We present ALMA ~0.02"-resolution observations of the nucleus of the nearby (~14 Mpc) type-2 AGN NGC 1068 at HCN/HCO+/HNC J=3-2 lines, as well as at their 13C isotopologue and vibrationally excited lines, to scrutinize the morphological/dynamical/chemical/physical properties of dense molecular gas in the putative dusty molecular torus around a mass-accreting supermassive black hole. We confirm almost east-west-oriented dense molecular gas emission both morphologically and dynamically, which we regard as coming from the torus. Bright emission is compact (<3 pc), and low-surface-brightness emission extends out to 5-7 pc. These dense molecular gas properties are not symmetric between the eastern and western torus. The HCN J=3-2 emission is stronger than the HCO+ J=3-2 emission within the ~7 pc torus region, with an estimated dense molecular mass of (0.4-1.0)x10^6Msun. We interpret that HCN abundance is enhanced in the torus. We detect signatures of outflowing dense molecular gas and a vibrationally excited HCN J=3-2 line. Finally, we find that in the innermost (<1 pc) part of the torus, the dense molecular line rotation velocity, relative to the systemic velocity, is the opposite of that in the outer (>2 pc) part, in both the eastern and western torus. We prefer a scenario of counter-rotating dense molecular gas with innermost almost-Keplerian-rotation and outer slowly rotating (far below Keplerian) components. Our high-spatial-resolution dense molecular line data reveal that torus properties of NGC 1068 are much more complicated than the simple axi-symmetrically rotating torus picture in the classical AGN unification paradigm.
Context. We present our findings for the HCN/H13CN 1-0 line ratio in the molecular outflow of Arp 220 west based on high-resolution ALMA data. Aims. Molecular gas masses in the outflowing gas of galaxies driven by active galactic nuclei (AGNs) or starbursts are important parameters for understanding the feedback of these latter two phenomena and star-formation quenching. The conversion factor of line luminosities to masses is related to the optical depth of the molecular lines. Methods. Using H13CN 1-0, the isotopic line of HCN 1-0, to obtain the line ratio of HCN/H13CN 1-0 is an ideal way to …
We present the results of ALMA Cycle 2 observations of the ultraluminous infrared galaxy, IRAS 20551-4250, at HCN/HCO+/HNC J=3-2 lines at both vibrational-ground (v=0) and vibrationally excited (v2=1) levels. This galaxy contains a luminous buried active galactic nucleus (AGN), in addition to starburst activity, and our ALMA Cycle 0 data revealed a tentatively detected vibrationally excited HCN v2=1f J=4-3 emission line. In our ALMA Cycle 2 data, the HCN/HCO+/HNC J=3-2 emission lines at v=0 are clearly detected. The HCN and HNC v2=1f J=3-2 emission lines are also detected, but the HCO+ v2=1f J…
We present the results of our ALMA observations of three AGN-dominated nuclei in optical Seyfert 1 galaxies (NGC 7469, I Zw 1, and IC 4329 A) and eleven luminous infrared galaxies (LIRGs) with various levels of infrared estimated energetic contributions by AGNs at the HCN and HCO+ J=3-2 emission lines. The HCN and HCO+ J=3-2 emission lines are clearly detected at the main nuclei of all sources, except for IC 4329 A. The vibrationally excited (v2=1f) HCN J=3-2 and HCO+ J=3-2 emission lines are simultaneously covered, and HCN v2=1f J=3-2 emission line signatures are seen in the main nuclei of tw…
We present our ALMA multi-transition molecular line observational results for the ultraluminous infrared galaxy, IRAS 20551-4250, which is known to contain a luminous buried AGN and shows detectable vibrationally excited (v2=1f) HCN and HNC emission lines. The rotational J=1-0, 4-3, and 8-7 of HCN, HCO+, and HNC emission lines were clearly detected at a vibrational ground level (v=0). Vibrationally excited (v2=1f) J=4-3 emission lines were detected for HCN and HNC, but not for HCO+. Their observed flux ratios further support our previously obtained suggestion, based on J=3-2 data, that (1) inf…
