Thermodynamics of the Casimir Effect - Asymptotic Considerations -
H. Mitter, D. Robaschik
备注：
Talk at the conference "Quantum Field Theory under the Influence of External Conditions " Leipzig, 14.-18.9.1998, submitted to the conference proceedings
We study the Casimir effect with different temperatures between the plates ($T$) resp. outside of them ($T'$). If we consider the inner system as the black body radiation for a special geometry, then contrary to common belief the temperature approaches a constant value for vanishing volume during isentropic processes. This means: the reduction of the degrees of freedom can not be compensated by a concentration of the energy during an adiabatic contraction of the two-plate system. Looking at the Casimir pressure, we find one unstable equilibrium point for isothermal processes with $T > T'$. For isentropic processes there is additionally one stable equilibrium point for larger values of the distances between the two plates.}
One loop field theory calculations of free energies quite often yield violations of the stability conditions associated with the thermodynamic second law. Perhaps the best known example involves the equation of state of black holes. Here, it is pointed out that the Casimir force between two parallel conducting plates also violates a thermodynamic stability condition normally associated with the second law of thermodynamics.
A complete thermodynamic treatment of the Casimir effect is presented. Explicit expressions for the free and the internal energy, the entropy and the pressure are discussed. As an example we consider the Casimir effect with different temperatures between the plates ($T$) resp. outside of them ($T'$). For $T'<T$ the pressure of heat radiation can eventually compensate the Casimir force and the total pressure can vanish. We consider both an isothermal and an adiabatic treatment of the interior region. The equilibrium point (vanishing pressure) turns out instable in the isothermal case. In the ad…
We review recent results on the low-temperature behaviors of the Casimir-Polder and Casimir free energy an entropy for a polarizable atom interacting with a graphene sheet and for two graphene sheets, respectively. These results are discussed in the wide context of problems arising in the Lifshitz theory of van der Waals and Casimir forces when it is applied to metallic and dielectric bodies. After a brief treatment of different approaches to theoretical description of the electromagnetic response of graphene, we concentrate on the derivation of response function in the framework of thermal qu…
The low-temperature behavior of the Casimir-Polder free energy and entropy for an atom near a dielectric plate are found on the basis of the Lifshitz theory. The obtained results are shown to be thermodynamically consistent if the dc conductivity of the plate material is disregarded. With inclusion of dc conductivity, both the standard Lifshitz theory (for all dielectrics) and its generalization taking into account screening effects (for a wide range of dielectrics) violate the Nernst heat theorem. The inclusion of the screening effects is also shown to be inconsistent with experimental data o…
We investigate the thermodynamical aspects of the Casimir effect in the case of plane parallel plates made of real metals. The thermal corrections to the Casimir force between real metals were recently computed by several authors using different approaches based on the Lifshitz formula with diverse results. Both the Drude and plasma models were used to describe a real metal. We calculate the entropy density of photons between metallic plates as a function of the surface separation and temperature. Some of these approaches are demonstrated to lead to negative values of entropy and to nonzero en…
In a recent letter, Martin and Zagrebnov [Europhys. Lett., 73 (2006) 1] discussed the thermodynamic Casimir effect for the ideal Bose gas confined in a thin film. We point out that their findings can be expressed in terms of previous general results for the Casimir effect induced by confined critical fluctuations. This highlights the links between the Casimir effect in the contexts of critical phenomena and Bose-Einstein condensation.
We give a rigorous analytical derivation of low-temperature behavior of the Casimir entropy in the framework of the Lifshitz formula combined with the Drude dielectric function. An earlier result that the Casimir entropy at zero temperature is not equal to zero and depends on the parameters of the system is confirmed, i.e. the third law of thermodynamics (the Nernst heat theorem) is violated. We illustrate the resolution of this thermodynamical puzzle in the context of the surface impedance approach by several calculations of the thermal Casimir force and entropy for both real metals and diele…
We consider Casimir-Polder and Casimir forces with finite dissipation by coupling heat baths to the dipoles introducing, this way, dissipation from 'first principles'. We derive a representation of the free energy as an integral over real frequencies, which can be viewd as an generalization of the 'remarkable formula' introduced by Ford et. al. 1985. For instance, we obtain a nonperturbative representation for the atom-atom and atom-wall interactions. We investigate several limiting cases. From the limit $T\to0$ we show that the third law of thermodynamics cannot be violated within the given a…
We study the fundamental limitations of cooling to absolute zero for a qubit, interacting with a single mode of the electromagnetic field. Our results show that the dynamical Casimir effect, which is unavoidable in any finite-time thermodynamic cycle, forbids the attainability of the absolute zero of temperature, even in the limit of an infinite number of cycles.
