This chapter reviews recent developments in the use of mixed-species ion chains in quantum information science, frequency metrology and spectroscopy. A growing number of experiments have demonstrated new methods in this area, opening up new possibilities for quantum state generation, quantum control of previously inaccessible ions, and the ability to maintain quantum control over extended periods. I describe these methods, providing details of the techniques which are required in order to work with such systems. In addition, I present perspectives on possible future uses of quantum logic spectroscopy techniques, which have the potential to extend precision control of atomic ions to a large range of atomic and molecular species.
Advanced techniques for manipulation of internal states, standard in atomic physics, are demonstrated for a charged molecular species for the first time. We address individual hyperfine states of ro-vibrational levels of a diatomic ion by optical excitation of individual hyperfine transitions, and achieve controlled transfer of population into a selected hyperfine state. We use molecular hydrogen ions (HD^{+}) as a model system and employ a novel frequency-comb-based, continuous-wave 5 \mum laser spectrometer. The achieved spectral resolution is the highest obtained so far in the optical domai…
We summarise important recent advances in quantum metrology, in connection to experiments in cold gases, trapped cold atoms and photons. First we review simple metrological setups, such as quantum metrology with spin squeezed states, with Greenberger-Horne-Zeilinger states, Dicke states and singlet states. We calculate the highest precision achievable in these schemes. Then, we present the fundamental notions of quantum metrology, such as shot-noise scaling, Heisenberg scaling, the quantum Fisher information and the Cramer-Rao bound. Using these, we demonstrate that entanglement is needed to s…
Information science is entering into a new era in which certain subtleties of quantum mechanics enables large enhancements in computational efficiency and communication security. Naturally, precise control of quantum systems required for the implementation of quantum information processing protocols implies potential breakthoughs in other sciences and technologies. We discuss recent developments in quantum control in optical systems and their applications in metrology and imaging.
We present an all optical technique to prepare a sample of $^{39}$K in a magnetically-insensitive state with 95\% purity while maintaining a temperature of 6 $μ$K. This versatile preparation scheme is particularly well suited to performing matter-wave interferometry with species exhibiting closely-separated hyperfine levels, such as the isotopes of lithium and potassium, and opens new possibilities for metrology with these atoms. We demonstrate the feasibility of such measurements by realizing an atomic gravimeter and a Ramsey-type spectrometer, both of which exhibit a state-of-the-art sensiti…
Quantum metrology is the science that aims to achieve precision measurements by making use of quantum principles. Attribute to the well-developed techniques of manipulating and detecting cold atoms, cold atomic systems provide an excellent platform for implementing precision quantum metrology. In this chapter, we review the general procedures of quantum metrology and some experimental progresses in quantum metrology with cold atoms. Firstly, we give the general framework of quantum metrology and the calculation of quantum Fisher information, which is the core of quantum parameter estimation. T…
Spin-exchange collisions in alkali vapors have been at the basis of several fundamental and applied investigations, like nuclear structure studies and tests of fundamental symmetries, ultra-sensitive atomic magnetometers, magnetic resonance and bio-magnetic imaging. Spin-exchange collisions cause loss of spin coherence, and concomittantly produce spin noise, both phenomena being central to quantum metrology. We here develop the quantum trajectory picture of spin-exchange collisions, consistent with their long-standing ensemble description using density matrices. We then use quantum trajectorie…
We use a small atomic Bose-Einstein condensate as an interferometric scanning probe to map out a microwave field near a chip surface with a few micrometers resolution. Using entanglement between the atoms we overcome the standard quantum limit of interferometry by 4 dB and maintain enhanced performance for interrogation times up to 20 ms. This demonstrates the usefulness of quantum metrology with entangled states when the particle number is limited due to the small probe size. Extending atom interferometry to micrometer spatial resolution enables new applications in electromagnetic field sensi…
Quantum metrology promises high-precision measurements of classical parameters with far reaching implications for science and technology. So far, research has concentrated almost exclusively on quantum-enhancements in integrable systems, such as precessing spins or harmonic oscillators prepared in non-classical states. Here we show that large benefits can be drawn from rendering integrable quantum sensors chaotic, both in terms of achievable sensitivity as well as robustness to noise, while avoiding the challenge of preparing and protecting large-scale entanglement. We apply the method to spin…
Quantum metrology overcomes standard precision limits and plays a central role in science and technology. Practically it is vulnerable to imperfections such as decoherence. Here, we demonstrate quantum metrology for noisy channels such that entanglement with ancillary qubits enhances the quantum Fisher information for phase estimation but not otherwise. Our photonic experiment covers a range of noise for various types of channels, including for two randomly alternating channels such that assisted entanglement fails for each noisy channel individually. We have simulated noisy channels by implem…
