Sulfur-driven Haze Formation in Warm CO2-rich Exoplanet Atmospheres
Chao He, Sarah M. Horst, Nikole K. Lewis, Xinting Yu, Julianne I. Moses, Patricia McGuiggan, Mark S. Marley, Eliza M. -R. Kempton, Sarah E. Moran, Caroline V. M… 展开作者
Chao He, Sarah M. Horst, Nikole K. Lewis, Xinting Yu, Julianne I. Moses, Patricia McGuiggan, Mark S. Marley, Eliza M. -R. Kempton, Sarah E. Moran, Caroline V. Morley, Veronique Vuitton
Sulfur gases significantly affect the photochemistry of planetary atmospheres in our Solar System, and are expected to be important components in exoplanet atmospheres. However, sulfur photochemistry in the context of exoplanets is poorly understood due to a lack of chemical-kinetics information for sulfur species under relevant conditions. Here, we study the photochemical role of hydrogen sulfide (H2S) in warm CO2-rich exoplanet atmospheres (800 K) by carrying out laboratory simulations. We find that H2S plays a significant role in photochemistry, even when present in the atmosphere at relatively low concentrations (1.6%). It participates in both gas and solid phase chemistry, leading to the formation of other sulfur gas products (CH3SH/SO, C2H4S/OCS, SO2/S2, and CS2) and to an increase in solid haze particle production and compositional complexity. Our study shows that we may expect thicker haze with small particle sizes (20 to 140 nm) for warm CO2-rich exoplanet atmospheres that possess H2S.
Recent work has shown that sulfur hazes may arise in the atmospheres of some giant exoplanets due to the photolysis of H$_{2}$S. We investigate the impact such a haze would have on an exoplanet's geometric albedo spectrum and how it may affect the direct imaging results of WFIRST, a planned NASA space telescope. For temperate (250 K $<$ T$_{\rm eq}$ $<$ 700 K) Jupiter--mass planets, photochemical destruction of H$_{2}$S results in the production of $\sim$1 ppmv of \seight between 100 and 0.1 mbar, which, if cool enough, will condense to form a haze. Nominal haze masses are found to drastically…
Early Earth may have hosted a biologically-mediated global organic haze during the Archean eon (3.8-2.5 billion years ago). This haze would have significantly impacted multiple aspects of our planet, including its potential for habitability and its spectral appearance. Here, we model worlds with Archean-like levels of carbon dioxide orbiting the ancient sun and an M4V dwarf (GJ 876) and show that organic haze formation requires methane fluxes consistent with estimated Earth-like biological production rates. On planets with high fluxes of biogenic organic sulfur gases (CS2, OCS, CH3SH, and CH3S…
We use a 1D model to address photochemistry and possible haze formation in the irradiated warm Jupiter, 51 Eridani b. The intended focus was to be carbon, but sulfur photochemistry turns out to be important. The case for organic photochemical hazes is intriguing but falls short of being compelling. If organic hazes form, they are likeliest to do so if vertical mixing in 51 Eri b is weaker than in Jupiter, and they would be found below the altitudes where methane and water are photolyzed. The more novel result is that photochemistry turns H$_2$S into elemental sulfur, here treated as S$_8$. In …
Despite surface liquid water's importance to habitability, observationally diagnosing its presence or absence on exoplanets is still an open problem. Inspired within the Solar System by the differing sulfur cycles on Venus and Earth, we investigate thick sulfate (H2SO4-H2O) aerosol haze and high trace mixing ratios of SO2 gas as observable atmospheric features whose sustained existence is linked to the near absence of surface liquid water. We examine the fundamentals of the sulfur cycle on a rocky planet with an ocean and an atmosphere in which the dominant forms of sulfur are SO2 gas and H2SO…
Sulfur gases are common components in the volcanic and biological emission on Earth, and are expected to be important input gases for atmospheres on terrestrial exoplanets. We study the atmospheric composition and the spectra of terrestrial exoplanets with sulfur compounds (i.e., H2S and SO2) emitted from their surfaces. We use a comprehensive one-dimensional photochemistry model and radiative transfer model to investigate the sulfur chemistry in atmospheres ranging from reducing to oxidizing. The most important finding is that both H2S and SO2 are chemically short-lived in virtually all types…
The Identification of CS2 and Evidence for Carbon-Sulfur Chemical Coupling in a Warm Giant Exoplanet Atmosphere
University of Wisconsin–Madison（威斯康星大学麦迪逊分校）；Arizona State University（亚利桑那州立大学）；Space Telescope Science Institute（太空望远镜科学研究所）；Schmidt Sciences（施密特科学）；California Institute of Technology（加州理工学院）；University of California Santa Cruz（加州大学圣克鲁兹分校）；Université Côte d’Azur（蔚蓝海岸大学）
