Mariusz Puchalski, Krzysztof Pachucki
Relativistic and QED corrections are calculated for the hyperfine splitting (hfs) in the $2S_{1/2}$ ground state of $^{9}$Be$^+$ ions with an exact account for electronic correlations. The achieved accuracy is sufficient to determine the finite nuclear size effects from the comparison to the experimental hfs value. The obtained results establish the ground to determine the neutron halo in $^{11}$Be.
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The one-loop self-energy correction to the hyperfine structure splitting of the 1s and 2s states of hydrogenlike ions is calculated both for the point and finite nucleus. The results of the calculation are combined with other corrections to find the ground state hyperfine splitting in lithiumlike ^{209}Bi^{80+} and ^{165}Ho^{64+}.
The ground state hyperfine splitting values and the transition probabilities between the hyperfine structure components of high Z lithiumlike ions are calculated in the range $Z=49-83$. The relativistic, nuclear, QED and interelectronic interaction corrections are taken into account. It is found that the Bohr-Weisskopf effect can be eliminated in a combination of the hyperfine splitting values of the hydrogenlike and lithiumlike ions of an isotope. This gives a possibility for testing the QED effects in a combination of the strong electric and magnetic fields of the heavy nucleus. Using the ex…
We perform accurate calculations of energy levels as well as fine and hyperfine splittings of the lowest $^{1,3}\!P_J$, $^{3}\!S_1$, $^{3}\!P^e_J$, and $^{1,3}\!D_J$ excited states of the $^9$Be atom using explicitly correlated Gaussian functions and report on the breakdown of the standard hyperfine structure theory. Because of the strong hyperfine mixing, which prevents the use of common hyperfine constants, we formulate a description of the fine and hyperfine structure that is valid for an arbitrary coupling strength and may have wide applications in many other atomic systems.
The rigorous calculation of the vacuum-polarization screening corrections to the hyperfine splitting in Li-like bismuth is presented. The two-electron diagrams with electric and magnetic vacuum-polarization loops are evaluated to all orders in alpha*Z, including the Wichmann-Kroll contributions. This improves the accuracy of the theoretical prediction for the specific difference of the hyperfine splitting values of H- and Li-like bismuth.
Relativistic corrections to the hyperfine splitting are calculated for the triplet $2^3S_1$ state of the helium isotope He$^3$. High precision variational wave functions are employed, where the electron-electron correlations are well accounted for. Due to the unknown nuclear structure a comparison with the experimental result is performed via He$^{3+}$ hyperfine splitting. Surprisingly, the second order contribution due to Fermi interaction, in spite of the additional small factor $m/M$, is very significant.
Accurate calculations of the fine and hyperfine splitting of the 2P state in Li and Be$^+$ isotopes using the explicitly correlated Hylleraas basis set are presented. Theoretical predictions including the mixing of $P_{1/2}$ and $P_{3/2}$ states, relativistic and quantum electrodynamics effects on hyperfine interactions, are compared with experimental values. It is concluded that precise spectroscopic determination of the nuclear magnetic moments requires elimination of nuclear structure effects by combining measurements for two different states.
The current status of the determination of corrections to the hyperfine splitting of the ground state in hydrogen is considered. Improved calculations are provided taking into account the most recent value for the proton charge radius. Comparing experimental data with predictions for the hyperfine splitting, the Zemach radius of the proton is deduced to be $1.045(16)$ fm. Employing exponential parametrizations for the electromagnetic form factors we determine the magnetic radius of the proton to be $0.778(29)$ fm. Both values are compared with the corresponding ones derived from the data obtai…
Recoil corrections to $μ$H hyperfine splitting
本文提出了μH超精细分裂的完整理论，直接计算QED和反冲修正，利用H超精细分裂得到质子结构修正，预测基态超精细分裂为182626(5) μeV。
The ground-state hyperfine splitting values of high-Z boronlike ions are calculated. Calculation of the interelectronic-interaction contribution is based on a combination of the 1/Z perturbation theory and the large-scale configuration-interaction Dirac-Fock-Sturm method. The screened QED corrections are evaluated utilizing an effective screening potential approach. Total hyperfine splitting energies are presented for several B-like ions of particular interest: {}^{45}Sc{}^{16+}, {}^{57}Fe{}^{21+}, {}^{207}Pb{}^{77+}, and {}^{209}Bi{}^{78+}. For lead and bismuth the experimental values of the …
The hyperfine splitting in hydrogenlike $^{209}$Bi, $^{203}$Tl, and $^{205}$Tl is calculated with the nuclear magnetization determined from experimental data on the hyperfine splitting in the corresponding muonic atoms. The single-particle and configuration-mixing nuclear models are considered. The QED corrections are taken into account for both electronic and muonic atoms. The obtained results are compared with other calculations and with experiment.
