Building a refrigerator based on the conversion of heat into optical energy is an ongoing engineering challenge. Under well-defined conditions, spontaneous anti-Stokes fluorescence of a dopant material in a host matrix is capable of lowering the host temperature. The fluorescence is conveying away a part of the thermal energy stored in the vibrational oscillations of the host lattice. In particular, applying this principle to the cooling of (solid-state) lasers opens up many potential device applications, especially in the domain of high-power lasers. In this paper, an alternative optical cooling scheme is outlined, leading to radiative cooling of solid-state lasers. It is based on converting the thermal energy stored in the host, into optical energy by means of a stimulated nonlinear process, rather than a spontaneous process. This should lead to better cooling efficiencies and a higher potential of applying the principle for device applications.
Here we present a semiclassical analysis of spontaneous and stimulated radiative emission from unmodulated and optically-modulated electron quantum wavepackets. We show that the radiative emission/absorption and corresponding deceleration/acceleration of the wavepackets depend on the controllable 'history-dependent' wavepacket size. The characteristics of the radiative interaction when a wavepacket of size (duration) is short relative to the radiation wavelength, are close to the predictions of the classical point-particle modeling. On the other hand, in the long-sized wavepacket limit, the in…
In the foundation of quantum mechanics, the spatial dimensions of electron wavepacket are understood only in terms of an expectation value - the probability distribution of the particle location. One can still inquire how the quantum electron wavepacket size affects a physical process. Here we address the fundamental physics problem of particle-wave duality and the measurability of a free electron quantum wavepacket. Our analysis of stimulated radiative interaction of an electron wavepacket, accompanied by numerical computations, reveals two limits. In the quantum regime of long wavepacket siz…
Robust Radiative Cooling in Functionalizable Silica Microsphere Paints
Instituto de Ciencia de Materiales de Madrid (ICMM), Consejo Superior de Investigaciones Científicas (CSIC)（马德里材料科学研究所（ICMM），西班牙国家研究委员会（CSIC））；Cooling Photonics Sociedad Limitada（冷却光子学有限公司）；Universitat Politècnica de Catalunya（加泰罗尼亚理工大学）
For commercial one-sun solar modules, up to 80% of the incoming sunlight may be dissipated as heat, potentially raising the temperature 20 C - 30 C higher than the ambient. In the long term, extreme self-heating erodes efficiency and shortens lifetime, thereby dramatically reducing the total energy output. Therefore, it is critically important to develop effective and practical (and preferably passive) cooling methods to reduce operating temperature of PV modules. In this paper, we explore two fundamental (but often overlooked) origins of PV self-heating, namely, sub-bandgap absorption and imp…
As an emerging electricity-free cooling technology, radiative cooling employs outer space as the heat sink. With this, a sky-facing thermal emitter is usually required. Due to the black-body radiation limit at ambient temperature, the maximum cooling power density for a single-faced radiative cooling device is ~156.9 W/m2. Here we report a double-sided radiative cooling architecture using graded nanocomposite metamaterials (GNM) designed for a vertically aligned thermal emitter. This GNM structure possesses an optical absorption of over 90% throughout the solar spectrum, and exceeds 90% reflec…
Passive radiative cooling is currently the frontier technology in renewable-energy research. In terms of extraterrestrial applications, radiative cooling is a critical component to the thermal management system of a spacecraft, where the extreme environment of space can cause large temperature variations that can break and damage equipment. For terrestrial applications, nocturnal or daytime radiative cooling is expected to lead to cost-effective passive heat management without the need of inefficient and costly artificial refrigeration technologies. However, most currently available radiative …
Radiative cooling is a passive cooling strategy with zero consumption of electricity. Although this technology can work well during optimal atmospheric conditions at nighttime, it is essential to achieve efficient radiative cooling during daytime when peak cooling demand actually occurs. In this article, we report an inexpensive planar polydimethylsiloxane (PDMS)/metal thermal emitter, i.e., a thin film structure fabricated using fast solution coating process that is scalable for large area manufacturing. By manipulating the beaming effect of the thermal radiation, temperature reduction of 9.5…
