With the advanced capabilities of ground- and space-based telescopes, exoplanet science is beginning to characterize the physics and chemistry of exoplanet atmospheres. However, interpreting exoplanet observations requires sophisticated modeling tools that rely on laboratory data to provide critical inputs and constraints. In preparation for the influx of observational data that the coming decades will bring, laboratory experiments that simulate the diverse conditions expected in exoplanet atmospheres, surfaces and interiors are vital to advancing models and thereby our understanding of these worlds. Here we discuss the key areas where laboratory experiments are providing fundamental data for exoplanet models, particularly for low-mass planets from rocky worlds to sub-Neptunes. First, we present a series of experiments to measure outgassing and volatile solubilities that are essential for establishing the connection between low-mass exoplanet interiors and their observable atmospheres. We then discuss additional laboratory techniques that can be used to understand the interior-atmosphere connection and simulate the high pressure-high temperature conditions of exoplanet interiors. Next, we summarize the experimental methods used to constrain the spectroscopic properties of atmospheric gases and aerosols along with their formation and reaction mechanisms. We also discuss how similar methods can be used to constrain exoplanet surface compositions, which is important for interpreting observations of atmosphere-less worlds. Finally, we conclude by presenting several examples of astrobiology experiments that constrain how life can modify the atmosphere and surface of rocky exoplanets. Together, these laboratory efforts are crucial to maximizing the scientific yield of exoplanet observations in the coming decades.
Continuous improvements of observations and modeling efforts have led to tremendous strides in exoplanetary science. However, as instruments and techniques advance laboratory data becomes more important to interpret exoplanet observations and verify theoretical modeling. Though experimental studies are often deferred due to their high costs and long timelines, it is imperative that laboratory investigations are prioritized to ensure steady advances in the field of exoplanetary science. This White Paper discusses the importance of prioritizing exoplanetary laboratory efforts, and discusses seve…
With the upcoming launch of space telescopes dedicated to the study of exoplanets, the \textit{Atmospheric Remote-Sensing Infrared Exoplanet Large-survey} (ARIEL) and the \textit{James Webb Space Telescope} (JWST), a new era is opening in the exoplanetary atmospheric explorations. However, especially in relatively cold planets around later-type stars, photochemical hazes and clouds may mask the composition of the lower part of the atmosphere, making it difficult to detect any chemical species in the troposphere or to understand whether there is a surface or not. This issue is particularly exac…
We present a theory for interpreting the sodium lines detected in transmission spectra of exoplanetary atmospheres. Previous analyses employed the isothermal approximation and dealt only with the transit radius. By recognising the absorption depth and the transit radius as being independent observables, we develop a theory for jointly interpreting both quantities, which allows us to infer the temperatures and number densities associated with the sodium lines. We are able to treat a non-isothermal situation with a constant temperature gradient. Our novel diagnostics take the form of simple-to-u…
Imaging rocky planets in reflected light, a key focus of future NASA missions and ELTs, requires advanced wavefront control to maintain a deep, temporally correlated null of stellar halo at just several diffraction beam widths. We discuss development of Linear Dark Field Control (LDFC) to achieve this aim. We describe efforts to test spatial LDFC in a laboratory setting for the first time, using the Ames Coronagraph Experiment (ACE) testbed. Our preliminary results indicate that spatial LDFC is a promising method focal-plane wavefront control method capable of maintaining a static dark hole, a…
Constraining planet formation based on the atmospheric composition of exoplanets is a fundamental goal of the exoplanet community. Existing studies commonly try to constrain atmospheric abundances, or to analyze what abundance patterns a given description of planet formation predicts. However, there is also a pressing need to develop methodologies that investigate how to transform atmospheric compositions into planetary formation inferences. In this study we summarize the complexities and uncertainties of state-of-the-art planet formation models and how they influence planetary atmospheric com…