We present observations of the dense molecular gas tracers HCN, HNC, and HCO+ in the J=1-0 transition using ALMA. We supplement our datasets with previous observations of CO J=1-0, which traces the total molecular gas content. We separate the Antennae into 7 bright regions in which we detect emission from all three molecules, including the nuclei of NGC 4038 and NGC 4039, 5 super giant molecular complexes in the overlap region and 2 additional bright clouds. We find that the ratio of L(HCN)/L(CO), which traces the dense molecular gas fraction, is greater in the two nuclei (L(HCN)/L(CO) ~ 0.07 …
We present the results of our ALMA observations of eleven (ultra)luminous infrared galaxies ((U)LIRGs) at J=4-3 of HCN, HCO+, HNC and J=3-2 of HNC. This is an extension of our previously published HCN and HCO+ J=3-2 observations to multiple rotational J-transitions of multiple molecules, to investigate how molecular emission line flux ratios vary at different J-transitions. We confirm that ULIRGs that contain or may contain luminous obscured AGNs tend to show higher HCN-to-HCO+ flux ratios than starburst galaxies, both at J=4-3 and J=3-2. For selected HCN-flux-enhanced AGN-important ULIRGs, ou…
We present the results of high spatial resolution HCO$^{+}$($1-0$) and HCN($1-0$) observations of N55 south region (N55-S) in the Large Magellanic Cloud (LMC), obtained with the Atacama Large Millimeter/submillimeter Array (ALMA). N55-S is a relatively less extreme star-forming region of the LMC characterized by a low radiation field. We carried out a detailed analysis of the molecular emission to investigate the relation between dense molecular clumps and star formation in the quiescent environment of N55-S. We detect ten molecular clumps with significant HCO$^{+}(1-0)$ emission and eight wit…
We report ALMA Band 7 (350 GHz) imaging at 0.4 - 0.6arcsec resolution and Band 9 (696 GHz) at ~0.25arcsec resolution of the luminous IR galaxies Arp 220 and NGC 6240. The long wavelength dust continuum is used to estimate ISM masses for Arp 220 East, West and NGC 6240 of 1.9, 4.2 and 1.6x10^9 msun within radii of 69, 65 and 190 pc. The HCN emission was modeled to derive the emissivity distribution as a function of radius and the kinematics of each nuclear disk, yielding dynamical masses consistent with the masses and sizes derived from the dust emission. In Arp 220, the major dust and gas conc…
We present the results of ALMA $\sim$2 mm, $\lesssim$1$''$-resolution observations of ten (ultra)luminous infrared galaxies ([U]LIRGs; infrared luminosity $\gtrsim$ 10$^{11.7}$L$_{\odot}$) at $z <$ 0.15, targeting dense ($>$10$^{4}$ cm$^{-3}$) molecular (HCN, HCO$^{+}$, and HNC J=2-1) and 183 GHz H$_{2}$O 3$_{1,3}$-2$_{2,0}$ emission lines. Higher HCN to HCO$^{+}$ J=2-1 flux ratios are observed in some, but not all, AGN-important ULIRGs than in starburst-classified sources. We detect 183 GHz H$_{2}$O emission in almost all AGN-important ULIRGs, and elevated H$_{2}$O emission is found in two so…
We use new HCN(1-0) data from the ALMOND (ACA Large-sample Mapping Of Nearby galaxies in Dense gas) survey to trace the kpc-scale molecular gas density structure and CO(2-1) data from PHANGS-ALMA to trace the bulk molecular gas across 25 nearby, star-forming galaxies. At 2.1 kpc scale, we measure the density-sensitive HCN/CO line ratio and the SFR/HCN ratio to trace the star formation efficiency in the denser molecular medium. At 150 pc scale, we measure structural and dynamical properties of the molecular gas via CO(2-1) line emission, which is linked to the lower resolution data using an int…
ALMA observations towards M83 reveal N2H+ tracing dense gas
National Astronomical Observatory of Japan（日本国立天文台）；Graduate Institute for Advanced Studies, SOKENDAI（日本综合研究大学院大学）；Faculty of Pure and Applied Sciences, University of Tsukuba（筑波大学理工学群）；Institute of Astronomy, The University of Tokyo（东京大学天体物理研究所）；Faculty of Global Interdisciplinary Science and Innovation, Shizuoka University（静冈大学全球跨学科科学与创新学部）；Observatorio Astronómico Nacional (IGN)（国家天文台（西班牙国家地理研究所））；Stony Brook University（石溪大学）；The Institute for Advanced Study, Kyushu University（九州大学高等研究院）；Department of Earth and Planetary Sciences, Faculty of Science, Kyushu University（九州大学理学部地球惑星科学科）