An angle-resolved x-ray spectroscopic scheme is presented for determining the hyperfine splitting of highly charged ions. For helium-like ions, in particular, we propose to measure either the angular distribution or polarization of the $1s2p~^{3}P_{1}, F \rightarrow 1s^{2}~^{1}S_{0}, F_{f}$ emission following the stimulated decay of the initial $1s2s~^{1}S_{0}, F_{i}$ level. It is found that both the angular and polarization characteristics of the emitted x-ray photons strongly depends on the (relative) \textit{splitting} of the partially overlapping hyperfine $1s2p~^{3}P_{1}, F$ resonances an…
The ground state hyperfine splitting values of high Z hydrogenlike ions are calculated. The relativistic, nuclear and QED corrections are taken into account. The nuclear magnetization distribution correction (the Bohr-Weisskopf effect) is evaluated within the single particle model with the g_{S}-factor chosen to yield the observed nuclear moment. An additional contribution caused by the nuclear spin-orbit interaction is included in the calculation of the Bohr-Weisskopf effect. It is found that the theoretical value of the wavelength of the transition between the hyperfine splitting components …
Using a technique based on production of ion Coulomb crystals, the isotope shifts of the 4s2 1S0 -> 4s5p 1P1 transition for all naturally occurring isotopes of calcium as well as the hyperfine splitting of the 4s5p 1P1 state in Ca-43 have been measured. The field shift and specific mass shift coefficients as well as the hyperfine structure constants for Ca-43 have been derived from the data.
We present a measurement of the hyperfine splitting of the 6S$_{1/2}$ excited level of rubidium using two photon absorption spectroscopy in a glass cell. The values we obtain for the magnetic dipole constant A are 239.18(03) MHz and 807.66(08) MHz for $^{85}$Rb and $^{87}$Rb, respectively. The combination of the magnetic moments of the two isotopes and our measurements show a hyperfine anomaly in this atomic excited state. The observed hyperfine anomaly difference has a value of $_{87}δ_{85}=-0.0036(2)$ due to the finite distribution of nuclear magnetization, the Bohr-Weisskopf effect.
The hyperfine structure of 5snd ^1D_2 states in ^{87}Sr was studied for principal quantum numbers 11 <= n <= 25 by Doppler-free two-photon excitation combined with thermionic detection. Based on the more accurate data, compared to previous results, the hyperfine structure was analysed by second order perturbation theory using MQDT wavefunctions. As a result we find that the surprisingly large B-factors obtained by fitting the data with the Casimir formula do not reflect a quadrupolar interaction but rather consist predominantly of second order magnetic dipole contributions. Further, inconsiste…
The screened QED corrections of the first orders in αand 1/Z to the g factor and the hyperfine splitting of lithiumlike ions are evaluated within ab initio quantum electrodynamical approach. The complete gauge-invariant set of the two-electron self-energy diagrams in the presence of the magnetic field and a dominant part of the two-electron vacuum-polarization diagrams are calculated. The most accurate values of the g factor of Li-like lead and uranium are presented. The theoretical prediction for the specific difference of the hyperfine splittings of H- and Li-like bismuth is improved.
