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arXiv 2201.05094math-phmath.DSmath.MPmath.PRquant-ph

连续时间量子马尔可夫半群的热力学正则法:详平衡条件、熵、压力和平衡量子过程

Thermodynamic formalism for continuous-time quantum Markov semigroups: the detailed balance condition, entropy, pressure and equilibrium quantum processes

Jader E. Brasil, Josue Knorst, Artur O. Lopes

AI总结:

本文提出连续时间量子马尔可夫半群的热力学正则法,研究详平衡条件、熵、压力及平衡量子过程,基于哈密顿量的变分原理和平衡密度矩阵的定义。

摘要:

$M_n(\mathbb{C})$ 表示 $n$ 乘 $n$ 的复数矩阵集。考虑连续时间量子半群 $\mathcal{P}_t= e^{t\\, \mathcal{L}}$,$t \geq 0$,其中 $\mathcal{L}:M_n(\mathbb{C}) \to M_n(\mathbb{C})$ 是无穷小生成元。如果假设 $\mathcal{L}(I)=0$,我们将称 $e^{t\\, \mathcal{L}}$,$t \geq 0$ 为量子马尔可夫半群。给定一个稳态密度矩阵 $ρ= ρ_{\mathcal{L}}$,对于量子马尔可夫半群 $\mathcal{P}_t$,$t \geq 0$,我们可以定义一个连续时间稳态量子马尔可夫过程,记为 $X_t$,$t \geq 0$。给定一个先验拉普拉斯算子 $\mathcal{L}_0:M_n(\mathbb{C}) \to M_n(\mathbb{C})$,我们将提出一个密度矩阵类上的自然熵的概念。给定一个厄米特算子 $A:\mathbb{C}^n\to \mathbb{C}^n$(扮演哈密顿量的角色),我们将研究 $A$ 的压力变分原理的一个版本。最大化压力的密度矩阵称为平衡密度矩阵。从 $ρ_A$ 我们将推导一个新的无穷小生成元 $\mathcal{L}_A$。最后,由半群 $\mathcal{P}_t= e^{t\\, \mathcal{L}_A}$,$t \geq 0$,以及初始稳态密度矩阵定义的连续时间量子马尔可夫过程,称为哈密顿量 $A$ 的连续时间平衡量子马尔可夫过程。它对应于哈密顿量 $A$ 作用下的量子热力学平衡。

英文摘要:

$M_n(\mathbb{C})$ denotes the set of $n$ by $n$ complex matrices. Consider continuous time quantum semigroups $\mathcal{P}_t= e^{t\, \mathcal{L}}$, $t \geq 0$, where $\mathcal{L}:M_n(\mathbb{C}) \to M_n(\mathbb{C})$ is the infinitesimal generator. If we assume that $\mathcal{L}(I)=0$, we will call $e^{t\, \mathcal{L}}$, $t \geq 0$ a quantum Markov semigroup. Given a stationary density matrix $ρ= ρ_{\mathcal{L}}$, for the quantum Markov semigroup $\mathcal{P}_t$, $t \geq 0$, we can define a continuous time stationary quantum Markov process, denoted by $X_t$, $t \geq 0.$ Given an {\it a priori} Laplacian operator $\mathcal{L}_0:M_n(\mathbb{C}) \to M_n(\mathbb{C})$, we will present a natural concept of entropy for a class of density matrices on $M_n(\mathbb{C})$. Given an Hermitian operator $A:\mathbb{C}^n\to \mathbb{C}^n$ (which plays the role of an Hamiltonian), we will study a version of the variational principle of pressure for $A$. A density matrix $ρ_A$ maximizing pressure will be called an equilibrium density matrix. From $ρ_A$ we will derive a new infinitesimal generator $\mathcal{L}_A$. Finally, the continuous time quantum Markov process defined by the semigroup $\mathcal{P}_t= e^{t\, \mathcal{L}_A}$, $t \geq 0$, and an initial stationary density matrix, will be called the continuous time equilibrium quantum Markov process for the Hamiltonian $A$. It corresponds to the quantum thermodynamical equilibrium for the action of the Hamiltonian $A$.

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