We present the results of our ALMA HCN J=3-2 and HCO+ J=3-2 line observations of a uniformly selected sample (>25) of nearby ultraluminous infrared galaxies (ULIRGs) at z < 0.15. The emission of these dense molecular gas tracers and continuum are spatially resolved in the majority of observed ULIRGs for the first time with achieved synthesized beam sizes of ~0.2 arcsec or ~500 pc. In most ULIRGs, the HCN-to-HCO+ J=3-2 flux ratios in the nuclear regions within the beam size are systematically higher than those in the spatially extended regions. The elevated nuclear HCN J=3-2 emission could be r…
ALMA 0.5 kpc Resolution Spatially Resolved Investigations of Nuclear Dense Molecular Gas Properties in Nearby Ultraluminous Infrared Galaxies Based on HCN and HCO$^{+}$ Three Transition Line Data
We present 1" (<100 pc) resolution maps of millimeter emission from five molecules-CN, HCN, HCO+, CH3OH, and HNCO-obtained towards NGC 4038, which is the northern galaxy of the mid-stage merger, Antennae galaxies, with the Atacama Large Millimeter/submillimeter Array. Three molecules (CN, CH3OH, and HNCO) were detected for the first time in the nuclear region of NGC 4038. High-resolution mapping reveals a systematic difference in distributions of different molecular species and continuum emission. Active star forming regions identified by the 3 mm and 850 um continuum emission are offset from …
We report ~2" resolution Atacama Large Millimeter/submillimeter Array observations of the HCN(1-0), HCO+(1-0), CO(1-0), CO(2-1), and CO(3-2) lines towards the nearby merging double-nucleus galaxy NGC 3256. We find that the high density gas outflow traced in HCN(1-0) and HCO+(1-0) emission is co-located with the diffuse molecular outflow emanating from the southern nucleus, where a low-luminosity active galactic nucleus (AGN) is believed to be the dominant source of the far-infrared luminosity. On the other hand, the same lines were undetected in the outflow region associated with the northern …
UV photochemistry in the surface layers of protoplanetary disks dramatically alters their composition relative to previous stages of star formation. The abundance ratio CN/HCN has long been proposed to trace the UV field in various astrophysical objects, however to date the relationship between CN, HCN, and the UV field in disks remains ambiguous. As part of the ALMA Large Program MAPS (Molecules with ALMA at Planet-forming Scales), we present observations of CN N=1-0 transitions at 0.3'' resolution towards five disk systems. All disks show bright CN emission within $\sim$50-150 au, along with…
CH$_3$OH and HCN in Interstellar Comet 3I/ATLAS Mapped with the ALMA Atacama Compact Array: Distinct Outgassing Behaviors and a Remarkably High CH$_3$OH/HCN Production Rate Ratio
NASA Goddard Space Flight Center（美国宇航局戈达德太空飞行中心）；American University（美国大学）；The Catholic University of America（美利坚天主教大学）；LIRA, Observatoire de Paris, Université PSL, CNRS, Sorbonne Université, Université Paris Cité（巴黎天文台，PSL大学，法国国家科学研究中心，索邦大学，巴黎西岱大学）
We present an estimate of the mass of the supermassive black hole (SMBH) in the nearby type-1 Seyfert galaxy \object{NGC 1097} using Atacamma Large Millimeter/Submillimeter Array (ALMA) observations of dense gas kinematics. Dense molecular gas dynamics are traced with ${\rm HCN} (J=1-0)$ and ${\rm HCO^{+}} (J=1-0)$ emission lines. Assuming a host galaxy inclination of $46^{\circ}$, we derive a SMBH mass, $M_{\rm BH}=1.40^{+0.27}_{-0.32} \times 10^{8}M_{\odot}$, and an I-band mass to light ratio to be $5.14^{+0.03}_{-0.04}$, using ${\rm HCN} (J=1-0)$. The estimated parameters are consistent bet…
We present the results of our ALMA Cycle 4 high-spatial-resolution (0.04-0.07") observations, at HCN J=3-2 and HCO+ J=3-2 lines, of the nucleus of NGC 1068, the nearby prototypical type 2 active galactic nucleus (AGN). Our previous ALMA observations identified the compact emission of these lines at the putative location of the torus around a mass-accreting supermassive black hole. We now report that we have detected the rotation of this compact emission, with the eastern and western sides being redshifted and blueshifted, respectively. Unlike the previously reported CO J=6-5 emission, both the…
We present ALMA Cycle 1 observations of the central kpc region of the luminous type-1 Seyfert galaxy NGC 7469 with unprecedented high resolution (0.5$"$ $\times$ 0.4$"$ = 165 pc $\times$ 132 pc) at submillimeter wavelengths. Utilizing the wide-bandwidth of ALMA, we simultaneously obtained HCN(4-3), HCO$^+$(4-3), CS(7-6), and partially CO(3-2) line maps, as well as the 860 $μ$m continuum. The region consists of the central $\sim$ 1$"$ component and the surrounding starburst ring with a radius of $\sim$ 1.5$"$-2.5$"$. Several structures connect these components. Except for CO(3-2), these dense g…