In quantum metrology, entanglement represents a valuable resource that can be used to overcome the Standard Quantum Limit (SQL) that bounds the precision of sensors that operate with independent particles. Measurements beyond the SQL are typically enabled by relatively simple entangled states (squeezed states with Gaussian probability distributions), where quantum noise is redistributed between different quadratures. However, due to both fundamental limitations and the finite measurement resolution achieved in practice, sensors based on squeezed states typically operate far from the true funda…
Estimation of physical parameters is a must in almost any part of science and technology. The enhancement of the performances in this task, e.g., beating the standard classical shot-noise limit, using available physical resources is a major goal in metrology. Quantum metrology in closed systems has indicated that entanglement in such systems may be a useful resource. However, it is not yet fully understood whether in open quantum systems such enhancements may still show up. Here, we consider a dissipative (open) quantum system of identical particles in which a parameter of the open dynamics it…
Metrology for Quantum Hardware Standardization -- Charting a Pathway: A Strategic Review
AIST, Global Research and Development Center for Business by Quantum-AI Technology (G-QuAT)（产业技术综合研究所，量子人工智能技术驱动业务全球研发中心）；National Metrology Institute of Japan (NMIJ)（日本国家计量院）
Estimation of parameters is a pivotal task throughout science and technology. Quantum Cramér-Rao bound provides a fundamental limit of precision allowed to achieve under quantum theory. For closed quantum systems, it has been shown how the estimation precision depends on the underlying dynamics. Here, we propose a general formulation for metrology scenarios in open quantum systems, aiming to relate the precision more directly to properties of the underlying dynamics. This feature may be employed to enhance an estimation precision, e.g., by quantum control techniques. Specifically, we derive a …
Near-optimal quantum metrology with few-qubit measurements
Institute for Advanced Study, Tsinghua University（清华大学高等研究院）；Institute for Quantum Information and Matter, California Institute of Technology（加州理工学院量子信息与物质研究所）；Oratomic（奥拉托米克公司）；Perimeter Institute for Theoretical Physics（理论物理珀蒂默研究所）；University of Waterloo（滑铁卢大学）
Quantum metrology has many important applications in science and technology, ranging from frequency spectroscopy to gravitational wave detection. Quantum mechanics imposes a fundamental limit on measurement precision, called the Heisenberg limit, which can be achieved for noiseless quantum systems, but is not achievable in general for systems subject to noise. Here we study how measurement precision can be enhanced through quantum error correction, a general method for protecting a quantum system from the damaging effects of noise. We find a necessary and sufficient condition for achieving the…
Quantum sensors are an established technology that has created new opportunities for precision sensing across the breadth of science. Using entanglement for quantum-enhancement will allow us to construct the next generation of sensors that can approach the fundamental limits of precision allowed by quantum physics. However, determining how state-of-the-art sensing platforms may be used to converge to these ultimate limits is an outstanding challenge. In this work we merge concepts from the field of quantum information processing with metrology, and successfully implement experimentally a *prog…
Sensing and imaging are among the most important applications of quantum information science. To investigate their fundamental limits and the possibility of quantum enhancements, researchers have for decades relied on the quantum Cramér-Rao lower error bounds pioneered by Helstrom. Recent work, however, has called into question the tightness of those bounds for highly nonclassical states in the non-asymptotic regime, and better methods are now needed to assess the attainable quantum limits in reality. Here we propose a new class of quantum bounds called quantum Weiss-Weinstein bounds, which in…
Quantum metrology provides a route to overcome practical limits in sensing devices. It holds particular relevance to biology, where sensitivity and resolution constraints restrict applications both in fundamental biophysics and in medicine. Here, we review quantum metrology from this biological context, focusing on optical techniques due to their particular relevance for biological imaging, sensing, and stimulation. Our understanding of quantum mechanics has already enabled important applications in biology, including positron emission tomography (PET) with entangled photons, magnetic resonanc…
Quantum error correction will be essential for realizing the full potential of large-scale quantum information processing devices. Fundamental to its experimental realization is the repetitive detection of errors via projective measurements of quantum correlations among qubits, and correction using conditional feedback. Performing these tasks repeatedly requires a system in which measurement and feedback decision times are short compared to qubit coherence times, where the measurement reproduces faithfully the desired projection, and for which the measurement process has no detrimental effect …
The estimation of parameters characterizing dynamical processes is central to science and technology. The estimation error changes with the number N of resources employed in the experiment (which could quantify, for instance, the number of probes or the probing energy). Typically, it scales as 1/N^(1/2). Quantum strategies may improve the precision, for noiseless processes, by an extra factor 1/N^(1/2). For noisy processes, it is not known in general if and when this improvement can be achieved. Here we propose a general framework for obtaining attainable and useful lower bounds for the ultima…
We show that, on the abstraction level of quantum circuit diagrams, quantum circuit algorithms belong to the species of interactive sequential algorithms that we studied in earlier work. This observation leads to a natural specification language for quantum circuit algorithms.