Radiative cooling emerged as a possible sustainable solution to the energy hungry vapor compression-based cooling. However, realizing subfreezing temperatures through radiative cooling remains challenging in environments with high humidity and often requires extreme heat management, e.g., by placing the thermal emitter in ultrahigh vacuum conditions. This work theoretically investigates the introduction of angular selective thermal emission through surrounding the emitter with an angular shield. The effect of the spectral selectivity of the emitter, the humidity of the environment, and the int…
Terrestrial radiative cooling is an intriguing way to mitigate the accelerating cooling demands in the residential and commercial sectors by offering zero-energy cooling. However, the ultra-white or mirror-like appearance of radiative coolers can be visually sterile and raise safety issues when broadly applied to building facades and vehicles. To overcome the fundamental trade-off between color diversity and cooling performance, we propose a radiatively integrated, conductively insulated system that exploits thermal non-equilibrium between colorants and thermal emitters. This allows such radia…
Buildings or vehicles with transparent envelope can be heated up by sunlight, causing energy consumption for cooling and in extreme cases leading to vehicular heatstroke in a hot climate. Because only visible light for illumination is essential for these applications, the NIR solar radiation should be reflected to reduce heat gain and the infrared radiation emission should be enhanced for further cooling by using the sky as a heat sink. With a high NIR reflection, a transparent radiative cooling photonic structure consisting of 2D silica gratings atop ZnO/Ag/ZnO is demonstrated for energy-savi…
We propose in this article a method to generate radiative coolers which are reflective in the solar spectrum and emissive in the transparency window of the atmosphere (8-13 $μ$m). We choose an approach combining thermal control capacity of gratings and multi-layers. We use optimized BN, SiC and SiO 2 gratings, which have emissivity peak in the transparency window. We place under these gratings a metal/dielectric multi-layer structure to obtain a near perfect reflectivity in the solar spectrum and to enhance the emissivity in the transparency window. The optimized structures produce a good radi…
Through passively emitting excess heat to the outer space, radiative cooling has been demonstrated as an efficient way for energy saving applications. Selective surface with unity emittance only within the atmospheric window as well as zero absorption within the solar spectrum is sought to achieve the best sub-ambient radiative cooling performance during the daytime. In this work, we proposed a bulk radiative cooler consisting of a 1-mm-thick lithium fluoride crystal coated with silver backing, which exhibits a solar absorptance of 4.7% and nearly ideal infrared selectivity with high emission …
The scattering of light by resonant nanoparticles is a key process for enhancing the solar reflectance in daylight radiative cooling. Here, we investigate the impact of material dispersion on the scattering performance of popular nanoparticles for radiative cooling applications. We show that, due to material dispersion, nanoparticles with a qualitatively similar response at visible frequencies exhibit fundamentally different scattering properties at infrared frequencies. It is found that dispersive nanoparticles exhibit suppressed-scattering windows, allowing for selective thermal emission wit…
Daytime radiative cooling is a promising passive cooling technology for combating global warming. Existing daytime radiative coolers usually show whitish colors due to their broadband high solar reflectivity, which severely impedes applications in real-life situations with aesthetic demands and effective display. However, there is a trade-off between vivid colors and high cooling performance because colors are often produced by absorption of visible light, decreasing net cooling power. To break this trade-off, we design multilayered structures with coupled nanocavities and produce structural c…
We present a systematic optimization of nighttime thermoelectric power generation system utilizing radiative cooling. We show that an electrical power density over 2 W/m2, two orders of magnitude higher than the previously reported experimental result, is achievable using existing technologies. This system combines radiative cooling and thermoelectric power generation and operates at night when solar energy harvesting is unavailable. The thermoelectric power generator (TEG) itself covers less than 1 percent of the system footprint area when achieving this optimal power generation, showing econ…