Observations of the isolated globule B335 with ALMA have yielded absorption features against the continuum that are redshifted from the systemic velocity in both HCN and HCO$^+$ lines. These features provide unambiguous evidence for infall toward a central luminosity source. Previously developed models of inside-out collapse can match the observed line profiles of HCN and HCO$^+$ averaged over the central 50 AU. At the new distance of 100 pc, the inferred infall radius is 0.012 pc, the mass infall rate is $3 \times 10^{-6}$ solar masses per year, the age is 50,000 years, and the accumulated ma…
PRUSSIC III -- ALMA and NOEMA survey of dense gas in high-redshift star-forming galaxies
Leiden University（莱顿大学）；Delft University of Technology（代尔夫特理工大学）；SRON - Netherlands Institute for Space Research（荷兰空间研究所）；Universität zu Köln（科隆大学）；European Southern Observatory (ESO)（欧洲南方天文台）；Cosmic Dawn Center (DAWN)（宇宙黎明中心）；Technical University of Denmark（丹麦技术大学）；University College London（伦敦大学学院）
The nearby Sy 1 galaxy NGC 1097 represents an ideal laboratory to explore the molecular chemistry in the presence and surroundings of an active galactic nucleus. Exploring the distribution of different molecular species allows us to understand the physical processes affecting the ISM both in the AGN vicinity as well as in the outer star forming molecular ring. We carried out 3 mm ALMA observations of HCN, HCO+, CCH, CS, HNCO, SiO, HC3N, and SO as well as the 13C isotopologues. All species were imaged over the central 2 kpc (~30") of the galaxy at a resolution of ~2.2"x1.5 (150 pc x 100 pc). HC…
We present the results of our ALMA Cycle 2 high angular resolution (0.1-0.2 arcsec) observations of the nuclear region of the nearby well-studied type-2 active galactic nucleus (AGN), NGC 1068, at HCN J=3-2 and HCO+ J=3-2 emission lines. For the first time, due to a higher angular resolution than previous studies, we clearly detected dense molecular gas emission at the putative AGN location, identified as a ~1.1 mm (~266 GHz) continuum emission peak, by separating this emission from brighter emission located at 0.5-2.0 arcsec on the eastern and western sides of the AGN. The estimated intrinsic…
Molecular Abundance of the Circumnuclear Region Surrounding an Active Galactic Nucleus in NGC 1068 based on Imaging Line Survey in the 3-mm Band with ALMA
We report ALMA observations of molecular gas and continuum emission in the 90 and 350 GHz bands toward a nearby Seyfert galaxy NGC 613. Radio continuum emissions were detected at 95 and 350 GHz from both the circum-nuclear disk (CND) ($r\leq90$ pc) and a star-forming ring (250 pc $\leq r\leq 340$ pc), and the 95 GHz continuum was observed to extend from the center at a position angle of $20^{\circ} \pm 8^{\circ}$. The archival 4.9 GHz data and our 95 GHz data show spectral indices of $α\leq -0.6$ and $-0.2$ along the jets and in the star-forming ring; these can be produced by synchrotron emiss…
We present high angular resolution observations of the HCN(1-0) emission (at ~1" or ~34 pc), together with CO J = 1-0, 2-1, and 3-2 observations, toward the Seyfert 2 nucleus of M51 (NGC 5194). The overall HCN(1-0) distribution and kinematics are very similar to that of the CO lines, which have been indicated as the jet-entrained molecular gas in our past observations. In addition, high HCN(1-0)/CO(1-0) brightness temperature ratio of about unity is observed along the jets, similar to that observed at the shocked molecular gas in our Galaxy. These results strongly indicate that both diffuse an…
We report a study of X-ray-irradiated gas in the central ~100 pc of the Circinus galaxy, hosting a Compton-thick active galactic nucleus (AGN), at 10-pc resolution using Chandra and ALMA. Based on ~200 ksec Chandra/ACIS-S data, we created an image of the Fe Kalpha line at 6.4 keV, tracing X-ray-irradiated dense gas. The ALMA data in Bands 6 (~270 GHz) and 7 (~350 GHz) cover five molecular lines: CO(J=3--2), HCN(J=3--2), HCN(J=4--3), HCO^+(J=3--2), and HCO^+(J=4--3). The detailed spatial distribution of dense molecular gas was revealed, and compared to the iron line image. The molecular gas emi…
