Differences in the confinement of electrons and holes in quantum dots are shown to profoundly impact the magnitude of scattering with acoustic phonons in materials where crystal deformation shifts the conduction and valence band in the same direction. Using an extensive model that includes the non-Markovian nature of the phonon reservoir, we show how the effect may be addressed by photoluminescence excitation spectroscopy of a single quantum dot. We also investigate the implications for cavity QED, i.e. a coupled quantum dot-cavity system, and demonstrate that the phonon scattering may be strongly quenched. The quenching is explained by a balancing between the deformation potential interaction strengths and the carrier confinement and depends on the quantum dot shape. Numerical examples suggest a route towards engineering the phonon scattering.
We present a detailed spectroscopic study of the photoluminescence quenching in an epitaxial structures containing CdSe/ZnSe quantum dots doped with low concentration of Mn$^{2+}$ ions. Our time-resolved and time-integrated experiments reveal the origin of the quenching observed in macro-photoluminescence studies of ensembles of such dots. We show that incorporation of even a few ions to an individual dot does not quench its luminescence effectively, although some fingerprints of expected spin-dependent quenching are visible. At the same time, the presence of Mn$^{2+}$ ions in the sample signi…
Nuclear spin polarization can be pumped into spin-blocked quantum dots by multiple Landau- Zener passages through singlet-triplet anticrossings. By numerical simulations of realistic systems including approximately $10^7$ nuclear spins during $10^5$ sweeps, we uncover a mechanism of dynamical self-quenching which results in a fast saturation of the nuclear polarization under stationary pumping. This is caused by screening of the field of the nuclear spins. In systems with moderate spin-orbit coupling, self-quenching also screens the spin-orbit interaction. The mechanism is generic and remains …
We present data on the electrical transport properties of highly-doped silicon-on-insulator quantum dots under the effect of pulsed magnetic fields up to 48 T. At low field intensities, B<7 T, we observe a strong modification of the conductance due to the destruction of weak localization whereas at higher fields, where the magnetic field length becomes comparable to the effective Bohr radius of phosphorous in silicon, a strong decrease in conductance is demonstrated. Data in the high and low electric field bias regimes are then compared to show that close to the Coulomb blockade edge magnetica…
Strong electrically tunable exciton g-factors are observed in individual (Ga)InAs self-assembled quantum dots and the microscopic origin of the effect is explained. Realistic eight band k.p simulations quantitatively account for our observations, simultaneously reproducing the exciton transition energy, DC Stark shift, diamagnetic shift and g-factor tunability for model dots with the measured size and a comparatively low In-composition of x(In)~35% near the dot apex. We show that the observed g-factor tunability is dominated by the hole, the electron contributing only weakly. The electric fiel…
Thermal quenching is one of the essential factors in reducing the efficiency of radiative processes in luminophores of various nature. The emission activity of low dimensional structures is influenced also by multiplicity of parameters that are related to synthesis processes, treatment regimes, etc. In the present work, we have investigated the temperature dependence of photoluminescence caused by exciton and defect-related transitions in ensembles of biocompatible InP/ZnS core/shell nanocrystals with an average size of 2.1 and 2.3 nm. The spread in the positions of energy levels is shown to b…
In quantum dots (QDs) the Auger recombination is a non-radiative process, where the electron-hole recombination energy is transferred to an additional carrier. It has been studied mostly in colloidal QDs, where the Auger recombination time is in the ps range and efficiently quenches the light emission. In self-assembled QDs, on the other hand, the influence of Auger recombination on the optical properties is in general neglected, assuming that it is masked by other processes such as spin and charge fluctuations. Here, we use time-resolved resonance fluorescence to analyze the Auger recombinati…
