Pyrochlores offer an ideal playground to investigate the magnetic ground state of frustrated magnetic systems. In this class of materials, competition between various magnetic interactions remains frustrated and prevents an ordered magnetic state at low temperatures. Tb2Sn2O7 has recently attracted significant attention due to its ordered spin-ice state. Additionally, in such systems, application of external magnetic field might result in exotic magnetic states. Our current investigation on Tb2Sn2O7 reveal the presence of a new phase associated with fifth order susceptibility at low temperatur…
Vacancy defects and monopole dynamics in oxygen-deficient pyrochlores
自旋冰中的磁单极子的想法在中温下取得了很大的成功,但在低温下,仅仅用磁动力学的描述是不够的。最近,数值模拟被用来争论磁性杂质通过在系统中引入剩余电阻的磁性等效物来解释这种差异。在这里,我们提出,氧的缺乏是主要原因的磁性杂质在生长的样品,我们确定的缺陷结构和磁性的Y2 Ti 2 O(7-δ)的漫中子散射和磁化测量。这些缺陷通过氧退火消除。氧空位的引入导致Ti 4+转变为具有淬灭轨道磁性的磁性Ti 3+,但浓度非常低。在自旋冰材料Dy 2 Ti 2 O 7中,我们发现相同的氧空位缺陷抑制了相邻稀土站点上的时刻,并且这些磁扭曲在亚开尔文温度下显着减缓了长时间的磁动力学。
Influence of controlled disorder on the dipolar spin ice state of Ho-based pyrochlores
Oak Ridge National Laboratory(橡树岭国家实验室);University of California Santa Barbara(加州大学圣塔芭芭拉分校);Perry College of Mathematics, Computing, and Sciences, University of West Georgia(佐治亚西部大学珀里数学、计算与科学学院);Japan Atomic Energy Agency(日本原子能机构);Brigham Young University(杨百翰大学)
We study the ground state and thermodynamic properties of the spin-half XXZ model, with an Ising interaction $J_z$ and a transverse exchange interaction $J_{x}$, on a pyrochlore tube obtained by joining together elementary cubes in a one-dimensional array. Periodic boundary conditions in the transverse directions ensure that the bulk of the system consists of corner-sharing tetrahedra, with the same local geometry as the pyrochlore lattice. We use exact diagonalization, the density matrix renormalization group (DMRG), and minimally entangled typical thermal states (METTS) methods to study the …
Antiferromagnetic Spin Ice Correlations at (1/2,1/2,1/2) in the Ground State of the Pyrochlore Magnet Tb2Ti2O7
本文报道了在低温和磁场中对候选的量子自旋液体烧绿石Tb 2 Ti 2 O 7的高分辨率单晶飞行时间中子散射测量。在~70 mK和零磁场下,Tb 2 Ti 2 O 7在倒易空间的(1/2,1/2,1/2)位置表现出弥散磁弹性散射,这与基于双倍常规单胞上的两进两出自旋冰结构的短程关联区一致.这种弹性散射与非常低能量的磁非弹性散射之间的能隙约为0.06-0.08 meV。在施加小磁场和升高温度时,弹性信号消失。在~70 mK的零场下,在(1,1,1)和(0,0,2)附近观察到类似夹点的弹性漫散射,与Fennell等人(参考文献1)一致,支持Tb 2 Ti 2 O 7的量子自旋冰解释。
Quantum spin liquids (QSL) have generated considerable excitement as phases of matter with emergent gauge structures and fractionalized excitations. In this context, phase transitions out of QSLs have been widely discussed as Higgs transitions from deconfined to confined phases of a lattice gauge theory. However the possibility of a wider range of novel phases, occuring between these two limits, has yet to be systematically explored. In this Letter, we develop a formalism which allows for interactions between fractionalised quasiparticles coming from the constraint on the physical Hilbert spac…
We report the low-temperature magnetothermal properties and spin dynamics of a mixed pyrochlore, Dy2GaSbO7 through the coordination of measurements of dc magnetization, ac susceptibility, and heat capacity, and CF computation. In Dy2GaSbO7, the spins freeze at temperature Tice = 3.1 K, corresponding to dynamical spin-freezing into a disordered state in compliance with the spin-ice rules, but with enhanced zero-point entropy, unlike cannonical dipolar spin-ice materials, Dy2Ti2O7 and Ho2Ti2O7, due to random disorder and varied chemical pressure of B-site (GaSb tetrahedra) ions.