Direct detection and detailed characterization of exoplanets using extreme adaptive optics (ExAO) is a key science goal of future extremely large telescopes (ELTs). However, wavefront errors will limit the sensitivity of this endeavor. Limitations for ground-based telescopes arise from both quasi-static and residual AO-corrected atmospheric wavefront errors, the latter of which generates short-lived aberrations that will average into a halo over a long exposure. We have developed and tested the framework for a solution to both of these problems using the self-coherent camera (SCC), to be appli…
Photochemistry induced by stellar UV flux should produce haze particles in exoplanet atmospheres. Recent observations indicate that haze and/or cloud layers exist in the atmospheres of exoplanets. However, photochemical processes in exoplanetary atmospheres remain largely unknown. We performed laboratory experiments with the PHAZER chamber to simulate haze formation in a range of exoplanet atmospheres (hydrogen-rich, water-rich, and carbon dioxide-rich at 300, 400, and 600 K), and observed the gas phase compositional change (the destruction of the initial gas and the formation of new gas speci…
Deep learning algorithms are growing in popularity in the field of exoplanetary science due to their ability to model highly non-linear relations and solve interesting problems in a data-driven manner. Several works have attempted to perform fast retrievals of atmospheric parameters with the use of machine learning algorithms like deep neural networks (DNNs). Yet, despite their high predictive power, DNNs are also infamous for being 'black boxes'. It is their apparent lack of explainability that makes the astrophysics community reluctant to adopt them. What are their predictions based on? How …
Refractive indices of photochemical haze analogs for Solar System and exoplanet applications : a cross-laboratory comparative study between the PAMPRE and COSmIC experimental set-ups
Theory and observation for the search for life on exoplanets via atmospheric "biosignature gases" is accelerating, motivated by the capabilities of the next generation of space- and ground-based telescopes. The most observationally accessible rocky planet atmospheres are those dominated by molecular hydrogen gas, because the low density of H$_2$-gas leads to an expansive atmosphere. The capability of life to withstand such exotic environments, however, has not been tested in this context. We demonstrate that single-celled microorganisms ($\textit{E. coli}$ and yeast) that normally do not inhab…
One of the desired outcomes of studying exoplanetary atmospheres is to set decisive constraints on exoplanet formation theories. Astronomers often speak of the "metallicity" in broad terms. When modeling the bulk metallicity, workers refer to the elemental iron abundance (Fe/H). By contrast, when exo-atmospheric astronomers speak of the "metallicity" derived from analysing low-resolution Hubble and Spitzer spectrophotometry, they are referring to the elemental abundances of oxygen (O/H), carbon (C/H) and nitrogen (N/H): in decreasing order of importance, since spectra from the Hubble Wide Fiel…
Super-Earths and mini-Neptunes are the most abundant types of planets among the ~3500 confirmed exoplanets, and are expected to exhibit a wide variety of atmospheric compositions. Recent transmission spectra of super-Earths and mini-Neptunes have demonstrated the possibility that exoplanets have haze/cloud layers at high altitudes in their atmospheres. However, the compositions, size distributions, and optical properties of these particles in exoplanet atmospheres are poorly understood. Here, we present the results of experimental laboratory investigations of photochemical haze formation withi…
The current goals of the astrobiology community are focused on developing a framework for the detection of biosignatures, or evidence thereof, on objects inside and outside of our solar system. A fundamental aspect of understanding the limits of habitable environments (surface liquid water) and detectable signatures thereof is the study of where the boundaries of such environments can occur. Such studies provide the basis for understanding how a once inhabitable planet might come to be uninhabitable. The archetype of such a planet is arguably Earth's sibling planet, Venus. Given the need to de…
Constraining the lives and times of exoplanets through evolutionary Bayesian retrievals
Institute of Astronomy, University of Cambridge（剑桥大学天文学研究所）；Kapteyn Astronomical Institute, University of Groningen（格罗宁根大学卡普坦天文研究所）；Helmholtz AI, Technical University of Munich（慕尼黑工业大学赫尔姆霍兹人工智能）；University of Technology Nuremberg（纽伦堡技术大学）
The majority of stars are now thought to support exoplanets. Many of those exoplanets discovered thus far are categorized as rocky objects with an atmosphere. Most of these objects are however hot due to their short orbital period. Models suggest that water is the dominant species in their atmospheres. The hot temperatures are expected to turn these atmospheres into a (high pressure) steam bath containing remains of melted rock. The spectroscopy of these hot rocky objects will be very different from that of cooler objects or hot gas giants. Molecules suggested to be important for the spectrosc…
