Quantum many-body systems out of equilibrium can host intriguing phenomena such as transitions to exotic dynamical states. Although this emergent behaviour can be observed in experiments, its potential for technological applications is largely unexplored. Here, we investigate the impact of collective effects on quantum engines that extract mechanical work from a many-body system. Using an opto-mechanical cavity setup with an interacting atomic gas as a working fluid, we demonstrate theoretically that such engines produce work under periodic driving. The stationary cycle of the working fluid features nonequilibrium phase transitions, resulting in abrupt changes of the work output. Remarkably, we find that our many-body quantum engine operates even without periodic driving. This phenomenon occurs when its working fluid enters a phase that breaks continuous time-translation symmetry: the emergent time-crystalline phase can sustain the motion of a load generating mechanical work. Our findings pave the way for designing novel nonequilibrium quantum machines.
We consider quantum heat engines that operate between nonequilibrium stationary reservoirs. We evaluate their maximum efficiency from the positivity of the entropy production and show that it can be expressed in terms of an effective temperature that depends on the nature of the reservoirs. We further compute the efficiency at maximum power for different kinds of engineered reservoirs and derive a nonequilibrium generalization of the Clausius statement of the second law.
A pair of two-level systems initially prepared in different thermal states and coupled to an external reversible work source, do not in general reach a common temperature at the end of a unitary work extraction process. We define an effective temperature for the final nonequilibrium but passive state of the bipartite quantum system and analyse its properties.
We propose a machine learning approach based on artificial neural network to gain faster insights on the role of geometric contributions to the nonequilibrium fluctuations of an adiabatically temperature-driven quantum heat engine coupled to a cavity. Using the artificial neural network we have explored the interplay between bunched and antibunched photon exchange statistics for different engine parameters. We report that beyond a pivotal cavity temperature, the Fano factor oscillates between giant and low values as a function of phase difference between the driving protocols. We further obser…
We analyze the efficiency of thermal engines (either quantum or classical) working with a single heat reservoir like atmosphere. The engine first gets an energy intake, which can be done in arbitrary non-equilibrium way e.g. combustion of fuel. Then the engine performs the work and returns to the initial state. We distinguish two general classes of engines where the working body first equilibrates within itself and then performs the work (ergodic engine) or when it performs the work before equilibrating (non-ergodic engine). We show that in both cases the second law of thermodynamics limits th…
We show that finite system-reservoir coupling imposes a distinct quantum limit on the performance of a non-equilibrium quantum heat engine. Even in the absence of quantum friction along the isentropic strokes, finite system-reservoir coupling induces correlations that result in the generation of coherence between the energy eigenstates of the working system. This coherence acts to hamper the engine's power output, as well as the efficiency with which it can convert heat into useful work, and cannot be captured by a standard Born-Markov analysis of the system-reservoir interactions.
The thermodynamic properties of quantum heat engines are stochastic owing to the presence of thermal and quantum fluctuations. We here experimentally investigate the efficiency and nonequilibrium entropy production statistics of a spin-1/2 quantum Otto cycle. We first study the correlations between work and heat within a cycle by extracting their joint distribution for different driving times. We show that near perfect anticorrelation, corresponding to the tight-coupling condition, can be achieved. In this limit, the reconstructed efficiency distribution is peaked at the macroscopic efficiency…
We study the stochastic energetic exchanges in quantum heat engines. Due to microreversibility, these obey a fluctuation relation, called the heat engine fluctuation relation, which implies the Carnot bound: no machine can have an efficiency larger than Carnot's efficiency. The stochastic thermodynamics of a quantum heat engine (including the joint statistics of heat and work and the statistics of efficiency) is illustrated by means of an optimal two-qubit heat engine, where each qubit is coupled to a thermal bath and a two-qubit gate determines energy exchanges between the two qubits. We disc…
We develop the effective field theoretical (EFT) approach to time-translational symmetry breaking of nonequilibrium open systems based on the Schwinger-Keldysh formalism. In the Schwinger-Keldysh formalism, all the symmetries of the microscopic Lagrangian are doubled essentially because the dynamical fields are doubled to describe the time-evolution along the closed-time-path. The effective Lagrangian for open systems are then obtained by coarse-graining the microscopic Schwinger-Keldysh Lagrangian. As a consequence of coarse-graining procedure, there appear the noise and dissipation effects, …