Ising models on a pyrochlore oxide lattice are usually associated with spin ice materials and "magnetic monopoles". Ever more often effects connecting magnetic and elastic degrees of freedom are reported on these and other related frustrated materials. Here we extend a spin-ice Hamiltonian to include coupling between spins and the O$^{-2}$ ions mediating superexchange; we call it the Magnetoelastic Spin Ice model (MeSI). There has been a long search for a model in which monopoles would spontaneously become the building blocks of new ground-states: the MeSI Hamiltonian is such a model. In spite…
Magneto-elastic induced vibronic bound state in the spin ice pyrochlore Ho$_2$Ti$_2$O$_7$
Ho $_2$ Ti $_2$ O $_7$的单离子物理被充分理解为产生强伊辛各向异性,这是其低温自旋冰态的基本成分。我们提出了非弹性中子散射测量Ho $_2$ Ti $_2$ O $_7$,揭示了一个明确的不一致,其建立的单离子哈密顿量。具体地说,我们表明,60 meV附近的晶体场偶极子分裂约3 meV。此外,这种晶场分裂并不孤立于Ho $_2$ Ti $_2$ O $_7$,而是也可以在其化学压力类似物Ho $_2$ Ge $_2$ O $_7$和Ho $_2$ Sn $_2$ O $_7$中发现。我们证明了这种效应的起源是一个振动束缚态,导致声子和晶体场激发的纠缠。我们推导出描述磁弹性耦合的微观哈密顿量,并提供了非弹性中子谱的定量描述。
Direct evidence for a dynamical ground state in the highly frustrated Tb$_2$Sn$_2$O$_7$ pyrochlore
对“有序自旋冰”Tb $_2$ Sn $_2$ O $_7$烧绿石化合物的粉末样品进行了MuSR实验。在基温(T=35mK),μ子弛豫具有动力学性质,表明在铁磁相变(T_C=0.87K)以下仍存在强涨落。长程序的暗示表现为μ子极化在外场作用下的振荡和T_C以下的滞后行为。我们提出了一个动态的和强相关的情况下,动力学的结果从大自旋团簇的波动与“有序自旋冰”的结构。
A spin liquid with pinch-line singularities on the pyrochlore lattice
从麦克斯韦的电磁学理论到爱因斯坦的广义相对论,规范理论的数学基础是过去200年来物理学中许多最深刻的进步。最近,人们已经清楚地看到,规范理论也出现在凝聚态物质中,一个最好的例子是自旋冰材料,它拥有一个新兴的电磁规范场。在自旋冰中,中子散射测量中的夹点奇点揭示了潜在的规范结构。在这里,我们报告的自旋液体的发现,其中的低温物理是自然描述的连续规范自由度的张量场的波动。这种规范结构支持一种不寻常的形式的自旋相关性,从而产生了捏线奇点-类似于在自旋冰中观察到的捏点。值得注意的是,这些特征可能已经在烧绿石材料Tb $_2$ Ti $_2$ O $_7$中观察到。
We study the $S=1/2$ pyrochlore Heisenberg antiferromagnet in a magnetic field. Using large scale density-matrix renormalization group (DMRG) calculations for clusters up to $128$ spins, we find indications for a finite triplet gap, causing a threshold field to nonzero magnetization in the magnetization curve. We obtain a robust saturation field consistent with a magnon crystal, although the corresponding $5/6$ magnetization plateau is very slim and possibly unstable. Most remarkably, there is a pronounced and apparently robust $\frac 1 2$ magnetization plateau where the groundstate breaks (re…
