Quantum Oscillations and the Quasiparticle Properties of Thin Film Sr$_2$RuO$_4$
Yawen Fang, Hari P. Nair, Ludi Miao, Berit Goodge, Nathaniel J. Schreiber, Jacob P. Ruf, Lena F. Kourkoutis, Kyle M. Shen, Darrell G. Schlom, B. J. Ramshaw
We measure the Shubnikov-de Haas effect in thin-film Sr$_2$RuO$_4$ grown on an (LaAlO$_3$)$_{0.29}$-(SrAl$_{1/2}$Ta$_{1/2}$O$_3$)$_{0.71}$ (LSAT) substrate. We detect all three known Fermi surfaces and extract the Fermi surface volumes, cyclotron effective masses, and quantum lifetimes. We show that the electronic structure is nearly identical to that of single-crystal Sr$_2$RuO$_4$, and that the quasiparticle lifetime is consistent with the Tc of comparably clean, single-crystal Sr$_2$RuO$_4$. Unlike single-crystal Sr$_2$RuO$_4$, where the quantum and transport lifetimes are roughly equal, we find that the transport lifetime is $1.3\pm0.1$ times longer than the quantum lifetime. This suggests that extended (rather than point) defects may be the dominant source of quasiparticle scattering in these films. To test this idea, we perform cross-sectional STEM and find that out-of-phase boundaries extending the entire thickness of the film occur with a density that is consistent with the quantum mean free path. The long quasiparticle lifetimes make these films ideal for studying the unconventional superconducting state in Sr$_2$RuO$_4$ through the fabrication of devices -- such as planar tunnel junctions and SQUIDs.
We report a polarization-resolved Raman spectroscopy study of the orbital dependence of the quasiparticles properties in the prototypical multi-band Fermi liquid Sr\textsubscript{2}RuO\textsubscript{4}. We show that the quasiparticle scattering rate displays $ω^{2}$ dependence as expected for a Fermi liquid. Besides, we observe a clear polarization-dependence in the energy and temperature dependence of the quasiparticle scattering rate and mass, with the $d_{xz/yz}$ orbital derived quasiparticles showing significantly more robust Fermi liquid properties than the $d_{xy}$ orbital derived ones. …
The single-layered ruthenate Sr$_2$RuO$_4$ is one of the most enigmatic unconventional superconductors. While for many years it was thought to be the best candidate for a chiral $p$-wave superconducting ground state, desirable for topological quantum computations, recent experiments suggest a singlet state, ruling out the original $p$-wave scenario. The superconductivity as well as the properties of the multi-layered compounds of the ruthenate perovskites are strongly influenced by a van Hove singularity in proximity of the Fermi energy. Tiny structural distortions move the van Hove singularit…
We will extend the concept of electron band Berry curvatures to superconducting materials. We show that this can be defined for the Bogoliubov-de Gennes equation describing the superconducting state in a periodic crystal. In addition, the concept is exploited to understand the driving mechanism for the optical Kerr effect in time reversal symmetry breaking superconductors. Finally, we establish a sum rule analogue to the normal state Hall sum rule making quantitative contact between the imaginary part of the optical conductivity and the Berry curvature. The general theory will be applied and t…
The synthesis of stoichiometric Sr$_2$RuO$_4$ thin films has been a challenge because of the high volatility of ruthenium oxide precursors, which gives rise to ruthenium vacancies in the films. Ru vacancies greatly affect the transport properties and electronic phase behavior of Sr$_2$RuO$_4$, but their direct detection is difficult due to their atomic dimensions and low concentration. We applied polarized X-ray absorption spectroscopy at the oxygen K-edge and confocal Raman spectroscopy to Sr$_2$RuO$_4$ thin films synthesized under different conditions. The results show that these methods can…
Motivated by the success of experimental manipulation of the band structure through biaxial strain in Sr$_2$RuO$_4$ thin film grown on a mismatched substrate, we investigate theoretically the effects of biaxial strain on the electronic instabilities, such as superconductivity (SC) and spin density wave (SDW), by functional renormalization group. According to the experiment, the positive strain (from lattice expansion) causes charge transfer to the $γ$-band and consequently Lifshitz reconstruction of the Fermi surface. Our theoretical calculations show that within a limited range of positive st…