The self-assembled quantum dot with lens domain has rotational symmetry but it is intrinsically asymmetric when the electron moves perpendicularly to its circular base, {\it i. e.} along the rotational axis. To characterize this asymmetry, an external electric field is applied along the positive or negative direction of the rotational axis. We report the different Stark shifts appearing in the spectra as a function of the field intensity for different lens domains. It is shown that for a flat lens domain the asymmetry effects decrease, but even for very flat lenses they can not be approximated…
We investigate theorerically the non-equilibrium transport through a molecular quantum dot as a function of gate and bias voltage, taking into account the typical situation in molecular electronics. In this respect, our study includes asymmetries both in the capacitances and tunneling rates to the source and drain electrodes, as well as an infinitely large charging energy on the molecule. Our calculations are based on the out-of-equilibrium Non-Crossing-Approximation (NCA), which is a reliable technique in the regime under consideration. We find that Coulomb blockade edges and Kondo peaks disp…
The central-spin problem, in which an electron spin interacts with a nuclear spin bath, is a widely studied model of quantum decoherence. Dynamic nuclear polarization (DNP) occurs in central spin systems when electronic angular momentum is transferred to nuclear spins and is exploited in spin-based quantum information processing for coherent electron and nuclear spin control. However, the mechanisms limiting DNP remain only partially understood. Here, we show that spin-orbit coupling quenches DNP in a GaAs double quantum dot, even though spin-orbit coupling in GaAs is weak. Using Landau-Zener …
Motivated by activities of several experimental groups we investigate electron transport through two coherent, strongly coupled quantum dots ("double quantum dots"), taking into account both intra- and inter-dot Coulomb interactions. The shot noise in this system is very sensitive to the internal electronic level structure of the coupled dot system and its specific coupling to the electrodes. Accordingly a comparison between experiments and our predictions should allow for a characterization of the relevant parameters. We discuss in detail the effect of asymmetries, either asymmetries in the c…
We report on the resonant emission in coherently-driven single semiconductor quantum dots. We demonstrate that an ultra-weak non-resonant laser acts as an optical gate for the quantum dot resonant response. We show that the gate laser suppresses Coulomb blockade at the origin of a resonant emission quenching, and that the optically-gated quantum dots systematically behave as ideal two-level systems in both regimes of coherent and incoherent resonant emission.
Two electron spins in quantum dots coupled through coherent tunneling are generally acknowledged to approximately obey Heisenberg isotropic exchange. This has not been established for two holes. Here we measure the spectra of two holes and of two electrons in two vertically stacked self-assembled InAs quantum dots using optical spectroscopy as a function of electric and magnetic fields. We find that the exchange is approximately isotropic for both systems, but that significant asymmetric contributions, arising from spin-orbit and Zeeman interactions combined with spatial asymmetries, are requi…
The observed intermittent light emission from colloidal semiconductor nanocrystals has long been associated with Auger recombination assisted quenching. We test this view by observing transient emission dynamics of CdSe/CdS/ZnS semiconductor nanocrystals using time-resolved photon counting. The size and intensity dependence of the observed decay dynamics are inconsistent with the those expected from Auger processes. Moreover, the data suggests that in the `off' state the quantum dot cycles in a three-step process: photoexcitation, rapid trapping and subsequent slow nonradiative decay.