The rigorous QED evaluation of the one- and two-photon exchange corrections to the ground-state hyperfine splitting in Li-like ions is presented for the wide range of nuclear charge number $Z= 7 - 82$. The calculations are carried out in the framework of the extended Furry picture, i.e., with inclusion of the effective local screening potential in the zeroth-order approximation. The interelectronic-interaction contributions of the third and higher orders are taken into account in the framework of the Breit approximation employing the recursive perturbation theory. In comparison to the previous…
Nuclear recoil correction to the hyperfine splitting in atomic systems
本文研究了轻原子系统超精细分裂的领先$O(m/M)$核反冲修正，引入核子电磁形状因子以处理超精细相互作用奇异性，给出了$O(Z\,α)$反冲修正公式，强调了真实描述核结构效应的重要性。
The influence of hyperfine interactions on the tune-out wavelengths of the $^{39,40,41}$K isotopes of the potassium atom was investigated. The hyperfine interaction of the $4s_{1/2}$ state result in a shift and splitting of the primary tune-out wavelength near 769 nm. The $4s_{1/2}$ ground state hyperfine splittings of the primary tune-out were almost equal to the hyperfine splittings of the ground states. The splittings in the wavelengths were 0.0008, 0.0027 and 0.0005 nm for $^{39}$K, $^{40}$K and $^{41}$K respectively. The hyperfine splitting of the $np_{J}$ levels leads to the creation of …
Regarding trapped-ion microwave-frequency standards, we report on the determination of hyperfine splittings and Landé $g_J$ factors of $^{111,113}$Cd$^+$. The hyperfine splittings of the $5p~^2P_{3/2}$ state of $^{111,113}$Cd$^+$ ions were measured using laser-induced fluorescence spectroscopy. The Cd$^+$ ions were confined in a linear Paul trap and sympathetically cooled by Ca$^+$ ions. Furthermore, the hyperfine splittings and Landé $g_J$ factors of the $5s~^2S_{1/2}$ and $5p~^2P_{1/2,3/2}$ levels of $^{111,113}$Cd$^+$ were calculated with greater accuracy using the multiconfiguration Dirac-…
Hyperfine structure splitting for the triplet $2^{3}S(L = 0)-$state in the two-muonic helium ${}^{3}$He $μ_{2}$ atom
本研究高精度计算了双μ子氦原子中三重态 $2^{3}S$ 态的超精细分裂，结果为 $5.1623403103010 \times 10^{7}$ MHz，不确定度仅 $\pm 10$ Hz，源于μ子壳层与核自旋相互作用。
We have systematically investigated the ground-state hyperfine structure for alkali-metal atoms ^{87}Rb, ^{133}Cs, ^{211}Fr and alkali-metal-like ions ^{135}Ba^+, ^{225}Ra^+, which are of particular interest for parity violation studies. The quantum electrodynamic one-loop radiative corrections have been rigorously evaluated within an extended Furry picture employing core-Hartree and Kohn-Sham atomic potentials. Moreover, the effect of the nuclear magnetization distribution on the hyperfine structure intervals has been studied in detail and its uncertainty has been estimated. Finally, the theo…
The 7 standard deviations between the proton rms charge radius from muonic hydrogen and the CODATA-10 value from hydrogen spectroscopy and electron-scattering has caused considerable discussions. Here, we review the theory of the 2S-2P Lamb shift and 2S hyperfine splitting in muonic hydrogen combining the published contributions and theoretical approaches. The prediction of these quantities is necessary for the determination of both proton charge and Zemach radii from the two 2S-2P transition frequencies measured in muonic hydrogen.
A two-step, two-color laser spectroscopy technique has been used to measure the hyperfine splittings of the $8p$ excited states in $^{203}$Tl and $^{205}$Tl, as well as the $7s - 8p$ transition isotope shifts. For the case of the $8p_{3/2}$ state, our results show a hyperfine anomaly consistent with our recent measurements of other hyperfine splittings, and in disagreement with older results for this state. Our measurement of the $8p_{1/2}$ isotope shift is also in disagreement with earlier work. In this series of experiments, a UV laser was locked to the first-step transition and directed thr…
The hyperfine splitting of the ground state of selected B-like ions within the range of nuclear charge numbers $Z=49-83$ is investigated in detail. The rigorous QED approach together with the large-scale configuration-interaction Dirac-Fock-Sturm method are employed for the evaluation of the interelectronic-interaction contributions of first and higher orders in $1/Z$. The screened QED corrections are evaluated to all orders in $αZ$ by using an effective potential. The influence of nuclear magnetization distribution is taken into account within the single-particle nuclear model.
