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arXiv 1201.1399cond-mat.str-elcond-mat.supr-con
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重掺杂Ba $_{1-x}$ K $_{x}$ Mn $_{2}$ As $_{2}$中新的弱铁磁金属态

Novel weak-ferromagnetic metallic state in heavily doped Ba$_{1-x}$K$_{x}$Mn$_{2}$As$_{2}$

Jin-Ke Bao, Hao Jiang, Yun-Lei Sun, Wen-He Jiao, Chen-Yi Shen, Zhu-An Xu, Guang-Han Cao, Ryo Sasaki, Toshiki Tanaka, Kazuyuki Matsubayashi, Yoshiya Uwatoko

摘要:

成功地生长了重掺杂Ba $_{1-x}$ K $_{x}$ Mn $_{2}$ As $_{2}$($x$ =0.19和0.26)单晶,并对其电阻率和各向异性磁化率进行了测量。与未掺杂的BaMn $_{2}$ As $_{2}$的反铁磁绝缘基态相反,K掺杂的晶体在低于$\sim$ 50 K时显示出金属导电性,具有弱铁磁性,而在高于$\sim$ 50 K时显示出Curie-Weiss类面内磁化率。在高达6 GPa的高压下,低温金属性转变为以Kondo型电阻率最小值为特征的状态,而在2.5K以上没有任何超导性特征。使用$2\times2\times1$超晶胞对$x$ =0.25的电子结构计算再现了空穴掺杂金属态。费米能级处的态密度具有明显的As 4 $p$分量,表明4 $p$空穴是金属导电的主要原因.我们的研究结果表明,巡游4 $p$空穴和本地3 $d$矩之间的相互作用是主要负责的新的金属状态。

英文摘要:

Heavily doped Ba$_{1-x}$K$_{x}$Mn$_{2}$As$_{2}$ ($x$=0.19 and 0.26) single crystals were successfully grown, and investigated by the measurements of resistivity and anisotropic magnetic susceptibility. In contrast to the antiferromagnetic insulating ground state of the undoped BaMn$_{2}$As$_{2}$, the K-doped crystals show metallic conduction with weak ferromagnetism below $\sim$50 K and Curie-Weiss-like in-plane magnetic susceptibility above $\sim$50 K. Under high pressures up to 6 GPa, the low-temperature metallicity changes into a state characterized by a Kondo-like resistivity minimum without any signature of superconductivity above 2.5 K. Electronic structure calculations for $x$=0.25 using $2\times2\times1$ supercell reproduce the hole-doped metallic state. The density of states at Fermi energy have significant As 4$p$ components, suggesting that the 4$p$ holes are mainly responsible for the metallic conduction. Our results suggest that the interplay between itinerant 4$p$ holes and local 3$d$ moments is mostly responsible for the novel metallic state.

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