Reliable detection of single electron tunneling in quantum dots (QD) is paramount to use this category of device for quantum information processing. Here, we report charge sensing in a degenerately phosphorus-doped silicon QD by means of a capacitively coupled single-electron tunneling device made of the same material. Besides accurate counting of tunneling events in the QD, we demonstrate that this architecture can be operated to reveal asymmetries in the transport characteristic of the QD. Indeed, the observation of gate voltage shifts in the detector's response as the QD bias is changed is …
We investigate entanglement transfer from a system of two spin-entangled electron-hole pairs, each placed in a separate single mode cavity, to the photons emitted during their recombination process. Dipole selection rules and a splitting between the light-hole and the heavy-hole subbands are the crucial ingredients establishing a one-to-one correspondence between electron spins and circular photon polarizations. To account for the measurement of the photons as well as dephasing effects, we choose a stochastic Schroedinger equation and a conditional master equation approach, respectively. The i…
We investigate the thermal quenching of the multimodal photoluminescence from InAs/InP (001) self-assembled quantum dots. The temperature evolution of the photoluminescence spectra of two samples is followed from 10 K to 300 K. We develop a coupled rate-equation model that includes the effect of carrier thermal escape from a quantum dot to the wetting layer and to the InP matrix, followed by transport, recapture or non-radiative recombination. Our model reproduces the temperature dependence of the emission of each family of quantum dots with a single set of parameters. We find that the main es…
We describe the optical emission and the carrier dynamics of an ensemble of self-assembled GaAs quantum dots embedded in GaP(001). The QD formation is driven by the 3.6 % lattice mismatch between GaAs and GaP in Stranski-Krastanow mode after deposition of more than 1.2 monolayers of GaAs. The quantum dots have an areal density between 6 and 7.6x1010 per cm-2 and multimodal size distribution. The luminescence spectra show two peaks in the range of 1.7 and 2.1 eV. The samples with larger quantum dots have red emission and show less thermal quenching compared to the samples with smaller QDs. The …
We have investigated the dynamics of bound particles in multilevel current-carrying quantum dots. We look specifically in the regime of resonant tunnelling transport, where several channels are available for transport. Through a non-Markovian formalism under the Born approximation, we investigate the real-time evolution of the confined particles including transport-induced decoherence and relaxation. In the case of a coherent superposition between states with different particle number, we find that a Fock-space coherence may be preserved even in the presence of tunneling into and out of the do…
We investigate experimentally and theoretically the resonant emission of single InAs/GaAs quantum dots in a planar microcavity. Due to the presence of at least one residual charge in the quantum dots, the resonant excitation of the neutral exciton is blocked. The influence of the residual doping on the initial quantum dots charge state is analyzed, and the resonant emission quenching is interpreted as a Coulomb blockade effect. The use of an additional non-resonant laser in a specific low power regime leads to the carrier draining in quantum dots and allows an efficient optical gating of the e…
Double-slit experiments inferring the phase and the amplitude of the transmission coefficient performed at quantum dots (QD), in the Coulomb blockade regime, present anomalies at the phase changes depending on the number of electrons confined. This phase change cannot be explained if one neglects the electron-electron interactions. Here, we present our numerical results, which simulate the real sample geometry by solving the Poisson equation in 3D. The screened potential profile is used to obtain energy eigenstates and eigenvalues of the QD. We find that, certain energy levels are coupled to t…
The separation dependence of the interaction between two resonant groups of CdSe/ZnS nanocrystallite quantum dots is studied at room temperature. A near-field scanning optical microscope is used to bring a group of mono-disperse ~6.5 nm diameter nanocrystallite quantum dots which are attached to the microscope probe, into close proximity of `~8.5 nm diameter group of nanocrystallite quantum dots which are deposited on a solid immersion lens. Information extracted from photoluminescence, photoluminescence excitation and absorption curves as well as numerical calculations of the energy levels, s…
Semiconductor light emitters compatible with standard Si integration technology (SIT) are of particular interest for overcoming limitations in the operating speed of microelectronic devices 1-3. Light sources based on group-IV elements would be SIT compatible but suffer from the poor optoelectronic properties of bulk Si and Ge. Here, we demonstrate that epitaxially grown Ge quantum dots (QDs) in a fully coherent Si matrix show extraordinary optical properties if partially amorphised by Ge-ion bombardment (GIB). The GIB-QDs exhibit a quasi-direct-band gap and show, in contrast to conventional S…
Experimental results for sequential transport through a lateral quantum dot in the regime of spin blockade induced by spin dependent tunneling are compared with theoretical results obtained by solving a master equation for independent electrons. Orbital and spin effects in electron tunneling in the presence of a perpendicular magnetic field are identified and discussed in terms of the Fock-Darwin spectrum with spin. In the nonlinear regime, a regular pattern of negative differential conductances is observed. Electrical asymmetries in tunnel rates and capacitances must be introduced in order to…