The autonomous heat engine is a model system of autonomous nonequilibrium systems like biological cells, exploiting nonequilibrium flow for operations. As the Carnot engine has essentially contributed to the equilibrium thermodynamics, autonomous heat engine is expected to play a critical role in the challenge of constructing nonequilibrium thermodynamics. However, the high complexity of the engine involving an intricate coupling among heat, gas flow, and mechanics has prevented simple modeling. Here, we experimentally characterized the nonequilibrium dynamics and thermodynamics of a low-tempe…
Laser technology has developed and accelerated photo-induced nonequilibrium physics from both scientific and engineering viewpoints. The Floquet engineering, i.e., controlling material properties and functionalities by time-periodic drives, is a forefront of quantum physics of light-matter interaction, but limited to ideal dissipationless systems. For the Floquet engineering extended to a variety of materials, it is vital to understand the quantum states emerging in a balance of the periodic drive and energy dissipation. Here we derive the general description for nonequilibrium steady states (…
A property of dynamical correlation functions for nonequilibrium states is discussed. We consider arbitrary dimensional quantum spin systems with local interaction and translationally invariant states with nonvanishing current over them. A correlation function between local charge and local Hamiltonian at different spacetime points is shown to exhibit slow decay.
Reducing work fluctuation and dissipation in heat engines or, more generally, information heat engines that perform feedback control is vital to maximize their efficiency. The same problem arises when we attempt to maximize the efficiency of a given thermodynamic task that undergoes nonequilibrium processes for arbitrary initial and final states. We find that the most general trade-off relation between work fluctuation and dissipation applicable to arbitrary nonequilibrium processes is bounded from below by the information distance characterizing how far the system is from thermal equilibrium.…
We consider the non-equilibrium time evolution of a translationally invariant state under a Hamiltonian with a localized defect. We discern the situations where a light-cone spreads out from the defect and separates the system into regions with macroscopically different properties. We identify the light-cone and propose a procedure to obtain a (quasi-)stationary state describing the late time dynamics of local observables. As an explicit example, we study the time evolution generated by the Hamiltonian of the transverse-field Ising chain with a local defect that cuts the interaction between tw…
Nonequilibrium thermodynamics of populations of weakly-coupled low-temperature-differential Stirling engines with synchronous and asynchronous transitions
A Stirling engine made of a colloidal particle in contact with a nonequilibrium bath is considered and analyzed with the tools of stochastic energetics. We model the bath by non Gaussian persistent noise acting on the colloidal particle. Depending on the chosen definition of an isothermal transformation in this nonequilibrium setting, we find that either the energetics of the engine parallels that of its equilibrium counterpart or, in the simplest case, that it ends up being less efficient. Persistence, more than non Gaussian effects, are responsible for this result.
Controlling transitions between nonequilibrium states through active bath engineering
University of Strasbourg（斯特拉斯堡大学）；Institut de Sciences et d’Ingénierie Supramoléculaires, University of Strasbourg（斯特拉斯堡大学超分子科学与工程研究所）；Laboratoire de Physique de l’ENS de Lyon, CNRS, ENS de Lyon（里昂高等师范学院物理实验室，法国国家科学研究中心）；Institut de Physique et Chimie des Matériaux de Strasbourg（斯特拉斯堡材料物理与化学研究所）；City University of Hong Kong（香港城市大学）
Thermodynamic Features of a Heat Engine Coupled with Exponentially Decreasing Temperature Across the Reaction Coordinate, as well as Perspectives on Nonequilibrium Thermodynamics
We study how translationally invariant couplings of many-particle systems and nonequilibrium baths can be used to rectify particle currents, for which we consider minimal setups to realize bath-induced currents in nonequilibrium steady states of one-dimensional open fermionic systems. We first analyze dissipative dynamics associated with a nonreciprocal Lindblad operator and identify a class of Lindblad operators that are sufficient to acquire a unidirectional current. We show that unidirectional particle transport can in general occur when a Lindblad operator is reciprocal provided that the i…
We apply the concept of a frequency-dependent effective temperature based on the fluctuation-dissipation ratio to a driven Brownian particle in a nonequilibrium steady state. Using this system as a thermostat for a weakly coupled harmonic oscillator, the oscillator thermalizes according to a canonical distribution at the respective effective temperature across the entire frequency spectrum. By turning the oscillator from a passive "thermometer" into a heat engine, we realize the cyclic extraction of work from a single thermal reservoir, which is feasible only due to its nonequilibrium nature.