Current and future high contrast imaging instruments aim to detect exoplanets at closer orbital separations, lower masses, and/or older ages than their predecessors, with the eventual goal of directly detecting terrestrial-mass habitable-zone exoplanets. However, continually evolving speckles in the coronagraphic science image still limit state-of-the-art ground-based exoplanet imaging instruments to contrasts at least two orders of magnitude worse than what is needed to achieve this goal. For ground-based adaptive optics (AO) instruments it remains challenging for most speckle suppression tec…
Advancements in our understanding of exoplanetary atmospheres, from massive gas giants down to rocky worlds, depend on the constructive challenges between observations and models. We are now on a clear trajectory for improvements in exoplanet observations that will revolutionize our ability to characterize the atmospheric structure, composition, and circulation of these worlds. These improvements stem from significant investments in new missions and facilities, such as JWST and the several planned ground-based extremely large telescopes. However, while exoplanet science currently has a wide ra…
Very little experimental work has been done to explore the properties of photochemical hazes formed in atmospheres with very different compositions or temperatures than that of the outer solar system or of early Earth. With extrasolar planet discoveries now numbering thousands, this untapped phase space merits exploration. This study presents measured chemical properties of haze particles produced in laboratory analogues of exoplanet atmospheres. We used very high resolution mass spectrometry to measure the chemical components of solid particles produced in atmospheric chamber experiments. Man…
Observations of exoplanet atmospheres have shown that aerosols, like in the Solar System, are common across a variety of temperatures and planet types. The formation and distribution of these aerosols are inextricably intertwined with the composition and thermal structure of the atmosphere. At the same time, these aerosols also interfere with our probes of atmospheric composition and thermal structure, and thus a better understanding of aerosols lead to a better understanding of exoplanet atmospheres as a whole. Here we review the current state of knowledge of exoplanet aerosols as determined …
We are now on a clear trajectory for improvements in exoplanet observations that will revolutionize our ability to characterize their atmospheric structure, composition, and circulation, from gas giants to rocky planets. However, exoplanet atmospheric models capable of interpreting the upcoming observations are often limited by insufficiencies in the laboratory and theoretical data that serve as critical inputs to atmospheric physical and chemical tools. Here we provide an up-to-date and condensed description of areas where laboratory and/or ab initio investigations could fill critical gaps in…
Carbon-enriched rocky exoplanets have been proposed around dwarf stars as well as around binary stars, white dwarfs and pulsars. However, the mineralogical make up of such planets is poorly constrained. We performed high-pressure high-temperature laboratory experiments ($P$ = 1$-$2 GPa, $T$ = 1523$-$1823 K) on carbon-enriched chemical mixtures to investigate the deep interiors of Pluto- to Mars-size planets the upper mantles of larger planets. Our results show that these exoplanets, when fully-differentiated, comprise a metallic core, a silicate mantle and a graphite layer on top of the silica…
We present a new method for performing atmospheric retrieval on ground-based, high-resolution data of exoplanets. Our method combines cross-correlation functions with a random forest, a supervised machine learning technique, to overcome challenges associated with high-resolution data. A series of cross-correlation functions are concatenated to give a "CCF-sequence" for each model atmosphere, which reduces the dimensionality by a factor of ~100. The random forest, trained on our grid of ~65,000 models, provides a likelihood-free method of retrieval. The pre-computed grid spans 31 values of both…
Current and future high contrast imaging instruments aim to detect exoplanets at closer orbital separations, lower masses, and/or older ages than their predecessors. However, continually evolving speckles in the coronagraphic science image limit contrasts of state-of-the-art ground-based exoplanet imaging instruments. For ground-based adaptive optics (AO) instruments it remains challenging for most speckle suppression techniques to attenuate both the dynamic atmospheric as well as quasi-static instrumental speckles on-sky. We have proposed a focal plane wavefront sensing and control algorithm …
The status of laboratory spectroscopic data for exoplanet characterisation missions such as EChO is reviewed. For many molecules (eg H2O, CO, CO2, H3+, O2, O3) the data are already available. For the other species work is actively in progress constructing this data. Much of the is work is being undertaken by ExoMol project (www.exomol.com). This information will be used to construct and EChO-specific spectroscopic database.