Sr$_2$RuO$_4$ has long been the focus of intense research interest because of conjectures that it is a correlated topological superconductor. It is the momentum space (k-space) structure of the superconducting energy gap $Δ_i(\mathbf{k})$ on each band $i$ that encodes its unknown superconducting order-parameter. But, because the energy scales are so low, it has never been possible to directly measure the $Δ_i(\mathbf{k})$ of Sr$_2$RuO$_4$. Here we implement Bogoliubov quasiparticle interference (BQPI) imaging, a technique capable of high-precision measurement of multiband $Δ_i(\mathbf{k})$. At…
Despite much effort for over the two decades, the paring symmetry of a Sr$_2$RuO$_4$ superconductor has been still unclear. In this Rapid Communication, motivated by the recent rapid progress in fabrication techniques for Sr$_2$RuO$_4$ thin-films, we propose a promising strategy for identifying the spin-triplet superconductivity in the thin-film geometry by employing an antisymmetric spin-orbit coupling potential and a Zeeman potential due to an external magnetic field. We demonstrate that a spin-triplet superconducting thin-film undergoes a phase transition from a helical state to a chiral st…
SrRuO$_3$ (SRO113) is an important material for device physics particularly as one of the best metallic oxide electrodes for ferroelectric devices. This oxide has moderate electron correlations with novel properties including ferromagnetic ordering, which can be utilized in future to spintronics and superconducting spintronics devices. Recently, we observed strongly enhanced magnetization of SRO113 thin films grown on single crystals of the spin-triplet superconductor Sr$_2$RuO$_4$ (SRO214). To clarify the origin of such an enhancement, we conducted systematic investigations of magnetic proper…
The binary ruthenate, RuO$_2$, has been the subject of intense interest due to its itinerant antiferromagnetism and strain-induced superconductivity. The strain mechanism and its effect on the microscopic electronic states leading to the normal and superconducting state, however, remain undisclosed. Here, we investigate highly-strained epitaxial (110) RuO$_2$ films using polarization-dependent oxygen K-edge X-ray absorption spectroscopy (XAS). Through the detection of pre-edge peaks, arising from O:$2p$ - Ru:$4d$ hybridization, we uncover the effects of epitaxial strain on the orbital/electron…
By tuning the physical and chemical pressures of layered perovskite materials we can realize the quantum states of both superconductors and insulators. By reducing the thickness of a layered crystal to a nanometer level, a nanofilm crystal can provide novel quantum states that have not previously been found in bulk crystals. Here we report the realization of high-temperature superconductivity in Ca$_2$RuO$_4$ nanofilm single crystals. Ca$_2$RuO$_4$ thin film with the highest transition temperature $T_c$ (midpoint) of 64~K exhibits zero resistance in electric transport measurements. The superco…
It is shown that there are a significant number of quasiparticles present in the superconductor even at the temperature far below the transition temperature and that those quasiparticles seriously contribute to the characteristics of superconducting thin-film resonators.
Scanning tunneling spectroscopy measurements of superconducting thin lanthanum films grown on a normal metal tungsten substrate reveal an extraordinarily large broadening of the coherence peaks. The observed broadening corresponds to very short electron-like quasiparticle lifetimes in the tunneling process. A thorough analysis considering the different relaxation processes reveals that the dominant mechanism is an efficient quasiparticle relaxation at the interface between the superconducting film and the underlying substrate. This process is of general relevance to scanning tunneling spectros…
Quasiparticle spectroscopy in tantalum films with different Ta/sapphire interfaces
Ames National Laboratory（艾姆斯国家实验室）；Iowa State University（爱荷华州立大学）；National Institute of Standards and Technology（国家标准与技术研究院）；University of Virginia（弗吉尼亚大学）
The response of superconducting pair-breaking detectors is dependent on the details of the quasiparticle distribution. In Kinetic Inductance Detectors (KIDs), where both pair breaking and non-pair breaking photons are absorbed simultaneously, calculating the detector response therefore requires knowledge of the often nonequilibrium distributions. The quasiparticle effective temperature provides a good approximation to these nonequilibrium distributions. We compare an analytical expression relating absorbed power and the quasiparticle effective temperature in superconducting thin films to full …