We investigate the long wavelength (1.2 to 1.55 micro-m) photoluminescence of high-density InAs quantum dots and dashes, which were grown on InP substrates. We analyze the temperature dependence of the recombination and carrier distribution on the alloy composition of the barrier materials, InGaAlAs, and on the existence of a wetting layer. Carrier escape and transfer are discussed based on temperature dependent photoluminescence measurements and theoretical considerations about the heterostructures' confinement energies and band structure. We propose two different contributions to the thermal…
Quantum dots play a promising role in the development of novel optical and biosensing devices. In this study, we investigated steady-state and time-dependent luminescence properties of InGaP/ZnS core/shell colloidal quantum dots in a solution phase at room temperature. The steady state experiments exhibited an emission maximum at 650 nm with full width at half maximum of ~ 85 nm, and strong first-excitonic absorption peak at 600 nm. The time-resolved luminescence measurements depicted a bi-exponential decay profile with lifetimes of τ1\sim 47 ns and τ 2\sim 142 ns at the emission maximum. Addi…
The self-assembled quantum dots (QDs) provide an ideal platform for realization of quantum information technology because it provides on demand single photons, entangled photon pairs from biexciton cascade pro- cess, single spin qubits, and so on. The fine structure splitting (FSS) of exciton is a fundamental property of QDs for thees applications. From the symmetry point of view, since the two bright exciton states belong to two different representations for QDs with C2v symmetry, they should not only have different energies, but also have different lifetimes, which is termed exciton lifetime…
We explore the effects of asymmetry of hopping parameters between double parallel quantum dots and the leads on the conductance and a possibility of local magnetic moment formation in this system using functional renormalization group approach with the counterterm. We demonstrate a possibility of a quantum phase transition to a local moment regime (so called singular Fermi liquid (SFL) state) for various types of hopping asymmetries and discuss respective gate voltage dependences of the conductance. It is shown, that depending on the type of the asymmetry, the system can demonstrate either a f…
The possibility to generate and manipulate non-classical light using the tools of mature semiconductor technology carries great promise for the implementation of quantum communication science. This is indeed one of the main driving forces behind ongoing research on the study of semiconductor quantum dots. Often referred to as artificial atoms, quantum dots can generate single and entangled photons on demand and, unlike their natural counterpart, can be easily integrated into well-established optoelectronic devices. However, the inherent random nature of the quantum dot growth processes results…
We present a hidden Markov model analysis for fluorescent time series of quantum dots. A fundamental quantity to measure optical performance of the quantum dots is a distribution function for the light-emission duration. So far, to estimate it, a threshold value for the fluorescent intensity was introduced, and the light-emission state was evaluated as a state above the threshold. With this definition, the light-emission duration was estimated, and its distribution function was derived as a blinking plot. Due to the noise in the fluorescent data, however, this treatment generates a large numbe…
For the last decade, tunable quantum dot systems have allowed the investigation of Kondo physics wherein the quenching of a single spin on an artificial atom affects the conductance. The pseudogap Kondo model featuring a density of states $ρ(ε)$ = C$|ε|^{r}$, introduced by Withoff and Fradkin in 1990 was predicted to exhibit Kondo-like physics above a critical value of the Kondo coupling, J$_c$, which several groups have shown by numerical renormalization group (RG) is finite for r$< {1/2}$. Gonzalez-Buxton {\it{et al}} showed that the strong coupling limit of the particle-hole symmetric model…
We study the variation in the Land$\acute{\text{e}}$ g-factor of electron spins induced by both anisotropic gate potentials and magnetic fields in InAs quantum dots for possible implementation towards solid state quantum computing. In this paper, we present analytical expressions and numerical simulations of the variation in the Land$\acute{\text{e}}$ g-factor for both isotropic and anisotropic quantum dots. Using both analytical techniques and numerical simulations, we show that the Rashba spin-orbit coupling has a major contribution in the variation of the g-factor with electric fields befor…
We consider a ring of three quantum dots mutually coupled by antiferromagnetic exchange interactions, and tunnel-coupled to two metallic leads: the simplest device in which the consequences of local frustration arising from internal degrees of freedom may be studied within a 2-channel environment. Two-channel Kondo (2CK) physics is found to predominate at low-energies in the mirror-symmetric systems considered, with a residual spin 1/2 overscreened by coupling to both leads. It is however shown that two distinct 2CK phases, with different ground state parities, arise on tuning the interdot exc…
Optical and electronic properties of symmetric InAs/InGaAlAs/InP quantum dots formed by a ripening process in molecular beam epitaxy: a promising system for broad-range single-photon telecom emitters