The applicability of the Lifshitz formula is discussed to the case of two thick parallel plates made of real metal. The usual description of the zero-point vacuum oscillations on the background of the frequency-dependent dielectric permittivity is shown to be in contradiction with thermodynamics. Instead, the Lifshitz formula for the Casimir free energy should be reformulated in terms of the reflection coefficients containing the surface impedance instead of the dielectric permittivity. This approach is presently confirmed experimentally by precision measurements of the van der Waals and Casim…
The analytic asymptotic expressions for the Casimir free energy and entropy for two parallel graphene sheets possessing nonzero energy gap $Δ$ and chemical potential $μ$ are derived at arbitrarily low temperature. Graphene is described in the framework of thermal quantum field theory in the Matsubara formulation by means of the polarization tensor in (2+1)-dimensional space-time. Different asymptotic expressions are found under the conditions $Δ>2μ$, $Δ=2μ$, and $Δ<2μ$ taking into account both the implicit temperature dependence due to a summation over the Matsubara frequencies and the explici…
The Casimir force has its origin in finite modification of the infinite zero-point energy induced by a specific boundary condition for the spatial configuration. In terms of the imaginary-time formalism at finite temperature, the root of Planck's law of radiation can be traced back to finite modification of the infinite vacuum energy induced by the periodic boundary condition in the temporal direction. We give the explicit conversion from the Casimir force to Planck's law of radiation, which shows the apparent correspondence between the system bounded by parallel conducting plates and the ther…
We investigate Casimir effect as well as thermal Casimir effect for a pair of parallel perfectly plates placed in general stationary space-time background. It is found that the Casimir energy is influenced by the 00-component of metric and the corresponding quantity in dragging frame. We give a scheme to renormalize thermal correction to free energy in curved space-time. It is shown that the thermal corrections to Casimir thermodynamic quantities not only depend on the proper temperature and proper geometrical parameters of the plates, but also on the determinant of space-time metric.
We present a quantum description of photon creation via dynamical Casimir effect based on the standard Hamiltonian formulation. The particle representation is constructed in the expansion of field operators fixed with the initial modes. The Hamiltonian is presented in terms of the creation and annihilation operators with the time-varying couplings which originate from the external properties such as an oscillating boundary or a plasma mirror of a semiconductor slab. Some consideration is also made for the experimental realization with a semiconductor plasma mirror.