Vapor condensation plays a crucial role in solar water-purification technologies. Conventional condensers in solar water-purification systems do not provide sufficient cooling power for vapor condensation, limiting the water production rate to $0.4 L m^{-2} hour^{-1}$. On the other hand, radiative dew condensation, a technique used by existing radiative dew condensers, only works at nighttime and is incompatible with solar water-purification technologies. Here, we develop daytime radiative condensers that reflect almost all solar radiation, and can thus create dew water even in direct sunlight…
We report a detailed formalism aimed at the thermal modeling and heat mitigation in high-power double-clad fiber amplifiers. Closed form analytical formulas are developed that take into account the spatial profile of the amplified signal and pump in the double-clad geometry, the presence of the amplified spontaneous emission, and the possibility of radiative cooling due to anti-Stokes fluorescence emission. The formalism is applied to a high-power Yb-doped silica fiber amplifier. The contributions to the heat-load from the pump-signal quantum defect, as well as the pump and signal parasitic ab…
The possibility of night-time power generation has recently stimulated interest in using the radiative sky cooling mechanism with thermoelectric generators (TEG). These passive, low-temperature difference devices have been shown to generate electricity at night with no active input of heat needed, instead using the ambient air itself as the heat source. Here, we optimize both the geometry and operating conditions of radiative cooling driven thermoelectric (RC-TE) generators. We determine the optimal operating conditions, including maximum power point and maximum efficiency point, by developing…
Dynamic radiative cooling with variable emissive power is experimentally demonstrated in this study by a wavelength-selective tunable metafilm emitter, which consists of an opaque aluminum film, a sputtered silicon spacer, and a thermochromic vanadium dioxide (VO2) layer fabricated by a furnace oxidation method. The temperature-dependent spectral emittance, experimentally obtained from spectral reflectance measurements, clearly shows a pronounced emission peak around 10 um wavelength when the VO2 experiences an insulator-to-metal phase transition near 65C. The tunable metafilm emitter achieves…
We theoretically study the thermal relaxation of many-body systems under the action of oscillating external fields. When the magnitude or the orientation of a field is modulated around values where the pairwise heat-exchange conductances depend non-linearly on this field, we demonstrate that the time symmetry is broken during the evolution of temperatures over a modulation cycle. We predict that this asymmetry enables a pumping of heat which can be used to cool down faster the system. This effect is illustrated through different magneto-optical systems under the action of an oscillating magnet…
College of Chemical Engineering, Zhejiang University of Technology（浙江工业大学化学工程学院）；School of Physical Science and Technology, Ningbo University（宁波大学物理科学与技术学院）；Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences（中国科学院宁波材料技术与工程研究所）；Institute of Vegetables, Ningbo Academy of Agricultural Sciences（宁波市农业科学院蔬菜研究所）
As a representative device exploiting both the solar energy and the radiative cooling of deep-sky, the radiative temperature regulator (RTR) could switch between heating and cooling modes self-adaptively at different temperatures. However, the concept of RTR is challenging to be implemented due to the intense parasitic absorption in phase-changing layers. Here, based on the theoretical framework of energy conservation, we quantitatively reveal the intrinsic relationships between solar heating and radiative cooling, especially addressing the fundamental limiting factors, including the parasitic…
Tropospheric Ozone Formation Potential and Related Design Considerations for Radiative Coolers
Oak Ridge National Laboratory（橡树岭国家实验室）；University “G. d’Annunzio” of Chieti-Pescara（基耶蒂-佩斯卡拉“G. d’Annunzio”大学）；Auburn University（奥本大学）；Princeton University（普林斯顿大学）
We report on optical design and applications of hybrid meso-scale devices and materials that combine optical and thermal management functionalities owing to their tailored resonant interaction with light in visible and infrared frequency bands. We outline a general approach to designing such materials, and discuss two specific applications in detail. One example is a hybrid optical-thermal antenna with sub-wavelength light focusing, which simultaneously enables intensity enhancement at the operating wavelength in the visible and reduction of the operating temperature. The enhancement is achiev…