The Keck Planet Imager and Characterizer (KPIC) is a series of upgrades for the Keck II Adaptive Optics (AO) system and the NIRSPEC spectrograph to enable diffraction-limited, high-resolution ($R>30,000$) spectroscopy of exoplanets and low-mass companions in the K and L bands. Phase I consisted of single-mode fiber injection/extraction units (FIU/FEU) used in conjunction with an H-band pyramid wavefront sensor. Phase II, deployed and commissioned in 2022, adds a 1000-actuator deformable mirror, beam-shaping optics, a vortex coronagraph, and other upgrades to the FIU/FEU. The use of single-mode…
The Effects of M Star Age Dependent Ultraviolet Emission on Detecting and Interpreting Exoplanet Biosignatures
University of California Santa Cruz（加州大学圣克鲁兹分校）；SETI Institute（SETI研究所）；University of Washington（华盛顿大学）；NASA NExSS Virtual Planetary Laboratory（NASA NExSS虚拟行星实验室）；Arizona State University（亚利桑那州立大学）；University of Maryland, Baltimore County（马里兰大学巴尔的摩分校）；NASA Goddard Space Flight Center（美国宇航局戈达德太空飞行中心）；United States Naval Observatory（美国海军天文台）
The ExTrA facility, located at La Silla observatory, will consist of a near-infrared multi-object spectrograph fed by three 60-cm telescopes. ExTrA will add the spectroscopic resolution to the traditional differential photometry method. This shall enable the fine correction of color-dependent systematics that would otherwise hinder ground-based observations. With both this novel method and an infrared-enabled efficiency, ExTrA aims to find transiting telluric planets orbiting in the habitable zone of bright nearby M dwarfs. It shall have the versatility to do so by running its own independent …
Understanding of clouds is instrumental in interpreting current and future spectroscopic observations of exoplanets. Modelling clouds consistently is complex, since it involves many facets of chemistry, nucleation theory, condensation physics, coagulation, and particle transport. We develop a simple physical model for cloud formation and transport, efficient and versatile enough that it can be used in modular fashion for parameter optimization searches of exoplanet atmosphere spectra. The transport equations are formulated in 1D, accounting for sedimentation and diffusion. The grain size is ob…
High-dispersion coronagraphy (HDC) optimally combines high contrast imaging techniques such as adaptive optics/wavefront control plus coronagraphy to high spectral resolution spectroscopy. HDC is a critical pathway towards fully characterizing exoplanet atmospheres across a broad range of masses from giant gaseous planets down to Earth-like planets. In addition to determining the molecular composition of exoplanet atmospheres, HDC also enables Doppler mapping of atmosphere inhomogeneities (temperature, clouds, wind), as well as precise measurements of exoplanet rotational velocities. Here, we …
Photochemistry has the potential to substantially impact the atmospheric composition of exoplanets with consequences on the radiative transfer, thermal structure and dynamics of the atmospheres, particularly in UV-rich stellar environments. Here, we present the results of a first laboratory experimental simulation of photochemistry in carbon-rich exoplanet atmospheres at elevated temperatures. Evolution of gas-phase molecular composition was quantitatively monitored with infrared spectroscopy and mass spectrometry. We found that H2/CO gas compositions can change significantly from thermal equi…
Earth is the only known habitable planet and it serves as a testbed to benchmark the observations of temperate and more Earth-like exoplanets. It is required to observe the disc-integrated signatures of Earth for a large range of phase angles, resembling the observations of an exoplanet. In this work, an AOTF (Acousto-Optic Tunable Filter) based experiment is designed to observe the spectro-polarimetric signatures of Earth. The results of spectroscopic and polarimetric laboratory calibration are presented here along with a brief overview of a possible instrument configuration. Based on the res…
Modeling the outflow of planetary atmospheres is important for understanding the evolution of exoplanet systems and for interpreting their observations. Modern theoretical models of exoplanet atmospheres become increasingly detailed and multicomponent, and this makes difficulties for engaging new researchers in the scope. Here, for the first time, we present the results of testing the gas-dynamic method incorporated in our aeronomic model, which has been proposed earlier. Undertaken tests support the correctness of the method and validate its applicability. For modeling the planetary wind, we …
For terrestrial exoplanets with thin atmospheres or no atmospheres, the surface contributes light to the reflected light signal of the planet. Measurement of the variety of disk-integrated brightnesses of bodies in the Solar System and the variation with illumination and wavelength is essential for both planning imaging observations of directly imaged exoplanets and interpreting the eventual datasets. Here we measure the change in brightness of the Galilean satellites as a function of planetocentric longitude, illumination phase angle, and wavelength. The data span a range of wavelengths from …
Spectral retrieval has long been a powerful tool for interpreting planetary remote sensing observations. Flexible, parameterised, agnostic models are coupled with inversion algorithms in order to infer atmospheric properties directly from observations, with minimal reliance on physical assumptions. This approach, originally developed for application to Earth satellite data and subsequently observations of other Solar System planets, has been recently and successfully applied to transit, eclipse and phase curve spectra of transiting exoplanets. In this review, we present the current state-of-th…