Recently J.S. Hoye, I.Brevik, J.B. Aarseth, and K.A. Milton [Phys. Rev. E v.67, 056116 (2003); quant-ph/0212125] proposed that if the Lifshitz formula is combined with the Drude model, the transverse electric zero mode does not contribute to the result for real metals and there arises a linear temperature correction to the Casimir force at small temperatures. The authors claim that in spite of the fact that the Casimir entropy in their approach is negative, the Nernst heat theorem is satisfied. In the present Comment we show that the authors' conclusion regarding the Nernst heat theorem is in …
The analytic expressions for the free energy and entropy of the Casimir-Polder interaction between a polarizable and magnetizable atom and a graphene sheet are found in the limiting case of low temperature. In so doing, the response of graphene to electromagnetic fluctuations is described in the framework of the Dirac model by means of the polarization tensor in (2+1)-dimensional space-time. It is shown that the dominant contribution to the low-temperature behavior is given by an explicit dependence of the polarization tensor on temperature as a parameter. We demonstrate that the Lifshitz theo…
By considering the effect of diffusion on the external electric field response of charge carriers in metals and semiconductors, it is shown that the finite temperature correction proposed Bostrom and Sernelius requires substantial modification, and there is no large correction as suggested for good conductors. The apparent violation of the Third Law of Thermodynamics of the various proposed temperature corrections to the Casimir force is also resolved. Finally, the effect of Debye screening on electrostatic calibrations between pure germanium surfaces is calculated
The Lifshitz theory of dispersion forces leads to thermodynamic and experimental inconsistencies when the role of drifting charge carriers is included in the model of the dielectric response. Recently modified reflection coefficients were suggested that take into account screening effects and diffusion currents. We demonstrate that this theoretical approach leads to a violation of the third law of thermodynamics (Nernst's heat theorem) for a wide class of materials and is excluded by the data from two recent experiments. The physical reason for its failure is explained by the violation of ther…
We calculate the Casimir energy at spherical cavities within a host made up of an arbitrary material described by a possibly dispersive and lossy dielectric response. To that end, we add to the coherent optical response a contribution that takes account of the incoherent radiation emitted by the host in order to guarantee the detailed balance required to keep the system at thermodynamic equilibrium in the presence of dissipation. The resulting boundary conditions allow a conventional quantum mechanical treatment of the radiation within the cavity from which we obtain the contribution of the ca…
The recently suggested modification of the transverse electric contribution to the Lifshitz formula (S. K. Lamoreaux, arXiv:0801.1283) is discussed. We show that this modification is inconsistent with the data of two precise experiments, and violates the Nernst heat theorem. The preprint's suggestion concerning the resolution of the "apparent violation of the Third Law of Thermodynamics" is shown to be incorrect.
We study the behavior of the critical Casimir force and its interplay with the van der Waals force acting between two parallel slabs separated at a distance $L$ from each other confining a non-polar simple fluid or a binary liquid mixture. The surfaces of the slabs are coated by thin layers exerting strong preference to the liquid phase of the fluid, or one of the components of the mixture. The slabs influence the fluid by long-range competing dispersion potentials. Under such conditions one usually expects {\it attractive} Casimir force governed by universal scaling function to which the disp…
The canonical quantization of macroscopic electromagnetism was recently presented in New J. Phys. 12 (2010) 123008. This theory is here used to derive the Casimir effect, by considering the special case of thermal and zero-point fields. The stress-energy-momentum tensor of the canonical theory follows from Noether's theorem, and its electromagnetic part in thermal equilibrium gives the Casimir energy density and stress tensor. The results hold for arbitrary inhomogeneous magnetodielectrics and are obtained from a rigorous quantization of electromagnetism in dispersive, dissipative media. Conti…
The nonlocal response functions to quantum fluctuations are used to find asymptotic expressions for the Casimir free energy and entropy at arbitrarily low temperature in the configuration of two parallel metallic plates. It is shown that by introducing an alternative nonlocal response to the off-the-mass-shell fluctuations the Lifshitz theory is brought into agreement with the requirements of thermodynamics. According to our results, the Casimir entropy calculated using the nonlocal response functions, which take into account dissipation of conduction electrons, remains positive and monotonous…