New observing capabilities coming online over the next few years will provide opportunities for characterization of exoplanet atmospheres. However, clouds/hazes could be present in the atmospheres of many exoplanets, muting the amplitude of spectral features. We use laboratory simulations to explore photochemical haze formation in H2-rich exoplanet atmospheres at 800 K with metallicity either 100 and 1000 times solar. We find that haze particles are produced in both simulated atmospheres with small particle size (20 to 140 nm) and relative low production rate (2.4 x 10-5 to 9.7 x 10-5 mg cm-3 …
We present and validate a new network of atmospheric thermo-chemical and photo-chemical sulfur reactions. We use a 1-D chemical kinetics model to investigate these reactions as part of a broader HCNO chemical network in a series of hot and warm Jupiters. We find that temperatures approaching $1400\,\mathrm{K}$ are favourable for the production of H2S and HS around $\mathrm{10^{-3}\,bar}$, the atmospheric level where detection by transit spectroscopy may be possible, leading to mixing ratios of around $10^{-6}$. At lower temperatures, down to $1000\,\mathrm{K}$, the abundance of S2 can be up to…
Photochemical Production of CS2 in Temperate-to-Warm Gas Giant Exoplanet Atmospheres
University of Chicago（芝加哥大学）；Arizona State University（亚利桑那州立大学）；University of California, Santa Cruz（加州大学圣克鲁兹分校）；Carnegie Institution for Science（卡内基科学机构）
Photochemical hazes have been frequently used to interpret exoplanet transmission spectra that show an upward slope towards shorter wavelengths and weak molecular features. While previous studies have only considered spherical haze particles, photochemical hazes composed of hydrocarbon aggregate particles are common throughout the solar system. We use an aerosol microphysics model to investigate the effect of aggregate photochemical haze particles on transmission spectra of warm exoplanets. We find that the wavelength dependence of the optical depth of aggregate particle hazes is flatter than …
Recently, properties of exoplanet atmospheres have been constrained via multi-wavelength transit observation, which measures an apparent decrease in stellar brightness during planetary transit in front of its host star (called transit depth). Sets of transit depths so far measured at different wavelengths (called transmission spectra) are somewhat diverse: Some show steep spectral slope features in the visible, some contain featureless spectra in the near-infrared, some show distinct features from radiative absorption by gaseous species. These facts infer the existence of haze in the atmospher…
Motivated by the work of Guillot (2010), we present a semi-analytical formalism for calculating the temperature-pressure profiles in hot Jovian atmospheres which includes the effects of clouds/hazes and collision-induced absorption. Using the dual-band approximation, we assume that stellar irradiation and thermal emission from the hot Jupiter occur at distinct wavelengths ("shortwave" versus "longwave"). For a purely absorbing cloud/haze, we demonstrate its dual effect of cooling and warming the upper and lower atmosphere, respectively, which modifies, in a non-trivial manner, the condition fo…
In a previous paper (Chassefière et al., Icarus 223, 878-891, 2013), we have shown that most volcanic sulfur released to early Mars atmosphere could have been trapped in the cryosphere under the form of CO2-SO2 clathrates. Huge amounts of sulfur, up to the equivalent of a ~1 bar atmosphere of SO2, would have been stored in the Noachian cryosphere, then massively released to the atmosphere during Hesperian due to rapidly decreasing CO2 pressure. It would have resulted in the formation of the large sulfate deposits observed mainly in Hesperian terrains, whereas no or little sulfates are found at…
Wet Removal and Cloud Enhancement: The Microphysics of Cloud-Haze Interactions on Sub-Neptunes
Department of Astronomy & Astrophysics, the University of Chicago（芝加哥大学天文与天体物理系）；Max Planck Institute for Astronomy, 69117 Heidelberg, Germany（马克斯·普朗克天文研究所）；Earth & Planets Laboratory, Carnegie Institution for Science, 5241 Broad Branch Road NW, Washington, DC 20015, USA（卡内基科学研究所地球与行星实验室）
Formation of hazes at microbar pressures has been explored by theoretical models of exoplanet atmospheres to explain Rayleigh scattering and/or featureless transmission spectra, however observational evidence of aerosols in the low pressure formation environments has proved elusive. Here, we show direct evidence of aerosols existing at $\sim$1 microbar pressures in the atmosphere of the warm sub-Saturn WASP-69b using observations taken with Space Telescope Imaging Spectrograph (STIS) and Wide Field Camera 3 (WFC3) instruments on the Hubble Space Telescope. The transmission spectrum shows a wav…
Some of the exoplanets so far observed show featureless or flat transmission spectra, possibly indicating the existence of clouds and/or haze in their atmospheres. Thanks to its large aperture size and broad wavelength coverage, JWST is expected to enable detailed investigation of exoplanet atmospheres, which could provide important constraints on the atmospheric composition obscured by clouds/haze. Here, we use four warm ($\lesssim 1000$ K) planets suitable for atmospheric characterization via transmission spectroscopy, GJ 1214b, GJ 436b, HD 97658b, and Kepler-51b, as examples to explore mole…
