arXivDaily arXiv每日学术速递 周一至周五更新
arXiv 1004.2137cond-mat.supr-con
收藏

热处理对掺银SrKFeAs化合物超导性能的影响

Heat treatment effects on the superconducting properties of Ag-doped SrKFeAs compound

Zhiyu Zhang, Lei Wang, Yanpeng Qi, Zhaoshun Gao, Dongliang Wang, Xianping Zhang, Yanwei Ma

摘要:

多晶Sr 0.6K 0.4Fe 2As 2的超导性能受到Ag掺杂的强烈影响(Supercond. Sci. 23(2010)025027)。Ag的掺杂主要是由Ag的扩散控制的,因此退火工艺是获得高质量Ag掺杂Sr0.6K0.4Fe2As2的关键因素之一。本文研究了一步固相反应法制备Ag掺杂Sr0.6K0.4Fe2As2块材的最佳退火条件。结果表明,退火温度对超导性能有很大的影响,特别是对临界电流密度Jc的影响。结果表明,较高的热处理温度(~ 900 ℃)有利于Ag的扩散,减少聚集在一起的杂质相,改善晶粒的连通性。相反,低温烧结对于Ag掺杂的样品是适得其反的。这些结果清楚地表明,在约900 ℃下退火是获得高Jc Ag掺杂样品所必需的。

英文摘要:

The superconducting properties of polycrystalline Sr0.6K0.4Fe2As2 were strongly influenced by Ag doping (Supercond. Sci. Technol. 23 (2010) 025027). Ag addition is mainly dominated by silver diffusing, so the annealing process is one of the essential factors to achieve high quality Ag doped Sr0.6K0.4Fe2As2. In this paper, the optimal annealing conditions were studied for Ag doped Sr0.6K0.4Fe2As2 bulks prepared by a one-step solid reaction method. It is found that the annealing temperature has a strong influence on the superconducting properties, especially on the critical current density Jc. As a result, higher heat treatment temperature (~900C) is helpful in diffusing Ag and reducing the impurity phase gathered together to improve the grain connectivity. In contrast, low-temperature sintering is counterproductive for Ag doped samples. These results clearly suggest that annealing at ~900C is necessary for obtaining high Jc Ag-doped samples.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

↑