Generating and detecting radiation in the technologically relevant range of the so-called terahertz gap ($0.1 - 10$ THz) is challenging because of a lack of efficient sources and detectors. Quantum dots in carbon nanotubes have shown great potential to build sensitive terahertz detectors usually based on photon-assisted tunnelling. A recently reported mechanism combining resonant quantum dot transitions and tunnelling barriers asymmetries results in a narrow linewidth photocurrent response with a large signal-to-noise ratio under weak THz radiation. That device was sensitive to one frequency, …
Quantum dots (QDs) are good model systems for fundamental studies of mesoscopic transport phenomena using thermoelectric effects because of their small size, electrostatically tunable properties and thermoelectric response characteristics that are very sensitive to small thermal biases. Here we provide a review of experimental studies on thermoelectric properties of single QDs realized in two-dimensional electron gases, single-walled carbon nanotubes and semiconductor nanowires. A key requirement for such experiments is methods for nanoscale thermal biasing. We briefly review the main techniqu…
Continuous and concerted development of colloidal quantum-dot light-emitting diodes over the past two decades has established them as a bedrock technology for the next generation of displays. However, a fundamental issue that limits the performance of these devices is the quenching of photoluminescence due to excess charges from conductive charge transport layers. Although device designs have leveraged various workarounds, doing so often comes at the cost of limiting efficient charge injection. Here we demonstrate that high-field terahertz (THz) pulses can dramatically brighten quenched QDs on…
We interpret the recent observation of a zero-bias anomaly in spin-1 quantum dots in terms of an underscreened Kondo effect. Although a spin-1 quantum dots are expected to undergo a two-stage quenching effect, in practice the log normal distribution of Kondo temperatures leads to a broad temperature region dominated by underscreened Kondo physics. General arguments, based on the asymptotic decoupling between the partially screened moment and the leads, predict a singular temperature and voltage dependence of the conductance $G$ and differential conductance $g$, resulting in $dg/dT\sim 1/T$ and…
Using analytical arguments and the numerical renormalization group method we investigate the spin-thermopower of a quantum dot in a magnetic field. In the particle-hole symmetric situation the temperature difference applied across the dot drives a pure spin current without accompanying charge current. For temperatures and fields at or above the Kondo temperature, but of the same order of magnitude, the spin-Seebeck coefficient is large, of the order of k_B/e. Via a mapping, we relate the spin-Seebeck coefficient to the charge-Seebeck coefficient of a negative-U quantum dot where the correspond…
We apply the semiclassical theory of transport to quantum dots with exact and approximate spatial symmetries; left-right mirror symmetry, up-down mirror symmetry, inversion symmetry or four-fold symmetry. In this work - the first of a pair of articles - we consider (a) perfectly symmetric dots and (b) nearly symmetric dots in which the symmetry is broken by the dot's internal dynamics. The second article addresses symmetry-breaking by displacement of the leads. Using semiclassics, we identify the origin of the symmetry-induced interference effects that contribute to weak-localization correctio…
The interplay between the coupling of an interacting quantum dot to a conduction band and its connection to localized levels has been studied in a triple quantum dot arrangement. The electronic Dicke effect, resulting from quasi-resonant states of two side-coupled non-interacting quantum dots, is found to produce important effects on the Kondo resonance of the interacting dot. We study in detail the Kondo regime of the system by applying a numerical renormalization group analysis to a finite-U multi-impurity Anderson Hamiltonian model. We find an extreme narrowing of the Kondo resonance, as th…
Size-Limited Room Temperature Single-Photon Emission from Sidewall-Treated Fractional Dimension InGaN Quantum Dots: Determined by Density-of-States-Corrected Ultrafast Carrier Dynamics and Improved Signal-to-Noise Ratio
Using the conformal field theory approach to the thermoelectric characteristics of fractional quantum Hall states, previously developed in Nucl. Phys. B 894 (2015) 284, we show that the thermoelectric power factor of Coulomb-blockaded islands, realized by point contacts in Fabry--Pérot interferometers in the $\mathbb{Z}_k$ parafermion Hall states, could give reliable signatures for distinguishing the topological orders of different quantum Hall states having identical electric properties. For example, while the conductance peak patterns in the Coulomb blockade regime for such states are practi…
Electrical transport in double quantum dots (DQDs) illuminates many interesting features of the dots' carrier states. Recent advances in silicon quantum information technologies have renewed interest in the valley states of electrons confined in silicon. Here we show measurements of DC transport through a mesa-etched silicon double quantum dot. Comparing bias triangles (i.e., regions of allowed current in DQDs) at positive and negative bias voltages we find a systematic asymmetry in the size of the bias triangles at the two bias polarities. Asymmetries of this nature are associated with blocki…
We discuss the realization of the quantum-critical non-Fermi liquid state, originally discovered within the two-impurity Kondo model, in double quantum-dot systems. Contrary to the common belief, the corresponding fixed point is robust against particle-hole and various other asymmetries, and is only unstable to charge transfer between the two dots. We propose an experimental set-up where such charge transfer processes are suppressed, allowing a controlled approach to the quantum critical state. We also discuss transport and scaling properties in the vicinity of the critical point.
