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arXiv 1302.2276cond-mat.mes-hallcond-mat.mtrl-sci
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单轴压力对Mn_{12} -Ac单分子磁体磁各向异性的影响

The effect of uniaxial pressure on the magnetic anisotropy of the Mn_{12}-Ac single-molecule magnet

J. H. Atkinson, K. Park, C. C. Beedle, D. N. Hendrickson, Y. Myasoedov, E. Zeldov, Jonathan R. Friedman

摘要:

研究了单轴压力对单分子磁体Mn_{12} -Ac磁滞回线的影响。我们发现,沿易磁化轴的压力的应用程序增加的领域,在量子隧穿磁化发生。这些观测结果归因于分子的磁各向异性常数D增加了0.142(1)%/kbar。D的增加产生磁化反转的有效能垒的小的但可测量的增加。密度泛函理论计算还预测势垒随施加的压力而增加。

英文摘要:

We study the effect of uniaxial pressure on the magnetic hysteresis loops of the single-molecule magnet Mn_{12}-Ac. We find that the application of pressure along the easy axis increases the fields at which quantum tunneling of magnetization occurs. The observations are attributed to an increase in the molecule's magnetic anisotropy constant D of 0.142(1)%/kbar. The increase in D produces a small, but measurable increase in the effective energy barrier for magnetization reversal. Density-functional theory calculations also predict an increase in the barrier with applied pressure.

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