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arXiv 1806.03056cond-mat.mtrl-sci
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混合p-n异质结MoS2/GaN(0001)中的界面偶极和能带弯曲

Interface Dipole and Band Bending in Hybrid p-n Heterojunction MoS2/GaN(0001)

Hugo Henck, Zeineb Ben Aziza, Olivia Zill, Debora Pierucci, Carl H. Naylor, Mathieu G. Silly, Noelle Gogneau, Fabrice Oehler, Stephane Collin, Julien Brault, Fa… 展开作者

Hugo Henck, Zeineb Ben Aziza, Olivia Zill, Debora Pierucci, Carl H. Naylor, Mathieu G. Silly, Noelle Gogneau, Fabrice Oehler, Stephane Collin, Julien Brault, Fausto Sirotti, François Bertran, Patrick Le Fèvre, Stéphane Berciaud, A. T Charlie Johnson, Emmanuel Lhuillier, Julien E. Rault, Abdelkarim Ouerghi

摘要:

基于块状GAN和二维(2D)材料的混合异质结构为具有工程特征的纳米电子器件提供了新的途径。在这里,我们研究了混合维异质结构的电子特性的本征n掺杂的二硫化钼薄片转移到p掺杂的GAN(0001)层。利用角分辨光电子能谱(ARPES)和高分辨X射线光电子能谱(HR-XPS)研究了MoS 2/GAN异质结构中层间相互作用引起的电子结构变化。特别是,观察到的价带相对于费米能级的位移的MoS 2/GAN异质结构,这是从二维单层的MoS 2到GAN的电荷转移的签名。ARPES和HR-XPS揭示了一个界面偶极子与局部电荷转移从GAN层的二硫化钼单层。MoS 2和GAN之间的价带和导带偏移被确定为分别为0.77和-0.51 eV。基于测得的功函数和能带弯曲,我们建立了GAN和MoS 2之间的0.2 eV的界面偶极子的形成。

英文摘要:

Hybrid heterostructures based on bulk GaN and two-dimensional (2D) materials offer novel paths toward nanoelectronic devices with engineered features. Here, we study the electronic properties of a mixed-dimensional heterostructure composed of intrinsic n-doped MoS2 flakes transferred on p-doped GaN(0001) layers. Based on angle-resolved photoemission spectroscopy (ARPES) and high resolution X-ray photoemission spectroscopy (HR-XPS), we investigate the electronic structure modification induced by the interlayer interactions in MoS2/GaN heterostructure. In particular, a shift of the valence band with respect to the Fermi level for MoS2/GaN heterostructure is observed; which is the signature of a charge transfer from the 2D monolayer MoS2 to GaN. ARPES and HR-XPS revealed an interface dipole associated with local charge transfer from the GaN layer to the MoS2 monolayer. Valence and conduction band offsets between MoS2 and GaN are determined to be 0.77 and -0.51 eV, respectively. Based on the measured work functions and band bendings, we establish the formation of an interface dipole between GaN and MoS2 of 0.2 eV.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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