The interaction between drifting carriers and traveling electromagnetic waves is considered within the context of the classical Boltzmann transport equation to compute the Casimir-Lifshitz force between media with small density of charge carriers, including dielectrics and intrinsic semiconductors. We expand upon our previous work [Phys. Rev. Lett. {\bf 101}, 163203 (2008)] and derive in some detail the frequency-dependent reflection amplitudes in this theory and compute the corresponding Casimir free energy for a parallel plate configuration. We critically discuss the the issue of verificatio…
Thermal Casimir Effect in A Schwarzschild-like Wormhole Spacetime
Sepuluh Nopember Institute of Technology（十十一月理工大学）；Universitas Islam Negeri Maulana Malik Ibrahim Malang（穆拉纳马利克伊布拉欣伊斯兰国立大学）；Asia Pacific Center for Theoretical Physics（亚太理论物理中心）；National Research and Innovation Agency (BRIN)（国家研究与创新署）；Universitas Indonesia（印度尼西亚大学）
For the Casimir interaction between two nearby objects, the plane-wave basis proves convenient for numerical calculations as well as for analytical considerations leading to an optical interpretation of the relevant scattering processes of electromagnetic waves. We review work on the proximity-force approximation and corrections to it within the plane-wave basis for systems involving spherical objects. Previous work is extended by allowing for polarization mixing during the reflection at a sphere. In particular, explicit results are presented for perfect electromagnetic conductors. Furthermore…
We explore an analogy between the thermodynamics of a free dissipative quantum particle and that of an electromagnetic field between two mirrors of finite conductivity. While a free particle isolated from its environment will effectively be in the high-temperature limit for any nonvanishing temperature, a finite coupling to the environment leads to quantum effects ensuring the correct low-temperature behavior. Even then, it is found that under appropriate circumstances the entropy can be a nonmonotonic function of the temperature. Such a scenario with its specific dependence on the ratio of te…
We review complicated problems in the Lifshitz theory describing the Casimir force between real material plates made of metals and dielectrics including different approaches to their resolution. It has been shown that both for metallic plates with perfect crystal lattices and for any dielectric plates the Casimir entropy calculated in the framework of the Lifshitz theory violates the Nernst heat theorem when the well approved dielectric functions are used in computations. The respective theoretical Casimir forces are excluded by the measurement data of numerous precision experiments. In the li…
The problem with the temperature dependence of the Casimir force is investigated. Specifically, the entropy behavior in the low temperature limit, which caused debates in the literature, is analyzed. It is stressed that the behavior of the relaxation frequency in the $T\to0$ limit does not play a physical role since the anomalous skin effect dominates in this range. In contrast with the previous works, where the approximate Leontovich impedance was used for analysis of nonlocal effects, we give description of the problem in terms of exact nonlocal impedances. It is found that the Casimir entro…
The controversy concerning the temperature correction to the Casimir force has been ongoing for almost a decade with no view to a solution and has recently been extended to include semiconducting materials. We review some theoretical aspects of formal violations of Nernst's heat theorem in the context of Casimir Lifshitz thermodynamics and the role of the exponent of the leading term of the dielectric permittivity with respect to imaginary frequency. A general formalism for calculating the temperature corrections to free energy at low temperatures is developed for systems which do not exhibit …
We consider the quantum Rabi model with external time modulation of the atomic frequency, which can be employed to create excitations from the vacuum state of the electromagnetic field as a consequence of the dynamical Casimir effect. Excitations can also be systematically subtracted from the atom-field system by suitably adjusting the modulation frequency, in the so-called anti-dynamical Casimir effect (ADCE). We evaluate the quantum thermodynamical work and show that a realistic out-of-equilibrium finite-time protocol harnessing ADCE allows for work extraction from the system, whose amount c…
There has been recent criticism of our approach to the Casimir force between real metallic surfaces at finite temperature, saying it is in conflict with the third law of thermodynamics and in contradiction with experiment. We show that these claims are unwarranted, and that our approach has strong theoretical support, while the experimental situation is still unclear.