Vacuum Polarization Effects in the Hyperfine Splitting of Hydrogen Like Ions
本文研究了类氢离子超精细结构中由真空极化引起的能级修正，分别计算了轻子型和强子型VP对波函数与磁势的影响，并探讨了不同核模型下结果的不确定性。
Relativistic nuclear recoil effects in hyperfine splitting of hydrogenic systems
本文计算了氢样体系超精细分裂中因有限核质量引起的修正，发现与Bodwin和Yennie的先前结果存在矛盾，并在氢中测量中发现2σ偏差，可能表明质子结构修正存在问题。
A high-precision numerical calculation is reported for the self-energy correction to the hyperfine splitting and to the bound-electron g factor in hydrogenlike ions with low nuclear charge numbers. The binding nuclear Coulomb field is treated to all orders, and the nonperturbative remainder beyond the known $Zα$-expansion coefficients is determined. For the $^3{\rm He}^+$ ion, the nonperturbative remainder yields a contribution of -450 Hz to the normalized difference of the 1S and 2S hyperfine-structure intervals, to be compared with the experimental uncertainty of 71 Hz and with the theoretic…
We measured the ground-state hyperfine splitting of trapped ${}^{113}$Cd${}^{+}$ ions to be 15199862855.02799(27) Hz with a fractional uncertainty of $1.8\times10^{-14}$. The ions were trapped and laser-cooled in a linear quadrupole Paul trap. The fractional frequency stability was measured to be ${4.2} \times 10^{-13}/\sqrtτ $, obtained from Ramsey fringes of high signal-to-noise ratio and taken over a measurement time of nearly 5 hours, which is close to the short-term stability limit estimated from the Dick effect. Our result is consistent with previous reported values, but the measurement …
Three-loop corrections to hyperfine splitting in muonium generated by the gauge invariant sets of diagrams with muon and tauon loop light-by-light scattering blocks are calculated. These results complete calculations of all light-by-light scattering contributions to hyperfine splitting in muonium.
Precise determination of ground-state hyperfine splitting and calculation of Zeeman coefficients for 171Yb+ microwave frequency standard
本文通过高分辨率双共振光谱学精确测量了171Yb+基态超精细分裂频率，并利用两种原子结构方法计算Zeeman系数，提高了二阶Zeeman频移修正的准确性，从而提升了微波频标的精度并支持基本常数约束的实验。
Nuclear structure corrections of orders $Zα\, E_F$ and $(Zα)^2 E_F$ are calculated for the hyperfine splitting of the muonic deuterium. The obtained results disagree with previous calculations and lead to a $5\,σ$ disagreement with the current experimental value of the $2S$ hyperfine splitting in $μ$D.
The muon and tauon light-by-light scattering contributions to hyperfine splitting in muonium are calculated. These results conclude calculation of all hard three-loop contributions to hyperfine splitting containing graphs with closed fermion loops. We discuss the special role that the lepton anomalous magnetic moments play in these calculations. The full result for all three-loop radiative-recoil corrections to hyperfine splitting generated by the graphs with closed lepton loops is presented.
The hyperfine structure splittings of the ground states of the $pdμ, ptμ$ and $dtμ$ ions are determined with the use of highly accurate expectation values of the interparticle delta-functions obtained in recent computations. The corresponding hyperfine structure splittings, e.g., $Δ_{12} =$ 1.3400149$\cdot 10^7$ $MHz$ and $Δ_{23} =$ 3.3518984$\cdot 10^7$ $MHz$ for the $ptμ$ ion, can directly be measured in modern experiments.
Muonium Hyperfine Splitting Uncertainty Revisited
本文重新审视反穆子基态超精细分裂理论预测的不确定性，并与最近的CODATA调整进行比较。
The hyperfine structure splittings are determined for all five bound $S(L = 0)-$states in the three symmetric muonic molecular ions: $ppμ, ddμ$ and $ttμ$. The expectation values of all interparticle delta-functions used in our calculations have been determined in recent highly accurate computations.
The interaction of orbital electrons with the charge and magnetic moment of the nucleus polarizes it, and the detailed description requires a careful treatment of the nuclear vector polarizability. We present a complete and closed form expression for the resulting contribution to hyperfine splitting in light atomic systems.
We calculate radiative corrections to the Lamb shift of order $α^3(Zα)^5m$ and radiative corrections to hyperfine splitting of order $α^3(Zα)E_F$ generated by the diagrams with insertions of radiative photons and electron polarization loops in the graphs with two external photons. We also obtain the radiative-recoil correction to hyperfine splitting in muonium generated by the diagrams with the $τ$ polarization loop.
We calculate radiative-recoil corrections of order $α^2(Zα)(m/M)E_F$ to hyperfine splitting in muonium generated by the diagrams with electron and muon polarization loops. These corrections are enhanced by the large logarithm of the electron-muon mass ratio. The leading logarithm cubed and logarithm squared contributions were obtained a long time ago. The single-logarithmic and nonlogarithmic contributions calculated here improve the theory of hyperfine splitting, and affect the value of the electron-muon mass ratio extracted from the experimental data on the muonium hyperfine splitting.