Near-IR observations are important for the detection and characterization of exoplanets using the transit technique, either in surveys of large numbers of stars or for follow-up spectroscopic observations of individual planets. In a controlled laboratory experiment, we imaged $\sim 10^4$ critically sampled spots onto an Teledyne Hawaii-2RG (H2RG) detector to emulate an idealized star-field. We obtained time-series photometry of up to $\simeq 24$ hr duration for ensembles of $\sim 10^3$ pseudo-stars. After rejecting correlated temporal noise caused by various disturbances, we measured a photome…
Photochemical hazes are suspected to obscure molecular features, such as water, from detection in the transmission spectra of exoplanets with atmospheric temperatures < 800 K. The opacities of laboratory produced organic compounds (tholins) from Khare et al. (1984) have become a standard for modeling haze in exoplanet atmospheres. However, these tholins were grown in an oxygen-free, Titan-like environment that is very different from typical assumptions for exoplanets, where C/O~0.5. This work presents the 0.13-10 micron complex refractive indices derived from laboratory transmission measuremen…
UV radiation can induce photochemical processes in exoplanet atmospheres and produce haze particles. Recent observations suggest that haze and/or cloud layers could be present in the upper atmospheres of exoplanets. Haze particles play an important role in planetary atmospheres and may provide a source of organic material to the surface which may impact the origin or evolution of life. However, very little information is known about photochemical processes in cool, high-metallicity exoplanetary atmospheres. Previously, we investigated haze formation and particle size distribution in laboratory…
Simulations of exoplanet albedo profiles are key to planning and interpreting future direct imaging observations. In this paper we demonstrate the use of the Planetary Spectrum Generator to produce simulations of reflected light exoplanet spectra. We use PSG to examine multiple issues relevant to all models of directly imaged exoplanet spectra and to produce sample spectra of the bright, nearby exoplanet $\upsilon$ Andromedae d, a potential direct imaging target for next-generation facilities. We introduce a new, fast, and accurate subsampling technique that enables calculations of disk-integr…
With TESS and ground-based surveys searching for rocky exoplanets around cooler, nearby stars, the number of Earth-sized exoplanets that are well-suited for atmospheric follow-up studies will increase significantly. For atmospheric characterization, the James Webb Space Telescope will only be able to target a small fraction of the most interesting systems, and the usefulness of ground-based observatories will remain limited by a range of effects related to Earth's atmosphere. Here, we explore a new method for ground-based exoplanet atmospheric characterization that relies on simultaneous, diff…
Sulfur gases significantly affect the photochemistry of planetary atmospheres in our Solar System, and are expected to be important components in exoplanet atmospheres. However, sulfur photochemistry in the context of exoplanets is poorly understood due to a lack of chemical-kinetics information for sulfur species under relevant conditions. Here, we study the photochemical role of hydrogen sulfide (H2S) in warm CO2-rich exoplanet atmospheres (800 K) by carrying out laboratory simulations. We find that H2S plays a significant role in photochemistry, even when present in the atmosphere at relati…
New observing capabilities coming online over the next few years will provide opportunities for characterization of exoplanet atmospheres. However, clouds/hazes could be present in the atmospheres of many exoplanets, muting the amplitude of spectral features. We use laboratory simulations to explore photochemical haze formation in H2-rich exoplanet atmospheres at 800 K with metallicity either 100 and 1000 times solar. We find that haze particles are produced in both simulated atmospheres with small particle size (20 to 140 nm) and relative low production rate (2.4 x 10-5 to 9.7 x 10-5 mg cm-3 …
Computing and using opacities is a key part of modeling and interpreting data of exoplanetary atmospheres. Since the underlying spectroscopic line lists are constantly expanding and currently include up to ~ 10^10 - 10^11 transition lines, the opacity calculator codes need to become more powerful. Here we present major upgrades to the HELIOS-K GPU-accelerated opacity calculator and describe the necessary steps to process large line lists within a reasonable amount of time. Besides performance improvements, we include more capabilities and present a toolbox for handling different atomic and mol…
Multi-wavelength transit and secondary-eclipse light-curve observations are some of the most powerful techniques to probe the thermo-chemical properties of exoplanets. Although the large planet-to-star brightness contrast and few available spectral bands produce data with low signal-to-noise ratios, a Bayesian approach can robustly reveal what constraints we can set, without over-interpreting the data. Here I performed an end-to-end analysis of transiting exoplanet data. I analyzed space-telescope data for three planets to characterize their atmospheres and refine their orbits, investigated co…
Clouds have an important role in the atmospheres of planetary bodies. It is expected that, like all the planetary bodies in our solar system, exoplanet atmospheres will also have substantial cloud coverage, and evidence is mounting for clouds in a number of hot Jupiters. In order to better characterise planetary atmospheres we need to consider the effects these clouds will have on the observed broadband transmission spectra. Here we examine the expected cloud condensate species for hot Jupiter exoplanets and the effects of various grain sizes and distributions on the resultant transmission spe…