Centaurus A, with its gas-rich elliptical host galaxy, NGC 5128, is the nearest radio galaxy at a distance of 3.8 Mpc. Its proximity allows us to study the interaction between an active galactic nucleus, radio jets, and molecular gas in great detail. We present ALMA observations of low J transitions of three CO isotopologues, HCN, HCO$^{+}$, HNC, CN, and CCH toward the inner projected 500 pc of NGC 5128. Our observations resolve physical sizes down to 40 pc. By observing multiple chemical probes, we determine the physical and chemical conditions of the nuclear interstellar medium of NGC 5128. …
We present spatially resolved ($\sim$50 pc) imaging of molecular gas species in the central kiloparsec of the nearby starburst galaxy NGC 253, based on observations taken with the Atacama Large Millimeter/submillimeter Array (ALMA). A total of 50 molecular lines are detected over a 13 GHz bandwidth imaged in the 3 mm band. Unambiguous identifications are assigned for 27 lines. Based on the measured high CO/C$^{17}$O isotopic line ratio ($\gtrsim$350), we show that $^{12}$CO(1-0) has moderate optical depths. A comparison of the HCN and HCO$^{+}$ with their $^{13}$C-substituted isotopologues sho…
We present ALMA observations of the inner 1' (1.2 kpc) of the Circinus galaxy, the nearest Seyfert. We target CO (1-0) in the region associated with a well-known multiphase outflow driven by the central active galactic nucleus (AGN). While the geometry of Circinus and its outflow make disentangling the latter difficult, we see indications of outflowing molecular gas at velocities consistent with the ionized outflow. We constrain the mass of the outflowing molecular gas to be 1.5e5 -5.1e6 solar masses, yielding a molecular outflow rate of 0.35-12.3 solar masses per year. The values within this …
We investigate the relationship between CN N = 1 - 0 and HCN J = 1 - 0 emission on scales from 30 pc to 400 pc using ALMA archival data, for which CN is often observed simultaneously with the CO J = 1 - 0 line. In a sample of 9 nearby galaxies ranging from ultra-luminous infrared galaxies to normal spiral galaxies, we measure a remarkably constant CN/HCN line intensity ratio of 0.86 $\pm$ 0.07 (standard deviation of 0.20). This relatively constant CN/HCN line ratio is rather unexpected, as models of photon dominated regions have suggested that HCN emission traces shielded regions with high col…
We aim to shed light on the physical properties and kinematics of the molecular material in the nucleus of one of the closest type 2 active galaxies. To this end, we obtained high angular resolution ALMA observations of the nucleus of the Circinus galaxy. The observations map the emission at 350GHz and 690GHz with spatial resolutions of ~3.8pc and ~2.2pc, respectively. The continuum emission traces cold ($T\lesssim100$K) dust in a circumnuclear disk with spiral arms on scales of 25pc, plus a marginally resolved nuclear emission peak. The latter is not extended in polar direction as claimed bas…
We present the ALMA detection of molecular outflowing gas in the central regions of NGC4945, one of the nearest starbursts and also one of the nearest hosts of an active galactic nucleus (AGN). We detect four outflow plumes in CO (3-2) at ~0.3" resolution that appear to correspond to molecular gas located near the edges of the known ionized outflow cone and its (unobserved) counterpart behind the disk. The fastest and brightest of these plumes has emission reaching observed line-of-sight projected velocities of over 450 km/s beyond systemic, equivalent to an estimated physical outflow velocity…
We study the relationship between dense gas and star formation in the Antennae galaxies by comparing ALMA observations of dense gas tracers (HCN, HCO$^+$, and HNC $\mathrm{J}=1-0$) to the total infrared luminosity ($\mathrm{L_{TIR}}$) calculated using data from the \textit{Herschel} Space Observatory and the \textit{Spitzer} Space Telescope. We compare the luminosities of our SFR and gas tracers using aperture photometry and employing two methods for defining apertures. We taper the ALMA dataset to match the resolution of our $\mathrm{L_{TIR}}$ maps and present new detections of dense gas emis…