Here we demonstrate how the Fermi surface topology and quantum many-body interactions can be manipulated via epitaxial strain in the spin-triplet superconductor Sr$_2$RuO$_4$ and its isoelectronic counterpart Ba$_2$RuO$_4$ using oxide molecular beam epitaxy (MBE), \emph{in situ} angle-resolved photoemission spectroscopy (ARPES), and transport measurements. Near the topological transition of the $γ$ Fermi surface sheet, we observe clear signatures of critical fluctuations, while the quasiparticle mass enhancement is found to increase rapidly and monotonically with increasing Ru-O bond distance.…
Experiments show that the Cooper pair transport in the insulator phase that forms at thin film superconductor to insulator transitions (SIT) is simply activated. This activated behavior depends on the microscopic factors that drive the localization of the Cooper pairs. To test proposed models, we investigated how a perturbation that weakens Cooper pair binding, magnetic impurity doping, affects the characteristic activation energy, $T_0$. The data show that $T_0$ decreases monotonically with doping in films tuned farther from the SIT and increases and peaks in films that are closer to the SIT …
We calculate nonequilibrium quasiparticle and phonon distributions for a number of widely-used low transition temperature thin-film superconductors under constant, uniform illumination by sub-gap probe and pair-breaking signal photons simultaneously. From these distributions we calculate material-characteristic parameters that allow rapid evaluation of an effective quasiparticle temperature using a simple analytical expression, for all materials studied (Mo, Al, Ta, Nb, and NbN) for all photon energies. We also explore the temperature and energy-dependence of the low-energy quasiparticle gener…
Giant Room-Temperature Third-Order Electrical Transport in a Thin-Film Altermagnet Candidate
School of Materials Science and Engineering, Beihang University（北京航空航天大学材料科学与工程学院）；School of Physics, Beihang University（北京航空航天大学物理学院）；State Key Laboratory of Tropic Ocean Engineering Materials and Materials Evaluation, Beihang University（北京航空航天大学热带海洋工程材料与材料评价国家重点实验室）；National Synchrotron Radiation Laboratory, University of Science and Technology of China（中国科学技术大学国家同步辐射实验室）；Anhui Key Laboratory of Low-Energy Quantum Materials and Devices, High Magnetic Field Laboratory, Hefei Institutes of Physical Science, Chinese Academy of Sciences（中国科学院合肥物质科学研究院高磁场中心安徽低能量子材料与器件重点实验室）
Designing the spatial profile of the superconducting gap -- gap engineering -- has long been recognized as an effective way of controlling quasiparticles in superconducting devices. In aluminum films, their thickness modulates the gap; therefore, standard fabrication of Al/AlOx/Al Josephson junctions, which relies on overlapping a thicker film on top of a thinner one, always results in gap-engineered devices. Here we reconsider quasiparticle effects in superconducting qubits to explicitly account for the unavoidable asymmetry in the gap on the two sides of a Josephson junction. We find that di…
We have solved numerically the diffusive Usadel equations that describe the spatially-varying superconducting proximity effect in Ti-Al thin-film bi- and trilayers with thickness values that are suitable for Kinetic Inductance Detectors (KIDs) to operate as photon detectors with detection thresholds in the frequency range of 50-90 GHz. Using Nam's extension of the Mattis-Bardeen calculation of the superconductor complex conductivity, we show how to calculate the surface impedance for the spatially varying case, and hence the surface impedance quality factor. In addition, we calculate energy-an…
Constraints on the Quasiparticle Density of States in High-$T_c$ Superconductors
在这封信中，我们提出了新的隧道YBa $_2$ Cu $_3$ O $_7$薄膜的低温扫描隧道光谱数据。在YBa $_2$ Cu $_3$ O $_7$中也发现了以前在Bi $_2$ Sr $_2$ CaCu $_2$ O $_{8+δ}$中报道的不寻常的峰-谷-驼峰特征。为了分析这些常见的签名，我们提出了一个新的启发式模型，其中，除了d-波对称性，间隙函数是能量依赖的。导出了一个简单的准粒子态密度的表达式，与实验符合得很好。讨论了准粒子态的动力学和超导转变的能量尺度。
We measure temperature dependent quasiparticle fluctuations in a small Al volume, embedded in a NbTiN superconducting microwave resonator. The resonator design allows for read-out close to equilibrium. By placing the Al film on a membrane, we enhance the fluctuation level and separate quasiparticle from phonon effects. When lowering the temperature, the recombination time saturates and the fluctuation level reduces a factor $\sim$100. From this we deduce that the number of free quasiparticles is still thermal. Therefore, the theoretical, inverse relation between quasiparticle number and recomb…