Ground state selection under pressure in the quantum pyrochlore magnet Yb2Ti2O7
量子自旋液体是一种新的物质状态,其特征是量子纠缠和不存在任何对称性破缺。在凝聚态中,受抑的稀土烧绿石磁体Ho $_2$ Ti $_2$ O $_7$和Dy $_2$ Ti $_2$ O $_7$,即所谓的自旋冰,表现出经典的自旋液体状态,具有分馏的热激发(磁单极)。量子自旋冰的证据,其中磁单极子成为长距离纠缠和涌现的量子电动力学出现,似乎触手可及。量子自旋冰候选物Yb $_2$ Ti $_2$ O $_7$的磁性一直没有得到全面的理解,甚至在低温下是否存在静态磁序也存在争议。在这里,我们表明,对压力的敏感性是Yb $_2$ Ti $_2$ O $_7$低温行为的关键。通过结合压力下的化学计量比样品的中子衍射和μ子自旋弛豫,我们证明了从无序的,非磁性的,基态到张开的铁磁基态的磁性转变。
Polynomial Expansion Monte Carlo Study of Frustrated Itinerant Electron Systems: Application to a Spin-ice type Kondo Lattice Model on a Pyrochlore Lattice
The pyrochlore oxides Dy$_{2}$Ti$_{2}$O$_{7}$ and Ho$_{2}$Ti$_{2}$O$_{7}$ are well studied spin ice systems and have shown the evidences of magnetic monopole excitations. Unlike these, Dy$_{2}$Zr$_{2}$O$_{7}$ is reported to crystallize in a distorted fluorite structure. We present here the magnetic and heat capacity studies of La substituted Dy$_{2}$Zr$_{2}$O$_{7}$. Our findings suggest the absence of spin ice state in Dy$_{2}$Zr$_{2}$O$_{7}$ but the emergence of the magnetic field induced spin freezing near T $\approx$ 10 K in ac susceptibility measurements which is similar to Dy$_{2}$Ti$_{2}…
Thermal Conductivity and Specific Heat of the Spin-Ice Compound Dy$_2$Ti$_2$O$_7$: Experimental Evidence for Monopole Heat Transport
自旋冰化合物Dy $_2$ Ti $_2$ O $_7$中的基元激发可以描述为在由磁性Dy离子形成的烧绿石晶格内独立传播的磁单极子。我们研究了B的热导率κ(B)与磁场的关系||[001]并观察到源自磁激发的磁热传输的明显证据。磁贡献κ mag与磁场有很强的相关性,并与磁化强度M(B)有关。由κ mag与磁比热之比得到的扩散系数在低于1K时大大增强,表明自旋冰态的自旋激发具有高的迁移率.
Evidence for the Confinement of Magnetic Monopoles in Quantum Spin Ice
磁单极子是由狄拉克弦连接起来的基本粒子,它们的行为就像无限薄的弦。尽管经过几十年的研究,自由磁单极子和它们的狄拉克弦仍然无法在实验中被探测到,尽管有大量证据表明自旋冰材料中存在非受限的磁单极子准粒子。在这里,我们报告的检测层次的不等间距磁激发\emph{via}高分辨率非弹性中子光谱测量的量子自旋冰候选人Pr $_{2}$ Sn $_{2}$ O $_{7}$。这些激发可以用一个简单的模型来描述,该模型是由一个有效张力为0.642(8)K~ $\cdot$/$^{-1}$(1.65 K)的线性势所束缚的电子对。线性势模型的成功表明,这些低能磁激发是量子自旋冰候选体Pr $_{2}$ Sn $_{2}$ O $_{7}$中磁束缚准粒子的直接光谱证据.
Soft dipolar spin ice physics and the ordered phase of the frustrated Tb2Sn2O7 pyrochlore magnet
从一个微观模型的烧绿石反铁磁体Tb 2Sn 2 O 7,包括晶体场的哈密顿量和角动量之间的相互作用,我们计算了一个有效的赝自旋-1/2哈密顿量Heff$,纳入微扰的有效相互作用的激发晶体场水平的影响。我们得到的半经典基态的Heff和找到一个区域的参数空间与两个在/两个出自旋冰配置上的每个四面体与有序波矢量q=0和自旋倾斜远离当地伊辛轴中发现Tb 2 Sn 2 O 7。这种基态也可以从偶极自旋冰模型中得到,其中伊辛约束被软化。后一种模型的蒙特卡罗模拟揭示了一个区域的相图与自旋冰状冻结和另一个过渡到Tb 2Sn 2 O 7型长程序。我们评论Tb_2Sn_2O_7和令人困惑的自旋液体Tb_2Ti_2O_7之间的差异。