We propose a tensor-network algorithm for discrete-time stochastic dynamics of a homogeneous system in the thermodynamic limit. We map a $d$-dimensional nonequilibrium Markov process to a $(d+1)$-dimensional infinite tensor network by using a higher-order singular-value decomposition. As an application of the algorithm, we compute the nonequilibrium relaxation from a fully magnetized state to equilibrium of the one- and two- dimensional Ising models with periodic boundary conditions. Utilizing the translational invariance of the systems, we analyze the behavior in the thermodynamic limit direc…
We generalize the second law of thermodynamics in its maximum work formulation for a nonequilibrium initial distribution. It is found that in an isothermal process, the Boltzmann relative entropy (H-function) is not just a Lyapunov function but also tells us the maximum work that may be gained from a nonequilibrium initial state. The generalized second law also gives a fundamental relation between work and information. It is valid even for a small Hamiltonian system not in contact with a heat reservoir but with an effective temperature determined by the isentropic condition. Our relation can b…
The breaking of the continuous time-translation symmetry manifests, in Markovian open quantum systems, through the emergence of non-stationary dynamical phases. Systems that display nonequilibrium transitions into these phases are referred to as time-crystals, and they can be realized, for example, in many-body systems governed by collective dissipation and long-ranged interactions. Here, we provide a complete analytical characterization of a boundary time-crystal phase transition. This involves exact expressions for the order parameter and for the dynamics of quantum fluctuations, which, in t…
The impacts of quantum coherence on nonequilibrium thermodynamics become observable by dividing the heat and work into the conventional diagonal part and the other part relaying on the superpositions and the time derivative of Hamiltonian. Specializing to exactly-solvable dynamics of Larmor precession, we build a quantum Otto heat engine employing magnetic-driven atomic rotations. The coherence induced by the population transition guarantees the positive work output when the control protocol is time dependent. The time-dependent control of a quantum heat engine implements the correspondence be…
We study the effect of an applied magnetic field on the nonequilibrium transport properties of a general cubic quantum network described by a tight-binding Hamiltonian with specially designed couplings to the leads that preserve open-system symmetries. We demonstrate that the symmetry of open systems can be manipulated by the direction of the magnetic field. Starting with all the symmetries preserved in absence of a field, the anisotropic and isotropic fields systematically break the symmetries, influencing all nonequilibrium properties. For simple cubic systems, we are able to identify the st…
Although nonequilibrium work and fluctuation relations have been studied in detail within classical statistical physics, extending these results to open quantum systems has proven to be conceptually difficult. For systems that undergo decoherence but not dissipation, we argue that it is natural to define quantum work exactly as for isolated quantum systems, using the two-point measurement protocol. Complementing previous theoretical analysis using quantum channels, we show that the nonequilibrium work relation remains valid in this situation, and we test this assertion experimentally using a s…
We demonstrate that a gas of classical particles trapped in an external asymmetric potential undergoes a quasiperiodic motion, if the temperature of its initial velocity distribution $T_{ne}$ differs from the equilibrium temperature, $T_{eq}$. The magnitude of the effect is determined by the value of $T_{ne}-T_{eq}$, and the direction of the motion is determined by the sign of this expression. The "loading'' and "unloading'' of the gas particles change directions of their motion, thereby creating a possibility of shuttle-like motion. The system works as a Carnot engine where the heat flow betw…
Nonequilibrium steady states in an open system connecting two reservoirs of platelike colloidal particles are investigated by means of a recently proposed phenomenological dynamic density functional theory [M. Bier and R. van Roij, Phys. Rev. E 76, 021405 (2007)]. The platelike colloidal particles are approximated within the Zwanzig model of restricted orientations, which exhibits an isotropic-nematic bulk phase transition. Inhomogeneities of the local chemical potential generate a diffusion current which relaxes to a nonvanishing value if the two reservoirs coupled to the system sustain diffe…