The Si/SiGe heterosystem would be ideally suited for the realization of complementary metal-oxide-semiconductor (CMOS)-compatible integrated light sources, but the indirect band gap, exacerbated by a type-II band offset, makes it challenging to achieve efficient light emission. We address this problem by strain engineering in ordered arrays of vertically close-stacked SiGe quantum dot (QD) pairs. The strain induced by the respective lower QD creates a preferential nucleation site for the upper one and strains the upper QD as well as the Si cap above it. Electrons are confined in the strain poc…
We study the nonlinear conductance through a quantum dot, specifically its dependence on the asymmetries in the tunnel couplings and bias voltages $V$, at low energies. Extending the microscopic Fermi-liquid theory for the Anderson impurity model, we obtain an exact formula for the steady current $I$ up to terms of order $V^3$ in the presence of these asymmetries. The coefficients for the nonlinear terms are described in terms of a set of the Fermi-liquid parameters: the phase shift, static susceptibilities, and three-body correlation functions of electrons in the quantum dots, defined with re…
Localized orbitals and tunnel couplings from general confinement potentials in gate-defined quantum-dot arrays
Institute for Quantum Computing and Department of Physics, University of Waterloo（滑铁卢大学量子计算研究所与物理系）；Institute for Quantum Computing and Department of Chemistry, University of Waterloo（滑铁卢大学量子计算研究所与化学系）
Nuclear quadrupole interaction extends the limits imposed by hyperfine interaction on the spin coherence of the electron and nuclei in a quantum dot. The strain-induced nuclear quadrupole interaction suppresses the nuclear spin flip and makes possible the zero-field dynamic nuclear polarization in self-organized InP/InGaP quantum dots. The direction of the effective nuclear magnetic field is fixed in space, thus quenching the magnetic depolarization of the electron spin in the quantum dot. The quadrupole interaction suppresses the zero-field electron spin decoherence also for the case of non-p…
Entanglement resources are key ingredients of future quantum technologies. If they could be efficiently integrated into a semiconductor platform a new generation of devices could be envisioned, whose quantum-mechanical functionalities are controlled via the mature semiconductor technology. Epitaxial quantum dots (QDs) embedded in diodes would embody such ideal quantum devices, but QD structural asymmetries lower dramatically the degree of entanglement of the sources and hamper severely their real exploitation in the foreseen applications. In this work, we overcome this hurdle using strain-tuna…
A detailed understanding of energy transduction is crucial for achieving precise control of energy flow in complex, integrated systems. In this context, carbon nanotubes (CNTs) are intriguing model systems due to their rich, chirality-dependent electronic and optical properties. Here, we study the quenching of fluorescence from isolated quantum dots (QDs) upon approach of individual CNTs attached to atomic force microscope probes. Precision measurements of many different CNT/QD pairs reveal behavior consistent with resonant energy transfer between QD and CNT excitons via a Fohrster-like dipole…