Sensing and metrology play an important role in fundamental science and applications, by fulfilling the ever-present need for more precise data sets, and by allowing to make more reliable conclusions on the validity of theoretical models. Sensors are ubiquitous, they are used in applications across a diverse range of fields including gravity imaging, geology, navigation, security, timekeeping, spectroscopy, chemistry, magnetometry, healthcare, and medicine. Current progress in quantum technologies inevitably triggers the exploration of quantum systems to be used as sensors with new and improve…
Recent developments in integrated photonics technology are opening the way to the fabrication of complex linear optical interferometers. The application of this platform is ubiquitous in quantum information science, from quantum simulation to quantum metrology, including the quest for quantum supremacy via the boson sampling problem. Within these contexts, the capability to learn efficiently the unitary operation of the implemented interferometers becomes a crucial requirement. In this letter we develop a reconstruction algorithm based on a genetic approach, which can be adopted as a tool to c…
It is known that more than 50 species use the Earth's magnetic field for orientation and navigation. Intensive studies particularly behavior experiments with birds, provide support for a chemical compass based on magnetically sensitive free radical reactions as a source of this sense. However, the fundamental question of how quantum coherence plays an essential role in such a chemical compass model of avian magnetoreception yet remains controversial. Here, we show that the essence of the chemical compass model can be understood in analogy to a quantum interferometer exploiting global quantum c…
Quantum entanglement is crucial for simulating and understanding exotic physics of strongly correlated many-body systems, such as high--temperature superconductors, or fractional quantum Hall states. The entanglement of non-identical particles exhibits richer physics of strong many-body correlations and offers more opportunities for quantum computation, especially with neutral atoms where in contrast to ions the interparticle interaction is widely tunable by Feshbach resonances. Moreover, the inter-species entanglement forms a basis for the properties of various compound systems, ranging from …
Precision control over hybrid physical systems at the quantum level is important for the realization of many quantum-based technologies. In the field of quantum information processing (QIP) and quantum networking, various proposals discuss the possibility of hybrid architectures where specific tasks are delegated to the most suitable subsystem. For example, in quantum networks, it may be advantageous to transfer information from a subsystem that has good memory properties to another subsystem that is more efficient at transporting information between nodes in the network. For trapped-ions, a h…
Retrieving the vast amount of information carried by a photon is an enduring challenge in quantum metrology science and quantum photonics research. The transverse spatial state of a photon is a convenient high-dimensional quantum system for study, as it has a well-understood classical analogue as the transverse complex field profile of an optical beam. One severe drawback of all currently available quantum metrology techniques is the need for a time-consuming characterization process, which scales very unfavorably with the dimensionality of the quantum system. Here we demonstrate a technique t…
Two level systems that can be reliably controlled and measured hold promise in both metrology and as qubits for quantum information science (QIS). When prepared in a superposition of two states and allowed to evolve freely, the state of the system precesses with a frequency proportional to the splitting between the states. In QIS,this precession forms the basis for universal control of the qubit,and in metrology the frequency of the precession provides a sensitive measurement of the splitting. However, on a timescale of the coherence time, $T_2$, the qubit loses its quantum information due to …
QuanEstimation.jl: An open-source Julia framework for quantum parameter estimation
Center for Theoretical Physics and School of Physics and Optoelectronic Engineering, Hainan University（海南大学理论物理中心与物理与光电工程学院）；School of Physics, Huazhong University of Science and Technology（华中科技大学物理学院）
Quantum metrology enables some of the most precise measurements. In the life sciences, diamond-based quantum sensing has enabled a new class of biophysical sensors and diagnostic devices that are being investigated as a platform for cancer screening and ultra-sensitive immunoassays. However, a broader application in the life sciences based on nanoscale nuclear magnetic resonance spectroscopy has been hampered by the need to interface highly sensitive quantum bit (qubit) sensors with their biological targets. Here, we demonstrate a new approach that combines quantum engineering with single-mole…
The NSF Workshop in Quantum Information and Computation for Chemistry assembled experts from directly quantum-oriented fields such as algorithms, chemistry, machine learning, optics, simulation, and metrology, as well as experts in related fields such as condensed matter physics, biochemistry, physical chemistry, inorganic and organic chemistry, and spectroscopy. The goal of the workshop was to summarize recent progress in research at the interface of quantum information science and chemistry as well as to discuss the promising research challenges and opportunities in the field. Furthermore, t…
