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arXiv 2501.16005cond-mat.softcond-mat.mtrl-sci
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具有较小或较大尺寸差异的二元超球体的随机堆积分数:一种几何方法

Random packing fraction of binary hyperspheres with small or large size difference: a geometric approach

H. J. H. Brouwers

AI总结:

本文利用几何方法研究了D维欧几里得空间中二元超球体的随机堆积分数,结合Onsager排除体积模型和Furnas经典理论,分别对较小和较大尺寸差异的堆积进行建模,并推导出渐近近似,证明几何理论是研究超球体堆积与非晶化的有效工具。

摘要:

使用几何方法研究了D维欧几里得空间R^D中二元粒子的随机堆积分数。首先,利用Onsager针对三维空间(D = 3)粒子的排除体积模型,研究了具有较小尺寸差异的集合体的二元堆积分数。根据该模型,由二元分散性引起的堆积增加与(1 - f)(u^D - 1)^2成正比,其中f为单分散堆积分数,u为尺寸比,D为空间维度。将模型预测与二维圆盘(D = 2)和大维度极限(D趋于无穷大)下的超球体的计算结果进行了比较,结果吻合良好。随后,采用Furnas经典理论对具有较大尺寸差异的超球体堆积进行了建模。该理论为三维空间开发,从较大和较小粒子的无限尺寸比(u趋于无穷大)出发。在此,将相关方程应用于超球体,并与大维度极限下超球体的计算结果成功进行了比较。此外,推导了大尺寸比下二元堆积分数的渐近近似,表明Furnas堆积分数(u^-1 = 0)的一阶变化与(2 - f)u^-1成正比。最后,提出了一个缩放的D维二元堆积图,该图控制着一个简化的相图,该相图界定了非晶集合体的二元随机堆积分数。总而言之,关于简单硬球的基本空间填充和几何(非热)理论似乎是研究超球体堆积和非晶化的宝贵工具。

英文摘要:

The random packing fraction of binary particles in D-dimensional Euclidean space R^D is studied using a geometric approach. First, the binary packing fraction of assemblies with small size difference are studied, using the excluded volume model by Onsager for particles in three-dimensional space (D = 3). According to this model the packing increase by bidispersity is proportional to (1 - f)(u^D - 1)^2, with f as monosized packing fraction, u as size ratio and D as space dimension. The model predictions are compared with computational results for disks in two dimensions (D = 2) and hyperspheres in the large-dimension limit (D to infinity), yielding good agreement. Subsequently, the packing of hyperspheres with large size difference is modeled, employing the classic theory of Furnas. This theory, developed for three dimensions, starts from an infinite size ratio of larger and smaller particles (u to infinity). Here, the pertaining equations are applied to hyperspheres, and successfully compared with computational results for hyperspheres in the large-dimension limit. Furthermore, an asymptotic approximation of the binary packing fraction for large size ratio is derived, which shows that the first order variation of the Furnas packing fraction (u^-1 = 0) is proportional to (2 - f)u^-1. Finally, a scaled D-dimensional binary packing graph is presented, governing a simplified phase diagram that borders the binary random packing fraction of amorphous assemblies. To summarize, basic space-filling and geometric (athermal) theories on simple hard spheres appear to be a valuable tool for the study of hyperspheres packing and amorphization.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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