A discrete time crystal is a phase unique to nonequilibrium systems, where discrete time translation symmetry is spontaneously broken. Most of conventional time crystals proposed so far rely on spontaneous breaking of on-site symmetries and their corresponding on-site symmetry operations. In this Letter, we propose a new time crystal dubbed "spatial-translation-induced discrete time crystal (STI-DTC)", which is realized by spatial translation and its symmetry breaking. Owing to the properties of spatial translation, in this new time crystal, various time crystal orders can emerge only by chang…
We show how a large family of interacting nonequilibrium phases of matter can arise from the presence of multiple time-translation symmetries, which occur by quasiperiodically driving an isolated quantum many-body system with two or more incommensurate frequencies. These phases are fundamentally different from those realizable in time-independent or periodically-driven (Floquet) settings. Focusing on high-frequency drives with smooth time-dependence, we rigorously establish general conditions for which these phases are stable in a parametrically long-lived `preheating' regime. We develop a for…
Optimal active engines obey the thermodynamic Lorentz force law
NSF-Simons National Institute for Theory and Mathematics in Biology（NSF-西蒙斯生物理论与数学国家研究所）；Department of Physics, University of California, Berkeley（加州大学伯克利分校物理系）；Redwood Center For Theoretical Neuroscience, University of California, Berkeley（加州大学伯克利分校红woods理论神经科学中心）；Department of Physics and Astronomy and the Center for Soft and Living Matter, University of Pennsylvania（宾夕法尼亚大学天体物理学与天文学系及软物质与生命物质中心）；Department of Neuroscience, University of California, Berkeley（加州大学伯克利分校神经科学系）
In this work we formulate the nonequilibrium dynamical renormalization group (ndRG). The ndRG represents a general renormalization-group scheme for the analytical description of the real-time dynamics of complex quantum many-body systems. In particular, the ndRG incorporates time as an additional scale which turns out to be important for the description of the long-time dynamics. It can be applied to both translational invariant and disordered systems. As a concrete application we study the real-time dynamics after a quench between two quantum critical points of different universality classes.…
We derive an efficiency bound for continuous quantum heat engines absorbing heat from squeezed thermal reservoirs. Our approach relies on a full-counting statistics description of nonequilibrium transport and it is not limited to the framework of irreversible thermodynamics. Our result, a generalized Carnot efficiency bound, is valid beyond the small squeezing and high temperature limit. Our findings are embodied in a prototype three-terminal quantum photoelectric engine where a qubit converts heat absorbed from a squeezed thermal reservoir into electrical power. We demonstrate that in the qua…
Describing open quantum systems far from equilibrium is challenging, in particular when the environment is mesoscopic, when it develops nonequilibrium features during the evolution, or when the memory effects cannot be disregarded. Here, we derive a master equation that explicitly accounts for system-bath correlations and includes, at a coarse-grained level, a dynamically evolving bath. Such a master equation applies to a wide variety of physical systems including those described by Random Matrix Theory or the Eigenstate Thermalization Hypothesis. We obtain a local detailed balance condition w…
We show that a weak periodic drive removes the accidental degeneracy in the ground state of the XY antiferromagnet on the triangular lattice in a uniform static magnetic field. The underlying mechanism involves adding a small periodically modulated component to the magnetic field, which influences finite-frequency modes to generate an effective potential for the accidental pseudo-Goldstone mode. This selection can be arranged to compete with the degeneracy lifting via the thermal order by disorder mechanism. This yields a non-equilibrium phase transition as the relative strength of the two mec…
We consider time-dependent Lifshitz-type solutions in type IIB supergravity. The solutions describe a time evolution from Lifshitz spacetimes to AdS spaces. We argue the holographic relation of them to aging phenomena in condensed matter physics. The solutions have no time-translation invariance and possess the dynamical scaling symmetry with z_c=2. In addition, the time evolution corresponds to slow (nonexponential) dynamics from nonequilibrium states to the equilibrium. We also discuss a mechanism of quantum quench to generate nonequilibrium states.
