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arXiv 2101.09696cond-mat.str-el
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Ce-和Yb-重费米子化合物中局域态和巡游态的光学证据

Optical evidence of local and itinerant states in Ce- and Yb-heavy-fermion compounds

Shin-ichi Kimura, Yong Seung Kwon, Cornelius Krellner, Jörg Sichelschmidt

摘要:

铈(Ce)和镱(Yb)金属间化合物的电子性质可以显示出更局部或更巡回的特征,这取决于$4f$电子之间的交换相互作用和$4f$与传导电子之间的近藤耦合的相互作用。对于更流动的情况,一旦近藤效应在低温下发展,材料就会形成重费米子。因此,在电子结构中发生温度变化,其可以通过研究光学电导率($σ(ω)$)谱来追踪。值得注意的是,在$σ(ω)$光谱中的温度变化仍然存在于更局部化的情况下,即使近藤效应被强烈抑制。在这里,我们澄清的本地和巡回字符的电子结构中的$σ(ω)$光谱中的各种Ce和Yb的化合物的温度依赖性的研究与tetratetratetratetrachThCr $_2$ Si $_2$型晶体结构。我们以统一的方式解释温度的变化。当温度高于100 K时,$σ(ω)$光谱的温度依赖性主要是由于电子-声子相互作用,而当温度低于100 K时,温度依赖性主要是由于近藤效应。

英文摘要:

The electronic properties of Cerium (Ce) and ytterbium (Yb) intermetallic compounds may display a more local or more itinerant character depending on the interplay of the exchange interactions among the $4f$ electrons and the Kondo coupling between $4f$ and conduction electrons. For the more itinerant case, the materials form heavy-fermions once the Kondo effect is developed at low temperatures. Hence, a temperature variation occurs in the electronic structure that can be traced by investigating the optical conductivity ($σ(ω)$) spectra. Remarkably, the temperature variation in the $σ(ω)$ spectrum is still present in the more localized case, even though the Kondo effect is strongly suppressed. Here, we clarify the local and itinerant character in the electronic structure by investigating the temperature dependence in the $σ(ω)$ spectra of various Ce and Yb compounds with a tetragonal ThCr$_2$Si$_2$-type crystal structure. We explain the temperature change in a unified manner. Above temperatures of about 100 K, the temperature dependence of the $σ(ω)$ spectra is mainly due to the electron-phonon interaction, while the temperature dependence below is due to the Kondo effect.

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