We use archival ALMA observations of the HCN and CO $J=1-0$ transitions, in addition to the radio continuum at 93 GHz, to assess the relationship between dense gas, star formation, and gas dynamics in ten, nearby (U)LIRGs and late-type galaxy centers. We frame our results in the context of turbulent and gravoturbulent models of star formation to assess if the HCN/CO ratio tracks the gravitationally-bound, star-forming gas in molecular clouds ($f_\mathrm{grav}$) at sub-kpc scales in nearby galaxies. We confirm that the HCN/CO ratio is a tracer of gas above $n_\mathrm{SF}\approx10^{4.5}$ cm$^{-3…
We use both new and archival ALMA data of three energy lines each of CN and HCN to explore intensity ratios in dense gas in NGC 3256, NGC 7469, and IRAS 13120-5453. The HCN (3-2)/HCN (1-0) intensity ratio varies in NGC 3256 and NGC 7469, with superlinear trends of 1.53$\pm$0.07 and 1.55$\pm$0.05, respectively. We find an offset to higher HCN (3-2)/HCN (1-0) intensity ratios (~0.8) in IRAS 13120-5453 compared to NGC 3256 (~0.3-0.4) and NGC 7469 (~0.3-0.5). The HCN (4-3)/HCN (3-2) intensity ratio in NGC 7469 has a slope of 1.34$\pm$0.05. We attribute the variation within NGC 3256 to excitation a…
We present new ALMA Band 7 ($\sim340$ GHz) observations of the dense gas tracers HCN, HCO$^+$, and CS in the local, single-nucleus, ultraluminous infrared galaxy IRAS 13120-5453. We find centrally enhanced HCN (4-3) emission, relative to HCO$^+$ (4-3), but do not find evidence for radiative pumping of HCN. Considering the size of the starburst (0.5 kpc) and the estimated supernovae rate of $\sim1.2$ yr$^{-1}$, the high HCN/HCO$^+$ ratio can be explained by an enhanced HCN abundance as a result of mechanical heating by the supernovae, though the active galactic nucleus and winds may also contri…
We analyze HCN and HNC emission in the nearby starburst galaxy NGC 253 to investigate its effectiveness in tracing heating processes associated with star formation. This study uses multiple HCN and HNC rotational transitions observed using ALMA via the ALCHEMI Large Program. To understand the conditions and associated heating mechanisms within NGC 253's dense gas, we employ Bayesian nested sampling techniques applied to chemical and radiative transfer models which are constrained using our HCN and HNC measurements. We find that the volume density $n_{\text{H}_{2}}$ and cosmic ray ionization ra…
A large effort has been made to detect warm gas in the planet formation zone of circumstellar discs using space and ground-based near infrared facilities. GV Tau N, the most obscured component of the GV Tau system, is an outstanding source, being one of the first targets detected in HCN and the only one detected in CH$_4$ so far. Although near infrared observations have shed light on its chemical content, the physical structure and kinematics of the circumstellar matter remained unknown. We use interferometric images of the HCN 3-2 and $^{13}$CO 3-2 lines, and far-IR observations of $^{13}$CO,…
M-stars are the most common hosts of planetary systems in the Galaxy. Protoplanetary disks around M-stars thus offer a prime opportunity to study the chemistry of planet-forming environments. We present an ALMA survey of molecular line emission toward a sample of five protoplanetary disks around M4-M5 stars (FP Tau, J0432+1827, J1100-7619, J1545-3417, and Sz 69). These observations can resolve chemical structures down to tens of AU. Molecular lines of $^{12}$CO, $^{13}$CO, C$^{18}$O, C$_2$H, and HCN are detected toward all five disks. Lines of H$_2$CO and DCN are detected toward 2/5 and 1/5 di…
We have complemented existing observations of HI absorption with new observations of HCO$^+$, C$_2$H, HCN, and HNC absorption from the Atacama Large Millimeter/submillimeter Array (ALMA) and the Northern Extended Millimeter Array (NOEMA) in the direction of 20 background radio continuum sources with $4^\circ \leq |b| \leq 81^\circ$ to constrain the atomic gas conditions that are suitable for the formation of diffuse molecular gas. We find that these molecular species form along sightlines where $A_V \gtrsim 0.25$, consistent with the threshold for the HI-to-H$_2$ transition at solar metallicit…