Higher-order QED corrections to the hyperfine splitting in $^3$He
本研究通过纳入直至 $α^3E_F$ 的全部 QED 效应计算 $^3$He 的 $2^3S$ 态超精细分裂，所得理论值与实验高度吻合，精度较此前提升40倍。
Sturmian basis set for the Dirac equation with finite nuclear size: Application to polarizability, Zeeman and hyperfine splitting, and vacuum polarization
本研究提出Sturmian基组在相对论原子结构计算中的简单实现方案，可计算类氢离子多种物理量，还能求解此前有限基组难以处理的全阶真空极化电荷密度，结果与已有计算吻合，且可推广至任意束缚势。
We consider three-loop radiative-recoil corrections to hyperfine splitting in muonium generated by the gauge invariant set of diagrams with virtual light-by-light scattering block. These corrections are enhanced by the large logarithms of the electron-muon mass ratio. We present the results of an analytic calculation of the single-logarithmic radiative-recoil corrections of order $α^2(Zα)(m/M)E_F$ to hyperfine splitting in muonium generated by these diagrams.
We present measurements of the hyperfine structure splittings of $nS_{1/2}$ Rydberg states of $^{85}$Rb for $n$= 43, 44, 45 and 46. From the splittings, the hyperfine coupling constant, $A_{\mathrm{HFS}}$, is determined to be 15.372(80) GHz. This result is an order-of-magnitude improvement from previous measurements. We study and account for systematic uncertainty sources, such as unwanted electric and magnetic fields, dipolar Rydberg-Rydberg interactions, and AC shifts. Initial evidence for hyperfine-mixed Rydberg pair states is found.
We present the most accurate up-to-date theoretical values of the {2p_{1/2}}-{2s} and {2p_{3/2}}-{2s} transition energies and the ground-state hyperfine splitting in ${\rm Sc}^{18+}$. All two- and three-electron contributions to the energy values up to the two-photon level are treated in the framework of bound-state QED without $\aZ$-expansion. The interelectronic interaction beyond the two-photon level is taken into account by means of the large-scale configuration-interaction Dirac-Fock-Sturm (CI-DFS) method. The relativistic recoil correction is calculated with many-electron wave functions …
The single photon annihilation contributions for the positronium ground state hyperfine splitting are calculated analytically to order $m_eα^6$ using NRQED. Based on intuitive physical arguments the same result can also be determined by a trivial calculation using results from existing literature. Our result completes the hyperfine splitting calculation to order $m_eα^6$. We compare the theoretical prediction with the most recent experimental measurement.
We have investigated the correction to the hyperfine structure of heavy multicharged ions, which is connected with the nuclear-polarization effect caused by the unpaired bound electron. Numerical calculations are performed for hydrogenlike ions taking into account the dominant collective nuclear excitations. The correction defines the ultimate limit of precision in accurate theoretical predictions of the hyperfine-structure splittings.
We consider three-loop radiative-recoil corrections to hyperfine splitting in muonium generated by diagrams with one-loop radiative photon insertions both in the electron and muon lines. An analytic result for these nonlogarithmic corrections of order $α(Z^2α)(Zα)(m/M)\widetilde E_F$ is obtained. This result constitutes a next step in the implementation of the program of reduction of the theoretical uncertainty of hyperfine splitting below 10 Hz.
Corrections of order $α^3(Zα)^5m$ to the Lamb shift and corrections of order $α^3(Zα)E_F$ to hyperfine splitting generated by the insertions of the three-loop one-particle reducible diagrams with radiative photons in the electron line are calculated. The calculations are performed in the Yennie gauge.
We consider three-loop corrections to hyperfine splitting in muonium generated by the gauge invariant set of diagrams with virtual light-by-light scattering block. These diagrams produce both recoil and nonrecoil contributions to hyperfine splitting. Recoil corrections are enhanced by large logarithms of the muon-electron mass ratio. Both nonrecoil and logarithmically enhanced radiative-recoil corrections where calculated some time ago. Here we calculate nonlogarithmic radiative-recoil corrections generated by the insertions of the light-by-light scattering block.