We present a computationally efficient 1-D seasonal radiative model, with convective adjustment, of Jupiter's atmosphere. Our model takes into account radiative forcings from the main hydrocarbons (methane, ethane, acetylene), ammonia, collision-induced absorption, four cloud and haze layers (including a UV-absorbing "polar" stratospheric haze) and an internal heat flux. We detail sensitivity studies of the equilibrium temperature profile to several parameters. We discuss the expected seasonal, vertical and meridional thermal structure and compare it to that derived from Cassini and ground-bas…
GJ 3470b is a warm Neptune-size planet transiting a M dwarf star. Like the handful of other small exoplanets for which transmission spectroscopy has been obtained, GJ 3470b exhibits a flat spectrum in the near- and mid-infrared. Recently, a tentative detection of Rayleigh scattering in its atmosphere has been reported. This signal manifests itself as an observed increase of the planetary radius as a function of decreasing wavelength in the visible. We set out to verify this detection and observed several transits of this planet with the LCOGT network and the Kuiper telescope in four different …
Recent transmission spectroscopy has revealed that clouds and hazes are common in the atmospheres of close-in exoplanets. In this study, using the photochemical, microphysical, and transmission spectrum models for close-in warm ($\lesssim$ 1000 K) exoplanet atmospheres that we newly developed in our preceding paper (Kawashima & Ikoma 2018), we investigate the vertical distributions of haze particles and gaseous species and the resultant transmission spectra over wide ranges of the model parameters including UV irradiation intensity, metallicity, carbon-to-oxygen ratio (C/O), eddy diffusion coe…
Relatively little is understood about the atmospheric composition of temperate to warm exoplanets (equilibrium temperature $T_{\rm eq}<$ 1000 K), as many of them are found to have uncharacteristically flat transmission spectra. Their flattened spectra are likely due to atmospheric opacity sources such as planet-wide photochemical hazes and condensation clouds. We compile the transmission spectra of 25 warm exoplanets previously observed by the Hubble Space Telescope and quantify the haziness of each exoplanet using a normalized amplitude of the water absorption feature ($A_{\rm H}$). By examin…
Context. Sulfur is used as a tracer of the evolution from interstellar clouds to stellar systems. However, most of the expected sulfur in molecular clouds remains undetected. Sulfur disappears from the gas phase in two steps. One first depletion occurs during the translucent phase, reducing the gas phase sulfur by 7-40 times, while the following freeze-out step occurs in molecular clouds, reducing it by another order of magnitude. This long-standing dilemma awaits an explanation. Aims. The aim of this study is to understand under which form the missing sulfur is hiding in molecular clouds. Dep…
GJ1214b is a warm sub-Neptune transiting in front of a nearby M dwarf star. Recent observations indicate the presence of high and thick clouds or haze whose presence requires strong atmospheric mixing. In order to understand the transport and distribution of such clouds/haze, we study the atmospheric circulation and the vertical mixing of GJ1214b with a 3D General Circulation Model for cloud-free hydrogen-dominated atmospheres (metallicity of 1, 10 and 100 times the solar value) and for a water-dominated atmosphere. We analyze the effect of the atmospheric metallicity on the thermal structure …
Water enhances the formation of refractory sulfur in interstellar ices
Centro de Astrobiología (CAB), INTA-CSIC（西班牙国家航空航天技术研究所-西班牙国家科学研究委员会天体生物学中心）；Departamento de Física de la Tierra y Astrofísica, Facultad de Ciencias Físicas, Universidad Complutense de Madrid（马德里康普顿斯大学物理科学学院地球与天体物理学系）；Instituto de Química Física Blas Cabrera (CSIC)（西班牙国家科学研究委员会布拉斯·卡布雷拉物理化学研究所）；Department of Physics, National Central University（中原大学物理系）
GJ 436b is a prime target for understanding warm Neptune exoplanet atmospheres and a target for multiple JWST GTO programs. Here, we report the first space-based optical transmission spectrum of the planet using two HST/STIS transit observations from 0.53-1.03 microns. We find no evidence for alkali absorption features, nor evidence of a scattering slope longward of 0.53 microns. The spectrum is indicative of moderate to high metallicity (~100-1000x solar) while moderate metallicity scenarios (~100x solar) require aerosol opacity. The optical spectrum also rules out some highly scattering haze…
The super-Neptune exoplanet WASP-107b is an exciting target for atmosphere characterization. It has an unusually large atmospheric scale height and a small, bright host star, raising the possibility of precise constraints on its current nature and formation history. We report the first atmospheric study of WASP-107b, a Hubble Space Telescope measurement of its near-infrared transmission spectrum. We determined the planet's composition with two techniques: atmospheric retrieval based on the transmission spectrum and interior structure modeling based on the observed mass and radius. The interior…