Several problems at the interface between the field-theoretical description of the Casimir effect and experiments on measuring the Casimir force are discussed. One of these problems is connected with the definition of the Casimir free energy in ideal metal rectangular boxes satisfying the general physical requirements. It is shown that the consideration of rectangular boxes with a partition (piston) does not negate the previously known results obtained for boxes without a piston. Both sets of results are found to be in mutual agreement. Another problem is related to the use of the proximity fo…
The application of the Lifshitz theory to describe the thermal Casimir force between dielectrics and semiconductors is considered. It is shown that for all true dielectrics (i.e., for all materials having zero conductivity at zero temperature) the inclusion of a nonzero conductivity arising at nonzero temperature into the model of dielectric response leads to the violation of the Nernst heat theorem. This result refers equally to simple insulators, intrinsic semiconductors, Mott-Hubbard dielectrics and doped semiconductors with doping concentration below a critical value. We demonstrate that i…
The temperature dependence of the Casimir force between a real metallic plate and a metallic sphere is analyzed on the basis of optical data concerning the dispersion relation of metals such as gold and copper. Realistic permittivities imply, together with basic thermodynamic considerations, that the transverse electric zero mode does not contribute. This results in observable differences with the conventional prediction, which does not take this physical requirement into account. The results are shown to be consistent with the third law of thermodynamics, as well as being consistent with curr…
Recently, we have demonstrated that for a certain class of Casimir-type systems ("devices") the energy of zero-point vacuum fluctuations reaches its global minimum when the device rotates about a certain axis rather than remains static. This rotational vacuum effect may lead to the emergence of permanently rotating objects provided the negative rotational energy of zero-point fluctuations cancels the positive rotational energy of the device itself. In this paper, we show that for massless electrically charged particles the rotational vacuum effect should be drastically (astronomically) enhance…
It is demonstrated that the general theory of Casimir and van der Waals forces describes the interaction-induced equilibrium thermodynamic potentials of the damped harmonic oscillator bilinearly coupled to the environment. An extended model for a damped oscillator is suggested along the lines of the general theory of Casimir and van der Waals forces, and the corresponding thermodynamic quantities obtained. While the original model involves a heat bath consisting of a large number of free oscillators having infinitesimal damping functions, the extended model allows any generally admissible freq…
Recently, Brevik et al. [Phys. Rev. E 71, 056101 (2005)] adduced arguments against the traditional approach to the thermal Casimir force between real metals and in favor of one of the alternative approaches. The latter assumes zero contribution from the transverse electric mode at zero frequency in qualitative disagreement with unity as given by the thermal quantum field theory for ideal metals. Those authors claim that their approach is consistent with experiments as well as with thermodynamics. We demonstrate that these conclusions are incorrect. We show specifically that their results are c…
The thermodynamical properties of a quantized electromagnetic field inside a box with perfectly conducting walls are studied using a regularization scheme that permits to obtain finite expressions for the thermodynamic potentials. The source of ultraviolet divergences is directly isolated in the expression for the density of modes, and the logarithmic infrared divergences are regularized imposing the uniqueness of vacuum and, consequently, the vanishing of the entropy in the limit of zero temperature. We thus obtain corrections to the Casimir energy and pressures, and to the specific heat that…
We calculate the Casimir energy and entropy for two perfect metal spheres in the large and short separation limit. We obtain nonmonotonic behavior of the Helmholtz free energy with separation and temperature, leading to parameter ranges with negative entropy, and also nonmonotonic behavior of the entropy with temperature and with the separation between the spheres. The appearance of this anomalous behavior of the entropy is discussed as well as its thermodynamic consequences.
It has been suggested by various authors that the `dynamical Casimir effect' might prove responsible for the production of visible-light photons in the bubble collapse which occurs in sonoluminescence. Previously, I have argued against this point of view based on energetic considerations, in the adiabatic approximation. Those arguments have recently been strengthened by the demonstration of the equivalence between van der Waals and Casimir energies. In this note I concentrate on the other extreme possibility, that of the validity of the `sudden approximation' where in effect the bubble instant…
Casimir forces are a manifestation of the change in the zero-point energy of the vacuum caused by the insertion of boundaries. We show how the Casimir force can be computed by consideration of the vacuum fluctuations that are suppressed by the boundaries, and rederive the scalar Casimir effects for a series of geometries. For the planar case a finite universal force is automatically found. For curved geometries formally divergent expressions are encountered which we argue are largely due to the divergent self-energy of the boundary contributing to the force. This idea is supported by computing…
