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arXiv 1509.08615cond-mat.softcond-mat.dis-nncond-mat.mtrl-scicond-mat.stat-mech
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颗粒堆积中硬球玻璃化转变的结构起源

The structural origin of the hard-sphere glass transition in granular packing

Chengjie Xia, Jindong Li, Yixin Cao, Binquan Kou, Xinaghui Xiao, Kamel Fezzaa, Tiqiao Xiao, Yujie Wang

摘要:

玻璃化转变伴随着结构弛豫时间的快速增长和伴随的构型熵的降低。目前还不清楚的过渡是否有热力学起源,以及是否动态逮捕是与一定的静态秩序的增长。使用颗粒填料作为模型硬球玻璃,我们显示的玻璃化转变作为一个热力学相变与“隐藏”的多面体秩序。这种多四面体有序在空间上与缓慢的动力学相关。它是几何挫折,并有一个特殊的分形维数。此外,随着填充分数的增加,它的增长遵循熵驱动的成核过程,类似于随机一级跃迁理论。我们的研究基本上确定了一个长期追求的结构玻璃秩序硬球玻璃。

英文摘要:

Glass transition is accompanied by a rapid growth of the structural relaxation time and a concomitant decrease of configurational entropy. It remains unclear whether the transition has a thermodynamic origin, and whether the dynamic arrest is associated with the growth of a certain static order. Using granular packing as a model hard-sphere glass, we show the glass transition as a thermodynamic phase transition with a "hidden" polytetrahedral order. This polytetrahedral order is spatially correlated with the slow dynamics. It is geometrically frustrated and has a peculiar fractal dimension. Additionally, as the packing fraction increases, its growth follows an entropy-driven nucleation process, similar to that of the random first-order transition theory. Our study essentially identifies a long-sought-after structural glass order in hard-sphere glasses.

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