We study the nonequilibrium dynamics of a periodically-driven anisotropic Kondo impurity model. The periodic time dependence is introduced for a local magnetic field which couples to the impurity spin and also for an in-plane exchange interaction. We obtain the exact results on the time evolution for arbitrary periodic time dependence at the special point in the parameter space known as the Toulouse limit. We first consider a specific case where the local magnetic field is periodically switched on and off. When the driving period is much shorter than the inverse of the Kondo temperature, an in…
Nonequilibrium steady states (NESSs) in periodically driven dissipative quantum systems are vital in Floquet engineering. We develop a general theory for high-frequency drives with Lindblad-type dissipation to characterize and analyze NESSs based on the high-frequency (HF) expansion with linear algebraic numerics and without numerically solving the time evolution. This theory shows that NESSs can deviate from the Floquet-Gibbs state depending on the dissipation type. We show the validity and usefulness of the HF-expansion approach in concrete models for a diamond nitrogen-vacancy (NV) center, …
We demonstrate the role of interactions in driving the relaxation of an isolated integrable quantum system following a sudden quench. We consider a family of integrable hard-core lattice anyon models that continuously interpolates between noninteracting spinless fermions and strongly interacting hard-core bosons. A generalized Jordan-Wigner transformation maps the entire family to noninteracting fermions. We find that, aside from the singular free-fermion limit, the entire single-particle density matrix and therefore all one-body observables relax to the predictions of the generalized Gibbs en…
A Brownian information engine is a device extracting a mechanical work from a single heat bath by exploiting the information on the state of a Brownian particle immersed in the bath. As for engines, it is important to find the optimal operating condition that yields the maximum extracted work or power. The optimal condition for a Brownian information engine with a finite cycle time $τ$ has been rarely studied because of the difficulty in finding the nonequilibrium steady state. In this study, we introduce a model for the Brownian information engine and develop an analytic formalism for its ste…
Periodic driving is used to operate machines that go from standard macroscopic engines to small non-equilibrium micro-sized systems. Two classes of such systems are small heat engines driven by periodic temperature variations and molecular pumps driven by external stimuli. Well known results that are valid for nonequilibrium steady states of systems driven by fixed thermodynamic forces, instead of an external periodic driving, have been generalized to periodically driven heat engines only recently. These results include a general expression for entropy production in terms of currents and affin…
Odd materials feature antisymmetric response to perturbations. This anomalous property can stem from the nonequilibrium activity of their components, which is sustained by an external energy supply. These materials open the door to designing innovative engines which extract work by applying cyclic deformations, without any equivalent in equilibrium. Here, we reveal that the efficiency of such energy conversion, from local activity to macroscopic work, can be arbitrarily close to unity when the cycles of deformation are properly designed. We illustrate these principles in some canonical viscoel…
It is by now well established that periodically driven quantum many-body systems can realize topological nonequilibrium phases without any equilibrium counterpart. Here we show that, even in the absence of time translation symmetry, nonequilibrium topological phases of matter can exist in aperiodically driven systems for tunably parametrically long prethermal lifetimes. As a prerequisite, we first demonstrate the existence of longlived prethermal Anderson localization in two dimensions under random multipolar driving. We then show that the localization may be topologically nontrivial with a qu…
Within the rigorous axiomatic framework for the description of quantum mechanical systems with a large number of degrees of freedom, we show that the nonequilibrium steady state, constructed in the quasifree fermionic system corresponding to the isotropic XY chain in which a finite sample, coupled to two thermal reservoirs at different temperatures, is exposed to a local external magnetic field, is breaking translation invariance and exhibits a strictly positive entropy production rate. Moreover, we prove that there exists a second-order nonequilibrium quantum phase transition with respect to …