In the present paper we investigate thermal fluctuation corrections to the vacuum energy at zero temperature of a conformally coupled massless scalar field whose modes propagate in the Einstein universe with a spherical boundary, characterized by both Dirichlet and Neumann boundary conditions. Thus, we generalize the results found in literature in this scenario, which has considered only the vacuum energy at zero temperature. To do this, we use the generalized zeta function method plus Abel-Plana formula and calculate the renormalized Casimir free energy as well as other thermodynamics quantit…
The analytic asymptotic expressions for the Casimir free energy, pressure and entropy at low temperature in the configuration of one metal and one dielectric plate are obtained. For this purpose we develop the perturbation theory in a small parameter proportional to the product of the separation between the plates and the temperature. This is done using both the simplified model of an ideal metal and of a dielectric with constant dielectric permittivity and for the realistic case of the metal and dielectric with frequency-dependent dielectric permittivities. The analytic expressions for all re…
With the intent of exploring how the interplay between boundary effects and chiral symmetry breaking may alter the thermodynamical behavior of a system of strongly interacting fermions, we study the Casimir effect for the setup of two parallel layers using a four-fermion effective field theory at zero density. This system reveals a number of interesting features. While for infinitely large separation (no boundaries), chiral symmetry is broken or restored via a second order phase transition, in the opposite case of small (and, in general, finite) separation the transition becomes first order, r…
We review recent results obtained in the physics of the thermal Casimir force acting between two dielectrics, dielectric and metal, and between metal and semiconductor. The detailed derivation for the low-temperature behavior of the Casimir free energy, pressure and entropy in the configuration of two real dielectric plates is presented. For dielectrics with finite static dielectric permittivity it is shown that the Nernst heat theorem is satisfied. Hence, the Lifshitz theory of the van der Waals and Casimir forces is demonstrated to be consistent with thermodynamics. The nonzero dc conductivi…
The finite temperature Casimir free energy, entropy, and internal energy are considered anew for a conventional parallel-plate configuration, in the light of current discussions in the literature. In the case of an "ideal" metal, characterized by a refractive index equal to infinity for all frequencies, we recover, via a somewhat unconventional method, conventional results for the temperature dependence, meaning that the zero-frequency transverse electric mode contributes the same as the transverse magnetic mode. For a real metal, however, approximately obeying the Drude dispersive model at lo…
The violation of the third law of thermodynamics for metals described by the Drude model and for dielectrics with finite \DC conductivity is one of the most interesting problems in the field of the Casimir effect. It manifests itself as a non-vanishing of the entropy for vanishing temperature. We review the relevant calculations for plane surfaces and calculate the corresponding contributions for a ball in front of a plane. In this geometry, these appear in much the same way as for parallel planes. We conclude that the violation of the 3rd law is not related to the infinite size of the planes.
It was recently found that thermodynamic anomalies which arise in the Casimir effect between metals described by the Drude model can be attributed to the interaction of fluctuating Foucault (or eddy) currents [Phys. Rev. Lett. 103, 130405 (2009)]. We show explicitly that the two leading terms of the low-temperature correction to the Casimir free energy of interaction between two plates, are identical to those pertaining to the Foucault current interaction alone, up to a correction which is very small for good metals. Moreover, a mode density along real frequencies is introduced, showing that t…
We find analytic asymptotic expressions at low temperature for the Casimir free energy, entropy and pressure of two parallel graphene sheets in the framework of the Lifshitz theory. The reflection coefficients of electromagnetic waves on graphene are described on the basis of first principles of quantum electrodynamics at nonzero temperature using the polarization tensor in (2+1)-dimensional space-time. The leading contributions to the Casimir entropy and to the thermal corrections to the Casimir energy and pressure are given by the thermal correction to the polarization tensor at nonzero Mats…
The physical reasons why the Drude dielectric function is not compatible with the Lifshitz formula, as opposed to the generalized plasma-like permittivity, are presented. Essentially, the problem is connected with the finite size of metal plates. It is shown that the Lifshitz theory combined with the generalized plasma-like permittivity is thermodynamically consistent.
Assuming the conventional Casimir setting with two thick parallel perfectly conducting plates of large extent with a homogeneous and isotropic medium between them, we discuss the physical meaning of the electromagnetic field energy $W_{\rm disp}$ when the intervening medium is weakly dispersive but nondissipative. The presence of dispersion means that the energy density contains terms of the form $d[ωε(ω)] /dω$ and $d[ωμ(ω)] /dω$. We find that, as $W_{\rm disp}$ refers thermodynamically to a non-closed physical system, it is {\it not} to be identified with the internal thermodynamic energy $U$…