We calculate three-loop radiative-recoil corrections to hyperfine splitting in muonium generated by the diagrams with the first order electron and muon polarization loop insertions in graphs with two exchanged photons. These corrections are enhanced by the large logarithm of the electron-muon mass ratio. The leading logarithm squared contribution was obtained a long time ago. Here we calculate the single-logarithmic and nonlogarithmic contributions. We previously calculated the three-loop radiative-recoil corrections generated by two-loop polarization insertions in the exchanged photons. The c…
We consider three-loop radiative-recoil corrections to hyperfine splitting in muonium. These corrections are enhanced by the large logarithm of the electron-muon mass ratio. The leading logarithm cubed and logarithm squared contributions were obtained a long time ago. We calculate the single-logarithmic and nonlogarithmic contributions of order $α^3(m/M)E_F$ generated by gauge invariant sets of diagrams with one- and two-loop polarization insertions in diagrams with two exchanged photons and radiative photons, and by diagrams with one-loop radiative photon insertions both in the electron and m…
We present direct measurements of the hyperfine splitting of Rydberg states in rubidium 87 using Electromagnetically Induced Transparency (EIT) spectroscopy in a room-temperature vapour cell. With this method, and in spite of Doppler-broadening, line-widths of 3.7 MHz FWHM, i.e. significantly below the intermediate state natural linewidth are reached. This allows resolving hyperfine splittings for Rydberg s-states with n=20...24. With this method we are able to determine Rydberg state hyperfine splittings with an accuracy of approximately 100 kHz. Ultimately our method allows accuracies of ord…
The two-photon-annihilation contribution to the true muonium hyperfine splitting arising from $e$ and $τ$ loops is obtained analytically at order $m_μα^6$. The contribution to the hyperfine splitting is $-2.031092873 m_μα^6/n^3π^2=-793.926988/n^3$ MHz. The contribution to the triplet true muonium decay rate has also been obtained and was found to be $9.825708266 m_μα^6/n^3π^2=3840.737698/n^3$ MHz. Additional results have been computed for other purely leptonic bound states.
We present a precise determination of the polarizability and other proton structure dependent contributions to the hydrogen hyperfine splitting, based heavily on the most recent published data on proton spin dependent structure functions from the EG1 experiment at the Jefferson Laboratory. As a result, the total calculated hyperfine splitting now has a standard deviation slightly under 1 part-per-million, and is about 1 standard deviation away from the measured value. We also present results for muonic hydrogen hyperfine splitting, taking care to ensure the compatibility of the recoil and pola…
A rigorous evaluation of the two-photon exchange corrections to the hyperfine structure in lithiumlike heavy ions is presented. As a result, the theoretical accuracy of the specific difference between the hyperfine splitting values of H- and Li-like Bi ions is significantly improved. This opens a possibility for the stringent test of the many-electron QED effects on a few percent level in the strongest electromagnetic field presently available in experiments.
We calculate corrections of order $α^3(Zα)E_F$ to hyperfine splitting in muonium generated by the gauge invariant set of diagrams with polarization insertions in the light by light scattering diagrams. This nonrecoil contribution turns out to be -2.63 Hz. The total contribution of all known corrections of order $α^3(Zα)E_F$ is equal to -4.28 Hz.
We present the derivation of the formulas for the proton structure-dependent terms in the hyperfine splitting of muonic hydrogen. We use compatible conventions throughout the calculations to derive a consistent set of formulas that reconcile differences between our results and some specific terms in earlier work. Convention conversion corrections are explicitly presented, which reduce the calculated hyperfine splitting by about 46 ppm. We also note that using only modern fits to the proton elastic form factors gives a smaller than historical spread of Zemach radii and leads to a reduced uncert…
We have investigated $4s\;^2S_{1/2} \rightarrow 5p\;^2P_{1/2}$ transition ($D_1$ line) of the potassium isotopes $^{39}$K, $^{40}$K, and $^{41}$K using Doppler-free laser saturation spectroscopy. Our measurements reveal the hyperfine splitting of the $5p\;^2P_{1/2}$ state of $^{40}$K and we have determined the specific mass shift and the nuclear field shift constants for the blue $D_1$ line.
We consider hard three-loop nonlogarithmic corrections of order $mα^7$ to hyperfine splitting in positronium. All these contributions are generated by the graphs with photon and/or electron loop radiative insertions in the two-photon exchange diagrams. We calculate contributions of six gauge invariant sets of diagrams. The total result for all these diagrams is $ΔE=-1.2917(1)mα^7/π^3=-5.672$ kHz.
We present the leading-order prediction of baryon chiral perturbation theory for the proton polarizability contribution to the 2S hyperfine splitting in muonic hydrogen, and compare with the results of dispersive calculations.
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