We report our spectroscopic investigation of the transiting ice giant GJ 3470b's atmospheric transmission, and the first results of extrasolar planet observations from the new Keck/MOSFIRE spectrograph. We measure a planet/star radius ratio of Rp/Rs = 0.0789 +/- 0.0020 in a bandpass from 2.09-2.36 micron and in six narrower bands across this wavelength range. When combined with existing broadband photometry, these measurements rule out cloud-free atmospheres in chemical equilibrium assuming either solar abundances (5.4 sigma confidence) or a moderate level of metal enrichment (50x solar abunda…
Precise atmospheric observations have been made for a growing sample of warm Neptunes. Here we investigate the correlations between these observations and a large number of system parameters to show that, at 95% confidence, the amplitude of a warm Neptune's spectral features in transmission correlates with either its equilibrium temperature (T_eq) or its bulk H/He mass fraction (f_HHe) --- in addition to the standard kT/mg scaling. These correlations could indicate either more optically-thick, photochemically-produced hazes at lower T_eq and/or higher-metallicity atmospheres for planets with s…
Clouds are ubiquitous in extrasolar planet atmospheres and are critical to our understanding of planetary climate and chemistry. They also represent one of the greater challenges to overcome when trying to interpret transit transmission spectra of exoplanet atmospheres as their presence can inhibit precise constraints on atmospheric composition and thermal properties. In this work we take a phenomenological approach towards understanding 1) our ability to constrain bulk cloud properties, and 2) the impact of clouds on constraining various atmospheric properties as obtained through transmission…
On 5-6 June 2012, Venus will be transiting the Sun for the last time before 2117. This event is an unique opportunity to assess the feasibility of the atmospheric characterisation of Earth-size exoplanets near the habitable zone with the transmission spectroscopy technique and provide an invaluable proxy for the atmosphere of such a planet. In this letter, we provide a theoretical transmission spectrum of the atmosphere of Venus that could be tested with spectroscopic observations during the 2012 transit. This is done using radiative transfer across Venus' atmosphere, with inputs from in-situ …
GJ 436b is a warm-- approximately 800 K--extrasolar planet that periodically eclipses its low-mass (half the mass of the Sun) host star, and is one of the few Neptune-mass planets that is amenable to detailed characterization. Previous observations have indicated that its atmosphere has a methane-to-CO ratio that is 100,000 times smaller than predicted by models for hydrogen-dominated atmospheres at these temperatures. A recent study proposed that this unusual chemistry could be explained if the planet's atmosphere is significantly enhanced in elements heavier than H and He. In this study we p…
The warm sub-Neptune GJ1214b has a featureless transit spectrum which may be due to the presence of high and thick clouds or haze. Here, we simulate the atmosphere of GJ1214b with a 3D General Circulation Model for cloudy hydrogen-dominated atmospheres, including cloud radiative effects. We show that the atmospheric circulation is strong enough to transport micrometric cloud particles to the upper atmosphere and generally leads to a minimum of cloud at the equator. By scattering stellar light, clouds increase the planetary albedo to 0.4-0.6 and cool the atmosphere below 1 mbar. However, the he…
TRAPPIST-1 planets are invaluable for the study of comparative planetary science outside our Solar System and possibly habitability. First, we derive from N-body simulations possible planetary evolution scenarios, and show that each of the planets are likely to be in synchronous rotation. We then use a 3-D Global Climate Model to explore the possible climates of cool planets of the TRAPPIST-1 system. In particular, we look at the conditions required for cool planets to prevent possible volatile species to be lost by permanent condensation, irreversible burying or photochemical destruction. We …
We present a comprehensive analysis of the 0.3--5\,$μ$m transit spectrum for the inflated hot Jupiter HAT-P-41b. The planet was observed in transit with Hubble STIS and WFC3 as part of the Hubble Panchromatic Comparative Exoplanet Treasury (PanCET) program, and we combine those data with warm \textit{Spitzer} transit observations. We extract transit depths from each of the data sets, presenting the STIS transit spectrum (0.29--0.93\,$μ$m) for the first time. We retrieve the transit spectrum both with a free-chemistry retrieval suite (AURA) and a complementary chemical equilibrium retrieval sui…
