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arXiv 2204.05686cond-mat.supr-con
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重电子掺杂La1111-based超导体的超导电性增强和低能量下适度自旋涨落的抑制

Enhanced superconductivity and moderate spin fluctuations suppressed at low energies in heavily electron-doped La1111-based superconductor

T. Kouchi, S. Nishioka, K. Suzuki, M. Yashima, H. Mukuda, T. Kawashima, H. Tsuji, K. Kuroki, S. Miyasaka, S. Tajima

摘要:

为了阐明重电子掺杂的铁磷族化合物中再增强的高$T_c$相的起源,通过控制氮族元素的高度,对重电子掺杂的LaFe $Pn$ O $_{0.75}$ H $_{0.25}$进行了系统的$^{75}$ As NMR研究通过在$Pn$(=As)位上用Sb或P取代,从Fe面获得了($h_{Pn}$).(1/ $T_1$)和奈特位移($K$)表明,在高温下的中等自旋涨落向低温方向被抑制.在具有较高$h_{Pn}$的较高$T_c$化合物中,这种在低能量下具有带隙特征的特征自旋涨落被更多地放大,而在具有较低$h_{Pn}$的非超导化合物中,这些特征自旋涨落被完全抑制。这意味着自旋涨落谱中的有限能量部分的贡献对于在重电子掺杂区域中增强$T_c$是至关重要的。这与具有类似尺寸的空穴和电子费米表面的典型铁基化合物的许多情况相反,其中在低能量下的自旋波动在低温下显著发展。讨论了重电子掺杂态的特征与由$d_{xy}$轨道导出的弱空穴费米面的特征的关系,该轨道在$h_{Pn}$高时上升,以及增强的电子相关效应。

英文摘要:

To elucidate the origin of re-enhanced high-$T_c$ phase in the heavily electron-doped Fe-pnictides, systematic $^{75}$As NMR studies are performed on heavily electron-doped LaFe$Pn$O$_{0.75}$H$_{0.25}$ by controlling the pnictogen height ($h_{Pn}$) from the Fe plane through the substitution at $Pn$(=As) site with Sb or P. The measurements of nuclear spin relaxation rate (1/$T_1$) and Knight shift ($K$) reveal that the moderate spin fluctuations at high temperatures are suppressed toward low temperatures. Such characteristic spin fluctuations with gap like feature at low energies are more enlarged in higher $T_c$ compounds with higher $h_{Pn}$, while those are totally suppressed in non-superconducting compounds with lower $h_{Pn}$. This implies that the contribution of the finite energy part in the spin fluctuation spectrum is crucial for enhancing $T_c$ in the heavily electron-doped regime. This is in contrast to many cases of typical Fe-based compounds with hole and electron Fermi surfaces of similar sizes, where the spin fluctuations at low energies develop significantly at low temperatures. The features in the heavily electron-doped states are discussed in relation with the characteristics of the faint hole Fermi surface derived from $d_{xy}$ orbital that rises when $h_{Pn}$ is high, together with the enhanced electron correlation effects.

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